Engineering Commons^™

Electrochemical Synthesis Of Acetylpyrazine, Lin Mao, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang

Journal of Electrochemistry

Acetylpyrazine is naturally presented in hazelnuts, peanuts, and sesame seeds. As an important food additive, it is widely used in baked foods, meat, sesame and tobacco. At the same time, acetylpyrazine is also an important pharmaceutical intermediate, which is used in the syntheses of anti-tuberculosis drugs, anti-tumor, anti-malaria, anti-viral, antibacterial and treatments of epilepsy, pain and Parkinson’s drugs. At present, the synthesis methods of acetylpyrazine include oxidation method, multi-step method and Grignard reagent method, which have the disadvantages of low yield, cumbersome process, severe reaction conditions and high cost. In this study, acetylation of pyrazine was used to synthesize acetylpyrazine …

Electrochemical Voltammetric Behavior Of Sulfur Mustard On The Bare Pt Electrode, Yu-Lin Yang, Jie Sun, Tian Zhou, Ji-Gang Li, Shou-Ping Wei

Journal of Electrochemistry

The sulfur mustard (bis(2-chloroethyl) sulphide, HD), one of highly toxic chemical weapon agents, can damage the alive tissue cells (such as skin, lung, respiratory mucosa and so on), and cause carcinogenic and mutagenic effects for a long time exposure, which imposes a great threat not only to the human health, but also to the sustainable development of the society. With its convenience, high sensitivity and rapid response, electrochemical technology exhibits considerable potential in the field-deployed detection toward HD, but the related reports are rare. Herein, the electrochemical behavior of HD on the bare Pt electrode was investigated by electrochemical measurements, …

Electrocatalytic "Volcano-Type" Effect Of Nano-Tio2 (A)/(R) Phase Content In Pt/Tio2-CnX Catalyst, Ai-Lin Cui, Yang Bai, Hong-Ying Yu, Hui-Min Meng

Journal of Electrochemistry

The relationship between the electrochemical activity of fuel cell catalysts and Pt particle size, as well as the catalyst support and co-catalyst is still unclear. In this work, FESEM, XRD, BET, TEM and CV techniques were adopted to investigate the effects of TiO₂ anatase (A)/rutile (R) phases content on the electrochemical activity of Pt electrocatalyst. The results showed that the anatase-rutile phase transformation occurred during the heat treatment of TiO₂ at 700 ~ 900 ^oC accompanied by the growth of two-phase crystalline size, and anatase was completely transformed into rutile at 900 ^oC. TEM results revealed …

Biofouling Behaviors Of Pure Titanium Surface Polarized At Different Potentials, Zhao-Xia Dai, Da-Jiang Zheng, Guang-Ling Song, Dan-Qing Feng, Pei Su

Journal of Electrochemistry

Titanium (Ti) and its alloys are commonly used as engineering materials. Although they have been widely used in marine environments, they are also facing serious threats of biofouling. Therefore, it is necessary to investigate the relationship between electrochemical behavior and bioaffinity of titanium oxide film in seawater to explore effective surface treatment technology to reduce biofouling. In this work, the cathodic potential of -0.8 V_SCE and the passivation potential of 0.5 V_SCE were directly applied to the TA2 Ti in artificial seawater for potentionstatic polarization treatment to prepare two kinds of surface films with different states and then …

Effect Of Chloride Ion On Electrochemical Behavior Of Silver Electrodeposition In Chcl-Urea Low Eutectic Solvent, Chong-Bo Zhan, Run-Jia Zhang, Xu Fu, Hai-Jing Sun, Xin Zhou, Bao-Jie Wang, Jie Sun

Journal of Electrochemistry

Metallic silver coating has been widely used in the fields of microelectronics industry, catalyst, sensor and preparation of magnetoresistive materials because of its excellent corrosion resistance, good lubricity, high conductivity, excellent decoration and high catalysis. Compared with the traditional aqueous solution system, the research on metal electrodeposition in ionic liquid system is developing rapidly. In addition, additives are the key factors in the silver plating process. Adding a small amount of organic or inorganic additives to the plating solution will significantly change the coating properties, such as improving brightness, hardness and ductility. In this paper, using choline chloride urea (ChCl-Urea) …

Simultaneous Hydrogen And (Nh4)2So4 Productions From Desulfurization Wastewater Electrolysis Using Mea Electrolyser, Ju-Cai Wei, Lin Shi, Xu Wu

