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Full-Text Articles in Engineering

Ultrahydrophobic Surface Modification Of Polymeric Fibers And Inorganic Substrates, Karthik Ramaratnam Dec 2007

Ultrahydrophobic Surface Modification Of Polymeric Fibers And Inorganic Substrates, Karthik Ramaratnam

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The wettability of a solid surface is a very important property, and is governed by both the chemical composition and the geometrical microstructure of the surface. Wettability and repellency are important properties of solid surfaces from both fundamental and practical aspects. The wettability of the solid surface is a characteristic property of materials and strongly depends on both the surface energy and the surface roughness. These properties may be approached by mimicking hydrophobic structures created by nature on lotus leaf surface. The lotus effect is based on surface roughness caused by different microstructures together with the hydrophobic properties of the …


Investigation Of Structure And Properties Of Novel Multi-Layer Clay Nanocomposite Films Produced Controllably By Continuous Chaotic Advection Blending, Chaitra Mahesha Dec 2007

Investigation Of Structure And Properties Of Novel Multi-Layer Clay Nanocomposite Films Produced Controllably By Continuous Chaotic Advection Blending, Chaitra Mahesha

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Polymer nanoclay composites have been studied extensively in the past decade due to the excellent combination of properties they can offer at low loadings of clay. Despite robust research, the potential enhancements that nanoclays are theoretically predicted to offer have not been achieved. Such potential improvements in mechanical and gas barrier properties are realized only when the internal structure of the nanocomposite is optimized in terms of arrangement and orientation of nanoclay within the matrix. The mixing-based approach and the accompanying complex flow fields of conventional processing techniques widely used to produce nanoclay composites are unable to control the internal …


Laser-Assisted Synthesis And Optical Properties Of Bismuth Nanorods, Jason Reppert Aug 2007

Laser-Assisted Synthesis And Optical Properties Of Bismuth Nanorods, Jason Reppert

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Bismuth in the bulk form is a semimetal with a rhombohedral structure. It has a small band overlap between the conduction and valence bands and a highly anisotropic electron effective-mass tensor. Thermoelectric materials, in which one of the three dimensions is in the nanometer regime, exhibit unique quantum confinement properties and have generated much interest in recent years. Theoretical investigations have suggested that nanowires with diameters <10 nm will possess a figure-of-merit ZT>2. Prior to this research, it has been shown by the Dresselhaus group at MIT that Bi nanowires with small enough diameters (~50 nm), prepared via the template-method, undergo a transition from a semimetal …


Development And In Vitro Examination Of Materials For Osseointegration, Sahil Jalota May 2007

Development And In Vitro Examination Of Materials For Osseointegration, Sahil Jalota

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Bone is a connective tissue with nanosized particles of carbonated apatitic calcium phosphate dispersed in a hydrated collagen matrix. With the ageing of the baby boomer population, an increasing number of people sustain bone fractures and defects. Hence, efforts are underway to develop materials to hasten the healing and repairing of such defects. These materials are termed as artificial bone substitutes.
This study represents innovative techniques for development of bone implant materials and improving the existing substitute materials. Emphasis was on three different kinds of materials: Metals (titanium and alloys), Ceramics (calcium phosphates), and Polymers (collagen). The bioactivity of titanium …


Study Of Structure Development During Melt Spinning Of Isotactic Polypropylene Fibers Using Raman Spectroscopy And Wide Angle X-Ray Diffraction Simultaneously , Dushyanth Pandana Jan 2007

Study Of Structure Development During Melt Spinning Of Isotactic Polypropylene Fibers Using Raman Spectroscopy And Wide Angle X-Ray Diffraction Simultaneously , Dushyanth Pandana

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ABSTRACT
Isotactic polypropylene (iPP) fibers have a wide variety of applications. Specific end-use applications require specific properties, which are dependent on the polymer morphology produced during processing. Therefore, the final properties of a material are dependent on the processing parameters. iPP fibers are produced mainly by melt spinning. The important processing parameters in the melt spinning process include, the extrusion temperatures, the throughput and shear rates, the rate of cooling, and the feed and draw roll take-up velocities. An understanding of how the morphology develops along the spinline, and the effect of processing parameters on the morphology is crucial in …


Synthesis And Photocatalysis Study Of Brookite Phase Titanium Dioxide Nanoparticles, Radhika Bhave Jan 2007

Synthesis And Photocatalysis Study Of Brookite Phase Titanium Dioxide Nanoparticles, Radhika Bhave

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Titanium dioxide is used in variety of applications like photocatalysis, self-cleaning coatings, fog proof glass and water purifier. A lot of research is being done in synthesis and applications of TiO2. Titanium dioxide or TiO2 mainly exists in three phases namely anatase, brookite and rutile. Current studies relate to synthesis of brookite phase TiO2 nanoparticles by ambient condition sol (ACS) process and characterization of these particles for phase purity, morphology and surface area analysis. The photoactivity of these particles was investigated and absorption in the visible light region was detected. This implies brookite to have good potential to be used …