Engineering Commons^™

An Investigation Of Size Effects On Thin Sheet Formability For Microforming Applications, Nasr Abdelrahman Shuaib

University of Kentucky Doctoral Dissertations

The increasing demand for powerful miniaturized products for all industrial applications has prompted the industry to develop new and innovative manufacturing processes to fabricate miniature parts. One of the major challenges facing the industry is the dynamic market which requires continuous improvements in design and fabrication techniques. This means providing products with complex features while sustaining high functionality. As a result, microfabrication has gained a wide interest as the technology of the future, where tabletop machine systems exist. Microforming processes have the capability of achieving mass production while minimizing material waste. Microforming techniques can produce net-shape products with intricacy in …

Surfactant And Metal Sorption Studies By Functionalized Membranes And Quartz Crystal Microbalance, Abhay R. Ladhe

University of Kentucky Doctoral Dissertations

Functionalized membranes provide an elegant platform for selective separations and sorptions. In this dissertation, application of functionalized membranes for surfactant and metal sorption studies are discussed. Sorption behavior of surfactants is also studied using quartz crystal microbalance (QCM) and other techniques.

Adsorption of the ethoxylated surfactants on polymeric materials (cotton and polyester) and model gold surface was quantified from a non-aqueous siloxane based solvent (D5) and water. The role of ethylene oxide group and the effect of nature of polymeric materials on adsorption behavior was quantified and established. In the case of gold-water interface, the adsorption data was fitted to …

Linking The Structure And Mechanical Behavior Of Nanoporous Gold, Ye Sun

University of Kentucky Doctoral Dissertations

The structure of nanoporous gold (np-Au) provides a very limited volume for deformation to occur, and thus offers an opportunity to study the role of defects such as dislocations in nanoscale metal volumes. A practical goal is to understand mechanical properties of np-Au so that it can be can produced in stable form, for use in applications that require some mechanical integrity. Bulk and thin film np-Au have been fabricated and studied here.

Bulk np-Au was prepared by electrochemically dealloying Au-Ag alloys with 25 and 30 at.% Au. In the lower Au content material, cracks always formed during dealloying. When …

Towards A Metric For The Assessment Of Safety Critical Control Systems, Oscar R. Gonzalez, Jorge R. Chavez-Fuentes, W. Steven Gray

Electrical & Computer Engineering Faculty Publications

There is a need for better integration of the fault tolerant and the control designs for safety critical systems such as aircraft. The dependability of current designs is assessed primarily with measures of the interconnection of fault tolerant components: the reliability function and the mean time to failure. These measures do not directly take into account the interaction of the fault tolerant components with the dynamics of the aircraft. In this paper, a first step to better integrate these designs is made. It is based on the observation that unstable systems are intrinsically unreliable and that a necessary condition for …

Unmanned Aerial Vehicle Routing With Limited Risk, Siriwat Visoldilokpun

Industrial, Manufacturing, and Systems Engineering Dissertations - Archive

Due to safety and uninhabitable surrounding environments, long range Unmanned Aerial Vehicles (UAVs) have become an increasingly popular option in both scientific and military applications. With troubling oil prices, a logistic planner requires an efficient method to identify an optimal routing solution. The solution should not only optimize the bottom line objective but must also control variations in an operation.We study the UAV routing problem with limited risk (URPR) in which the considered risk is a fuel burn variance caused by wind variation. The URPR determines the optimal route that minimizes total expected fuel burn to visit all assigned targets …

Spotlight On Construction: St. Simons' Library Welcomed 70th Anniversary In New Facility

Georgia Library Quarterly

The article announces the grand opening event of the St. Simons Public Library in Georgia in January 2007. The library also celebrated its 70th anniversary on March 16. According to Libby Hogan, chair of the library's board of directors, they have 1,200 extra square feet of space in the renovated building. St. Simons joined the Three Rivers Public Library System (TRRLS) and PINES (Public Information Network for Electronic Services), bringing its patrons access to more than 8.5 million items owned by other PINES member libraries. The library currently has approximately 35,000 volumes, according to manager Maureen Hersey.

