Engineering Commons^™

Analysis And Structural Health Monitoring Of Composite Plates With Piezoelectric Sensors And Actuators, Richard C. Mewer

Electronic Theses and Dissertations

Structural vibration suppression and health-monitoring have been the focus of intense research over the past decade, and piezoelectric actuators and sensors are particularly well suited to serve in this application. The first part is an analytical investigation into the cylindrical bending vibrations of piezoelectric composite plates. The second part is a fully experimental investigation into various vibration based structural health-monitoring techniques for bolted composites. The analytical solution consists of Fourier basis functions that satisfy the equations of motion and charge equation. The accuracy of the mechanical displacements, electric potential, and stresses are dependent on the number of terms in the …

Effects Of Strand Geometry On Selected Properties Of Long-Stand Structural Composite Lumber Made From Northeastern Hardwoods, Russell Edgar

Electronic Theses and Dissertations

Structural composite lumber (SCL) products often possess significantly higher design values than the top grades of solid lumber, making it a popular choice for both residential and commercial applications. The enhanced mechanical properties of SCL are mainly due to defect randomization and densification of the wood fiber, both largely functions of the size, shape and composition (species) of the wood element. Traditionally, SCL manufacturers have used thin, rectangular elements produced from either moderate density softwoods or low density hardwoods. Higher density hardwood species have been avoided, as they require higher pressures to adequately densify and consolidate the wood furnish. These …

Theoretical Analysis For Obtaining Physical Properties Of Composite Electrodes, Parthasarathy M. Gomadam, John W. Weidner, Thomas A. Zawodzinski, Andrew P. Saab

Faculty Publications

A theoretical analysis is presented that allows in situ measurements of the physical properties of a composite electrode, namely, the electronic conductivity, the ionic conductivity, the exchange-current density, and the double-layer capacitance. Use is made of the current-voltage responses of the composite electrode to dc and ac polarizations under three different experimental configurations. This analysis allows the physical properties to be obtained even when the various resistances in the composite (e.g., ionic, electronic, and charge-transfer) are of comparable values.

A Mathematical Model Of Oxide/Carbon Composite Electrode For Supercapacitors, Hansung Kim, Branko N. Popov

Faculty Publications

A pseudo two-dimensional model is developed for the general application of supercapacitors consisting of an oxide/carbon composite electrode. The model takes into account the diffusion of protons in the oxide particle by employing the method of superposition. RuO₂/carbon system is modeled as a specific example. From the simulation data, it is found that the oxide particle size and proton diffusion coefficient have an enormous effect on the performance at high discharge rate due to the limitation of proton transport into RuO₂ particles. With increasing carbon ratio, the porosity of electrode increases, which causes the potential drop in …

Distributions Of Noble Metal Pd And Pt In Mesoporous Silica, J. Arbiol, A. Cabot, J. R. Morante, Fanglin Chen, Meilin Liu

Faculty Publications

Mesoporous silica nanostructures have been synthesized and loaded with Pd and Pt catalytic noble metals. It is found that Pd forms small nanoclusters (3–5 nm) on the surface of the mesoporous structure whereas Pt impregnation results in the inclusion of Pt nanostructures within the silica hexagonal pores (from nanoclusters to nanowires). It is observed that these materials have high catalytic properties for CO–CH4 combustion, even in a thick film form. In particular, results indicate that the Pt and Pd dispersed in mesoporous silica are catalytically active as a selective filter for gas sensors.

Study Of Sn-Coated Graphite As Anode Material For Secondary Lithium-Ion Batteries, Basker Veeraraghavan, Anand Durairajan, Bala Haran, Branko N. Popov, Ronald Guidotti

Faculty Publications

Tin-graphite composites have been developed as an alternate anode material for Li-ion batteries using an autocatalytic deposition technique. The specific discharge capacity, coulombic efficiency, rate capability behavior, and cycle life of Sn-C composites has been studied using a variety of electrochemical methods. The amount of tin loading and the heating temperature have a significant effect on the composite performance. The synthesis conditions and Sn loading on graphite have been optimized to obtain the maximum reversible capacity for the composite electrode. Heating the composite converts it from amorphous to crystalline form. Apart from higher capacity, Sn-graphite composites possesses higher coulombic efficiency, …

Synthesis And Characterization Of Hydrous Ruthenium Oxide-Carbon Supercapacitors, Manikandan Ramani, Bala S. Haran, Ralph E. White, Branko N. Popov

