Engineering Commons^™

Structure And Stability Of Ag-Ir Bimetallic Catalysts Prepared By Electroless Deposition And Synthesis And Performance Of High Selectivity Movnbsbteox Mixed Oxides For Oxidative Dehydrogenation Of Ethane, Mozhdeh Parizad

Theses and Dissertations

Improvements in industrial thermal conversions can be realized through comprehensive catalytic studies, where enhanced catalyst stability and activity are desired. Catalyst performance can be greatly affected by structural changes at high temperatures. In the case of supported Ag-Ir particles, the surface free energy (SFE) can determine preferred arrangement of the component metals. The well-established methods of strong electrostatic adsorption (SEA) and electroless deposition (ED) have been used to synthesize highly-dispersed Ag/Ir on different alumina supports (δ,θ-Al2O3 and γ-Al2O3). Surface thermodynamics dictate that the Ir-Ag system should conform to minimize free energy resulting in a low SFE Ag layer localized on …

Development Of A Multi-Scale Mechano-Electrochemical Battery Model, Drew J. Pereira

Theses and Dissertations

As the automotive industry moves towards large format electric vehicles, such as trucks and SUVs, the need for highly efficient, energy-dense electrodes rapidly increases. Several promising active materials have been studied and proposed, however, many of these materials undergo significant volume change upon lithiation and de-lithiation. Cell and pack designers struggle to understand and predict how active material volume change at the particle scale will affect mechano-electrochemical behavior on the electrode, cell, and pack scales. Additionally, many of these active materials suffer in their cycle life due to a mechanically-driven degradation of the electrode matrix. Therefore, the focus of this …

Adopting A Risk-Intelligent Approach To Digital Transformation: Four Traits Of Digitally Mature Organisations, Clarence Goh, Gary Pan, Poh Sun Seow, Yuanto Kusnadi, Seah Gek Choo, Cheryl Lim

Research Collection School Of Accountancy

Our objective is to understand how digitally mature organisations are managing the GRC aspects of their digital transformation programmes, and identify any traits or behaviours that could inform the development of best practices.

Empirical Modeling Of Tilt-Rotor Aerodynamic Performance, Michael C. Stratton

Mechanical & Aerospace Engineering Theses & Dissertations

There has been increasing interest into the performance of electric vertical takeoff and landing (eVTOL) aircraft. The propellers used for the eVTOL propulsion systems experience a broad range of aerodynamic conditions, not typically experienced by propellers in forward flight, that includes large incidence angles relative to the oncoming airflow. Formal experiment design and analysis techniques featuring response surface methods were applied to a subscale, tilt-rotor wind tunnel test for three, four, five, and six blade, 16-inch diameter, propeller configurations in support of development of the NASA LA-8 aircraft. Investigation of low-speed performance included a maximum speed of 12 m/s and …

The Professional Constructor, Full Issue, Volume 46, Number 02

The Professional Constructor

No abstract provided.

Aessa Young Professionals Forum Webinar “Technologies And Skills That Will Gearup The Aerospace Industry Post Pandemic” - A Global Perspective With An Emphasis On South Africa October 2021, Linda Vee Weiland

Publications

A webinar presentation for AeSSA Young Professionals.

Perovskite Film Formation For Solar Cell Absorbers: Effects Of Substrate Modification, Mirra M. Rasmussen, Kyle M. Crowley, Ina T. Martin

Student Scholarship

As perovskite solar cell efficiencies have risen rapidly, practical constraints have made durability a critical concern. Whereas much attention has been paid to the development of the perovskite absorber layer, the charge transport layers can also be engineered to better the performance and stability of the device. This work uses the molecular modifier bromopropyltrimethoxysilane (BPTMS) to alter the interface between indium tin oxide (ITO, a common thin film solar cell transparent electrode) and methylammonium lead iodide (MAPbI3, a common perovskite absorber) to improve the morphology and stability of the perovskite absorber film. The substrate, molecular modifier, and perovskite film were …

