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2008

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Articles 271 - 300 of 4190

Full-Text Articles in Engineering

Student Achievement And Affective Traits In Electrical Engineering Laboratories Using Traditional And Computer-Based Instrumentation, Matthew D. Lammi Dec 2008

Student Achievement And Affective Traits In Electrical Engineering Laboratories Using Traditional And Computer-Based Instrumentation, Matthew D. Lammi

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Distance education has the ability to transcend distance and time, reaching students anywhere at any time, particularly those underrepresented in engineering. Engineering is a practice-oriented profession requiring an interweaving of scientific theory and applied hands-on activities. Despite the need for distance education in engineering, few studies have systematically investigated the impact of student achievement and attitude in distance engineering laboratories. This quasi-experimental research addressed that need by studying the cognitive and affective domains of achievement in engineering laboratories while employing computer-based and traditional oscilloscopes. The students from two courses, electrical engineering for nonmajors and electronic fundamentals, were randomly assigned into …

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Safety And Operational Impacts Of Alternative Intersections, Andrew P. Tarko, Mike Inerowicz, Brandon Lang Dec 2008

Safety And Operational Impacts Of Alternative Intersections, Andrew P. Tarko, Mike Inerowicz, Brandon Lang

JTRP Technical Reports

As the degradation of service at some conventional intersections increases, there becomes a need for alternative solutions other than expensive interchanges. Many alternative intersections have been proposed in the past. Under certain traffic and local conditions some solutions are more promising than other. In some cases, the conventional intersection may still be the optimal choice. The presented research focused on developing guidelines that would help planners and designers identify the most promising solutions for further analysis. This objective has been addresses in two ways. Firstly, the existing knowledge on alternative intersections has been identified. Secondly, the performance of conventional and …

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A Device For Noninvasive Assessment Of Vascular Impairment Risk In The Lower Extremity, Michael J. Hoffmann, Paul E. Knudson, M. Barbara Silver-Thorn Dec 2008

A Device For Noninvasive Assessment Of Vascular Impairment Risk In The Lower Extremity, Michael J. Hoffmann, Paul E. Knudson, M. Barbara Silver-Thorn

Biomedical Engineering Faculty Research and Publications

The repeatability and resolution of the clinical gold standard of vascular assessment, the ankle-brachial index (ABI), was compared to that of a new device that dynamically assesses tissue perfusion during external loading utilizing laser Doppler flowmetry. Eight subjects of varying levels of vascular impairment were tested in successive weeks using two different sites on the subject's posterior calf. These new measures included the perfusion decrease as well as the unloading delay during cyclic loading. Some new dynamic tissue perfusion measures demonstrated comparable levels of reproducibility with the ABI (e.g., 10%-20%). Only the unloading delay showed potentially enhanced resolution over ABI …

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High Speed Wavelength Tuning Of Sgdbr Lasers For Optical Coherence Tomography Applications, Benjamin Maher Dec 2008

High Speed Wavelength Tuning Of Sgdbr Lasers For Optical Coherence Tomography Applications, Benjamin Maher

Master's Theses

The application of Sample Grated Distributed Bragg Reflector (SGDBR) wavelength tunable lasers for swept-wavelength Optical Coherence Tomography (OCT) is explored. OCT is a method of measuring reflectivity versus distance into samples under test with a focused infrared light source. Swept wavelength OCT requires a laser light source that is capable of sweeping its wavelength quickly over the entire wavelength range of the tunable laser. Fast sweeping of the laser's wavelength enables real-time imaging of a wide surface area of the surface under test. This thesis will show that SGDBR lasers can be designed to meet the fast wavelength ramp speeds …

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Analysis And Design Of Interleaving Multiphase Dc-To-Dc Converter With Input Lc Filter, Kevin Thomas Delrosso Dec 2008

Analysis And Design Of Interleaving Multiphase Dc-To-Dc Converter With Input Lc Filter, Kevin Thomas Delrosso

Master's Theses

The future of microprocessors is unknown. Over the past 40 years, their historical trend has been for adopting smaller and more powerful designs that drive the world that we live in today. The state of the microprocessor business today faces a crossroad, wishing to continue on the historical trend of doubling the number of transistors on a chip every 18 months (Moore’s Law) but also facing the realistic task of needing to power these sophisticated devices. With the low voltages and high currents that are required for these microprocessors to operate, it poses a difficult task for the future designers …