Dependable And Certifiable Real-World Systems – Issue Of Software Engineering Education, Andrew J. Kornecki

Department of Electrical Engineering and Computer Science - Daytona Beach

Embedded software and dedicated hardware are vital elements of the modern world, from personal electronics to transportation, from communication to aerospace, from military to gaming, from medical systems to banking. Combinations of even minor hardware or software defects in a complex system may lead to violation of safety with or even without evident system failure, a major problem that the computing profession faces is the lack of a universal approach to unite the dissimilar viewpoints presented by computer science, with its discrete and mathematical underpinnings, and by computer engineering, which focuses on building real systems and considering spatial and material …

A New Method Of Synthesizing Black Birnessite Nanoparticles: From Brown To Black Birnessite With Nanostructures, Shizhi Qian, Marcos A. Cheney, Pradip K. Bhowmik, Sang W. Joo, Wensheng Hou, Joseph M. Okoh

Mechanical Engineering Faculty Research

A new method for preparing black birnessite nanoparticles is introduced. The initial synthesis process resembles the classical McKenzie method of preparing brown birnessite except for slower cooling and closing the system from the ambient air. Subsequent process, including wet-aging at 7◦C for 48 hours, overnight freezing, and lyophilization, is shown to convert the brown birnessite into black birnessite with complex nanomorphology with folded sheets and spirals. Characterization of the product is performed by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), thermogravimetric analysis (TGA), and N2 adsorption (BET) techniques. Wet-aging and lyophilization times are shown to …

Decoupling And Disturbance Rejection Control For Target Circulation, Jian Ma, Joon S. Lee, Woosoon Yim

Reactor Campaign (TRP)

The Target Complex loop TC-1 was originally conceived as part of an accelerator-driven system (ADS) pilot plant that was designed and developed by the Institute of Physics and Power Engineering (IPPE) and Experimental and Development Organization (EDO) “Gidropress” in Obninsk, Russia, under the International Science and Technology Center Project #559 in 1998. It was to be used as the target in a 1 MWth ADS experiment run off of the LANSCE proton accelerator at Los Alamos National Laboratory (LANL). When the U.S. transmutation program changed priorities from accelerator-driven systems towards nuclear fission reactors, the TC-1 loop was brought to UNLV …

Modeling And Design Algorithms For Electromagnetic Pumps, Daniel P. Cook, Yitung Chen, Jian Ma

Reactor Campaign (TRP)

Electromagnetic (EM) induction pumps are used extensively in current and proposed nuclear power systems and industrial molten metal transfer operations. Although the Magnetohydrodynamic (MHD) theory that underlies the operation of these types of pumps has been studied extensively in the past few decades, the design of specific EM pumping systems for specific flow cases requires computational tools and expertise, which is lacking in the U.S. However, for the past two years, researchers at UNLV have been utilizing the TC-1 liquid metal loop system at UNLV and an Annular Linear Induction Pump (ALIP) to drive the liquid metal and to develop …

Thermal Transient Flow Rate Sensor For High Temperature Liquid Metal Cooled Nuclear Reactor, Yingtao Jiang, Jian Ma

Reactor Campaign (TRP)

In nuclear power plants and accelerator driven systems (ADS) for nuclear waste treatment, it is important to monitor the coolant flow rate in the reactor core and pipe-line. In such a strong irradiation, high pressure, and temperature environment, the existing flow measurement techniques (such as Electromagnetic flow meters, Ultrasonic flow meters, Turbine flow meters, etc.) are not accurate and reliable.

The measurement of flow rates (mass flow rates or volume flow rate) plays a notable role in monitoring and controlling the experimental conditions. The bulk flow rates can be obtained through direct methods, which measure the amount of discharged fluids …

Knowledge-Based Information Resource Management System For Materials Of Sodium-Cooled Fast Reactor, Sean Hsieh

Reactor Campaign (TRP)

In the development of advanced fast reactors, materials and coolant/ material interactions pose a critical barrier for higher temperature and longer core life designs. For sodium-cooled fast reactors (SFRs) such as the Experimental Breeder Reactors in Idaho and the Fast Flux Test Facility in Hanford, experience has shown that qualified structural materials and fuel cladding severely limits their economic performance.