Quantifying And Elucidating The Effect Of Co2 On Aemfcs, Yiwei Zheng

Theses and Dissertations

Anion exchange membrane fuel cells (AEMFCs) have recently received significant attention as a future high efficiency, environmentally friendly energy conversion device. This attention is due to the potential advantages that AEMFCs can offer compared the much more common, and commercialized, proton exchange membrane fuel cells (PEMFCs) – most notably lower cost. However, there are several remaining roadblocks for the AEMFC technology to be widely adopted, such as: i) the stability of the anion exchange membranes (AEMs) and anion exchange ionomer (AEIs); ii) the development of highly active catalysts with either low platinum group metal (PGM) loading or catalysts that are …

The Role Pde11a4 Signaling And Compartmentalization In Social Behavior, Kaitlyn Pilarzyk

Theses and Dissertations

People tend to be social by nature. Being socially connected not only helps people live longer and healthier lives, but being an engaged and contributing member of society strengthens our communities overall. Maintaining intact social behaviors is key to maintaining this wellbeing, with disruptions negatively affecting both mental and physical health. Indeed, social isolation and feelings of loneliness can significantly increase a person’s risk of premature death, heart disease, and stroke as well as depression, anxiety, suicide, and dementia. Maintaining the ability to create and store social memory with age is, therefore, key to maintaining proper social behaviors. Unfortunately, individuals …

Impact Of Acetylcholine On Internal Pathways To Basal Amygdala Pyramidal Neurons, Tyler Daniel Anderson-Sieg

Theses and Dissertations

The basolateral nuclear complex of the amygdala (BNC) – consisting of the lateral (LA), basolateral (BL), and basomedial nuclei (BM) – detects salient environmental stimuli (cue-detection) and motivates appropriate behavioral responses to their implied meaning (cue-guided behavior) via a precise pattern of internal circuitry. Glutamatergic signals representing environmental stimuli enter the LA and split into parallel streams that activate pyramidal neurons (PNs) in the anterior and posterior BL (BLa and BLp), which putatively mediate negative and positive emotions, respectively. The BL is the most densely innervated target of the cholinergic basal forebrain (CBF) and ACh transients (phasic ACh) in cortex …

Impact Of Graphene On Microstructure And Compressive Strength Of Cement Mortars Utilizing Two Different Dispersion Methods, Elhussien Khaled Elbatanouny

Theses and Dissertations

Carbon-based nanomaterials are currently used to reinforce cement-based composite materials based on their superior properties. This study investigates the mechanical property (compressive strength) of cement mortars incorporated with pristine graphene. The dosages of graphene materials used were 0.01%, 0.02%, 0.03%, and 0.04% by weight of cement. Moreover, this study compares two dispersion techniques: ultrasonication with surfactant coating and mechanical blending with surfactant coating to promote the use of graphene in cement mortars. A commonly used polycarboxylate superplasticizer Sika-Viscocrete Ultra 2100, was used as a dispersant agent (surfactant) of graphene with a surfactant to graphene weight ratio of 9 to 1. …

Recent Advances In Catalytic Ethylene Epoxidation: Synthesis, Characterization, And Evaluation, Benjamin Thomas Egelske

Theses and Dissertations

First synthesized in 1859 by French chemist Charles-Adolphe Wurtz, ethylene oxide (EO) is produced from the direct epoxidation of ethylene and molecular oxygen over a low surface area α-Al₂O₃ supported silver (Ag) catalyst [1-6]. With a production capacity over 35 Mt/year, EO is the largest chemical by volume synthesized from a heterogeneously catalyzed process and is used in the production of ethylene glycol, ethoxylates, and ethanolamines [6, 7]. State-of-the-art catalyst formulations contain high loadings of Ag, typically 12-30wt%, required to recover activity in the presence of promoter elements which increase EO selectivity from ~75% for unsupported Ag to 80% for …

Identification Of Structural Signature Responses From Response Time Histories Using B-Spline Impulse Response Techniques, Shadhan Ahmed Al Kharusi

Theses and Dissertations

Structure Health Monitoring (SHM) is an essential practice for ensuring the safety of people and the structures itself. For this purpose, variety of global and local damage detection methods have been used to investigate damages. Global damage detection focus on identifying damage in early stages while local damage detection related to damage location, severity, and prediction of the remaining of the structure. Any damage in structure leads to a change to the properties and characteristics of the dynamic response.