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Maximizing Warfighter Capability Using Surveyed Necessity Measurement: Application To The Usaf F-15c Fleet, John M. Colombi, David R. Jacques, Dennis D. Strouble Dec 2008

Maximizing Warfighter Capability Using Surveyed Necessity Measurement: Application To The Usaf F-15c Fleet, John M. Colombi, David R. Jacques, Dennis D. Strouble

Faculty Publications

Within the Department of Defense, with changing missions to counter dynamic and asymmetrical threats, the acquisition workforce strives to maximize capability for joint warfighting. How acquisition professionals measure and select capability improvements for the nation’s weapon systems is a perpetual challenge, made even more complex with constrained defense budgets. This study identifies a method for determining which upgrades should be purchased (production) for which aircraft in the F- 15C fleet by optimizing a capability proxy measure. Each upgrade’s “necessity” for a given mission area was obtained by conducting a survey of over 250 experienced F-15C pilots. The solution presented in …

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A Reconfigurable Motor For Experimental Emulation Of Stator Winding Inter-Turn And Broken Bar Faults In Polyphase Induction Machines (Journal Article), Chia-Chou Yeh, Gennadi Y. Sizov, Ahmed Sayed-Ahmed, Nabeel Demerdash, Richard J. Povinelli, Edwin E. Yaz, Dan M. Ionel Dec 2008

A Reconfigurable Motor For Experimental Emulation Of Stator Winding Inter-Turn And Broken Bar Faults In Polyphase Induction Machines (Journal Article), Chia-Chou Yeh, Gennadi Y. Sizov, Ahmed Sayed-Ahmed, Nabeel Demerdash, Richard J. Povinelli, Edwin E. Yaz, Dan M. Ionel

Electrical and Computer Engineering Faculty Research and Publications

The benefits and drawbacks of a 5-hp reconfigurable induction motor, which was designed for experimental emulation of stator winding interturn and broken rotor bar faults, are presented in this paper. It was perceived that this motor had the potential of quick and easy reconfiguration to produce the desired stator and rotor faults in a variety of different fault combinations. Hence, this motor was anticipated to make a useful test bed for evaluation of the efficacy of existing and new motor fault diagnostics techniques and not the study of insulation failure mechanisms. Accordingly, it was anticipated that this reconfigurable motor would …

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Dependence Of The Performance Of Single Photon Avalanche Diodes On The Multiplication Region Width, David A. Ramirez, Majeed M. Hayat, Mark A. Itzler Dec 2008

Dependence Of The Performance Of Single Photon Avalanche Diodes On The Multiplication Region Width, David A. Ramirez, Majeed M. Hayat, Mark A. Itzler

Electrical and Computer Engineering Faculty Research and Publications

The dependence of the performance of separate-absorption-multiplication (SAM) single-photon avalanche diodes (SPADs) on the width of the multiplication region is theoretically investigated. The theory is applied to SAM SPADs with InP homojunction multiplication regions and InAlAs-InP heterojunction multiplication regions. In both cases the absorber layer is InGaAs. Two scenarios for the dark counts are considered: (i) low-temperature operation, when the number of dark carriers is dominated by field-assisted mechanisms of band-to-band tunneling and tunneling through defects; and (ii) room-temperature operation, when the number of dark carriers in the multiplication region is dominated by the generation/recombination mechanism. The analysis utilizes a …

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Decentralized Perimeter Surveillance Using A Team Of Uavs, Randal Beard, David Casbeer, Derek Kingston Dec 2008

Decentralized Perimeter Surveillance Using A Team Of Uavs, Randal Beard, David Casbeer, Derek Kingston

Faculty Publications

Sponsorship: NASA, AFOSR. This paper develops a distributed algorithm to maintain a current estimate of the state of the perimeter using a team of UAVs. Using notions of consensus, an algorithm is developed and shown to distribute a UAV team uniformly around the perimeter.