Journal of Electrochemistry

It is preferred to simultaneously recover resource and energy from waster. Sulfur dioxide, SO₂, a common air pollutant, a potential energy resource, is a key link to sulfur nature circulation. SO₂ can be conversed to NH₄HSO₃ and (NH₄)₂SO₃ during the ammonia desulfurization process, which can be used to produce (NH₄)₂SO₄ fertilizer. For high quality (NH₄)₂SO₄ fertilizer and high heat transfer efficiency of the evaporative crystallization, HSO₃^- or SO₃^2- needs to be oxidized to form SO …

Study And Improvement On Expansion Property Of Silicon Oxide, Wei-Chuan Qiao, Fang-Ru Li, Jin-Lin Xiao, Li-Juan Qu, Xiao Zhao, Meng Zhang, Chun-Lei Pang, Zi-Kun Li, Jian-Guo Ren, Xue-Qin He

Journal of Electrochemistry

The silicon-based anode materials have the potential to meet the ever-increasing demand for energy density in lithium-ion batteries market owing to their high theoretical specific capacity. Unfortunately, their commercialization was hindered by the continuous volume expansion. Herein, the expansion characteristics and corresponding mechanism of the silicon oxide and graphite-silicon oxide composites were investigated by in-situ displacement detection systematically. The results showed that the expansion property was improved by material process modifications. During the de/lithiation processes of graphite, the expansion ratio in 30% ~ 50% SOC changed little because of the small interlayer spacing variation of the intercalated graphite. …

Preparation And Properties Of Gcp-Supported Palladium Particles Composite Towards Electrochemical Ammonia Synthesis, Ying-Chao Wang, Zi-Zai Ma, Yi-Fan Wu, Xiao-Guang Wang

Journal of Electrochemistry

Ammonia (NH₃) plays an essential role in agriculture and modern industries. Electrochemical fixation of nitrogen (N₂) to ammonia (NRR) under ambient conditions with renewable electricity is a promising strategy to replace the industrial Haber-Bosch method. However, it usually suffers from extremely poor ammonia yield and low Faraday efficiency due to the poor electrocatalysts. Therefore, intensive studies have been devoted to developing efficient NRR catalysts till now. Among them, palladium (Pd) can capture protons in the aqueous phase to form stable α-PdH, which balances the competitive adsorption between nitrogen and protons as well as reduces the …

Electroanalytical Measurements Of Lanthanum (Iii) Chloride In Molten Calcium Chloride And Molten Calcium Chloride And Lithium Chloride, Mark H. Schvaneveldt, Ranon Fuller, Devin Rappleye

Faculty Publications

Cyclic voltammetry (CV), square wave voltammetry (SWV) and other electroanalytical methods have been applied to molten chloride salts to study metal ion behavior. These studies have been useful for understanding and optimizing the electrowinning of metals. Notable ions that have been studied are rare earth and actinide metal ions in LiCl-KCl salts. However, the behavior of lanthanum (La³⁺) ions in some molten chlorides or chloride mixtures (e.g., CaCl₂) has not been studied. CV experiments were conducted to evaluate La³⁺ behavior in CaCl₂-LiCl and CaCl₂ and were compared to La³⁺ behavior in …

An Injury Severity Prediction-Driven Accident Prevention System, Gulsum Alicioglu, Bo Sun, Shen-Shyang Ho

College of Science & Mathematics Departmental Research

Traffic accidents are inevitable events that occur unexpectedly and unintentionally. Therefore, analyzing traffic data is essential to prevent fatal accidents. Traffic data analysis provided insights into significant factors and driver behavioral patterns causing accidents. Combining these patterns and the prediction model into an accident prevention system can assist in reducing and preventing traffic accidents. This study applied various machine learning models, including neural network, ordinal regression, decision tree, support vector machines, and logistic regression to have a robust prediction model in injury severity. The trained model provides timely and accurate predictions on accident occurrence and injury severity using real-world traffic …

Optimum Biodiesel Production Using Ductile Cast Iron As A Heterogeneous Catalyst, Nada Amr El-Khashab, Marwa Mohamed Naeem, Mai H. Roushdy

Chemical Engineering

Biofuels production become a target for many researchers nowadays. Biodiesel is one the most important biofuels that are produced from biomass using economics and modern techniques. The ductile cast iron solid waste dust is one of the wastes produced by the cast iron industry which has a bad effect on the environment. This paper investigates the possibility of reusing ductile cast iron solid waste as a biodiesel heterogeneous catalyst used in its production from sunflower waste cooking oil. Four reaction parameters were chosen to determine their effect on the reaction responses. The reaction parameters are M:O ratio, reaction time and …

Enhancement Of Cement Paste With Carboxylated Carbon Nanotubes And Poly(Vinyl Alcohol), Yuyang Zhao, Jinrui Zhang, Gang Qiao, Dongshuai Hou, Biqin Dong, Hongyan Ma