Existing methods uses modal-based and response-based for damage detection. Both have several shortcoming associate with sensitivity of the damage and measurement …

Predicting Pavement Structural Condition Using Machine Learning Methods, Nazmus Sakib Ahmed

Theses and Dissertations

State departments of transportation recognize the need to incorporate pavement structural condition in their pavement performance models and/or decision processes used to select candidate projects for preservation, rehabilitation, or reconstruction at the network level. However, pavement structural condition data are costly to obtain. To this end, this paper develops and evaluates the effectiveness of two machine learning methods, Random Forest (RF) and eXtreme Gradient Boosting (XGBoost), for predicting a flexible pavement’s structural condition. The aim is to be able to predict whether a pavement section’s structural condition is poor or not based on Annual Average Daily Traffic (AADT), truck percentage, …

Leveraging Digital Transformation To Build The Technology Of Tomorrow Using Yesterday’S Equipment, Evan Barnett

Theses and Dissertations

Today’s industry sectors are filled with machines developed years ago. Healthcare, manufacturing, sustainment operations, and many others have equipment that may be reliable, but lacks certain capabilities that the newest technology delivers. The digital environment is becoming a necessity for users who want greater insights into how to improve their processes. A solution to this problem would be to purchase the newest equipment that contains robust measures to generate, collect, and analyze data. However, this solution may not be financially feasible for some and for others may sacrifice machine downtime and reliability. To combat these issues, this research focuses on …

Development Of A First-Generation Prototype Laboratory System For Rail Neutral Temperature Measurements, Ellie Yi-Hsien Chao

Theses and Dissertations

Modern railway tracks worldwide standardize the use of Continuous Welded Rail (CWR) due to its ability to prevent disadvantages associated with rail joints in a track. CWR is laid when the rail is free of thermal stresses, also known as Rail Neutral Temperature (RNT). RNT is controlled in the CWR installation procedure; however, over time, the temperatures deviate from the RNT. The deviation causes significant thermal stresses introduced in the longitudinal direction of the rail, leading to potential failures such as pull-apart and buckling, causing track integrity and safety of train operation. The most significant potential failure is track buckling …

Hydrodeoxygenation Of Biomass Derived Sugar Alcohols To Platform Chemicals Using Heterogeneous Catalysts, Blake Macqueen

Theses and Dissertations

This work set out to investigate biomass derived sugar alcohol upgrading via the removal of oxygen and hydroxyl groups via the hydrodeoxygenation reaction utilizing heterogeneous catalysts. The importance of reaction conditions, catalyst meal loadings, catalyst structure and properties were probed using techniques such as design of experiments, and spectroscopic techniques including Raman and DRIFTS. The state of the art simultaneous hydrodeoxygenation (S-HDO) catalyst ReO_x-Pd/CeO₂ was investigated and optimized for various sugar alcohol substrates. The kinetics and associated mass transfer were also investigated to give further insight into the reaction over the ReO_xPd/CeO₂ catalyst.

First, …

Development Of Acoustic Metamaterial Noise Barriers And Simultaneously Harvesting Energy Using Smart Materials, Fariha Mir

Theses and Dissertations

In our surroundings abundant energy, we either feel through component vibration or hear noises from acoustic sources. Harvesting these unused and untapped green energy in the form of ambient vibration, and acoustic sounds is an emerging field of research in recent years. Utilization of the energy within a wide band of the frequency spectrum originated from the vibrational sources alone stands as one of the most promising ways to power small electronic devices, smartphones, local structural health monitoring sensors, home, and workshop appliances. These abundant sources of green energy are available in almost all the engineering industries, workshops, manufacturing facilities, …

Development Of A Rapid Compression And Expansion Machine To Characterize The Ignition Propensity Of Multi-Component Liquid Fuels, Jonathan Joseph Morreale