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Survey Of Wind Power Potential For Wind-Based Electricity At Makambako, Iringa Tanzania, Rmr Kainkwa Nov 2008

Survey Of Wind Power Potential For Wind-Based Electricity At Makambako, Iringa Tanzania, Rmr Kainkwa

Tanzania Journal of Science

The potential for wind-generated electricity is examined using 22 months wind data collected from a prospective site located in the southern highlands of Tanzania. While the data for the year 2001 was from March to December that of 2002 was for all the twelve months of the year.Characteristics of monthly and annual wind speed and direction are systematically investigated based on hourly time-series data using Windographer software. The Weibull shape factors k corresponding to a height of 50 m were found to be 3.10 and 3.80 while the scale factors c were 11.06 and 12.27 m/s for the years 2001 …

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Primary Study Of Tiron As Active Materials For The Redox Flow Battery, Yan Xu, Yue-Hua Wen, Jie Cheng, Yu-Sheng Yang, Zi-Li Xie Nov 2008

Primary Study Of Tiron As Active Materials For The Redox Flow Battery, Yan Xu, Yue-Hua Wen, Jie Cheng, Yu-Sheng Yang, Zi-Li Xie

Journal of Electrochemistry

Effects of solution pH on the electrochemical behavior of tiron(sodium 4,5-dihydroxy-1,3-benzendisulfonic) couple(on a graphite electrode) were studied by cyclic voltammetry in aqueous solutions.It is shown that at pH<4,tiron exhibited a redox process at a relatively high potential with a good reversibility.A redox flow battery was formed employing tiron as the positive active species and V(III)/V(II) as the negative redox couple.In sulfuric acid medium,the coulombic efficiency of the tiron-V redox flow cell was more than 90% with a good cycle life.The decay in the cycle performance was minimal.Therefore,the feasibility of tiron as active materials for redox flow battery application is demonstrated.

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Studies Of Surface Diffusion In Pemfc Electrodes, Jiang-Shui Luo, Jian Chen, Bao-Lian Yi, Chuan-Sin Cha, Hua-Min Zhang Nov 2008

Studies Of Surface Diffusion In Pemfc Electrodes, Jiang-Shui Luo, Jian Chen, Bao-Lian Yi, Chuan-Sin Cha, Hua-Min Zhang

Journal of Electrochemistry

A PEMFC electrode consisting of dual-layer catalyst layer(CL) was fabricated in this work. The outer CL was Nafion-free,while the inner CL was Nafion-bonded. The effects of Pt/C catalyst in the outer CL that did not contact with Nafion on the current generation in PEMFC electrodes were investigated. Cyclic voltammetric studies indicated that the Pt/C catalyst in the outer CL without direct contact with Nafion was still electrochemically active in taking part in the adsorption/desorption of hydrogen and the electrochemical oxidation/reduction of the oxygen-containing species occurring at the interface of "Pt/Nafion" in the inner CL. The polarization curves showed that the …

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Preparation And Optical Transmission Of The Zno Nanorod Array Films, Feng Ye, Jing-Jing Li, Tong-Tao Wang, Yong-Liang Wang, Yun Liu, Xin-Dong Wang Nov 2008

Preparation And Optical Transmission Of The Zno Nanorod Array Films, Feng Ye, Jing-Jing Li, Tong-Tao Wang, Yong-Liang Wang, Yun Liu, Xin-Dong Wang

Journal of Electrochemistry

By using a galvaostatic electrodeposition method in the ZnCl2 solution,the highly oriented ZnO nanorod array films have been successfully prepared on ITO substrate after the pretreatment with ZnO nanoparticles.And they were characterized by scanning electron microscope,X-ray diffraction and transmittance spectra.The results indicated that the ZnO nanorod arrays grew along(001) direction with an orientation perpendicular to the substrate.When the wavelength of incident was over 380 nm,the ZnO nanorod arrays showed high optical transmission of above 95%.Furthermore,the band gap became narrower.

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Preparations Of Composite Electrodes Of Pt With HXWo3 And Catalytic Activity Toward Oxygen Reduction Reaction, Pan-Pan Guo, You-Ju Huang, Hong-Yan Yang, Wei Li, Qing-Long Zhang, Wei-Shan Li Nov 2008

Preparations Of Composite Electrodes Of Pt With HXWo3 And Catalytic Activity Toward Oxygen Reduction Reaction, Pan-Pan Guo, You-Ju Huang, Hong-Yan Yang, Wei Li, Qing-Long Zhang, Wei-Shan Li

Journal of Electrochemistry

Three composite electrodes of platinum with hydrogen tungsten bronze(HxWO3)were prepared by voltammetry: hydrogen tungsten bronze deposited on platinum(HxWO3/Pt);platinum deposited on hydrogen tungsten bronze(Pt/HxWO3) and codeposited platinum and hydrogen tungsten bronze(Pt-HxWO3).The eletro-catalytic activities of three electrodes toward oxygen reduction reaction were studied.It is found that the catalytic activity of platinum can be improved by introducing with hydrogen tungsten bronze.Among these composite electrodes Pt/HxWO3,and the electrode shows the best eletro-catalytic activity toward oxygen reduction reaction,hence,provides a new way for reducing loading of …

