Engineering Commons^™

Pd-Based Electrocatalysts For Oxygen Reduction And Ethanol Oxidation Reactions: Some Recent Insights Into Structures And Mechanisms, Zhi-Peng Wu, Chuan-Jian Zhong

Journal of Electrochemistry

The development of efficient electrocatalysts for applications in fuel cells, including proton-exchange membrane fuel cell (PEMFC) and direct ethanol fuel cell (DEFC), has attracted extensive research attention in recent years. Oxygen reduction reaction and ethanol oxidation reaction are two of the key reactions where the design of active, stable and low-cost electrocatalysts is critical for the mass commercializations of PEMFCs and DEFCs. This challenge stems largely from the limited understanding of the catalyst structures and reaction mechanisms. Progress has been made in investigations of electrocatalysts derived from Pd-based alloy nanomaterials both experimentally and computationally. We highlight herein some of the …

Six Sigma Process Improvement For Ksu Mailroom, Raven Pierson, Kailyn Mcleod, Brett Teems, Gabi Tawil

Senior Design Project For Engineers

The Kennesaw State University mailroom on the Marietta Campus is utilized by faculty and students to receive letter mail alongside packages that are delivered directly to the university. The team decided to enhance the mailroom and their way of processing mail and serving their customers. For the best interest of the mailroom, the team went on to implement a Locker System, Appointment/ Card Reader System, as well as office space improvements guided by the Lean Six Sigma concept of 6s. As a result of putting forward these ideals, it was apparent that students and faculty were supportive of the Locker …

Delivery Route Optimization, Adam Esasky, Mark Iltsenko, Sean Jones, Matthew Tharakan

Senior Design Project For Engineers

“The Carrier Company” is a service that delivers motorcycle parts all over South East, US. They have over 38 routes that each have a driver designated to deliver products to their clients twice a day. The majority of the company’s time and expenses are focused on the delivery of the products to their respected clients. Recently, due to COVID-19, the Carrier Company has had a number of issues with new drivers not knowing the routes and in turn taking too long to deliver the products. The Carrier Company has asked Team Dive Fast to work on developing a program that …

Preparation And Characterization Of "Water-In-Salt" Polymer Electrolyte For Lithium-Ion Batteries, Xu Hou, Xin He, Jie Li

Journal of Electrochemistry

Since the development of wearable and flexible electronic products, the demand of flexible energy storage devices such as batteries and super capacitors is in urgent. To enhance the safety and cycling stability for flexible lithium-ion batteries, “water-in-salt” polymer electrolyte was prepared by introducing 21 mol·kg^-1 LiTFSI electrolyte into cross-linked polyacrylamide (PAM) after freeze-drying. A great amount of holes with the size range of 10 ~ 20 μm can be found on the surface and in the bulk of polyacrylamide, which is benefited from the freeze-drying process and acts as a great support for the electrolyte uptake. The “water-in-salt” polymer …

Electrochemical Surface-Enhanced Raman Spectroscopic Studies On Nickel Ultramicroelectrode, Li-Wen Wu, Wei Wang, Yi-Fan Huang

Journal of Electrochemistry

Nickel (Ni) electrodes are widely used in electrochemical researches. Understanding electrochemical processes on Ni electrodes through in-situ characterization of adsorbed species on their surfaces is helpful for rational optimization and application of Ni electrochemistry. Microelectrochemical surface-enhanced Raman spectroscopy (μEC-SERS) combines the mass transfer feature of ultramicroelectrode with high-sensitivity characterizations of molecular structures, which is a powerful method for studying Ni electrochemistry on polarization and non-equilibrium conditions. The key point of performing μEC-SERS is to make a SERS-active Ni ultramicroelectrode.
Here, we demonstrate a method of preparing a SERS-active Ni ultramicroelectrode through electrochemical deposition of several atomic layers of …

A Numerical Circuit Simulation Study Of High Voltage, Multi-Pulse Transmission Lines And Spark Gap Switches, Joe Ming Ju Chen

Electrical and Computer Engineering ETDs

The design and development of high voltage, multi-pulse transmission line generators is of high interest for linear accelerator and other pulse power applications. Los Alamos National Laboratory and L3 Applied Technologies are in development and testing of a multi-pulse series pulse forming water transmission line system dubbed the Series Pulse-Line Integrated Test Stand (SPLITS). The system consists of up to four water lines in series charged by a Marx bank of total capacitance and voltage of 39nF and -600kV, respectively, to produce multiple 120ns, -300kV pulses on a matched resistive load of 5.5 . There is a need for a …