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Cement has been a major consumable material for construction in the world since its invention, but its low flexural strength is the main defect affecting the service life of structures. To adapt cement-based materials to a more stringent environment, carboxylated carbon nanotubes (CNTs-COOH) and poly(vinyl alcohol) (PVA) are proposed to enhance the mechanical properties of cement paste. This study systematically verifies the synergistic effect of CNTs-COOH/PVA on the performance of cement paste. First, UV-Vis spectroscopy and FTIR spectroscopy prove that CNTs-COOH can provide attachment sites for PVA and PVA can improve the dispersion and stability of CNTs-COOH in water, which …

A High-Density Theta Burst Paradigm Enhances The Aftereffects Of Transcranial Magnetic Stimulation: Evidence From Focal Stimulation Of Rat Motor Cortex, Qinglei Meng, Hieu Nguyen, Antonia Vrana, Simone Baldwin, Charlotte Qiong Li, Antonia Giles, Jun Wang, Yihong Yang, Hanbing Lu

Department of Electrical and Computer Engineering: Faculty Publications

Background: Theta burst stimulation (TBS) is an efficient noninvasive neuromodulation paradigm that has been widely adopted, clinically. However, the efficacy of TBS treatment remains similarly modest as conventional 10 Hz repetitive transcranial magnetic stimulation (rTMS).

Objective/hypothesis: To develop a new TBS paradigm that enhances the effects of TMS administration while maintaining high time-efficiency.

Methods: We describe here a new TMS paradigm, named High-Density Theta Burst Stimulation (hdTBS). This paradigm delivers up to 6 pulses per burst, as opposed to only 3 in conventional TBS, while maintaining the inter-burst interval of 200 ms (or 5 Hz) - a …

Free-Decay Heave Motion Of A Spherical Buoy, Jacob K. Colling, Saeed Jafari Kang, Esmaeil Dehdashti, Salman Husain, Hassan Masoud, Gordon Parker

Michigan Tech Publications, Part 1

We examined the heave motion of a spherical buoy during a free-decay drop test. A comprehensive approach was adopted to study the oscillations of the buoy involving experimental measurements and complementary numerical simulations. The experiments were performed in a wave tank equipped with an array of high-speed motion-capture cameras and a set of high-precision wave gauges. The simulations included three sets of calculations with varying levels of sophistication. Specifically, in one set, the volume-of-fluid (VOF) method was used to solve the incompressible, two-phase, Navier–Stokes equations on an overset grid, whereas the calculations in other sets were based on Cummins and …

Text Summarization Towards Scientific Information Extraction, Abigail Keller

College of Computing and Digital Media Dissertations

Despite the exponential growth in scientific textual content, research publications are still the primary means for disseminating vital discoveries to experts within their respective fields. These texts are predominantly written for human consumption resulting in two primary challenges; experts cannot efficiently remain well-informed to leverage the latest discoveries, and applications that rely on valuable insights buried in these texts cannot effectively build upon published results. As a result, scientific progress stalls. Automatic Text Summarization (ATS) and Information Extraction (IE) are two essential fields that address this problem. While the two research topics are often studied independently, this work proposes to …

Characterization Of Gas Hydrate Formation And Its Impact On Slope Stability In Offshore Environments, Sulav Dhakal

LSU Doctoral Dissertations

Natural gas hydrates (NGH) are predominantly methane hydrates formed at high pressure and low temperature conditions typically in submarine sediments and permafrost. This dissertation is focused on the submarine methane hydrates formed by upward migration of free and dissolved gas. The methane gas stored within natural hydrates has more energy potential than all the combined oil and gas resources around the world. Numerical simulation of fluid flow, heat transport, and geomechanical stresses is used to characterize and evaluate the saturation, distribution, reservoir quality, and geohazards associated with hydrate-bearing sediments. Coupled thermo-hydro-mechanical (THM) simulation of hydrate formation, dissociation, and slope stability …

Metasoftware: Building Blocks For Legal Technology, Houman Shadab

Seattle Journal of Technology, Environmental, & Innovation Law

This Article develops a novel concept in information technology called “metasoftware.” It then applies the concept of metasoftware to developing legal technology.

Metasoftware enables users to create the software of their choosing and stands in sharp contrast to traditional, functional. Functional software is the default type of software that is currently produced and includes word processing, email, social networking, enterprise resource management, online marketplaces, and video game software. Metasoftware, by contrast, is not functional. Metasoftware presents the user with a blank slate upon which to build functional software.