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High Performance Fuel Cell Catalyst And 5kw Pemfc Stack Without Humidification At Room Temperature And Atmosphere, Xin-Fa Hu, Min Chen, Shi-Jun Liao Nov 2008

High Performance Fuel Cell Catalyst And 5kw Pemfc Stack Without Humidification At Room Temperature And Atmosphere, Xin-Fa Hu, Min Chen, Shi-Jun Liao

Journal of Electrochemistry

The Pt/C catalyst with high dispersion and high performance was prepared successfully by an organic colloidal method and small batch production(10g) of Pt/C catalyst has been realized.The particle sizes of the active components in the catalyst could be as small as 2.8 nm and the active surface area was up to 450 m2/g.A high performance membrane-electrode assembly(MEA) with surface area of 275 cm2 has been prepared by using the home-made catalyst with a catalyst coated membrane method invented in the lab,and a 5 kW stack has been assembled.The stack showed working 10 h at room temperature,atmosphere and …

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Ceo2/Pt Composite Electrodes And Their Catalytic Performance, Ying Fu, Zi-Dong Wei, Yong-Chao Feng, Xin-Li Ma, Ming-Jia Liao, Chao Liao, Jie Zhang, Huan Zhang Nov 2008

Ceo2/Pt Composite Electrodes And Their Catalytic Performance, Ying Fu, Zi-Dong Wei, Yong-Chao Feng, Xin-Li Ma, Ming-Jia Liao, Chao Liao, Jie Zhang, Huan Zhang

Journal of Electrochemistry

In this paper,the cerium oxide(CeO2) nanoparticles were electrochemically deposited on a Pt electrode by potentiostatic deposition(psd) and potential pulse deposition(ppd) to form CeO2/Pt composite electrodes,CeO2/Pt(psd) and CeO2/Pt(ppd).The properties of the CeO2 were characterized by field emission scanning electron microscope(FESEM) and X-ray diffraction(XRD).The results showed that the CeO2 nanoparticles prepared by psd and ppd were homogeneous and dense.The methanol oxidation reaction(MOR) and oxygen reduction reaction(ORR) on the Pt electrode were enhanced with the introduction of CeO2 into Pt.In addition,the catalytic capability of the CeO2/Pt electrode can be further …

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Ec-Pt/Cnts Glucose Oxidative Electrode, Jia-Hua Liang, Chun-Mei Zhou, Hong-Juan Wang Nov 2008

Ec-Pt/Cnts Glucose Oxidative Electrode, Jia-Hua Liang, Chun-Mei Zhou, Hong-Juan Wang

Journal of Electrochemistry

A glucose oxidative electrode(GOD),EC-Pt/CNTs glucose oxidative electrode,was constructed by ethyl cellulose(EC) and Pt/CNTs.The sensitivity of the EC-Pt/CNTs GOD is 0.85 μA/mM in the concentration range of 0～4 mmol/L of glucose.After dipped in PBS(4℃) for 18 days,the activity of the EC-Pt/CNTs GOD can reach 80%.It is promising for the EC-Pt/CNTs GOD to be used to construct glucose biosensor.

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Corrosion Inhibition Of Magnesium Alloy In 3.5% Nacl Medium By Tungstate, Ling-Jie Li, Zhi-Ming Yao, Jing-Lei Lei, Dong-Hai He, Sheng-Tao Zhang, Fu-Sheng Pan Nov 2008

Corrosion Inhibition Of Magnesium Alloy In 3.5% Nacl Medium By Tungstate, Ling-Jie Li, Zhi-Ming Yao, Jing-Lei Lei, Dong-Hai He, Sheng-Tao Zhang, Fu-Sheng Pan

Journal of Electrochemistry

Electrochemical impedance spectroscopy(EIS),Tafel polarization curves and scanning electron microscopy(SEM) were used to study the corrosion inhibition of AZ61 magnesium alloy in 3.5% NaCl medium with tungstate.Results showed that tungstate demonstrates strong inhibition to the corrosion of AZ61 magnesium alloy.At the concentration of 0.01 mol/L,tungstate has a high inhibition efficiency 75.5%.Tungstate is an anodic inhibitor that mainly inhibited the anodic reactions of magnesium alloy through forming a compact protective layer that covered the magnesium alloy surface active sites.