Realtime Sensor For Detecting Gallium Infiltration Attack, Peter Holtmann

Undergraduate Research Conference at Missouri S&T

The proposed research is to create a real-time sensor for detecting aluminum degradation due to gallium infiltration attacks, specifically in military vehicles and structures. Gallium acts as a poison to aluminum, leading to catastrophic failures of structural integrity. The proliferation of educational material on this subject raises security concerns for the United States Military, where nearly all structures utilize aluminum due to its high-strength, light-weight profile. Utilizing Fiber-Bragg Grating (FBG) sensors and machine learning techniques, this research aims to develop a real-time sensor to detect these attacks.

Behavioral Science Can Increase Zipper Merge Usage, Maria Galbraith

Undergraduate Research Conference at Missouri S&T

Research demonstrates that zipper merges (or late merges), under heavy traffic conditions, are safer and faster than a traditional early merge. In implementation, zipper merges can be less efficient due to a lack of compliance on the part of drivers, often more accustomed to early merging. Behavioral science has been applied to a many transportation-related challenges, such as increasing seat belt usage and decreasing drinking and driving but has not yet been applied to the zipper merge. We have identified six relevant behavioral science strategies including (1) social norms, (2) appeals to reason, (3) emotional appeals, (4) humor, (5) memory …

Thermal Modeling Of Li-Ion Batteries Using Sp+3d Model, Derrick Barger

Undergraduate Research Conference at Missouri S&T

An ideal battery model must gather sufficient electrochemical data about the system while remaining being computationally efficient. To prevent failure from thermal runaway, understanding the thermal characteristics of a battery is essential.

To achieve this, we have developed a single particle (SP) model, a simplified but accurate approach to battery modeling, and compared this to a previously designed 3D model. After validating the battery electrochemistry, equations were introduced to calculate the heat generation with a coupled 3D heat transfer component to provide data on the cell temperature. This same model was used to simulate a multi-cell pack.

The results indicate …

Feedstock Processing For Extraterrestrial Metal Additive Manufacturing, Japheth A. Hayman

Honors Capstone Projects and Theses

No abstract provided.

Sustainable Water Treatment Systems: A Direct Potable Proposal, Kayla Alsup, Kayla E. Alsup

Honors College Theses

A common need among all people is water—we cannot survive without it. And yet, all around the world, achieving a high quality of drinking water is a constant struggle. This water crisis is brought on by many different factors. Some are natural, such as droughts and flooding, but as the effects of climate change continue to reveal themselves, some areas are becoming drier, while other areas are experiencing less predictable and harsher weather patterns.

Our current approach towards water is not sustainable, and we are starting to see that in both under-developed and developed countries alike. Indiscriminate use of water …

Optimized Automated Checkout Process For Major Food Retailers, Matthew Ritchie, Tiana Longino, Daniel Garza, Alp Katranci

Senior Design Project For Engineers

There has been a push for automation in countless industries to save time and money, increase customer satisfaction, increase customer purchasing options, increase efficiency, and reduce waste. This design project will focus on optimizing the automated checkout process at major grocery retailers. The goal of the design is to reduce customer wait times at the checkout line, thus increasing customer satisfaction and save the retailer cashier expenses. The design was created using the DMAIC (define, measure, analyze, improve, control) process tool. Customers were surveyed to define if there was a problem, and 52.5% of customers felt the wait times at …

Characterizing Students’ Engineering Design Strategies Using Energy3d, Jasmine Singh, Viranga Perera, Alejandra Magana, Brittany Newell

Discovery Undergraduate Interdisciplinary Research Internship

The goals of this study are to characterize design actions that students performed when solving a design challenge, and to create a machine learning model to help future students make better engineering design choices. We analyze data from an introductory engineering course where students used Energy3D, an open source computer-aided design software, to design a zero-energy home (i.e. a home that consumes no net energy over a period of a year). Student design actions within the software were recorded into text files. Using a sample of over 300 students, we first identify patterns in the data to assess how students …

Detection And Aggregation Of Listeria Monocytogenes Using Polyclonal Antibody Gold-Coated Magnetic Nanoshells Surface-Enhanced Raman Spectroscopy Substrates, Robert T. Busch, Farzia Karim, Yvonne Sun, H. Christopher Fry, Yuzi Liu, Chenglong Zhao, Erick S. Vasquez

