Engineering Commons^™

Catalytic Carbon Dioxide Hydrogenation To Methanol/Dimethyl Ether Over Copper-Based Catalysts, Xiao Fan

Doctoral Dissertations

Direct synthesis of dimethyl ether (DME) via CO₂ hydrogenation has received great attention, owing to the global warming caused by CO₂ emission and increasing energy demand worldwide. In this works, three major aspects of bifunctional catalysts development were studied: (1) investigation of the roles of interaction in the CuO-ZnO-ZrO₂-Al₂O₃/HZSM-5 bifunctional catalysts, (2) deactivation and regeneration of CuO-ZnO-ZrO₂-Al₂O₃ with different zeolitic catalysts for one-step CO₂ hydrogenation to dimethyl ether, and (3) study on the enhancement of activity and stability of CZZA/HZSM-5 bifunctional catalysts via the introduction of …

Use Of Portable Seismic Property Analyzer And Ground Penetrating Radar To Assess Bridge Decks, Samie Ramadan A Hamad

Doctoral Dissertations

The Montauk Bridge deck was assessed based on the portable seismic property analyzer and ground penetrating radar data. Based on the analysis of the portable seismic property analyzer data, it was determined that over 65% of bridge conditions were rated serious to poor condition with an average compressive strength of less than 2500 psi; less than 35% of bridge deck conditions were rated fair to good with an average compressive strength over 2500 psi. Based on ground penetrating radar data, it was determined that 72% of the bridge deck was in serious to poor condition, and only 28% of the …

Relating Detonation Parameters To The Detonation Synthesis Of Nanomaterials, Martin Langenderfer

Doctoral Dissertations

“This research investigates the physical and chemical processes that contribute to the detonation synthesis of silicon carbide nanoparticles. Bulk production of SiC nanoparticles through detonation is possible due to pressures achieved over 20 GPa and temperatures over 2000 K as well as quenching rates in excess of 13 billion K/second. These conditions catalyze reaction and bottom-up molecular growth while retaining particles < 100 nm in diameter. In this work, detonation synthesis of SiC was demonstrated by incorporation of polycarbosilane, an SiC precursor material, into an RDX/TNT explosive matrix prior to detonation. Detonation Synthesis of SiC was also accomplished by reacting elemental silicon with carbon liberated by the detonation of negatively oxygen balanced TNT. Hydrodynamic simulation of a 60:40 mass ratio RDX/TNT detonation created conditions thermodynamically suitable to produce cubic silicon carbide within the first 500 nanoseconds after the passage of the detonation wave while carbon remains chemically reactive for molecular formation. Simulations and experimental tests indicated that loading configuration and impedance mismatch of the precursor additives used in detonation synthesis results in conditions in the additives that exceed the accepted detonation pressure of the explosive by greater than three times. Finally, a full factorial experimental design showed increasing silicon concentration, reducing silicon size, and reducing oxygen balance by adjusting the ratio of RDX to TNT decreased the explosives detonation pressure by 20% and increased the soot yield and concentration of SiC observed in the detonation products by 82% and 442% respectively”--Abstract, page iv.

Dynamic Behavior And Interactions Of Ferrofluid Droplets Under Magnetic Fields In Low Reynolds Number Flows, Md Rifat Hassan

Doctoral Dissertations

Digital microfluidics in combination with emulsion microfluidics are crucial building blocks of droplet-based microfluidics, which are prevalent in a wide variety of industrial and biomedical applications, including polymer processing, food production, drug delivery, inkjet printing, and cell-based assays. Therefore, understanding the dynamics and interactions of droplets as well as the interactions between the droplets and solid surfaces are of great importance in order to improve the performance or product in these applications.

Recently, several studies in the literature have demonstrated the potential of magnetic fields in controlling the behavior of droplets in microscale; however, the fundamental mechanism behind the interesting …

Investigation Of Anomalous Data Trends During Coal Dust Explosibilty Testing, Jacob Lee Miller

Doctoral Dissertations

Coal dust explosibility is a health and safety concern that has been a recognized hazard for over 100 years. Initial testing by the Author using a Siwek 20L apparatus recorded a secondary maximum pressure at higher dust concentrations (1,000-7,000g/m³) with Pulverized Pittsburgh Coal (PCC). Higher dust concentrations are beyond the typical ASTM E1226 testing procedure but are possible in mining and processing scenarios. No reference documents have been discovered that show a secondary maximum pressure at higher dust concentrations. Literature reviewed identified that once a coal dust concertation generates a peak pressure, the pressure remains constant or decreases …

Experimental And Numerical Studies Of Novel Thermal Energy Storage Materials For Applications In Concrete And Energy Storage Systems, Wenyu Liao

Doctoral Dissertations

In this work, several types of novel thermal energy storage (TES) materials and composites are explored, and a series of numerical simulation models and experimental protocols are developed to evaluate the potentials of these materials to be applied in concrete, pavement, and thermal energy storage systems.