I argue that software is metasoftware to that extent that (1) it …

Assessing The Effectiveness Of Problem-Based Learning Across Two Concrete Construction Courses, Anthony Torres, Jiong Hu, Vedaraman Sriraman, Araceli Martínez-Ortiz, Jorge Membrillo-Hernández

Department of Civil and Environmental Engineering: Faculty Publications

The goal of this study is to assess the effectiveness of a Problem-Based Learning (PBL) pedagogy that was implemented in two different concrete construction courses. Both courses are a part of an industry focused four-year undergraduate concrete degree program. One of the classes focused on concrete problems, diagnosis, and repair of existing concrete, while the other class focused on handling and management methods of various concrete mixtures. In both courses, a PBL pedagogy was implemented such that students were self-learning and discovering the knowledge through an action-research case study. The action-research case study was specific to the course outcomes relevant …

Collaborative Design And Simulation Integrated Method Of Civil Aircraft Take-Off Scenarios Based On X Language, Pengfei Gu, Lin Zhang, Zhen Chen, Junjie Ye

Journal of System Simulation

Abstract: For the large and complex products, the current traditional model-based systems engineering (MBSE) method of the integrated implementation of multiple modeling and simulation languages and platforms for system design and simulation verification can not ensure the efficient and accurate feedback of system design to realize the quick design optimization. X language, a new generation of integrated modeling and simulation language based on complex systems and supporting MBSE, is used to realize the integrated modeling and simulation on cross-domain subsystems of civil aircraft for the take-off scenarios. From the demand analysis of the take-off process of civil aircraft, the system-level …

Cross Level Switching Technology For Multi-Resolution Model Of Complex Products, Wei Li, Wenjia Zhang, Heming Zhang

Journal of System Simulation

Abstract: In the R&D of complex products, different design stages have different design goals and different simulation tasks, which need different resolution complex products simulation models. The models and interfaces for the multi-resolution characteristics are defined and thus the resolution control mechanism is studied. The description mechanisms for the system structure status and model resolution state are established separately, the control mechanism for the system resolution is proposed, and a cross level switching technology is sorted out. The experimental results show that the method can effectively solve the problem of model resolution switching, which ensures the simulation accuracy, improves …

A Cyber-Physical Integrated Modeling Method Oriented For Motion Simulation Of Complex Systems, Wenzheng Liu, Heming Zhang

Journal of System Simulation

Abstract: The traditional virtual modeling of motion simulation lacks the dynamic modeling of cyber subsystems and physical subsystems in complex systems. The advantages of the traditional kinematic virtual modeling and cyber calculation are combined, and aiming at the problem that the accuracy and real-time property of motion simulation cannot meet the actual industrial manufacturing requirements, a cyber physical integrated modeling method for the motion simulation of complex systems is proposed. The inconsistency between real robotic driving and virtual robot motion is solved, which is verified by a case study of mechanical arm motion control. A virtuality-reality mapping platform for complex …

Uav Formation Recovery And Consistency Simulation Based On Improved Potential Field, Ning Wang, Jiyang Dai, Jin Ying

Journal of System Simulation

Abstract: Aiming at the problems of multi-UAV formation collision avoidance, formation recovery and the consistency of position and velocity convergence, a distributed cooperative formation control algorithm based on the improved potential field principle and consistency theory is proposed. The static obstacle model, UAV particle model and the second-order system dynamic model are established; the coordination potential field function with coordination factors and communication weights is defined, which can achieve the control objectives of collision avoidance and formation recovery; on the basic consistency protocol, the formation center reference vector, expected speed and speed stabilization items are introduced to achieve the convergence …

Multi-Objective Optimization Configuration Of Agv System Based On Response Surface And Nsga-Ii, Jianlin Fu, Guofu Ding, Jian Zhang, Haifan Jiang, Peipei Guo

Journal of System Simulation

Abstract: Automated guided vehicle(AGV) system plays an important role in the production flexibility and efficiency in manufacturing systems. Due to the dynamic and stochastic characteristics of AGV system with many variables, its optimal configuration is relatively complex. A method combining system simulation, mathematical analysis and multi-objective optimization is proposed to optimize the configuration of AGV system. The discrete event simulation is used to simulate the operation of AGV system, the sensitivity analysis is used to separate design variables, the factorial experiments and response surface methods are used to build the fitting multi-objective optimization mathematical model, and the non-dominated sorting genetic …

Study On The Scale Characteristics Of Permeability Of Tpms Porous Materials, Tong Wu, Qinghui Wang, Zhijia Xu