Chemical and Materials Engineering Faculty Publications

Magnetic nanoshells with tailored surface chemistry can enhance bacterial detection and separation technologies. This work demonstrated a simple technique to detect, capture, and aggregate bacteria with the aid of end-functionalized polyclonal antibody gold-coated magnetic nanoshells (pAb-Lis-AuMNs) as surface-enhanced Raman spectroscopy (SERS) probes. Listeria monocytogenes were used as the pathogenic bacteria and the pAb-Lis-AuMNs, 300 nm diameter, were used as probes allowing facile magnetic separation and aggregation. An optimized covalent bioconjugation procedure between the magnetic nanoshells and the polyclonal antibody was performed at pH six via a carbodiimide crosslinking reaction. Spectroscopic and morphological characterization techniques confirmed the fabrication of stable pAb-Lis-AuMNs. …

Bibliometric Analysis Of Particle Swarm Optimization Techniques Used To Enhance Low-Energy Adaptive Clustering Hierarchy Protocol For Wireless Sensor Networks, Anupkumar M. Bongale Dr.

Library Philosophy and Practice (e-journal)

Wireless Sensor Network (WSN) is a network of tiny wireless sensor nodes. The sensor nodes sense information and transmit the sensed information to a data collection point known as Base Station. WSNs have gained massive popularity due to their incredible benefits, and active research is ongoing for the past two decades. The primary concern with WSN is that the sensor operates on a limited power supply. Due to the nature of applications of WSNs and the hostile environment where the sensors are deployed, providing unlimited power or energy supply is not an option. Hence, the research work mainly focuses on …

Editors’ Choice-Examining Performance And Durability Of Anion Exchange Membrane Fuel Cells With Novel Spirocyclic Anion Exchange Membranes, Ami C. Yang-Neyerlin, Samantha Medina, Kelly M. Meek, Derek J. Strasser, Cheng He, Daniel M. Knauss, Mustain E William, Svitlana Pylypenko, Bryan S. Pivovar

Faculty Publications

A series of spirocyclic copolymer membranes with varying ion exchange capacities (IECs) were investigated to probe the impact of polymer properties on in situ fuel cell performance and stability. In-situ electrochemical tests and post-mortem electron microscopy analysis of cross-sectioned membrane electrode assemblies (MEAs) have been combined with voltage loss breakdown analysis to evaluate the performance and degradation of different MEAs, and to probe the catalyst morphology and electrode structure at different stages of operation. Voltage loss breakdown results show that membrane degradation and kinetic losses played only a minor role in observed performance degradation and that performance losses were primarily …

Electrostatic Levitation: An Elegant Method To Control Mems Switching Operation, Mohammad Mousavi, Mohammad Alzgool, Shahrzad Towfighian

Mechanical Engineering Faculty Scholarship

This paper investigates the characteristics of a micro-switch that uses two side electrodes to open a normally closed switch. The side electrodes surround the xed electrode in the well-known gap-closing electrode configuration. The side electrodes can open a closed switch and be tuned to respond appropriately to outside forces. The combined electrode system dramatically improves the control of a standard gap-closing electrode configuration. In conventional switches, a DC voltage above a certain value closes the switch. To re-open the switch, the voltage difference is reduced to peel o the moving electrode. Currently the contact area is carefully designed to avoid …

Highly Branched Polymers Based On Poly(Amino Acid)S For Biomedical Application, Marisa Thompson, Carmen Scholz

PRC-Affiliated Research

Polymers consisting of amino acid building blocks continue to receive consideration for biomedical applications. Since poly(amino acid)s are built from natural amino acids, the same building blocks proteins are made of, they are biocompatible, biodegradable and their degradation products are metabolizable. Some amino acids display a unique asymmetrical AB2 structure, which facilitates their ability to form branched structures. This review compares the three forms of highly branched polymeric structures: structurally highly organized dendrimers, dendrigrafts and the less organized, but readily synthesizable hyperbranched polymers. Their syntheses are reviewed and compared, methods of synthesis modulations are considered and variations on their traditional …

Highly Branched Polymers Based On Poly(Amino Acid)S For Biomedical Application, Marisa Thompson, Carmen Scholz