The first two types of novel TES materials/composites are at the micro-scale, which use micro diatomite (DE) and cenosphere (Ceno) as carriers of phase change material (PCM), respectively. The third type of novel TES material is at the macro-scale, utilizing lightweight sand (LWS) and lightweight coarse aggregate as carriers to load PCM. The last …

An Investigation Of Unsteady Thermal Exchange Processes In Geothermal Heat Exchangers, Ganesh Ravi Shanker

Doctoral Dissertations

“Geothermal heat exchangers, has become one of the highly recognized non conventional heat exchangers as they utilize renewable energy source earth to initiate the thermal energy transfer. However, these heat exchangers suffer from a expensive installation cost due to their conservative design model, thereby facilitating the need to identify and improve the design. In this dissertation, three gaps, which identifies improvement over conservative design were investigated, to assess the heat exchanger performance. In the first approach, borehole thermal and geometrical properties were investigated keeping the outlet leg of the heat exchanger as adiabatic, which neglects the thermal short-circuiting between the …

Investigating The Focusing Effect Of Charge Geometry With Computer Simulations, Witness Plates, And High-Speed Videography, Kelly Ray Williams

Doctoral Dissertations

"Scaled distance is used to calculate a safe standoff radius from the detonation of a known mass of an explosive. It has been shown that varying only the geometry of the charge significantly overdrives regions of the blast wave potentially resulting in hazardous overpressure levels at scaled distance safe radii. Pressure transducers are used to measure overpressure surrounding spherical, cylindrical, and cubic charges to determine if bridge waves were formed at the edges between flat sides as seen in published studies of cylindrical charges. In the fireball field a witness plate is used to evaluate radial energy distribution with a …

Modeling For Off-Chip High-Speed Designs, Siqi Bai

Doctoral Dissertations

”Signal integrity (SI) and power integrity (PI) are essential for datacenter application. A typical datacenter rack consists of a switch on the top of the rack, servers, and storage units. Three SI/PI related problems for datacenter application are analyzed in this research.

The first topic is analysis on power via induced Quasi-quarter-wavelength resonance to reduce crosstalk. Using an analytical model and 3D full-wave simulation models, a physical explanation for the unexpected resonance in the differential signal pairs is proposed. Considering the difficulty in changing the pin map of the IC-package, several PCB layouts to eliminate the power via induced quasi-quarter-wavelength …

Designing Transition Metal Chalcogenides Electrocatalyst Surfaces For High-Efficiency Water Oxidation, Umanga De Silva

Doctoral Dissertations

”The rising demand for energy security and reducing fossil fuel dependence has prompted researchers to search for a clean, sustainable, and efficient energy generation system with low environmental impact. Water electrolysis has been identified as one of the most important processes satisfying the above needs to generate hydrogen as a clean fuel. Two half-cell reactions of oxygen evolution reaction (OER) at the anode and hydrogen evolution reaction (HER) at the cathode comprise the main process of water electrolysis. However, the oxygen evolution reaction is the most crucial step for efficient water splitting. Traditionally, metal oxides have been utilized as catalysts …

Fiber-Optic And Coaxial-Cable Extrinsic Fabry-Perot Interferometers For Sensing Applications, Chen Zhu

Doctoral Dissertations

”The fiber-optic extrinsic Fabry-Perot interferometer (EFPI) is one of the simplest sensing configurations and is widely used in various applications due to its prominent features, such as high sensitivity, immunity to electromagnetic interference, and remote operation capability. In this research, a novel one-dimensional wide-range displacement sensor and a three-dimensional displacement sensor based on fiber-optic EFPIs are demonstrated. These two robust and easy-to-manufacture sensors expand the application scope of the fiber-optic EFPI sensor devices, and have great potential in structural health monitoring, the construction industry, oil well monitoring, and geo-technology.