Journal of System Simulation

Abstract: Triply Periodic Minimal Surface (TPMS) has been widely used in the design of porous materials, however, there is insufficient research on the scale characteristics of permeability. Four commonly used TPMS units are chosen as the research object, based on the introduction of their mathematical models and porosity control methods, a numerical simulation model based on CFD (computational fluid dynamics) is established; TPMS units and cubic porous structures with different porosities are analyzed, the quantitative correlation between their scales and permeability is clarified, i.e., within the selected scale range, the permeability of various TPMS units and cubic porous structures is …

Triangular Mesh Boolean Operation Method For Finite Element Analysis, Yufei Guo, Kang Zhao, Yongqing Hai

Journal of System Simulation

Abstract: To shorten the cycle of finite element analysis (FEA), an adaptive triangular mesh Boolean operation method for finite element analysis is proposed. The ADT (alternating digital tree) data structure is applied to the intersection calculation of triangular meshes, which improves the efficiency of the intersection calculation of Boolean operations. A sphere packing algorithm and a node addition/deletion algorithm are used to remesh some remeshing regions, which ensures the efficiency of the method and the high-quality of remeshed meshes. An improved octree background grid is used to record and smooth the size field, which can generate size-adaptive meshes. The size …

Cellular Automata Model Of Mixed Traffic Flow Composed Of Intelligent Connected Vehicles’ Platoon, Yangsheng Jiang, Sichen Wang, Kuan Gao, Meng Liu, Zhihong Yao

Journal of System Simulation

Abstract: To solve the existing cellular automata model of automatic-manual driving that does not consider the behavior of vehicle platoon, a cellular automata model of mixed traffic flow with the intelligent connected vehicles platoon is proposed, and the characteristics of mixed traffic flow are analyzed. The existing car-following behaviors in mixed traffic flow are analyzed. Based on the characteristics of the car-following behaviors, the cellular automata rules of human-driven vehicles (HDV), adaptive cruise control (ACC), and cooperative adaptive cruise control (CACC) are developed, respectively. Based on the numerical simulation experiments, the mixed traffic flow characteristics and congestion conditions are analyzed …

Water Body Extraction From High Resolution Remote Sensing Images Based On Fused Visual Word Bags, Xin Wang, Mingjun Xu, Jian Xiao, Lizhong Xu

Journal of System Simulation

Abstract: Aiming at the problem that water body extraction is easily influenced by shadow or light in high resolution remote sensing images, an improved algorithm based on fusion of visual word bags is proposed. Based on the deep analysis of the characteristics of remote sensing water body targets, a spectral feature extraction approach is designed. To enhance the description ability of water body targets, a novel visual word bag fusion model based on local binary pattern and spectral feature is constructed. Based on the proposed visual word bag fusion model, a water body target classifier is presented. …

Study On Building Fire Evacuation Path Planning Based On Improved Ant Colony Algorithm, Jiangtao Liang, Huiqin Wang

Journal of System Simulation

Abstract: Aiming at the problem of dynamic planning of evacuation paths in comprehensive building fires, with the shortest escape time required for evacuees as the goal, considering the impact of fire products and crowd density on the evacuation speed of personnel, an evacuation path planning model based on improved ant colony algorithm is constructed. A evacuation network data model composed of an obstacle vertex grid is established, the inspiration function of the ant colony algorithm and the deadlock processing strategy are improved, the explosion operator in the fireworks algorithm is introduced to optimize the ant path, and a comprehensive building …

Teaching-Learning-Based Optimization Algorithm For Permutation Flowshop Scheduling, Qiwen Zhang, Bin Zhang

Journal of System Simulation

Abstract: A multi-classes teaching-learning-based optimization (MCTLBO) algorithm is proposed for the permutation flowshop scheduling problem (PFSP) by combining continuous algorithm with discrete strategy. An improved nawaz enscore ham (NEH) population initialization method based on permutation mutation is adopted, which takes into account the quality and diversity of initial solutions. In the teaching stage, discrete adaptive teaching with duplicate removal is introduced to avoid meaningless teaching processes. A new self-learning strategy based on Levy flight is added, and the self-learning in discrete stage is simulated by variable neighborhood search. Learner phase and class communication are combined to improve the efficiency of …

Supply Chain Delivery Model And Simulation Based On Product Experience, Genshang Xing, Fang Lu, Shushan Li, Dingti Luo

Journal of System Simulation

Abstract: With the higher demand of consumers for delivery time of products purchased online, it is becoming more important for retailers to determine the delivery time of products based on product experience and market position. By constructing a supply chain delivery model under the three channel rights structure, the impact of product experience on the optimal delivery time, the retailer’s decision mode selection considering the delivery time and the supply chain profit after delivery are analyzed, and the correctness and reliability of the model are verified by numerical simulation. Research shows that the optimal product delivery time of retailers …