Engineering Commons^™

Electrical Activation Studies Of Silicon Implanted Aluminum Gallium Nitride With High Aluminum Mole Fraction, Elizabeth A. Moore

Theses and Dissertations

This research demonstrates a method for producing highly conductive Si-implanted n-type aluminum gallium nitride (Al_xGa_1-xN) alloys, and represents a comprehensive analysis of the resulting material's electrical and optical properties as a function of Al mole fraction, anneal temperature, anneal time, and implantation dose. Highly conductive alloys are critical to the fabrication of devices operating in deep UV, high-temperature, high-power, and high-frequency environments, and thus this research is significant in regard to the application of such devices. The Al_xGa_1-xN wafers of this study, with Al concentrations of 10 to 50%, were implanted at …

Ultrahydrophobic Surface Modification Of Polymeric Fibers And Inorganic Substrates, Karthik Ramaratnam

All Dissertations

The wettability of a solid surface is a very important property, and is governed by both the chemical composition and the geometrical microstructure of the surface. Wettability and repellency are important properties of solid surfaces from both fundamental and practical aspects. The wettability of the solid surface is a characteristic property of materials and strongly depends on both the surface energy and the surface roughness. These properties may be approached by mimicking hydrophobic structures created by nature on lotus leaf surface. The lotus effect is based on surface roughness caused by different microstructures together with the hydrophobic properties of the …

Investigation Of Structure And Properties Of Novel Multi-Layer Clay Nanocomposite Films Produced Controllably By Continuous Chaotic Advection Blending, Chaitra Mahesha

All Dissertations

Polymer nanoclay composites have been studied extensively in the past decade due to the excellent combination of properties they can offer at low loadings of clay. Despite robust research, the potential enhancements that nanoclays are theoretically predicted to offer have not been achieved. Such potential improvements in mechanical and gas barrier properties are realized only when the internal structure of the nanocomposite is optimized in terms of arrangement and orientation of nanoclay within the matrix. The mixing-based approach and the accompanying complex flow fields of conventional processing techniques widely used to produce nanoclay composites are unable to control the internal …

Laser Surface Structuring Of Alumina, Sandip Pundlikrao Harimkar

Doctoral Dissertations

Alumina ceramic is an important abrasive material for grinding wheels used for rough grinding/machining of materials in manufacturing industry. Purpose of this work is to explore laser surface structuring of alumina grinding wheels for precision machining/grinding of materials by modifying surface microstructure of wheels. Major objective of this work is to study the evolution of surface microstructure and depth of modification such that microstructures/properties of modified wheels can be efficiently tailored based on fundamental understanding of physical processes taking place during laser surface structuring.

Surface structuring of alumina using a continuous wave Nd:YAG laser resulted in significant surface melting and …

A Finite Element Study Of The Contact Stiffness Of Homogenous Materials And Thin Films, Haitao Xu

Doctoral Dissertations

The applicability of the stiffness equation S=2E_ra to elastic and elastic-plastic homogeneous materials and thin films on substrates is studied by finite element techniques. It is found that the stiffness equation works well in all these materials provided that a correction factor β is included. For elastic homogenous materials, the correction factor is examined for different friction conditions, Poisson’s ratios, and indenter cone angles. In the case of elastic-plastic indentation with a 70.3° cone, the correction factor is very close to that for elastic indentation of a matching conical hole, which provides a convenient way to model the …

Processing And Phase Formation In Zr-Based Bulk-Metallic Glass-Forming Alloys, James Joseph Wall

Doctoral Dissertations

Bulk-metallic glasses have established a formidable presence in the scientific community in recent years, due to a number of properties that are uncharacteristic of metallically-bonded materials. One of the fundamental challenges facing researchers in this field is to develop new and improved processing methods with the ultimate goal of facilitating a large-scale industrial integration of the materials.

The research described herein is directed toward the pursuit of developing and improving upon the current state-of-the art in the science of bulk-metallic glass processing. A number of research and development projects were undertaken in this pursuit. First, the technology to process bulk-metallic …

Degradation Mechanism Of Expanded Polystyrene (Eps) Foam In Lost Foam Casting, Pips Approach For Synthesis And Novel Expansion Techniques For Cellular Foam, Indraneel Sen

Doctoral Dissertations

Lost Foam Casting (LFC) is a metal casting technology that facilitates fabrication of near-net shape metal castings using expanded polystyrene (EPS) foam patterns that are coated with refractory slurry and is effective for producing aluminum or iron castings of complicated geometry. However, the LFC process can produce considerable amount of scrap due to casting defects. Removing the EPS thermal decomposition products through the ceramic coating ahead of the advancing metal front during the liquid metal pour is a key factor in obtaining a defect free casting. Developing a fundamental understanding of foam degradation mechanism is essential in improving LFC process. …

A Study Of The Secondary Electrons, Yinghong Lin

Doctoral Dissertations

Slow secondary electrons (SEs) (E<50 eV) are those emitted from a sample as the result of bombardment by energetic particles. They are the most important signal source for SEM and for other advanced microanalysis techniques. SE yield δ and spectrum N(E) are the two important parameters evaluating the capability of a sample on producing SEs and the energy distribution of SEs generated from the sample respectively. Measuring δ and N(E) is not easy since SEs are easily affected by sample surface condition and by experimental configuration. Though SE has been studied since its first find in 1902, experimental date of it are inconsistent and unsystematic. Theoretical models on the SE production are not well established.