Furthermore, inspired by the fiber-optic EFPI, a novel and universal ultra-sensitive …

Adaptive Dynamic Programming Methods For Tracking Current Control Of Switched Reluctance Motor Drive, Hamad Alharkan

Doctoral Dissertations

“This research investigates the application of adaptive dynamic programming (ADP) methods for the current control of switched reluctance motors (SRM). Since the traditional current controllers have large current ripples that increase torque ripples and acoustic noise, optimal tracking controllers using reinforcement learning (RL) approaches are introduced as an alternative adaptive technique for SRM drives. The proposed optimal tracking controllers can minimize current ripples and cope with uncertainties within the inductance profile of the SRM. The work is composed of three papers. In the first paper, a novel Q-learning scheduling method for the current controller of a switched reluctance motor (SRM) …

Advanced Control Techniques For Modern Inertia Based Inverters, Sepehr Saadatman

Doctoral Dissertations

”In this research three artificial intelligent (AI)-based techniques are proposed to regulate the voltage and frequency of a grid-connected inverter. The increase in the penetration of renewable energy sources (RESs) into the power grid has led to the increase in the penetration of fast-responding inertia-less power converters. The increase in the penetration of these power electronics converters changes the nature of the conventional grid, in which the existing kinetic inertia in the rotating parts of the enormous generators plays a vital role. The concept of virtual inertia control scheme is proposed to make the behavior of grid connected inverters more …

3d-Printed Adsorbents For Gas Separations: A Material Development, Kinetic Assessment, And Process Performance Investigation, Shane Lawson

Doctoral Dissertations

“Adsorbent materials are promising for various gas purification processes, however, forming them into structured contactors is paramount in enhancing mass transfer properties and reducing pressure losses. In this research, various adsorbents were engineered into structured contactors with 3D printing. The overall goal of this research was to improve the formulation methods of 3D-printed adsorbents and understand their performances in gas separation processes. The specific objectives were to 1) develop new adsorbent 3D-printing strategies, 2) understand the kinetic properties of printed adsorbent monoliths, and 3) assess their process performances. Objective one was addressed by developing five 3D printing techniques: i) oxide …

Development Of In-Situ Radiometric Inspection Methods For Quality Assurance In Laser Powder Bed Fusion, Cody S. Lough

Doctoral Dissertations

“Laser Powder Bed Fusion (LPBF) metal Additive Manufacturing (AM) fabricates 3D metal parts layer-by-layer. The process enables production of geometrically complex parts that are difficult to inspect with traditional methods. The LPBF parts experience significant geometry driven thermal variations during manufacturing. This creates microstructure and mechanical property inhomogeneities and can stochastically cause defects. Mission critical applications require part qualification by measuring the defects non-destructively. The layer-to-layer nature of LPBF permits non-intrusive measurement of radiometric signals for a part’s entire volume. These measurements provide thermal features that correlate with the local part health. This research establishes Optical Emission Spectroscopy (OES) and …

Additively Manufactured Metallic Cellular Structures, Okanmisope Aziel Fashanu

Doctoral Dissertations

"Cellular structures are lightweight structures with excellent mechanical, thermal, and acoustic properties. They offer promise in a series of applications, including lightweight applications, sandwich cores, mechanical damping, acoustic absorption, strain isolation, and thermal management. The manufacturing of these complex cellular structures is expensive and time-consuming, which hinders the adoption of these structures in many industries. Advancement in manufacturing technologies, such as additive manufacturing (AM), however, have changed this. AM allows for the rapid and less expensive manufacturing of complex cellular structures. This work aimed to investigate the performance of additively manufactured cellular structures for lightweight and sandwich core applications. In …

Advanced Battery Modeling For Interfacial Phenomena And Optimal Charging, Yaqi Zhu

Doctoral Dissertations

"Lithium-ion batteries are one of the most promising energy storage systems for portable devices, transportation, and renewable grids. To meet the increasing requirements of these applications, higher energy density and areal capacity, long cycle life, fast charging rate and enhanced safety for lithium-ion battery (LIBs) are urgently needed. To solve these challenges, the relevant physics at different length scale need to be understood. However, experimental study is time consuming and limited in small scale’s study. Modeling techniques provide us powerful tools to get a deep understanding of the relevant physics and find optimal solutions. This work focuses on studying the …

Thermal And Mechanical Properties Of Novel Carbide Materials, Evan Charles Schwind

Doctoral Dissertations

"This research focuses on studying the thermal and mechanical properties of novel carbide materials at room and elevated temperatures. The novel carbide materials investigated include zeta phase tantalum carbide (ζ-Ta₄C_3-x) and a high entropy (Ta,Hf,Nb,Zr)C carbide. The electrical resistivity and thermal conductivity of zeta phase tantalum carbide (~96 wt.%) were measured as 160 ± 4.2 μΩ-cm and 9.6 W/m•K. These are higher and lower (respectively) than for cubic tantalum carbide, most likely due to planes of carbon vacancies present in the ζ-Ta₄C_3-x crystal structure. The thermal conductivity of (Ta,Hf,Nb,Zr)C was lower than any …

Prediction Of Battery Health Dynamics, Damola Martins Ajiboye

Doctoral Dissertations

"The successful market penetration of lithium-ion batteries in the last 30 years has ushered in a new dawn in energy applications. Notwithstanding their widespread use, lithium-ion batteries are affected by a plethora of fundamental issues — safety, cycle life, performance, and cost. In this work, advanced modeling techniques are developed to tackle some of these issues. This dissertation is subdivided into four parts, the first is introduction while the remaining are dedicated to the development of computational techniques for predicting battery health dynamics.