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Behavior Of Copper Electrodeposition In Copper Electroplating Solution With Different Peg Molecular Weight, Lie Yin, Zeng-Lin Wang Nov 2008

Behavior Of Copper Electrodeposition In Copper Electroplating Solution With Different Peg Molecular Weight, Lie Yin, Zeng-Lin Wang

Journal of Electrochemistry

The effect of the polyethylene glycol(PEG) molecular weight(MW) upon via-hole filling with diameter of 50 μm and aspect ratio of 1 in the acid copper plating solution was studied.The cathodic polarization in copper electroplating bath with PEG of different molecule weights was investigated by linear sweep voltammetry.The surface roughness,crystallography,and the resistivity of copper films were characterized by X-ray diffraction(XRD),atomic force microscopy(AFM) and the four-point probe measurements.The results showed that the polarization on the cathode and the hole-filling capability of electroplating copper bath were increased evidently with an increase of PEG molecular weight from 600 to 8000.When the PEG MW was …

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Voltammetric Determination Of Iodate Ion In Table Salt By Carboxylic Carbon Nanotubes Modified Carbon Paste Electrode, Jun-Hua Li, Fu-Xing Zhang, Jian-Qiu Wang, Zhi-Feng Xu, Rong-Ying Zeng, Yan Yu Nov 2008

Voltammetric Determination Of Iodate Ion In Table Salt By Carboxylic Carbon Nanotubes Modified Carbon Paste Electrode, Jun-Hua Li, Fu-Xing Zhang, Jian-Qiu Wang, Zhi-Feng Xu, Rong-Ying Zeng, Yan Yu

Journal of Electrochemistry

A highly-sensitive and mercury-free method of determining iodate ion in table salt was established based on carboxylic carbon nanotubes modified carbon paste electrode.In 0.1 mol/L NaOH solution,there was a sensitive cathodic stripping peak on voltammograms.The stripping peak potential was-0.52 V when accumulation time of IO-3 at the modified electrode was 60 s and the potential scan rate was 300 mV/s.There was a good liner relationship between the peak current and IO-3 concentration in the range of 8.0×10-10 ～ 5.0×10-8 mol/L and 1.0×10-7 ～ 3.0×10-6 mol/L with the correlation coefficient of 0.999 and 0.998,respectively.The detection limit was …

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Fabrication Of Superhydrophilic Aluminum Oxide Through Single-Step Anodic Oxidation, Qin Zhang, Qi-Ming Yin, Jia-Ming Ye, Yuan-Rong Zhu Nov 2008

Fabrication Of Superhydrophilic Aluminum Oxide Through Single-Step Anodic Oxidation, Qin Zhang, Qi-Ming Yin, Jia-Ming Ye, Yuan-Rong Zhu

Journal of Electrochemistry

Hydrophilic aluminum oxide is popularly used for heat exchanger of air-condition.Herein,we developed a simple method to prepare superhydrophilic aluminum oxide on the surface of aluminum through single-step electrochemical oxidization.The morphologies and water contact angles on surfaces of alumina fabricated under different electrochemical conditions were investgated.Superhydrophilic surfaces fabricated by this method have good stability and high mechanical strength with water contact angle almost 0°.Coated with low surface energy materials,superhydrophilc alumina will be converted to superhydrophobic.

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Study On The Texturization Of C-Si Wafers By Different Kinds Of Alkaline For Heterojunction Solar Cells, Yu-Hua Dou, Yu-Qin Zhou, Mei-Fang Zhu, Shuang Song, Feng-Zhen Liu, Jin-Long Liu, Zhan-Jun Zhang Nov 2008

Study On The Texturization Of C-Si Wafers By Different Kinds Of Alkaline For Heterojunction Solar Cells, Yu-Hua Dou, Yu-Qin Zhou, Mei-Fang Zhu, Shuang Song, Feng-Zhen Liu, Jin-Long Liu, Zhan-Jun Zhang