PRC-Affiliated Research

Polymers consisting of amino acid building blocks continue to receive consideration for biomedical applications. Since poly(amino acid)s are built from natural amino acids, the same building blocks proteins are made of, they are biocompatible, biodegradable and their degradation products are metabolizable. Some amino acids display a unique asymmetrical AB2 structure, which facilitates their ability to form branched structures. This review compares the three forms of highly branched polymeric structures: structurally highly organized dendrimers, dendrigrafts and the less organized, but readily synthesizable hyperbranched polymers. Their syntheses are reviewed and compared, methods of synthesis modulations are considered and variations on their traditional …

Project Blipper, Peter Jacobs, Preston Delaware, Ryan Foster

Senior Design Project For Engineers

This project was sponsored by Clorox to design and create an automatic bottle-unscrambling system for possible implementation at their bottling plant in Chile. The objective was to use a robotic arm to unscramble bottles from an incoming conveyor belt and place them upright on an outbound conveyor belt. Throughout the research, design, and testing of solutions for this project, several design alternatives were found for each discipline, and will be presented to Clorox so that they can make an informed decision for how and if they want to move forward with implementation of this project.

The project was split into …

Aviation English In A Bilingual Context: Bilingual Spanish-English Pilots, Seneca Doty

Honors Projects

The purpose of this study is to investigate the use of English and Spanish in the applied context of aviation by researching pilot experiences in the cockpit within the register of aviation English. This study investigates pilot’s in-flight experiences in relation to language proficiency in the hopes of improving future standards of communication. Expounding on previous research with a focus on native Spanish speaking pilots, this research utilizes a Likert scale survey and demographic assessment to evaluate proficiencies inside the cockpit of bilingual Spanish-English participants. By determining each pilot´s use of English outside of the workplace as well as how …

Agent-Based Coordinated Control Of Power Electronic Converters In A Microgrid, Maryam Nasri, Hebert L. Ginn Iii, Mehrdad Moallem

Faculty Publications

This paper presents the implementation of an agent-based architecture suitable for the coordination of power electronic converters in stand-alone microgrids. To this end, a publish-subscribe agent architecture was utilized as a distributed microgrid control platform. Over a distributed hash table (DHT) searching overlay, the publish-subscribe architecture was identified based on a numerical analysis as a scalable agent-based technology for the distributed real-time coordination of power converters in microgrids. The developed framework was set up to deploy power-sharing distributed optimization algorithms while keeping a deterministic time period of a few tens of milliseconds for a system with tens of converters and …

Spontaneous Formation Of Multilayer Refractory Carbide Coatings In A Molten Salt Media, Loic Constantin, Lisha Fan, Mathilde Pouey, Jérôme Roger, Bai Cui, Jean-François Silvain, Yongfeng Lu

Department of Electrical and Computer Engineering: Faculty Publications

Refractory materials hold great promise to develop functional multilayer coating for extreme environments and temperature applications but require high temperature and complex synthesis to overcome their strong atomic bonding and form a multilayer structure. Here, a spontaneous reaction producing sophisticated multilayer refractory carbide coatings on carbon fiber (CF) is reported. This approach utilizes a relatively low-temperature (950 °C) moltensalt process for forming refractory carbides. The reaction of titanium (Ti), chromium (Cr), and CF yields a complex, high-quality multilayer carbide coating composed of 1) Cr carbide (Cr₃C₂), 2) Ti carbide, and 3) Cr₃C₂ layers. …

Sorption-Spectrometric Determination Of Nickel By Monoammonium Salt Of Glycirrizic Acid, Ugilay Abdurakhmanova, Khabibjon Kushiev

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to develop a sensitive, selective and rapid method for the determination of nickel ions using the monoammonium salt of glycyrrhizic acid as an analytical reagent. There obtained IR spectra of the nickel diglycyrrhizinate complex. A simple and express spectral method for determination of the nickel ion is presented. The optimal conditions for the determination of the nickel ion are found. Under optimal conditions, a gradual graph was drawn up, which is linear in the concentration range for nickel of 20.0–40.0 μg/25 ml, the composition of the complex of nickel with the monoammonium salt …

Features Of Chloridizing Roasting Of Almalyk Mining Metallurgical Combinate Wastes, Malokhat Atamuratova, Dildora Khakimboeva, Khasan Sharipov, Zuhra Kadirova, Tulkin Shakarov

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim to develop a comprehensive technology for processing Almalyk Mining Metallurgical Combinate (AMMC) wastes, the influence of chloride additives on the copper and zinc chloride volatilization process is considered. The relationship between presence of the calcium, potassium and sodium chlorides chlorinating additive on the copper and zinc chlorides sublimation from the AGMK wastes at roasting temperatures up to 700-1000˚C was established.