In the second part of this work, we developed fast and accurate algorithms for modeling essential battery …

Assessment Of Rib Failure Mechanisms Using Discontinuum Mechanics Based Modeling Approach, Maurice Nuonituo Sunkpal

Doctoral Dissertations

"Coal mine rib failures are major safety and health challenge for coal mines worldwide. The need for clear procedures to evaluate mine rib behavior and to provide an efficient, reliable, and consistent rib control protocol is needed. Understanding coal rib geomechanics is essential for improving rib stability and eliminating fatality and injury trends due to rib failures. This knowledge is also vital to determine support requirements.

The rib control practices used in the 21st Century in most countries originated in roof control techniques. Understandably, applying roof control methods to coal rib does not yield desirable results. The geology of structures …

Studying The Effects Of New Additive Materials For The Improvement Of The Capacity And Cycle Life Performance Of The Lead-Acid Battery, Julian Kosacki

Doctoral Dissertations

"Lead-acid batteries are an established technology with nearly 99% recyclability; however, lead-acid batteries produce only 40% of their theoretical capacity due to poor active mass utilization and PbSO4 pore blockage, and the longevity of the batteries is hampered by secondary reactions during the cycle life such as corrosion and gassing.

Lead-acid batteries were investigated and improved through several different approaches: an alternative electrolyte to mitigate secondary reactions, graphite additives to improve positive active mass (PAM) utilization, and dispersant additives to help the industrial pasting process.

The thermodynamics and chemical reactions of a commercial electrolyte replacement called Tydrolyte^TM were investigated …

Hydromechanical Stress And Internal Erosion Under Earthen Structures, Kerry Allen Magner

Doctoral Dissertations

"Dam failures by seepage and internal erosion have reportedly been attributed to up to 40% of all dam failures in the United States. Backwards piping erosion either through the embankment or foundation soils has been reported to be the major contributing method to seepage and internal erosion dam failures. This proposed research is motivated by the lack of understanding of the complex stress regimes associated with internal erosion in cohesionless soils under earthen structures. The overall goal of this research is to provide a fundamental understanding of internal erosion and the hydromechanical stress conditions necessary for the initiation and continuation …

Sources Of Quality Uncertainty In Laser Powder Bed Fusion Metal Additive Manufacturing, Zachary Young

Doctoral Dissertations

"Powder based additive manufacturing (AM) exhibits tremendous uncertainties, where variations in build quality is present despite utilizing similar build processing parameters. First, this work reports the features and formation mechanisms of five unique types of spatter during the LPBF process by in-situ high-speed, high-energy x-ray imaging. The unique physical characteristics of spatter are determined. The effect of laser scan speed and laser power on spatter formation, ejection, and mitigation are determined. Second, this work addresses the uncertainty challenge by identifying the sources of uncertainty in SLM by in-situ characterization due to variations from the additive manufacturing processing parameters needed for …

Investigating The Impact Of Rock Bridges On The Mechanical Behavior Of Jointed Rock Mass Using Lattice Spring-Based Synthetic Rock Mass (Ls-Srm) Approach, Mariam Salem Alebayat

Doctoral Dissertations

"Rock bridges were defined as a segment of intact rock that separates from discontinuities. Numerous studies are focused on developing methods to quantify their significance in rock mass strength and deformability behavior. This thesis aimed to enhance understanding of the effect of rock bridges on jointed rock masses in both laboratory and slope scales. For this purpose, the lattice spring base Synthetic Rock Mass (LS-SRM) method was adopted to conduct the numerical models, distinguished in computational efficiency, and simulates the brittle failure and roughness of discontinuities.

