Engineering Commons^™

New Effects Of Aging And Lattice Intercalation On Surface Properties Of Titanate Nanobelts, Roger Williams

Graduate Theses and Dissertations

Titanate nanobelts (NBs) have structural characteristics beyond that of clays. Due to a negatively charged lattice matrix of edge-shared TiO6-octahedra, the location of intercalated cations within the interlayer space may dictate the charge-conductions. This environment may in turn govern the lattice-framework's stability and surface properties, based upon our preliminary

data.

On that basis, these nanomaterials have been found in our lab to possess superb biological compatibility that is closely related to the types of the intercalated cations. In addition, a prolonged agitation was proven to enable us to manipulate the titanate NBs' length. In a parallel study, a ripening was …

Surveillance Planning Against Smart Insurgents In Complex Terrain, Nabil Lehlou

Graduate Theses and Dissertations

This study is concerned with finding a way to solve a surveillance system allocation problem based on the need to consider intelligent insurgency that takes place in a complex geographical environment. Although this effort can be generalized to other situations, it is particularly geared towards protecting military outposts in foreign lands. The technological assets that are assumed available include stare-devices, such as tower-cameras and aerostats, as well as manned and unmanned aerial systems. Since acquiring these assets depends on the ability to control and monitor them on the target terrain, their operations on the geo-location of interest ought to be …

Cad Tools For Synthesis Of Sleep Convention Logic, Parviz Palangpour

Graduate Theses and Dissertations

This dissertation proposes an automated flow for the Sleep Convention Logic (SCL) asynchronous design style. The proposed flow synthesizes synchronous RTL into an SCL netlist. The flow utilizes commercial design tools, while supplementing missing functionality using custom tools. A method for determining the performance bottleneck in an SCL design is proposed. A constraint-driven method to increase the performance of linear SCL pipelines is proposed. Several enhancements to SCL are proposed, including techniques to reduce the number of registers and total sleep capacitance in an SCL design.

Load Mixing To Improve Container Utilization, Crystal Wilson

Graduate Theses and Dissertations

The under utilization in trucking leads to nearly 5 billion gallons of wasted fuel annually. One way to recapture part of this waste is to use collaborative logistics. This research focuses on one specific aspect of collaborative logistics: load mixing. Load mixing is the idea of mixing two or more items of different weights in the same container to reduce the number of trucks needed.

Load mixing is similar to other packing problems such as the knapsack and container loading problems. However, traditional packing problems typically only assume a single type of capacity (e.g., weight), whereas load mixing must simultaneously …

Design And Implementation Of Wireless Point-Of-Care Health Monitoring Systems: Diagnosis For Sleep Disorders And Cardiovascular Diseases, Se Chang Oh

Graduate Theses and Dissertations

Chronic sleep disorders are present in 40 million people in the United States. More than 25 million people remain undiagnosed and untreated, which accounts for over $22 billion in unnecessary healthcare costs. In addition, another major chronic disease is the heart diseases which cause 23.8% of the deaths in the United States. Thus, there is a need for a low cost, reliable, and ubiquitous patient monitoring system. A remote point-of-care system can satisfy this need by providing real time monitoring of the patient's health condition at remote places. However, the currently available POC systems have some drawbacks; the fixed number …

Synthesis And Characterization Of Iron Pyrite Nanocrystals For Photovoltaic Devices, Scott Curtis Mangham

Graduate Theses and Dissertations

Iron pyrite nanocrystals have been synthesized using a hot-injection method with a variety of amines and characterized with properties necessary for photovoltaic devices. The iron pyrite nanocrystals were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, optical absorption, micro-Raman, and micro-Photoluminescence. The optical absorbance spectra showed the large absorption in the visible and near infrared spectral range for the nanocrystals as well as to show the band gap. The face-centered cubic crystal structure of the iron pyrite nanocrystals was shown by matching the measured X-ray diffraction pattern to a face-centered cubic iron pyrite reference pattern. Using Bragg's law …

Expression, Production, And Purification Of Novel Therapeutic Proteins, Mckinzie Shea Fruchtl

Graduate Theses and Dissertations

Interest in the production of recombinant proteins consisting of collagen binding domain (CBD) fused to a bioactive material has increased due to the targeting/attachment capabilities of CBD. For example, CBD fusions can be applied to the reversing of bone density loss and the repair of the eardrum, specifically, by choosing an appropriate fusion partner (parathyroid hormone or epidermal growth factor). The production of CBD fusions was examined using batch and fed-batch culturing of Escherichia coli to express the fusion proteins, and affinity chromatography to isolate the final product.