Faculty Publications

It is shown that composite Ru oxide-carbon based supercapacitors possess superior energy and power densities as compared to bare carbon. An electroless deposition process was used to synthesize the ruthenium oxide-carbon composites. Ru is dispersed on the carbon matrix as small particles. The effect of electrochemical oxidation and temperature treatment on the material performance has been studied extensively. Increasing the oxidation temperature reduces the proton transport rate and also increases the degree of crystallinity of the deposits. This adversely affects the performance of the composite. Loading a small amount of Ru oxide (9 wt %) on carbon increases the capacitance …

The Effects Of Patch Properties On The Debonding Behavior Of Patched Beam-Plates, Anette M. Karlsson

Mechanical Engineering Faculty Publications

The debonding characteristics of patched structures are investigated in this study by means of an analytical model. In particular, the effects the lay-up sequence and edge tapering of a carbon-reinforced epoxy patch, as well as the beveling of an aluminum patch, have on the initiation, stability, and extent of the debonding are considered. The results presented show that both the degree of edge-tapering and the patch properties must be carefully selected in order to optimize the patched structure. It is also shown that when designing a patched system, it is important to model the correct boundary and load conditions to …

Mechanics Of A Functionally-Graded Titanium Matrix Composite, G. Brandt Miller

Theses and Dissertations

Functionally-graded Titanium Matrix Composites, (F/G TMCs) combine the ideal properties of titanium matrix composites with the more practical machining qualities of monolithic (unreinforced) alloy. This material shows great promise in application to aerospace structural components - even in parts whose design requirements have defied the use of composite materials in the past. Successful implementation of such a material would lead to enhanced aircraft performance. However, the basic properties of a functionally-graded titanium matrix composite need to be investigated. The composite/alloy transition region, or joint area, may be less strong than its constituents and therefore determine the overall performance of the …

Evaluating The Durability Of Wood/Frp Bonds Through Chemical Kinetics Using A Range Of Mechanical Test Methods, Jonathan Philip Alexander

Electronic Theses and Dissertations

Hybrid composites of wood and fiber reinforced polymers (FRP) exhibit a flexibility of design properties through choices in fiber type, amount, orientation and resin type. With this flexibility comes the need to measure the durability of the composite material system, especially the bond between these two materials due to their markedly different responses to moisture. This study is two-fold; the first section examines methods for the mechanical testing and durability of wood/FRP laminations. Six mechanical tests were evaluated and a modified block shear method was identified as the most suitable due to its ability to provide representative results independent of …

Progressive Failure Analysis Of Composite Panels, Stephen M. Spottswood

Theses and Dissertations

The objective of this research was to determine the physical response, including material failure, of a curved composite panel designed to resist transverse loading. The cause of the material failure, in the form of delamination, fiber and/or matrix failure, was determined through various criterion based on non-linear movement using a finite element analysis technique. Data generated both with and without the addition of progressive failure criteria, was compared with previously published experimental data, noting where the theory diverges from the experimental results. The inclusion of various failure criterion, to include maximum stress, Lee, and Hashin, provided a more realistic representation …

Fatigue Response Of Repaired Thick Aluminum Panels With Bondline Flaws, David S. Conley

Theses and Dissertations

his research investigated the fatigue response of precracked 558 x 177.8 x 6.35 mm (22.0 x 7.0 x 0.25 in) 2024-T351 aluminum panels repaired with single-sided partially bonded, unidirectional, eighteen ply boron/epoxy reinforcements. Disbonds were introduced into the bondline of each repair during the adhesion process using teflon inserts. Five different disbond configurations, with varying disbond locations and sizes, were tested. Each repaired panel was subjected to constant amplitude cyclic fatigue loading with a maximum stress of 120MPa. Results from the different configurations were compared against one another and against repaired panels with no debonds to assess the effect of …

Chemical Kinetics And Heat Transfer In Polyurethane Foam And Resin Composites, Yumi Morisaki

Master's Theses - Daytona Beach

A development of the composite materials parts require knowledge of the theoretical model that describes the physics, the chemical kinetics, and the heat-transfer properties of the materials.