Theses and Dissertations

Combustion has been the primary source for energy production, whether it be from coal, oil, or natural gas, for a very long time. With increasing population and therefore an increased demand for energy, efficiency is becoming a concern. In order to increase efficiency, engines have been downsized and compression ratios have been increased. In doing so, problems have arisen such as knock and low speed pre-ignition. To better understand these problems, an investigation into how fuels ignite at higher pressures is necessary. Real fuels are comprised of multiple components that exhibit significant variations in their own physical and chemical characteristics. …

Ultrawide Bandgap Algan-Channel Metal Oxide Semiconductor Heterostructure Field Effect Transistors With High-K Gate Dielectrics, Md Abu Shahab Mollah

Theses and Dissertations

Ultra-wide Band Gap (UWBG) (E_G > 3.4 eV) Al_xGa_1-xN channel devices are promising candidates for compact next-generation power electronics due to the scaling of the breakdown field with alloy composition. The huge opportunity in consumer electronics is the major driving force behind the recent developments of UWBG AlGaN-channel HEMTs. One of the most critical issues limiting the device performance at high power level is device degradation primarily caused by gate leakage current. Use of SiO₂ gate insulator is a standard method to suppress gate leakage but it causes threshold voltage shift towards more negative requiring …

Searching Extreme Mechanical Properties Using Active Machine Learning And Density Functional Theory, Joshua Ojih

Theses and Dissertations

Materials with extreme mechanical properties leads to future technological advancements. However, discovery of these materials is non-trivial. The use of machine learning (ML) techniques and density functional theory (DFT) calculation for structure properties prediction has helped to the discovery of novel materials over the past decade. ML techniques are highly efficient, but less accurate and density functional theory (DFT) calculation is highly accurate, but less efficient. We proposed a technique to combine ML methods and DFT calculations in discovering new materials with desired properties. This combination improves the search for materials because it combines the efficiency of ML and the …

Effect Of Crystal Size On The Failure Mechanics Of Polymer Bonded Explosives, Chizoba Onwuka

Theses and Dissertations

Polymer bonded explosives (PBXs), typically constitute 80-95% of energetic crystals and 5-20% of a soft polymer binder, are widely used in extreme loading conditions such as rocket propellants and explosive munitions because of their high performance and low sensitivity. The particle size of crystals has a significant effect on the mechanical properties of most polymer particulate composites.

In the study, the effect of particle size on the deformation behavior of PBX under dynamic loading is investigated. The study involves testing polymer bonded sugar (PBS) samples, a well-known mechanical simulant of PBXs, with four different crystal sizes: coarse, intermediate, fine and …

Catalytic And Non-Catalytic Methods For Hydrocarbon Upgrading, Valorization, And Pollutant Control, Michael Morgan Royko

Theses and Dissertations

This work investigates catalytic and non-catalytic oxidative chemical upgrading and pollutant remediation techniques to responsibly utilize hydrocarbon feedstocks with existing infrastructure as the transition to more renewable and cleaner feedstocks for energy generation are developed. These technologies include oxidative dehydrogenation of ethane, development of magnetically separable catalysts to reduce carbon monoxide emissions during biomass upgrading as well as the subsequent use of the upgraded biomass for partial coal replacement, and electrochemical treatment of a washcoat free wire mesh supported catalyst to reduce carbon monoxide emissions in combustion exhaust.

First, doping of secondary metals in M1/M2 catalysts for oxidative dehydrogenation of …

Fate And Transport Of The Microbiome In Built Environments, Dahae Seong

Theses and Dissertations

Buildings are complex ecosystems evolving continuously. Indoor components such as occupants, ventilation system, and building structures influence the microbiome. To shed light on how the microbial population in a building will respond to such a fluid system, the fundamental interactions between microbes and the indoor ecosystem must be understood. Buildings are being designed as air-tight structures to save energy; however, this could lead to degradation of indoor air quality through indoor sources of contaminants and/or containment of pollutants in the room or introduce outdoor pollutants indoors depending on the ventilation conditions. In addition, transmission of infectious microbes in indoors threaten …