Liquid sodium has been selected as the primary coolant candidate for the Advanced Burner Reactor (ABR) of the Global Nuclear Partnership (GNEP). Materials improvement has been identified as a major thrust to improve fast reactor economics. Researchers from universities, national …

Monaco/Mavric Evaluation For Facility Shielding And Dose Rate Analysis, Charlotta Sanders, Denis Beller

Reactor Campaign (TRP)

The dimensions and the large amount of shielding required for Global Nuclear Energy Partnership (GNEP) facilities, advanced radiation shielding, and dose computation techniques are beyond today’s capabilities and will certainly be required. With the Generation IV Nuclear Energy System Initiative, it will become increasingly important to be able to accurately model advanced Boiling Water Reactor and Pressurized Water Reactor facilities, and to calculate dose rates at all locations within a containment (e.g., resulting from radiations from the reactor as well as the from the primary coolant loop) and adjoining structures (e.g., from the spent fuel pool).

The MAVRIC sequence is …

University Of Nevada, Las Vegas Transmutation Research Program Annual Progress Report Academic Year 2007-2008, Anthony Hechanova, Rebecca Paulson

Transmutation Research Program Reports (TRP)

It is my pleasure to present the UNLV Transmutation Research Program’s seventh annual report that highlights the academic year 2007-2008. Supporting this document are the many technical reports and theses that have been generated over the past seven years.

In the seventh year of our program, we continued to see growth in the Radiochemistry Ph.D. program with a total of 20 students in the fourth year of the program (we anticipated twelve in the program proposal). Since our inception, the program has sponsored to their conclusion 48 M.S. and 6 Ph.D. degrees. The program supported 53 graduate students, 11 undergraduates, …

Combined Radiation Detection Methods For Assay Of Higher Actinides In Separation Processes, Denis Beller, Charlotta Sanders, Warnick Kernan

Safeguards Campaign (TRP)

In the MPAC project, faculty and students are investigating the potential to use combined neutron and gamma-ray detector systems to measure quantities and isotopic constituents contained during separations and intermediate storage. This will require knowledge of the nuclear and decay characteristics of materials during processing, the development of conceptual designs of monitoring systems, radiation transport studies to develop an understanding of operational regimes, and experiments to confirm performance. In addition, both passive and active concepts will be investigated, including collaborations with the Idaho Accelerator Center at Idaho State University (ISU) to use electron linear accelerators for producing photoneutrons in situ, …

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry Morphology, And Surface Preparation, John Farley, Allen L. Johnson

Transmutation Sciences Materials (TRP)

Advanced nuclear processes and facilities (e.g., transmutation of nuclear waste, fast reactors, and spallation neutron sources) impose special demands on materials, which must withstand high temperatures, high radiation fields, and chemical corrosion. Proposed schemes for transmuting nuclear waste require a nonmoderating coolant such as lead-bismuth eutectic (LBE) or liquid sodium. While LBE corrodes most steels, small amounts of oxygen in the LBE greatly reduces the corrosion rate, and could ideally re-grow a damaged oxide layer in situ. The protective oxide layer would thus be self-healing. However, a fundamental understanding of the role of oxygen and passivating oxide layers is presently …

Effect Of Silicon Content On The Corrosion Resistance And Radiation-Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems, Ajit K. Roy

Transmutation Sciences Materials (TRP)

The beneficial effects of Si on both the metallurgical and corrosion properties of Cr-Mo steels have previously been demonstrated at UNLV. Therefore, additions of Si ranging from 0.5-2.0 weight percent (wt%) was attempted in this investigation to explore Si effect on both the high temperature tensile properties and corrosion behavior of T91 grade steel. Corrosion studies in the presence of molten LBE could not be performed due to a lack of proper experimental facilities at UNLV. Therefore, detailed corrosion studies involving Si-containing T91 grade steels were performed in an aggressive aqueous solution of acidic pH. Further, significant efforts have been …