The Role Of The 2,7-Dinitroso-1,8-Dihydroxynaphthalene-3,6-Disulfonic Acid Reagent In Determining The Thorium Ion (Iv), Nigora Qutlimurotova, Salohiddin Mahmadoliyev, Khabibullo Todjimukhamedov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim is to develop a method for the amperometric determination of thorium (IV) ion with 2,7-dinitroso-1,8-dihydroxynaphthalene-3,6-disulfoxyl reagent. Methods of amperometric determination of thorium by solution of 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid on different acid-base properties of background electrolytes and buffer mixtures are considered. The half-wave potential of new reagent was found by logarithmic analysis equal 0.72 V at pH 2.82, which once again indicates on the irreversibility of the process of electrooxidation of the studied organic reagent in used acid-base medias. The conditions for amperometric titration of thorium are optimized, and the influence of outside accompanying metals on the shape of curves …

Synthesis Of Some N-Oxides Of Pyridylacethylene Amines Based On 2-Methyl-5-Ethynylpyridine, Abduvakhab Ikramov, Odiljon Ziyadullayev, Adkham Khamidjanov, Shavkat Bojariev, Davron Khandamov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to study the reaction of 2-methyl-5-ethynylpyridine N-oxide with some aliphatic and aromatic amines to obtain N-oxides of pyridylacetylenic amines. 2-Methyl-5-ethylpyridine converted to 2-methyl-5-vinylpyridine by dehydrogenation, and 2-methyl-5-ethynylpyridine obtained by bromination and dehydrobromination. 2-methyl-5-ethynylpyridine N-oxide synthesized by oxidation of 2-methyl-5-ethynylpyridine with perhydrol in acetic anhydride. The synthesis of N-oxides of pyridylacetylenic amines by the Mannich reaction carried out. The effect of the solvents: methanol, ethanol and n-dioxane, the catalyst, and the reaction time on the yield of the final product studied. The structure and composition of the synthesized PAA N-oxides were established using IR and …

The Role Of Hydrogen Bonds In Diluted Ethanol Solutions Of Cyclohexane And Dimethylformamide, Dilbar Bozorova, Shukur Gofurov, Mavlonbek Ziyayev, Dildora Mirtojiyeva, Odina Ismanova, Oksana Ismoilova

CHEMISTRY AND CHEMICAL ENGINEERING

The refractometric method and Fourier transform infrared spectroscopy were used to determine the optical features of the concentration characteristics of diluted ethanol solutions of cyclohexane and dimethylformamide. It was found for the first time that at some concentrations the hydrogen bond is stronger than for a pure ethanol solution. The first maximum of the excess refractive index of solutions is formed at a concentration of 0.02 mole fraction of cyclohexane and dimethylformamide, which is in good correlation with IR spectroscopy, indicating the largest number of formed hydrogen bonds.

Synthesis Of Superabsorbing Hydrogels Based On Starch Copolymers, Baxodir Kholnazarov, Khayit Turaev, Abdulakhat Jalilov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to synthesize highly swellable superabsorbent hydrogels based on starch copolymers. To achieve this goal, mineral-containing superabsorbent hydrogels based on starch, acrylamide, binder and initiator were synthesized. The optimal synthesis conditions were determined and studies were carried out on the influence of the molar ratios of the starting substances on the composition and physicochemical properties of the synthesized superabsorbent hydrogel. In the course of research, the optimum copolymerization temperature was 60 ° C, and the reaction time was 3 hours.

As a result of the study, a superabsorbent hydrogel based on starch, acrylamide and bentonite …

Synthesis Of Thiocol Oligomer Based On Sodium Tetrasulphide, Epichlorhydrine And Ammonium Phosphate, Bakhtiyor Normurodov, Khayit Turaev, Abdulakhat Jalilov, Sherzod Kasimov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this study is the synthesis and study of thiokol oligomer NEP-12 brand based on sodium tetrasulfide, epichlorohydrin and ammonium phosphate, which is intended for use as a main component of Thiokol sealant. To achieve this goal, a thiokol oligomer based on sodium tetrasulfide, epichlorohydrin, and ammonium phosphate was synthesized and investigated, and the optimal conditions for the synthesis of a thiokol oligomer were determined. Research has been carried out on the influence of the molar ratios of the starting substances on the composition and physicochemical properties of the synthesized thiocol oligomer. The optimum polycondensation temperature was taken …