A robust approach was developed to optimize the calibration procedure to avoid the complex …

In Situ Recrystallization Of Co-Evaporated Cu(In,Ga)Se2 Thin Films By Copper Chloride Vapor Treatment Towards Solar Cell Applications, Deewakar Poudel, Benjamin Belfore, Tasnuva Ashrafee, Elizabeth Palmiotti, Shankar Karki, Grace Rajan, Thomas Lepetit, Angus Rockett, Sylvain Marsillac

Applied Research Center Publications

Cu(In,Ga)Se₂ (or CIGS) thin films and devices were fabricated using a modified three-stage process. Using high deposition rates and a low temperature during the process, a copper chloride vapor treatment was introduced in between the second and third stages to enhance the films properties. X-ray diffraction and scanning electron microscopy demonstrate that drastic changes occur after this recrystallization process, yielding films with much larger grains. Secondary ion mass spectrometry shows that the depth profile of many elements is not modified (such as Cu, In and Se) while others change dramatically (such as Ga and Na). Because of the competing …

Effect Of Random Pinning On Nonlinear Dynamics And Dissipation Of A Vortex Driven By A Strong Microwave Current, W.P.M.R. Pathirana, Alex Gurevich

Physics Faculty Publications

We report numerical simulations of a trapped elastic vortex driven by a strong ac magnetic field H(t)=Hsinωt parallel to the surface of a superconducting film. The surface resistance and the power dissipated by an oscillating vortex perpendicular to the film surface were calculated as functions of H and ω for different spatial distributions, densities, and strengths of pinning centers, including bulk pinning, surface pinning, and cluster pinning. Our simulations were performed for both the Bardeen-Stephen viscous vortex drag and the Larkin-Ovchinnikov (LO) drag coefficient η(v) decreasing with the vortex velocity v. The local residual surface resistance R_i(H) …

Effect Of Hearing And Head Protection On The Localization Of Tonal And Broadband Reverse Alarms, Chantal Laroche, Christian Giguère, Véronique Vaillancourt, Claudia Marleau, Marie-France Cadieux, Karina Laprise-Girard, Emily Gula, Véronique Carroll, Manuelle Bibeau, Hugues Nélisse

Études primaires

Objective

This study explored the effects of hearing protection devices (HPDs) and head protection on the ability of normal-hearing individuals to localize reverse alarms in background noise.

Background

Among factors potentially contributing to accidents involving heavy vehicles, reverse alarms can be difficult to localize in space, leading to errors in identifying the source of danger. Previous studies have shown that traditional tonal alarms are more difficult to localize than broadband alarms. In addition, HPDs and safety helmets may further impair localization.

Method

Standing in the middle of an array of eight loudspeakers, participants with and without HPDs (passive and level-dependent) …

Evaluation Of Various Separation Techniques For The Removal Of Actinides From A Rare Earth-Containing Solution Generated From Coarse Coal Refuse, Deniz Talan

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rare earth elements have emerged as a vital commodity due to their significance in the production of high-tech devices as well as their utilization in defense and military systems. They are deemed critical due to potential scarcity, supply constraints, and the lack of minable concentrations. Therefore, alternative sources are needed to meet the demand and continue manufacturing rare earth-required products. Coal and coal by-products, in that regard, have presented a significant opportunity and proven to contain a considerable amount of rare earths. However, toxic elements such as thorium and uranium are frequently seen in the same mineralization as rare earths. …

Identification Of Crash Contributing Factors In Av Involved Crashes, Md Tanvir Ashraf

Graduate Theses, Dissertations, and Problem Reports (ETD)

Autonomous Vehicles (AVs) can dramatically reduce the number of traffic crashes and associated fatalities by eliminating the avoidable human-errors related crash contributing factors. Many companies have been conducting pilot tests on public roads in several states in the United States and other countries to accelerate AV mass deployment. AV pilot operations on California public roads saw 251 AV-involved crashes (as of February 2020). These AV-involved crashes provide a unique opportunity to investigate AV crash risks in a mixed traffic environment. This study collected the AV crash reports from the California Department of Motor Vehicles and applied the Decision Tree (DT), …

Telehealth Optimization – Role Of Clinical Athletic Trainers In Orthopedic/Sports Medicine Practice, Katie Harbacheck, Laura Grambo, Shaun Keefer, Eric Klein, Christine Boyd, Carolyn Ford-Hemann, Cameron D’Alpe, Steve Frick, Kevin Shea

Clinical Practice in Athletic Training

Background: Prior to COVID-19, telehealth (TH) implementation in most health systems was minimal. The transition to high rates of TH was dramatic in response to COVID-19, and many health systems struggled to develop optimal, efficient TH workflows. Hypothesis/Purpose: The primary purpose of this study was to evaluate the role of clinically integrated athletic trainers (ATs) into the TH transition of a major orthopedic academic center through growth of TH visits as well as physician satisfaction. Methods: Workflows and tip sheets were designed to include considerations of TH visit increases, adoption of appropriate technology platforms and optimal staff models. The rapid …