Engineering Commons^™

Effect Of Ionic Surfactants On Electrostatic Charging Of Spray Droplets, Mark T. Warren

Theses and Dissertations--Chemical and Materials Engineering

Dust capture for small coal particles (<2.5µm) can be improved if one takes advantage of electrostatic charges that resides on the surface of coal dust particles and on the surface of water spray droplets used to capture coal dust. Traditional dust capture methods that use water sprays are ineffective in capturing small dust particles since the motion of small dust particles is governed by electrostatic forces. If additives such as ionic surfactants could be added to water that would enhance the surface charge on water spray droplets, dust capture with water sprays could be improved.

The results presented show that n-sodium octyl sulfate causes the greatest charge enhancement versus the longer chained n-sodium dodecyl sulfate and n-sodium octadecyl sulfate. This can be explained by considering the factors that lead to droplet charge enhancement. Those factors are the mass of surfactant ions at the droplet surface, and the diffusion rate of the surfactant ions from the bulk droplet to the surface of the droplet. Sodium octyl sulfate will have a faster diffusion rate to the droplet surface because of its relatively short length, and will also maximize the mass …

Nanoparticle Additives For Multiphase Systems: Synthesis, Formulation And Characterization, Vinod Kanniah

Theses and Dissertations--Chemical and Materials Engineering

Study on nanoparticle additives in multiphase systems (liquid, polymer) are of immense interest in developing new product applications. Critical challenges for nanoparticle additives include their synthesis, formulation and characterization. These challenges are addressed in three application areas: nanofluids for engine lubrication, ultrathin nanocomposites for optical devices, and nanoparticle size distribution characterization.

Nanoparticle additives in oligomer mixtures can be used to develop extended temperature range motor oils. A model system includes poly(α-olefin) based oligomers with a modest fraction of poly(dimethylsiloxane) oligomers along with graphite as nanoparticle additive. Partition coefficients of each oligomer are determined since the oligomer mixture phase separated at …

Fabrication Of An Epithelial Cell-Based Ion-Selective Electrode And Its Application For Use As Alternative Tumor Angiogenesis Assay, Christina Nicole Simmons

Theses and Dissertations--Chemical and Materials Engineering

Previous studies have provided evidence that endothelial cell-based potassium ion selective electrodes possess the ability to quantify substances that have permeability-altering effects on those endothelial cells. The capability of these so-called biosensors to detect elevated concentrations of certain chemical agents found following tumor formation make them useful in the application as an alternative tumor angiogenesis assay. In this study an epithelial cell line, human colon adenocarcinoma epithelial cells (Caco-2), was used to fabricate membranes that were used to test concentrations of these chemical agents, known as cytokines, mimicking the concentrations that have been observed in the serum of healthy individuals …

Biodegradable Hydrogels And Nanocomposite Polymers: Synthesis And Characterization For Biomedical Applications, Ashley Marie Hawkins

Theses and Dissertations--Chemical and Materials Engineering

Hydrogels are popular materials for biological applications since they exhibit properties like that of natural soft tissue and have tunable properties. Biodegradable hydrogels provide an added advantage in that they degrade in an aqueous environment thereby avoiding the need for removal after the useful lifetime. In this work, we investigated poly(β-amino ester) (PBAE) biodegradable hydrogel systems. To begin, the factors affecting the macromer synthesis procedure were studied to optimize the reproducibility of the resulting hydrogels made and create new methods of tuning the properties. Hydrogel behavior was then tuned by altering the hydrophilic/hydrophobic balance of the chemicals used in the …

Understanding Degradation And Lithium Diffusion In Lithium Ion Battery Electrodes, Juchuan Li

Theses and Dissertations--Chemical and Materials Engineering

Lithium-ion batteries with higher capacity and longer cycle life than that available today are required as secondary energy sources for a wide range of emerging applications. In particular, the cycling performance of several candidate materials for lithium-ion battery electrodes is insufficient because of the fast capacity fading and short cycle life, which is mainly a result of mechanical degradation.