Journal of Electrochemistry

The texturization of(100) crystalline silicon(c-Si) wafer was studied by field-emission scanning electron microscope using different kinds of etchant: sodium hydroxide,sodium carbonate and tribasic sodium phosphate.By optimizing the etching parameters,the lowest values of averaged reflectance(Rav) were obtained to be 9.70% for NaOH,9.76% for Na2CO3 and 8.63% for Na3PO4·12H2O,which is comparable to that of the wafer with textured surface covered with an anti-reflection coating of either silicon nitride or thermally grown silicon dioxide.The relation of Rav and surface morphology of textured wafer was analyzed.Moreover,special emphasis was put on the role of isopropyl alcohol(IPA) …

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The Hydrothemal Synthesis Of Nanoscale Lifepo4 And Its Electrochemical Performance, Si-Min Wang, Ming-Sen Zheng, Quan-Feng Dong Nov 2008

The Hydrothemal Synthesis Of Nanoscale Lifepo4 And Its Electrochemical Performance, Si-Min Wang, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

The cathode materials of LiFePO4 were prepared via a hydrothermal reduction method using FeCl3 as Fe source and iron as a reducing agent.The results showed that ferric salt could be reduced to ferrous salt completely under the hydrothermal condition and pure-phase LiFePO4 was obtained based on the test results of XRD and FTIR. Carbon-coated LiFePO4 was synthesized by pyrolysisng glucose at high temperature. The morphologies of pure LiFePO4 displayed cluster-like while the LiFePO4/C displayed sphere-like particles. The electrochemical test showed that the LiFePO4/C had good rate performance,while LiFePO4 delivered much …

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Combustion Product Characterization Of The Iron-Heated Powders In Thermal Batteries, Jin Chong, Xue-Ping Gao, Ji-Qiang Wang Nov 2008

Combustion Product Characterization Of The Iron-Heated Powders In Thermal Batteries, Jin Chong, Xue-Ping Gao, Ji-Qiang Wang

Journal of Electrochemistry

The combustion products of thermal battery used iron-heated powders have been studied.It is identified by X-ray diffraction (XRD) analysis that the main compositions of the combustion products are Fe, FeO and KCl. The transmission electron microscopy(TEM) shows a typical core-shell structure with un-reacted Fe particle core coated by FeO shell with a shell thickness of around 200 nm. The combusted iron-heated powders exhibit no metal property, which is contrast to previous assumption. Further measurement indicates that at the ambient temperature the combustion products show semiconductor property of the p-type with conductivity in the order of 103 S·cm-1, which …

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Synthesis Of The Lifepo4 By Co Reduction: Reaction Mechanism And Kinetics, Yun-Hua Chen, Yong Yang Nov 2008

Synthesis Of The Lifepo4 By Co Reduction: Reaction Mechanism And Kinetics, Yun-Hua Chen, Yong Yang

Journal of Electrochemistry

LiFePO4 cathode material was synthesized by CO reducing FePO4 and LiOH precursors.The structure,morphology and electrochemical performances of such LiFePO4 material were characterized by XRD,SEM and charge-discharge tests.It was shown that the particle size of the LiFePO4 synthesized with 5% excess of LiOH in the precursor was about 200 nm.By carbon coating,the LiFePO4 electrode was able to deliver a reversible capacity of 158 mAh·g-1 at 0.1C discharge rate.Temperature-programmed X-ray diffraction was employed to monitor the reaction during the formation of LiFePO4,and Li3Fe2(PO4)3 was found to be …

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Electrochemical Behavior And Determination Of Paracetamol On Activated Glassy Carbon Electrode, Bao-Yu Tan, Fang Liao, Xiao-Ying He, Qing-Tao Zhu, Jun Hua, Xiao-Li Jiang Nov 2008

Electrochemical Behavior And Determination Of Paracetamol On Activated Glassy Carbon Electrode, Bao-Yu Tan, Fang Liao, Xiao-Ying He, Qing-Tao Zhu, Jun Hua, Xiao-Li Jiang

Journal of Electrochemistry

The electrochemical behavior of paracetamol(PCT) was studied at glassy carbon electrode activated by cyclic voltammetry.In HAc-NaAc buffer solution(pH=4.00),a couple of sensitive redox peaks were recorded about 0.54 V in the cyclic voltammograms.The result indicated that the process was controlled by adsorption and nearly reversible.The reaction electron and proton numbers were estimated,respectively,to be two.Excllent linearity was observed in the correlation between the oxidation peak current and the concentration of PCT in the range of 8.00×10-6～2.00×10-4 mol·L-1.The correlative coefficient was-0.999 18.The detection limit was 6.34×10-6 mol·L-1.This method can be used for the determination of PCT real …