Different medium formulations, feeding strategies, and induction methods were tested in order …

Design, Layout, And Testing Of A Silicon Carbide-Based Under Voltage Lock-Out Circuit, Michael Dalan Glover

Graduate Theses and Dissertations

Silicon carbide-based power devices play an increasingly important role in modern power conversion systems. Finding a means to reduce the size and complexity of these systems by even incremental amounts can have a significant impact on cost and reliability. One approach to achieving this goal is the die-level integration of gate driver circuitry with the SiC power devices. Aside from cost reductions, there are significant advantages to the integration of the gate driver circuits with the power devices. By integrating the gate driver circuitry with the power devices, the parasitic inductances traditionally seen between the gate driver and the switching …

Synthesis Of Optimized Inp/Zns Core/Shell Nanocrystals And Tio2 Nanotubes For Quantum Dot Sensitized Solar Cells, Seungyong Lee

Graduate Theses and Dissertations

Synthesis of InP/ZnS core/shell nanocrystals and TiO₂ nanotubes and the optimization study to couple them together were explored for quantum dot sensitized solar cells. Its intrinsic nontoxicity makes the direct band gap InP/ZnS core/shell be one of the most promising semiconductor nanocrystals for optoelectric applications, with the advantage of tuning the optical absorption range in the desired solar spectrum region. Highly luminescent and monodisperse InP/ZnS nanocrystals were synthesized in a non-coordinating solvent. By varying the synthesis scheme, different size InP/ZnS nanocrystals with emission peaks ranging from 520 nm to 620 nm were grown. For the purpose of ensuring air …

Device Characterization And Compact Modeling Of The Sige Hbt In Extreme Temperature Environments, Beth Olivia Woods

Graduate Theses and Dissertations

The silicon germanium heterojunction bipolar transistor, SiGe HBT, has very high frequency response but limited voltage range. Commercial communication applications in wireless and system integration have driven the development of the SiGe HBT. However, the device's excellent electrical performance goes beyond the commercial environment. The SiGe HBT performs exceptionally at low temperatures. The device DC current gain and AC small-signal gain significantly increase in the cryogenic temperature range. Applications at low temperatures with expansive temperature range specifications need an HBT compact model to accurately represent the device's performance.

In this work, a compact model referenced at 300K was developed to …

Tdma Slot Reservation In Cluster-Based Vanets, Mohammad Salem Almalag

Computer Science Theses & Dissertations

Vehicular Ad Hoc Networks (VANETs) are a form of Mobile Ad Hoc Networks (MANETs) in which vehicles on the road form the nodes of the network. VANETs provide several services to enhance the safety and comfort of drivers and passengers. These services can be obtained by the wireless exchange of information among the vehicles driving on the road. In particular, the transmission of two different types of messages, safety/update and non-safety messages.

The transmission of safety/update message aims to inform the nearby vehicles about the sender's current status and/or a detected dangerous situation. This type of transmission is designed to …

Modeling Tools For Conformal Orthotic Devices, Steven David Riddle

Open Access Theses

The purpose of this thesis is to advance the design of conformal orthotic devices through the development of two modeling tools to address knowledge gaps in the field.