This dissertation mainly focuses on the issue of mechanical degradation in advanced lithium-ion battery electrodes. Thin films of tin electrodes were studied where we observed whisker growth as a result of electrochemical cycling. These whiskers bring safety concerns because they may …

Application Of Thin Film Analysis Techniques And Controlled Reaction Environments To Model And Enhance Biomass Utilization By Cellulolytic Bacteria, Hsin-Fen Li

Theses and Dissertations--Chemical and Materials Engineering

Cellulose from energy crops or agriculture residues can be utilized as a sustainable energy resource to produce biofuels such as ethanol. The process of converting cellulose into solvents and biofuels requires the saccharification of cellulose into soluble, fermentable sugars. However, challenges to cellulosic biofuel production include increasing the activity of cellulose-degrading enzymes (cellulases) and increasing solvent (ethanol) yield while minimizing the co-production of organic acids. This work applies novel surface analysis techniques and fermentation reactor perturbations to quantify, manipulate, and model enzymatic and metabolic processes critical to the efficient production of cellulosic biofuels.

Surface analysis techniques utilizing cellulose thin film …

Membrane Immobilized Reactive Fe/Pd Nanoparticles: Modeling And Tce Degradation Results, Ruo He

Theses and Dissertations--Chemical and Materials Engineering

Detoxification of chlorinated organic compound is an important and urgent issue in water remediation nowadays. Trichloroethylene (TCE), as a model compound in this study, has been proved to be degraded effectively by bimetallic nanoparticles (NPs) in solution phase. In this study, Fe/Pd bimetallic NPs were synthesized in poly (acrylic acid) (PAA) functionalized polyvinylidene fluoride (PVDF) microfiltration membranes. TCE dechlorination with these bimetallic NPs was conducted under different pH values and different metal loadings to study the role of corrosion on reaction rates.

One-dimensional mathematical model with pseudo first-order reaction kinetic was introduced to discuss the TCE dechlorination profile in membrane …

Finite Element Analysis Of The Contact Deformation Of Piezoelectric Materials, Ming Liu

Theses and Dissertations--Chemical and Materials Engineering

Piezoelectric materials in the forms of both bulk and thin-film have been widely used as actuators and sensors due to their electromechanical coupling. The characterization of piezoelectric materials plays an important role in determining device performance and reliability. Instrumented indentation is a promising method for probing mechanical as well as electrical properties of piezoelectric materials.

The use of instrumented indentation to characterize the properties of piezoelectric materials requires analytical relations. Finite element methods are used to analyze the indentation of piezoelectric materials under different mechanical and electrical boundary conditions.

For indentation of a piezoelectric half space, a three-dimensional finite element …

Study Of Characterization Of Submicron Coal Particles Dispersed In Air And Capture Of Coal Particles By Water Drops In A Scrubbing Column, Utshab Chakravorty

Theses and Dissertations--Chemical and Materials Engineering

Present day water spray based dust removal technologies do not effectively remove respirable submicron coal and silica dust particles in the underground coal mines causing Coal worker’s pneumoconiosis (CWP). The objective of this research was to study the electrostatic charges present in the airborne coal dust in order to develop efficient water spraying based dust removal technology where water drops charged using ionic compounds and surfactants would be used to capture the oppositely charged coal particles. In an experimental scrubbing column, coal particles dispersed in an air stream by a Fluidized Bed Aerosol Generator were captured by water drops sprayed …

Background Factors That Affect Pilot Success In Regional Airline Training, Derek Alan Herchko

Doctoral Dissertations and Master's Theses

Following the Colgan Air accident in February 2009, the U.S. Congress and the traveling public called for increased flight experience requirements for pilots of regional airlines. In response, Congress enacted the Airline Safety and Federal Aviation Administration Act of 2010 . This legislation required that regional airline pilots, inclusive of first officers, have an Airline Transport Pilot certificate and a minimum of 1,500 total flight hours. This legislation had a provision that allowed the Federal Aviation Administration to create credit toward flight hours for pilots who had specific academic training courses above normal pilot certification. The Pilot Source Study was …

Ranging Of Aircraft Using Wide-Baseline Stereopsis, Kevin Todd Rigby

Doctoral Dissertations and Master's Theses

The purpose of this research was to investigate the efficacy of wide-baseline stereopsis as a method of ranging aircraft, specifically as a possible sense-and-avoid solution in Unmanned Aerial Systems. Two studies were performed: the first was an experimental pilot study to examine the ability of humans to range in-flight aircraft and the second a wide-baseline study of stereopsis to range in-flight aircraft using a baseline 14.32 meters and two 640 x 480 pixel charge coupled device camera. An experimental research design was used in both studies. Humans in the pilot study ranged aircraft with a mean absolute error of 50.34%. …