Theoretical Modeling Of Protective Oxide Layer Growth In Non-Isothermal Lead Alloy Coolant Systems, Yitung Chen, Taide Tan, Jinsuo Zhang, Jichun Li

Transmutation Sciences Materials (TRP)

In advanced nuclear energy systems, lead alloys emerge as strong candidates for transmutation and advanced reactor systems as nuclear coolants and spallation neutron targets. However, it is widely recognized that corrosion of materials caused by lead alloys presents a critical barrier to their industrial use. A few experimental research and development projects have been set up by different groups such as at Los Alamos National Laboratory to study the corrosion phenomena in their test facilities and to develop mitigation techniques and materials. One of the central or main techniques under development is to use active control of oxygen thermodynamic activity …

Development Of Nanostructure Based Corrosion-Barrier Coatings On Steel For Transmutation Applications, Biswajit Das

Transmutation Sciences Materials (TRP)

Advanced transmutation systems require structural materials that are able to withstand high neutron fluxes, high thermal cycling, and high resistance to chemical corrosion. The current candidate materials for such structures are ferritic and ferritic-martensitic steels due to their strong resistance to swelling, good microstructural stability under irradiation, and the retention of adequate ductility at typical reactor operating temperatures.

In parallel, lead-bismuth eutectic (LBE) has emerged as a potential spallation target material for efficient production of neutrons, as well as a coolant in the accelerator system. While LBE has excellent properties as a nuclear coolant, it is also highly corrosive to …

Reactor Physics Studies For The Afci Reactor-Accelerator Coupling Experiments Project, Denis Beller

Transmutation Sciences Physics (TRP)

The specific research objective of this three-year project was to design and conduct accelerator driven experiments, to help demonstrate the ability to design, compute, and conduct ADS experiments and to predict and measure source importance, coupling efficiency, sub-critical reactor kinetics and source-driven transients. In addition, databases were created for both steady state and transient ADS experiments for the nuclear community to develop and test new computational codes and methods. The importance of a driving neutron source in various regions of different subcritical assemblies was mapped. Experiments were conducted and compared to calculations with radiation transport and thermal hydraulics codes such …

Separation Of Technetium From Uranium And Waste Form Synthesis, Kenneth Czerwinski

Waste Forms Campaign (TRP)

In this project, systematic investigations on the Tc-Zr binary metal system will be evaluated for the first time. The synthesis of metallic Tc as well as its alloys with Zr will be evaluated. In order to provide valuable data to AFC R&D, the thermodynamic equilibrium phases, as well as their performance under repository conditions, will be examined.

The research objectives of this project are as follows:

• Evaluate anion exchange methods for achieving the separation of Tc from U.

• Synthesize metallic Tc from the separated product.

• Synthesize and characterize Tc alloys.

• Investigate Tc-corrosion and Tc-leaching of binary …

Evaluation Of Cs/Sr Waste Form For Long Term Storage And Disposal, Gary Cerefice, Longzhou Ma

Waste Forms Campaign (TRP)

To facilitate long-term storage, the disposal containers will need to be able to survive for the entire storage interval. The first aspect of the project will explore the potential interaction of the aluminosilicate waste form with the storage canister materials to determine if there is any corrosion or chemical interaction concerns for the storage of the materials. At the end of the storage interval, most of the cesium (¹³⁷Cs) in the waste form will have decayed to its daughter, barium (¹³⁷Ba). While this decay provides a significant reduction in the decay heat generated by the waste …

Final Report: Phase Stability And Segregation In Alloy 22 Base Metal And Weldments, Jeffrey Lacombe

Publications (YM)

At the outset of this project, the design of the waste disposal containers relied heavily on encasement in a multi-layered container, featuring a corrosion barrier of Alloy 22, a Ni-Cr- Mo-W based alloy with excellent corrosion resistance over a wide range of conditions. The fundamental concern from the perspective of the Yucca Mountain Project, however, was the inherent uncertainty in the (very) long-term stability of the base metal and welds. Should the properties of the selected materials change over the long service life of the waste packages, it was conceivable that the desired performance characteristics (such as corrosion resistance) would …