For this work, the chemical kinetics of the polyurethane foam and the fiberglass-reinforced resin is investigated individually. An adiabatic method, which is commonly used by many investigators, is used for the polyurethane foam, while an isothermal degree and the rate of cure relationship is applied for the resin. A heat transfer effect during the curing process of both polyurethane foam and the resin is also investigated. A common approximate method for the heat-conduction …

Nonlinear Geometric And Material Behavior Of Composite Shells With Large Strains, Scott A. Schimmels

Theses and Dissertations

A two-dimensional, geometrically and materially nonlinear shell theory applicable to arbitrary geometries described by orthogonal curvilinear coordinates and encompassing large displacements, moderate rotations for large strain situations has been developed. Additionally, the theory includes Jacobian transformation matrices, based upon displacement parameters, for the Cauchy - 2nd Piola-Kirchhoff stress-state and the Cauchy (Almansi) - Green strain-state transformations, and a layered material approach is included for the elastoplastic analysis to allow for variation of plasticity through-the-thickness. Doubly curved 20, 28, and 36 degree-of-freedom finite elements are defined based on specialization of the theory to spherical coordinates. The computer program includes algorithms for …

Investigation Into The Behavior Of Geometrically Nonlinear Composite Arches, John C. Bailey

Theses and Dissertations

This research modifies the existing finite element formulation of a potential energy based large deformation and moderate rotation theory. Hermitian shape functions replace the existing linear bending angle interpolations. Negligible differences between the two formulations indicate the underlying kinematics limit the accuracy, not the finite element interpolations. Using the new program, numerous nonlinear arch geometries are modeled to investigate the effects of arc length and thickness variations. Local and global snapping phenomena are captured as well as through the thickness shear driven nonlinearities.

An Experimental And Analytical Investigation Of The Iosipescu Shear Test For Composite Materials, Barry Stuart Spigel

Mechanical & Aerospace Engineering Theses & Dissertations

Mechanical properties of composite materials under shear loading are difficult to determine. The Iosipescu Shear test, originally proposed for metals, has in recent years been applied to composites. It has the advantages of small specimen size, simple loading and a reasonably uniform shear stress in the test section.

The purpose of this work is to study the validity of the Iosipescu test method for measuring the shear modulus and shear strength of composites. Finite element analyses indicate that optimum specimen geometry and load locations depend upon the degree of orthotropy of the composite. Test results for a quasi-isotropic graphite/epoxy laminate …

Morphological Composite Materials Formed From Different Precursors, Ravi F. Saraf

Department of Chemical and Biomolecular Engineering: Patents

A method of producing a multiphase polymer is disclosed whereby the phases have the same chemical structure but have different morphological states and thus different properties. This is achieved by forming a mixture of precursors of the polymer, at least one of the precursors having a reaction rate higher than the other precursor or precursors in the mixture. The precursor having the highest reaction rate is then converted to obtain a composite of a polymer and the precursors that are not polymerized. This mixture might also be formed by mixing a soluble polymer with its precursor. The polymer/precursor composite is …

Influence Of Embedded Optical Fibers On Compressive Strength Of Advanced Composites, Stefan B. Dosedel

Theses and Dissertations

This study investigated the effects of embedding optical fibers into advanced composite materials. This combination was meant to simulate 'smart structures' that have been shown to sense several different variables in the composite including strain, temperature, and damage. A laminate orientation taken from an existing aircraft structure was used to fabricate sixteen groups of specimens which were subjected to compression testing in an IITRI fixture to determine the ultimate compressive strength and modulus of elasticity. Ten of these groups were fabricated with optical fibers while the other six were control groups and contained no optical fibers. This study showed that …

The Effect Of Cutout Dimensionality On The Collapse Characteristics Of Cylindrical Composite Shells Of Varying Thickness, John C. Del Barga

Theses and Dissertations

This study involved a numerical and experimental investigation of the (geometric instability of graphite/epoxy cylindrical panels with free vertical edges undergoing axial compression. Symmetric quasi-isotropic laminates with five different size centralized cutouts, were investigated for two axial lengths of panels and three thicknesses. The study compared experimental data to results from SHELL, a geometrically nonlinear finite-element program which incorporates a parabolic transverse shear strain distribution through the thickness. The research verified that the SHELL program will provide good predictions of the collapse characteristics of a panel with large cutouts of varying dimensions undergoing large displacements and rotations. The best correlation …

Solving Nonlinear Composite Material Problems Using The Automated Structural Optimization System (Astros), Robert Bolha

Theses and Dissertations

Most advanced composite materials have nonlinear stress versus strain curves--grossly so in the laminas shear direction. If linear approximations are used, overly conservative design will result. This thesis expands the usefulness of the Automated Structural Optimization System (ASTROS) finite element (FE) program by incorporating a newly developed capability to include material nonlinearities. By dividing a FE problem into several intervals, and incorporating the changing nature of the nonlinear material properties within each element, a good approximation of the laminate's actual stresses and strains can be obtained without the undue experimentation involved in testing every individual configuration. Each material property is …

The Evaluation Of Polysulfone Composites As Structural Implants In Orthopaedic Surgery, Howard L. Scalzo