An In Vitro Comparative Study Of Intracanal Fluid Motion And Wall Shear Stress Induced By Ultrasonic And Polymer Rotary Finishing Files In A Simulated Root Canal Model, Jon Koch, John Borg, Abby Mattson, Kris Olsen, James Bahcall

Mechanical Engineering Faculty Research and Publications

Objective. This in vitro study compared the flow pattern and shear stress of an irrigant induced by ultrasonic and polymer rotary finishing file activation in an acrylic root canal model. Flow visualization analysis was performed using an acrylic canal filled with a mixture of distilled water and rheoscopic fluid. The ultrasonic and polymer rotary finishing file were separately tested in the canal and activated in a static position and in a cyclical axial motion (up and down). Particle movement in the fluid was captured using a high-speed digital camera and DaVis 7.1 software. The fluid shear stress analysis was …

Investigation Into The Usability Of Micromechanical Models To Predict The Behavior Of A Nanocomposite Polymer, Jason Handlogten

All Graduate Theses, Dissertations, and Other Capstone Projects

The purpose of this thesis was to determine the acceptability of a set of existing nanocomposite test specimens for tensile testing and then to determine the Young's and shear modulus of these test specimens. If the test specimens were found to be acceptable, the accuracy of three micromechanical models was to be evaluated by comparing their predictions to the mechanical properties determined from testing the specimens. The set of existing nanocomposite test specimens had a distinct concave shape on two surfaces that were believed to be intended as flat. In order to determine if they adhered to the Type I …

State (Hydrodynamics) Identification In The Lower St. Johns River Using The Ensemble Kalman Filter, Hitoshi Tamura

Electronic Theses and Dissertations

This thesis presents a method, Ensemble Kalman Filter (EnKF), applied to a highresolution, shallow water equations model (DG ADCIRC-2DDI) of the Lower St. Johns River with observation data at four gauging stations. EnKF, a sequential data assimilation method for non-linear problems, is developed for tidal flow simulation for estimation of state variables, i.e., water levels and depth-integrated currents for overland unstructured finite element meshes. The shallow water equations model is combined with observation data, which provides the basis of the EnKF applications. In this thesis, EnKF is incorporated into DG ADCIRC-2DDI code to estimate the state variables. Upon its development, …

Failure Analysis Of Impact-Damaged Metallic Poles Repaired With Fiber Reinforced Polymer Composites, Robert Arthur Slade

Electronic Theses and Dissertations

Metallic utility poles, light poles, and mast arms are intermittently damaged by vehicle collision. In many cases the vehicular impact does not cause immediate failure of the structure, but induces localized damage that may result in failure under extreme service loadings or can promote degradation and corrosion within the damaged region. Replacement of these poles is costly and often involves prolonged lane closures, service interruption, and temporary loss of functionality. Therefore, an in situ repair of these structures is required. This thesis examines the failure modes of damaged metallic poles reinforced with externally-bonded fiber reinforced polymer (FRP) composites. Several FRP …

X-Ray Radiation Enabled Cancer Detection And Treatment With Nanoparticles, Mainul Hossain

Electronic Theses and Dissertations

Despite significant improvements in medical sciences over the last decade, cancer still continues to be a major cause of death in humans throughout the world. Parallel to the efforts of understanding the intricacies of cancer biology, researchers are continuously striving to develop effective cancer detection and treatment strategies. Use of nanotechnology in the modern era opens up a wide range of possibilities for diagnostics, therapies and preventive measures for cancer management. Although, existing strategies of cancer detection and treatment, using nanoparticles, have been proven successful in case of cancer imaging and targeted drug deliveries, they are often limited by poor …

Completeness For The Coalgebraic Cover Modality, Clemens Kupke, Alexander Kurz, Yde Venema

Engineering Faculty Articles and Research

We study the finitary version of the coalgebraic logic introduced by L. Moss. The syntax of this logic, which is introduced uniformly with respect to a coalgebraic type functor, required to preserve weak pullbacks, extends that of classical propositional logic with a so-called coalgebraic cover modality depending on the type functor. Its semantics is defined in terms of a categorically defined relation lifting operation.