Interaction Between Metal Fission Products And Triso Coating Materials, Clemens Heske

Fuels Campaign (TRP)

This project focuses on the chemical bonding and interface formation of metal fission products with the coating materials used in tri-isotropic (TRISO) fuel particles for gas-cooled reactors. By combining surface- and bulk-sensitive spectroscopic and microscopic methods, intermediate chemical phases at the interface, intermixing/diffusion behavior, and the electronic interface structure for different coating materials and metals are examined.

In detail, the project studies the interface formation of Pd, Cs, and Ag with SiC and pyrolytic carbon. Using SiC single crystals and highly-ordered pyrolytic carbon (HOPG) as substrates, interfaces are prepared under controlled conditions in an ultra-high vacuum environment and are studied …

Design Concepts And Process Analysis For Transmuter Fuel Manufacturing, Georg F. Mauer

Fuels Campaign (TRP)

The safe and effective manufacturing of actinide-bearing fuels for any transmutation strategy requires that the entire manufacturing process be contained within a shielded hot cell environment. To ensure that the fabrication process is feasible, the entire process must be designed for remote operation. The equipment must be reliable enough to perform over several decades, and also easy to maintain or repair remotely. The facility must also be designed to facilitate its own decontamination and decommissioning. In addition to these design factors, the potential viability of any fuel fabrication process will also be impacted by a number of variables, such as …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert fuels containing ZrO₂ and MgO as the inert matrix. Ceramics with this inert matrix, Ce, U and eventually Pu will be synthesized and examined. While the Advanced Fuel Cycle Initiative focus is on inert fuels with Pu as the fissile component, this task will perform initial laboratory experiments with Ce and U. The initial work with Ce will be performed early in the project with results used as a basis for U studies. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf. …

Impact Of The Synthesis Process On Structure Properties For Afci Fuel Candidates, Kenneth Czerwinski

Fuels Campaign (TRP)

The research objectives are:

• To explore a low-temperature fluoride route to synthesize actinide nitrides. • To characterize actinide nitrides structurally and thermally.

• To use high resolution TEM techniques to explore the microstructure of the radioactive samples.

Solution-Based Synthesis Of Nitride Fuels, Kenneth Czerwinski, Tyler A. Sullens

Fuels Campaign (TRP)

One of the original synthetic routes devised for the synthesis of U (III)N involved the entire reaction taking place in liquid ammonia. Several experimental reactions were conducted in an attempt to synthesize the UI₃(NH₃)_x and U(NH₂)₃(NH₃)_x precursors of U(III) N. Each attempt involved cleaning of the uranium metal to remove the oxide coating of the metal reagent with 3 washes of concentrated nitric acid, each followed by a rinse with liquid ammonia. Success of this cleaning procedure was varied, with a majority of cleaned metal oxidizing rapidly once …

Improved High-Temperature Stability And Sun-Light-Driven Photocatalytic Activity Of Sulfur-Doped Anatase Tio2, Suresh Pillai, Declan Mccormack, Pradeepan Periyat, John Colreavy, Steve Hinder

Articles

No abstract provided.

Performance Comparison Of Thermal Insulated Packaging Boxes, Bags And Refrigerants For Single-Parcel Shipments, S. P. Singh, Gary J. Burgess, Jay Singh

Industrial Technology and Packaging

A range of packaging solutions exists for products that must be kept within a specific temperature range throughout the supply-and-distribution chain. This report summarizes the results of studies conducted over a span of 2 years by the Consortium for Distribution Packaging at Michigan State University. Thermal insulation packaging materials such as expanded polystyrene, polyurethane, corrugated fibreboard, ThermalCor® and other composite packaging such as thermal insulating bags were studied. Phase change materials such as gel packs were also evaluated. Properties such as R-value, melting point and heat absorption were examined and are reported.