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Voltammetric Determination Of L-Cysteine At Bipyrine Bridged Copper(Ⅱ) Complex Modified Glassy Carbon Electrode, Ming-Yan Wang, Fan Yang, Sheng-Yu Zhang, Xing-You Xu, Xu-Jie Yang Nov 2008

Voltammetric Determination Of L-Cysteine At Bipyrine Bridged Copper(Ⅱ) Complex Modified Glassy Carbon Electrode, Ming-Yan Wang, Fan Yang, Sheng-Yu Zhang, Xing-You Xu, Xu-Jie Yang

Journal of Electrochemistry

A modified electrode has been constructed by depositing a novel copper(Ⅱ) complex 2biPy(ClO4)4 on the glassy carbon electrode through the method of cyclic voltammetry(CV).It was found that the modified electrode exhibited high electrocatalytic activity toward L-Cysteine oxidation with good reproducibility and high sensitivity.The peak current of semi-derivative linear scan was proportional to the concentration of L-cys in the range of 1×10-6～3×10-4 mol·L-1.The detection limit was 5×10-7 mol·L-1.

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Preparation And Electrocatalystic Performance Of Ir/C Catalyst For Ammonia Oxidation, Qing-Mei Kong, Yi-Ping Han, Ling-Juan Deng, Tian-Hong Lu, Ya-Wen Tang Nov 2008

Preparation And Electrocatalystic Performance Of Ir/C Catalyst For Ammonia Oxidation, Qing-Mei Kong, Yi-Ping Han, Ling-Juan Deng, Tian-Hong Lu, Ya-Wen Tang

Journal of Electrochemistry

The Ir/C catalyst with 30%(by mass) Ir was prepared in the CH3CH2OH and H2O binary system.The X-ray diffraction(XRD) data showed that the average sizes of the Ir particles in the Ir/C catalyst was about 2.2 nm.The results of the electrochemical measurements indicated that the electrocatalytic activity of the Ir/C catalyst for the ammonia oxidation in the neutral NaClO4 solution was similar to the Ir catalyst,while electrocatalytic stability was much better than that of the Ir catalyst.Furthermore,the peak current density of the ammonia oxidation at the Ir/C catalyst electrode showed a good linear relationship …

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Direct Electrochemistry Of Chloroperoxidase At Gc Electrode Modified With Swnts, Hong-Xia Zhang, Xia-Qin Wu, Wen-Jing Hou, Wen Xie, Zhong-Qing Lu, Rong Wang, He-Xing Li Nov 2008

Direct Electrochemistry Of Chloroperoxidase At Gc Electrode Modified With Swnts, Hong-Xia Zhang, Xia-Qin Wu, Wen-Jing Hou, Wen Xie, Zhong-Qing Lu, Rong Wang, He-Xing Li

Journal of Electrochemistry

The chloroperoxidase(CPO) was immobilized onto the surface of SWNTs modified electrodes.The electrochemical behaviors of modified electrode have been investigated by cyclic voltammetry.The appearance of a pair of well-defined redox peaks in the CV curve indicated that SWNTs can promote the electron transfer reaction of CPO.The results of cyclic voltammetry in PBS of different pH,from 3~9,showed that the reaction of CPO on the modified electrode was with equal numbers of electron and protein.This readily prepared SWNTs modified electrode showed excellent stability and good catalysis to O2.

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Solutions In Folded Geometries, And Associated Cloaking Due To Anomalous Resonance, Graeme W. Milton, Nicolae-Alexandru P. Nicorovici, Ross C. Mcphedran, Kirill Cherednichenko, Zubin Jacob Nov 2008

Solutions In Folded Geometries, And Associated Cloaking Due To Anomalous Resonance, Graeme W. Milton, Nicolae-Alexandru P. Nicorovici, Ross C. Mcphedran, Kirill Cherednichenko, Zubin Jacob

Birck and NCN Publications

Solutions for the fields in a coated cylinder where the core radius is bigger than the shell radius are seemingly unphysical, but can be given a physical meaning if one transforms to an equivalent problem by unfolding the geometry. In particular, the unfolded material can act as an impedance matched hyperlens, and as the loss in the lens goes to zero finite collections of polarizable line dipoles lying within a critical region surrounding the hyperlens are shown to be cloaked having vanishingly small dipole moments. This cloaking, which occurs both in the folded geometry and the equivalent unfolded one, is …

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