The field of human orthotics has been continually troubled by identifying successful methods of harnessing devices to the body. Past orthotics have utilized a rigid framework with minimal degrees of freedom (DOFs) driven by hard actuators attached to the body at select anchor points. Many devices design the structure and anchor points such that they reduce the degrees of freedom of a targeted joint, limiting the user's mobility and often causing the …

Product Characterization And Headspace Analysis Of Solar Irradiated Aqueous C60 Clusters, Dan Su

Open Access Theses

Buckminsterfullerene (C60) is an important fullerene material that has drawn much attention and is currently being applied in many different fields. It was discovered in 1985. As its production has largely increased to meet these industrial needs, it is obvious that its environmental occurrence, especially in aqueous systems, will occur. To further provide information for environmental toxicity studies and for its risk assessment, this thesis focuses on the photo transformation processes of aqueous C60 clusters (Aqu/nC60), with a particular interest in measuring any mineralization that occurs under different irradiation conditions. Two sets of experiments were conducted to test for CO2 …

The Use Of Complexity Theory And Strange Attractors To Understand And Explain Information System Development, Arthur P. Tomasino

2013

In spite of the best efforts of researchers and practitioners, Information Systems (IS) developers are having problems "getting it right". IS developments are challenged by the emergence of unanticipated IS characteristics undermining managers ability to predict and manage IS change. Because IS are complex, development formulas, best practices or development guides simply will not work. The difficulties in these system developments stem from the complexity of IS arising from the inter-relationship, interaction, and interconnectivity of the elements in the system and its environment. This research uses complexity concepts to help solve the problem with IS development and explain why so …

Accurate Prediction Of Spectral Phonon Relaxation Time And Thermal Conductivity Of Intrinsic And Perturbed Materials, Tianli Feng

Open Access Theses

The prediction of spectral phonon relaxation time, mean-free-path, and thermal conductivity can provide significant insights into the thermal conductivity of bulk and nanomaterials, which are important for thermal management and thermoelectric applications. We perform frequency-domain normal mode analysis (NMA) on pure bulk argon and pure bulk germanium. Spectral phonon properties, including the phonon dispersion, relaxation time, mean free path, and thermal conductivity of argon and germanium at different temperatures have been calculated. We find the dependence of phonon relaxation time τ on frequency ω and temperature T vary from ~ω^-1.3 to ~ω^-1.8 and ~T^-0.8 to ~T^{-1.8 …}

High Speed Turning Of Compacted Graphite Iron (Cgi) Using Controlled Modulation, Tyler Paul Stalbaum

Open Access Theses

Compacted graphite iron (CGI) is a material which emerged as a candidate material to replace cast iron (CI) in the automotive industry for engine block castings. Its thermal and mechanical properties allow the CGI-based engines to operate at higher cylinder pressures and temperatures than CI-based engines, allowing for lower fuel emissions and increased fuel economy. However, these same properties together with the thermomechanical wear mode in the CGI-CBN system result in poor machinability and inhibit CGI from seeing wide spread use in the automotive industry.

In industry, machining of CGI is done only at low speeds, less than V = …

Scheduling In Mohs Micrographic Surgery Clinics, Stephen Vincent Steidle

Open Access Theses

Mohs Micrographic Surgery (MMS) is a surgical method used for the excision of aggressive skin cancers in areas of high cosmetic importance, such as the face and hands. The practice has been gaining popularity worldwide for its low recurrence rates and cosmetic results. Current clinics though are plagued by extreme wait times and an overall poor patient experience. In this paper we look to explore this problem by applying systems engineering principles including optimization and scheduling with the goal of improving the patient experience. Currently, little literature exists exploring the difficulties associated with scheduling for MMS clinic which primarily revolve …

A Study Of Inkjet Printed Line Morphology Using Volatile Ink With Non-Zero Receding Contact Angle For Conductive Trace Fabrication, Chenchao Shou

Open Access Theses

Inkjet printed lines on a homogeneous solid substrate are studied under the condition that ink evaporation is not negligible and the contact angle exhibits hysteresis with non-zero receding contact angle (NRCA). A new family of line instability is discovered, featured by formation of agglomerations within a line. The agglomeration is explained by a hydrodynamic flow that consistently drives a bead on the substrate towards fresh deposited droplets due to concentration-induced surface tension gradient. Morphologies of lines printed with multiple layers are also explored for the purpose of conductive trace fabrication. A non-uniform morphology is observed across a multi-layer line when …