As the main contributions of our paper we introduce a derivation system, and prove that it provides a sound and complete axiomatization for the collection of coalgebraically valid inequalities. Our soundness and completeness proof is algebraic, …

Coalgebraic Logics (Dagstuhl Seminar 12411), Ernst-Erich Doberkat, Alexander Kurz

Engineering Faculty Articles and Research

This report documents the program and the outcomes of Dagstuhl Seminar 12411 “Coalgebraic Logics”. The seminar deals with recent developments in the area of coalgebraic logic, a branch of logics which combines modal logics with coalgebraic semantics. Modal logic finds its uses when reasoning about behavioural and temporal properties of computation and communication, coalgebras have evolved into a general theory of systems. Consequently, it is natural to combine both areas for a mathematical description of system specification. Coalgebraic logics are closely related to the broader categories semantics/formal methods and verification/logic.

Anchoring Of Drifting Spiral And Scroll Waves To Impermeable Inclusions In Excitable Media, Christian W. Zemlin, Arkady M. Pertsov

Bioelectrics Publications

Anchoring of spiral and scroll waves in excitable media has attracted considerable interest in the context of cardiac arrhythmias. Here, by bombarding inclusions with drifting spiral and scroll waves, we explore the forces exerted by inclusions onto an approaching spiral and derive the equations of motion governing spiral dynamics in the vicinity of inclusion. We demonstrate that these forces nonmonotonically depend on distance and can lead to complex behavior: (a) anchoring to small but circumnavigating larger inclusions; (b) chirality-dependent anchoring.

Intercritical Heat Treatments In Ductile Iron And Steel, Ricardo Emilio Aristizabal

All ETDs from UAB

Materials such as dual phase (DP) steels, transformation induced plasticity (TRIP) steels and dual phase ductile irons are produced by intercritical heat treatments. These materials can provide significant weight savings in the automotive industry. The goal of this dissertation is to study intercritical heat treatments in ductile iron and steel to optimize the production parameters. Three different aspects were addressed. First, common steels were intercritically austenitized and austempered (intercritically austempered) under a variety conditions. The results showed that common grade steels that were intercritically austempered exhibited tensile properties in the same range as DP and TRIP steels. The second study …

Investigation Of Wellbore Stability In A North Sea Field Development, Steven Austin Hilgedick

Doctoral Dissertations

"Planning drilling operations is key to the development of oil and natural gas fields. As part of well design, wellbore stability and pore pressure analysis are main factors in determining the safe operating window for selecting mud density. The motivation for this research was to conduct wellbore stability based on exploration wells as basis for planning new offshore field developments with deviated and horizontal wells. A second objective was to investigate the use of a probabilistic approach to wellbore stability, and compare it to the conventional deterministic methods, in order to evaluate the value of including a probabilistic approach to …

Meso-Scale Fluidic Devices With Chemical Sensors For Biological Applications, Satya Gowthami Achanta

Doctoral Dissertations

"Molecular oxygen and humidity are some of the major environmental quantities being measured for various industrial and commercial applications. This dissertation focuses on the design, fabrication and characterization of optofluidic biosensor systems for oxygen and humidity quantification using color charge-coupled device (CCD) camera as a photodetector and LED panel as an excitation source. Meso-scale fluidic devices with integrated oxygen and humidity sensors for potential applications to hydrotropic and oxytropic studies of small plant roots have been investigated in this study. Meso-scale sensor platform was fabricated using porphyrine complex as the sensitive dye embedded within Ethyl Cellulose (EC) polymer matrix. Green …

Role Of Alloy Additions On Strengthening In 17-4 Ph Stainless Steel, Arpana S. Murthy

Doctoral Dissertations

"Alloy modifications by addition of niobium (Nb ), vanadium (V), nitrogen (N) and cobalt (Co) to cast 17-4 PH steel were investigated to determine the effect on mechanical properties. Additions of Nb, V, and N increased the yield strength from 1120 MPa to 1310 MPa while decreased the room temperature charpy V notch (CVN) toughness from 20 J to four Joules. The addition of Co to cast 17-4 PH steel enhanced the yield strength and CVN toughness from 1140 MPa to 1290 MPa and from 3.7 J to 5.5 J, respectively. In the base 17-4 PH steel, an increase in …

Strategic Management And Entrepreneurship As Economic Development Tools, Norbert Ziemer

Doctoral Dissertations

This research develops a framework of Biobased Entrepreneurial Ventures for Rural Economic Development. Rural economic development poses unique challenges and opportunities, based on available production assets, workforce trends like "brain drain," and access to industry clusters. However, certain entrepreneurial venture opportunities are preferable for rural economic development. Since supply chains are vital to business success, initial emphasis is placed on the biomass resource base to be transformed through entrepreneurial activity into higher economic value outputs. The literature contains research on specific opportunities in rural economic development (e.g. ethanol, wind power). Many of these are limited in scope and depend on …