Insights Into Rational Catalysts Synthesis, Abolfazl Shakouri

Theses and Dissertations

Atomically distributed metal centers with maximized atom utilization efficiency called single-atom catalysts (SACs) have attracted significant attention in catalysis. SACs with the advantages of both homogeneous and heterogeneous catalysts have been rising as a new frontier in the field of catalysis. New catalytic technologies are ever-growing, considering 90% of all chemical processes employ catalysts, securing modern society’s sustainable future. A classical field in catalysis has been dedicated to catalysis by supported metals. Recently, a vast effort has been devoted to smaller catalyst particles where size is restricted to a single atom on a surface. Single atoms supported or embedded on …

Shape-Selective Silver Catalysts For Ethylene Epoxidation, Kaveh Shariati

Theses and Dissertations

Epoxidation of ethylene with oxygen over promoted silver catalyst is one of the most important examples of heterogeneous catalysis to date with a multi-billion dollar annual market. Ethylene oxide (EO) can be used directly as a sterilizer, disinfectant, and fungicide, or as an intermediate chemical for producing ethylene glycol, detergents, antifreeze, polyesters, as well as a variety of other commercial chemicals. Thus, ethylene oxide is known as one of the highest volume chemicals produced in the chemical industry, accounting for approximately 40-50% of the total value of organic chemicals produced by heterogeneous oxidation. Considering the application of EO in detergents …

Preparation, Characterization And Evaluation Of Rationally Designed Catalysts By Electroless Deposition, Wen Xiong

Theses and Dissertations

In heterogeneous catalysis, it is a proven factor that the surface-specific activity and the catalyst selectivity strongly depends on the active sites which are determined by the composition, size, and shape of the particle. For structure-sensitive reactions favored by specific surface sites, such as corners, steps, or edges, TOF and selectivity can be greatly changed by the size of catalyst particles since the active site distribution will change with the size of the catalysts. Usually, metal particles are synthesized by two methods in industry, namely precipitation and impregnation, which often exhibit a broad size distribution. The grand challenge of colloidal …

A Novel Model To Study Adipose-Derived Stem Cell Differentiation, Austin N. Worden

Theses and Dissertations

The use of three-dimensional (3D) culture systems (hydrogels) and adipose-derived stem cells (ADSCs) in regenerative medicine to advance early-stage investigation and modeling of the mechanisms of diseases, treatments, targets, etc. has recently increased. ADSCs, specifically, are utilized due to their innate programming during embryogenesis and in adult tissues in addition to their ability to differentiate into mesodermal, endodermal, and ectodermal cell-specific lineages. Of importance is that these advancements do not involve a model specimen (i.e. mice or rats) and simulate the numerous conflicting signals a migrating cell is exposed to in vivo such as chemokines, extracellular matrix (ECM), growth factors, …

Implementation Of Stereo Digital Image Correlation For In-Plane Strain Measurements To Quantify The Anisotropic Behavior, Plastic Flow, And Strain Hardening Of Extruded Aluminum Alloy, Farzana Yasmeen

Theses and Dissertations

The efficient use of metals is important in various industries, including aerospace, automotive, and energy systems. In each case, the type and range of combined loading conditions can be quite different. The approaches to stress analysis of such complex engineering components and assemblies often are limited to elastic conditions. For those cases where components are relatively thin, elastic-plastic conditions are present; there is continuing interest in assessing the accuracy of analytic and computational models for combined loading conditions. In such cases, experiments performed with axial and shear loads (e.g., tension-torsion) provide baseline data regarding the relationship between applied stresses and …

Application Of Digital Transformation In The Water Desalination Industry To Develop Smart Desalination Plants, Ibrahim Yousif

Theses and Dissertations

Fresh water shortage threatens the development and prosperity of many countries including several areas in the United States. Sea and ground water reverse osmosis desalination is rapidly becoming a dominant technology for overcoming water shortage threats by providing cost-effective freshwater production. Digital transformation can be used to help facilitate and advance water treatment technologies by reducing costs and minimizing downtime. Digital transformation is a process that encapsulates digital tools and technologies such as cloud computing, machine learning, artificial intelligence, the internet of things, and virtual/augmented reality. It is a process where objects in the physical world are given virtual replicas …