Finfet Device Optimization At 15nm For Near-Threshold Operation, Jolene Singh

Open Access Theses

Much of the current research in the electronic industry focuses on reducing power consumption of digital circuits. Towards the same many attempts are being made to reduce the operating voltage of the circuits. It has been shown through device and circuit analysis that a circuit consumes minimum energy when operated near threshold voltage. In this thesis I vary device parameters and study their effects on energy consumption and delay of the device for the two regions of operation - superthreshold and near-threshold, using LUTs of IV and CV characteristics, verilogA and hSpice. Finally, device parameters are obtained for an optimum …

Modulation Of Cell-Matrix Interaction For Cryopreservation Of Engineered Tissue, Angela Christine Seawright

Open Access Theses

Long term preservation of functional engineered tissues can significantly advance tissue engineering industry and regenerative medicine. Several preservation techniques have been proposed and investigated for this purpose, and cryopreservation is a leading candidate. While tissues are cryopreserved, ice forms in both the extracellular and intracellular spaces and causes freezing-induced spatiotemporal deformation of the tissue. During this process the cells undergo dehydration by the freezing-induced osmotic pressure difference and mechanical deformation, transmitted through cell-extracellular matrix adhesions. However, the significance and interaction of these cellular level transport and mechanics processes are not well understood. Therefore, this study aims to establish mechanistic understanding …

Analysis Of Cyberattacks On Unmanned Aerial Systems, Andrew Morris Shull

Open Access Theses

With the increasing power and convenience offered by the use of embedded systems in control applications, such systems will undoubtedly continue to be developed and deployed. Recently, however, a focus on data-centric systems and developing network-enabled control systems has emerged, allowing for greater performance, safety, and resource allocation in systems such as smart power grids and unmanned military aircraft. However, this increase in connectivity also introduces vulnerabilities into these systems, potentially providing access to malicious parties seeking to disrupt the operation of those systems or to cause damage. Given the high potential cost of a failure in these systems in …

Flow And Heat Transfer In An L-Shaped Cooling Passage With Ribs And Pin Fins For The Trailing Edge Of A Gas-Turbine Vane And Blade, Irsha Ashok Pardeshi

Open Access Theses

Efficient and effective cooling of the trailing edges of gas-turbine vanes and blades is challenging because there is very little space to work with. In this study, CFD simulations based on steady RANS closed by the shear-stress transport turbulence model were performed to study the flow and heat transfer in an L-shaped duct for the trailing edge under two operating conditions. One operating condition, referred to as the laboratory condition, where experimental measurements were made, has a Reynolds number at the duct inlet of Re_D = 15,000, coolant inlet temperature of T_inlet = 300 K, wall temperature of …

An Evaluation Of Spatial Variability Of Water Stress Index Across The United States: Implications Of Supply And Demand In The East Vs The West, Jennifer Ann Roath

Open Access Theses

In order to support both human and environmental needs, high quality fresh water must be available when and where it is required. As a metric for indicating unsustainable water usage, WSI is only useful when the values reflect accurate interactions between supply and demand; however, the complexity of temporal and spatial variability of available fresh water complicates the analysis of water stress.

The overall goal of this project was to investigate the spatial variability of water stress across the United States and the appropriate spatial scale for management decisions. To accomplish this, a national dataset describing spatial distribution and breakdown …

Quantum Computing With Steady State Spin Currents, Brian Matthew Sutton

Open Access Theses

Many approaches to quantum computing use spatially confined qubits in the presence of dynamic fields to perform computation. These approaches are contrasted with proposals using mobile qubits in the presence of static fields. In this thesis, steady state quantum computing using mobile electrons is explored using numerical modeling. Firstly, a foundational introduction to the case of spatially confined qubits embodied via quantum dots is provided. A collection of universal gates implemented with dynamic fields is described using simulations. These gates are combined to implement a five-qubit Grover search to provide further insight on the time-dependent field approach. Secondly, the quantum …

Nutrient Recovery From Anaerobically-Digested Dairy Manure By Struvite Formation And Its Effect On Gas Releases, Zhong Qiao

Open Access Theses

Manure management practices such as anaerobic digestion and lagoon storage have become important issues for large dairy farms partially due to water quality and air quality concerns caused by excess nitrogen and phosphorus. Prior research efforts have proven that struvite formation is an effective method for nutrients recovery from both municipal and agricultural wastewaters. However, little is known about nutrient recovery through struvite formation from anaerobically-digested dairy manure effluents.The effects of struvite precipitation on the releases of gases such as NH3, H2S, and CO2 are also unclear.