Theses

Two polysulfone composites were evaluated to determine their use as structural implants in orthopaedic surgery. The first composite, carbon fiber reinforced polysulfone (C/PS), was evaluated for environmental degradation in an in vivo and in vitro study. The C/PS composites were implanted subcutaneously in the abdomen of rabbits for the in vivo study and immersed in saline solution at 32° C for the in vitro study. The second composite, hydroxylapatite coated polysulfone (HA/PS), was evaluated for bone ingrowth in an in vivo study, and for attachment strength between the HA and the PS in an in vitro study. Also, two surface …

Transport Processes In Random Arrays Of Cylinders. I. Thermal Conduction, Ashok S. Sangani, C. Yao

Ashok S. Sangani

A numerical method is developed that takes into account the many particle interactions in a rigorous manner to determine the effective thermal conductivity of Km of a composite medium consisting of parallel circular cylinders of thermal conductivity ak suspended in a matrix of conductivity k. Numerical results for Km are presented for a wide rane of a and o, the area fraction of the cylinders, after averaging over several computer-generated random arrays of cylinders. The results obtained via this exact method are compared with those of various approximate analystical methods to assess their utility in predicting Km.

Transport Processes In Random Arrays Of Cylinders. I. Thermal Conduction, Ashok S. Sangani, C. Yao

Biomedical and Chemical Engineering - All Scholarship

A numerical method is developed that takes into account the many particle interactions in a rigorous manner to determine the effective thermal conductivity of Km of a composite medium consisting of parallel circular cylinders of thermal conductivity ak suspended in a matrix of conductivity k. Numerical results for Km are presented for a wide rane of a and o, the area fraction of the cylinders, after averaging over several computer-generated random arrays of cylinders. The results obtained via this exact method are compared with those of various approximate analystical methods to assess their utility in predicting Km.

Solution To Eigenvalue Problems Of Antisymmetric Cross-Ply And Antisymmetric Angle-Ply Laminated Plates Using Affine Transformations, Zaffir A. Chaudry

Theses and Dissertations

Using affine transformations and suitably recasting the buckling vibration differential equations, the eigenvalue problem of anti-symmetric cross-ply and antisymmetric angle-ply laminated rectangular plates has been reduced to a function of two strong material constants, the generalized rigidity ratio, whose range is in the closed interval from 0 to 1, and the ratio of principal lamina stiffness. With the reduction in number of constants an exhaustive parameter study of buckling and vibration solution trends, is possible. The buckling coefficients decrease with decreasing value of generalized rigidity ratio for both antisymmetric cross-ply and antisymmetric angle-ply laminates. For a given aspect ratio, and …

An Experimental And Analytical Investigation Of The Iosipescu Shear Test For Composite Materials, Barry Stuart Spigel

Mechanical & Aerospace Engineering Theses & Dissertations

Mechanical properties of composite materials under shear loading are difficult to determine. The Iosipescu Shear test, originally proposed for metals, has in recent years been applied to composites. It has the advantages of small specimen size, simple loading and a reasonably uniform shear stress in the test section.

The purpose of this work is to study the validity of the Iosipescu test method for measuring the shear modulus and shear strength of composites. Finite element analyses indicate that optimum specimen geometry and load locations depend upon the degree of orthotropy of the composite. Test results for a quasi-isotropic graphite/epoxy laminate …

Curing And Flow Of Thermosetting Resins For Composite Materials Pultrusion, Howard L. Price Jr.

Mechanical & Aerospace Engineering Theses & Dissertations

Fibrous composite materials for mechanical and structural applications often are expensive due to high labor costs. One economical way of making composites is pultrusion, a manufacturing process in which resin-impregnated fibers are pulled at a constant speed through a heated die which shapes the resin-fiber mass and cures the resin. Most of the work which has been done on the process has been of an empirical nature, with limited understanding of the process principles. Most of the experience with pultrusion has been gained with polyester resins and glass fibers. Very little experience has been gained with higher performance, more costly …

Analysis Of Moisture Absorption And Diffusion In Fiber Reinforced Polymeric Resin-Matrix Composite Materials, Stephen Stern Tompkins

Mechanical & Aerospace Engineering Theses & Dissertations

The diffusion of moisture through fiber reinforced polymeric-matrix composite materials has been studied analytically. The diffusion in the orthotropic, nonhomogeneous material was modeled, in detail, with a two-dimensional transient diffusion analysis. An effective diffusivity for the composite was determined in terms of the fiber volume fraction and the resin diffusivity. This effective diffusivity is in better agreement with recent data than those previously determined using less complex models.

The influence of both material and environmental parameters on the moisture content of the composite was determined analytically. Predicted moisture contents were compared over a wide range of values for emittance, solar …