Stability Challenges And Solutions In Current-Mode Controlled Power Electronic Converters, Seyed Mostafa Khazraei

Doctoral Dissertations

"This dissertation focuses on stability issues in single-staged and multi-staged current controlled power electronic converters. Most current-mode control (CMC) approaches suffer from sub-harmonic oscillations. An external ramp is usually added to solve this problem. However, to guarantee stability this ramp has to be designed for the worst possible case which consequently over damps the response. Adaptive slope compensation (ASC) methods are the solution for this problem. In paper 1 of this dissertation, first three ASC methods will be investigated and analyzed through their small signal models. Then, through simulation analyses and experimental test of a variable-input voltage converter the results …

Spatial-Temporal Reasoning Applications Of Computational Intelligence In The Game Of Go And Computer Networks, Tae-Hyung Kim

Doctoral Dissertations

"Spatial-temporal reasoning is the ability to reason with spatial images or information about space over time. In this dissertation, computational intelligence techniques are applied to computer Go and computer network applications. Among four experiments, the first three are related to the game of Go, and the last one concerns the routing problem in computer networks.

The first experiment represents the first training of a modified cellular simultaneous recurrent network (CSRN) trained with cellular particle swarm optimization (PSO). Another contribution is the development of a comprehensive theoretical study of a 2x2 Go research platform with a certified 5 dan Go expert. …

The Effects Of Personal Protective Respirators On Human Motor, Visual, And Cognitive Skills, Anas Ahmed Alghamri

Doctoral Dissertations

"In oxygen-deficient or toxic environments in which controlling the hazard is not feasible, workers wear personal protective respirators. Hazard controls include but are not limited to engineering controls, such as ventilation, and substituting less hazardous materials. However, respirator selection and the design of tasks that require respirators are critical issues. Understanding the effects of respirators on human abilities is critical to respirator selection and therefore to the safety and efficiency of workers. This research investigated the effect of respirators on human abilities. A review of the relevant literature was conducted, revealing that respirators can affect physiological, psychological, motor, and visual …

The Effect Of Supercritical Water On Crude Glycerin Solution, Jared Bouquet

Doctoral Dissertations

"Crude glycerin solution, a principal byproduct of the conventional biodiesel process, was reacted in supercritical water using a specially designed Haynesʼ Alloy 282 reactor system for the production of hydrogen rich syngas. The effects of temperature, pressure, water-to-carbon molar ratio, reactor residence time, and glycerin-to-methanol weight ratio on the extent of carbon gasification and gas composition were explored. Based on the results, the extent and selectivity of reactions that concurrently occur when methanol and glycerin are in the presence of supercritical water were analyzed. A decomposition reaction pathway for glycerin conversion to syngas was hypothesized, and then utilizing the results …

Shear And Fracture Behavior Of High-Volume Fly Ash Reinforced Concrete For Sustainable Construction, Carlos Andres Ortega Ordonez

Doctoral Dissertations

"Concrete is the most widely used man-made material on the planet. Unfortunately, producing Portland cement generates carbon dioxide (a greenhouse gas) at roughly a pound for pound ratio. High-volume fly ash (HVFA) concrete- concrete with at least 50% of the cement replaced with fly ash - offers a potential "green" solution. However, because it is still relatively new and has some disadvantages, there are still many questions that need to be answered. Most research to date has consisted only of the evaluation of the strength and durability of HVFA concrete mixtures, while only a limited number of studies have implemented …

Hollow Hydroxyapatite Microspheres As Devices For Controlled Delivery Of Proteins And As Scaffolds For Tissue Engineering, Hailuo Fu

Doctoral Dissertations

"Hollow HA microspheres were prepared by converting Li₂O-CaO-B₂O₃ glass microspheres in a K₂HPO₄ solution. Process parameters, such as reaction temperature (25°C-60°C) and concentration of the phosphate solution (0.02-0.25 M) significantly influenced the microstructure of the hollow HA microspheres. Microspheres with the largest hollow core size were obtained at lower temperature or with low K₂HPO₄ concentration. In comparison, microspheres with high surface area (~140 m²/g) were obtained at higher K₂HPO₄ concentration (0.25 M). Upon heat treatment (up to 900°C), the surface area of the hollow HA microspheres decreased (from ~100 m²/g to ~2 m²/g), and the rupture strength increased (from ~11 …