In this thesis, both bench-scale tests and pilot-scale storage tests were conducted to …

Analysis Of An Actuated Two Segment Leg Model Of Locomotion, Nikhil Vinayak Rao

Open Access Theses

Research studies on dynamic models of legged locomotion have generally focused on telescoping-type leg models. Such telescoping spring loaded inverted pendulum (SLIP) models have been able to accurately predict observed center of mass (CoM) trajectories. There have been comparatively fewer studies on dynamics of locomotion

with segmented legs. Some earlier studies on the dynamics due to leg segmentation appear straightforward. For example, a simple model with the only joint moment being due to a passive springy knee has been shown to behave similarly to a telescoping spring-mass model. However, in real-life animal locomotion, there are multiple joint-moments acting at the …

Simulating Land Use Land Cover Change Using Data Mining And Machine Learning Algorithms, Amin Tayyebi

Open Access Dissertations

The objectives of this dissertation are to: (1) review the breadth and depth of land use land cover (LUCC) issues that are being addressed by the land change science community by discussing how an existing model, Purdue's Land Transformation Model (LTM), has been used to better understand these very important issues; (2) summarize the current state-of-the-art in LUCC modeling in an attempt to provide a context for the advances in LUCC modeling presented here; (3) use a variety of statistical, data mining and machine learning algorithms to model single LUCC transitions in diverse regions of the world (e.g. United States …

Orientation Controllable Epitaxial Vapor-Liquid-Solid Semiconductor Nanowire Synthesis On Silicon Substrate, Sung Hwan Chung

Open Access Dissertations

Semiconductor nanowires synthesized via the vapor-liquid-solid (VLS) mechanism have attracted extensive research interest in recent years owing to their unique structure as a promising candidate for the future electronic devices. Germanium and silicon nanowires, in particular, are compatible with the current silicon-based technology via direct assembly. However, one of the main challenges for the successful nanowire application in large-scale is the lack of the method for obtaining nanowires in desired positions and directions. Therefore, the comprehensive, systematic understanding of epitaxial nanowire growth and the more suitable method to align nanowires on novel structure are required. In this work, the synthesis …

Interactional Analysis Of Emergent Risks In Institutionally Diverse Construction Projects, Nader Naderpajouh

Open Access Dissertations

Naderpajouh, Nader Ph.D., Purdue University, December 2013. Interactional Analysis of Emergent Risks in Institutionally Diverse Construction Projects. Major Professor: Makarand Hastak.

Construction projects, as complex systems of systems (SOS), increasingly involve institutionally diverse actors that escalate complexity of the projects. Examples of these actors include the export credit agencies, international organizations such as the World Bank, non-governmental organizations (NGO), regulatory actors, transnational organizations, as well as public and community groups. The observed surge in complexity of the projects aim to enhance their robustness in: i) sustaining the increasing demand for service of these projects, and ii) sustaining the contextual fluctuation …

Information Measures For Statistical Orbit Determination, Alinda Kenyana Mashiku

Open Access Dissertations

The current Situational Space Awareness (SSA) is faced with a huge task of tracking the increasing number of space objects. The tracking of space objects requires frequent and accurate monitoring for orbit maintenance and collision avoidance using methods for statistical orbit determination. Statistical orbit determination enables us to obtain estimates of the state and the statistical information of its region of uncertainty given by the probability density function (PDF). As even collision events with very low probability are important, accurate prediction of collisions require the representation of the full PDF of the random orbit state. Through representing the full PDF …