To better understand the secondary electrons, an optimization of a scattered experimental SE yield database was carried out by fitting the data to a semi-empirical universal curve and by a Monte Carlo simulation. The profiles of SE yield versus beam energy and the values of SE excitation energyε and mean SE escape depthλ were generated for 44 elements. An atomic shell filling effect was found on the maximum SE yields and the corresponding beam energies.

To obtain more accurate and systematic SE yield data, a novel experimental method by collecting electron spectra on an AES …

An Investigation On The Corrosion Resistance And Stress Corrosion Cracking Of Ductile Ni-Resist Cast Irons In Desalination Plants., Yahya Abdulla Alzafin

Theses

Two cases of stress corrosion cracking failures of brine pumps casings have been reported. These pumps are installed in two desalination plants located on the coast of Arabian Gulf in UAE. The materials of construction of failed parts are Ni-Resist Ductile Irons (NDI) and the environment is brine, which is concentrated seawater. Two brands of pumps had different lives to total failure; one lived 18 years while the other lasted only 5 years. The failed parts of former pumps were made out of NDI material as per American standard ASTM A439 D2 (designated D material) whereas those of latter pumps …

Synthesis And Structure Of Li6Y(Bo3)3 As A Neutron Scintillator, Emily Ann Sheats

Masters Theses

Single phase polycrystalline Li₆Y(BO₃)₃:Ce has been produced with substitutions of Ca, Sc, La, Sr, Gd, and Lu substituting for Y. Samples included isotopes of 6-Li and 11-B through isotopically enriched Li₂CO₃ and H₃BO₃. X-ray powder diffraction was used to verify the phase(s) present, while Rietveld refinements provided lattice parameters. Photoluminescence data were collected to verify Ce activation and proper location within the crystal structure. The amount of Ce and Ca were then varied to survey the best composition for scintillation properties within Li₆Y(BO₃) …

Correlating Grain Boundary Microstructure And Ductility Loss On Aging In Haynes® 25, Darryl Britt Glanton

Masters Theses

Haynes® 25 is a cobalt-base superalloy known for its excellent high temperature strength and corrosion resistance. However, this alloy undergoes severe embrittlement on aging at elevated temperatures. Historical research associated this ductility loss with the formation of a Co₂W Laves phase, but more recent studies have challenged the existence of this phase after prolonged aging at temperatures above 600°C. In this study, scanning and transmission electron microscopy were used to characterize the chemistry and location of precipitates in the alloy after aging at temperatures of 675 and 850°C for times up to 12,000 hours. These data were compared …

Ultrasonic Seaming Of Pet, Pet/Cotton Blend, And Spectra Fabrics, Renuka Kadiri Reddy

Master's Theses and Doctoral Dissertations

Ultrasonic seaming offers many advantages as an alternative for joining fabrics, such as efficiency, reduced cost, conservation of energy, and recyclability of the product.

The objective of this study was to investigate the effect of ultrasonic weld parameters – weld pressure, weld time, amplitude of vibration, seam design, and material properties – on seam efficiency and stiffness of a seam. This study also compares seam efficiency and stiffness of (a) ultrasonic seam to that of sewn seam and (b) ultrasonic seam from continuous mode of operation to that of plunge mode. Regression and analytical tests were used to analyze the …

Sistema De Control De Inyección Y Movimiento Para Trayectorias En Una Máquina Inyectora De Poliuretano, Orlando Pérez Rivera

Ingeniería en Automatización

No abstract provided.

Simulación Y Diseño De Un Mecanismo Automático Para Desplazamiento De Piezas En El Área De Pre-Tratamiento Químico De Partes Metálicas, Luis Carlos Romero Bonilla, Rodrigo Quiroga Contreras

Ingeniería en Automatización

No abstract provided.

Bulk Behavior Of Nanostructured Aluminum: Nanocrystalline Powders Compaction, Canning And Consolidation Via Intense Plastic Straining, Mohamed Mahmoud Hamed Shamma

Archived Theses and Dissertations

No abstract provided.

Ion Assisted Magnetron Sputtering Of Tantalum Thin Film Deposition And Characterization, Hua Ren

Dissertations

The purpose of this research was to investigate the effects of ion bombardment on the crystallographic phases of tantalum films during their deposition by magnetron sputtering process, and to gain understanding of the mechanism of the ion-solid interactions during the thin film growth. Tantalum (Ta) exists in two distinct crystallographic phases: a stable α-phase with a body centered cubic (bcc) lattice structure and a metastable β-phase with a tetragonal lattice structure. The tough and ductile α-phase Ta is desired in most industrial applications, such as diffusion barrier layers in integrated circuits, metallic corrosion protective layers, and in biomedical devices. The …

Laser-Assisted Synthesis And Optical Properties Of Bismuth Nanorods, Jason Reppert

All Theses

Bismuth in the bulk form is a semimetal with a rhombohedral structure. It has a small band overlap between the conduction and valence bands and a highly anisotropic electron effective-mass tensor. Thermoelectric materials, in which one of the three dimensions is in the nanometer regime, exhibit unique quantum confinement properties and have generated much interest in recent years. Theoretical investigations have suggested that nanowires with diameters <10 nm will possess a figure-of-merit ZT>2. Prior to this research, it has been shown by the Dresselhaus group at MIT that Bi nanowires with small enough diameters (~50 nm), prepared via the template-method, undergo a transition from a semimetal …

A Study Of Fabrication Of Ultra-High Resolution Nano Devices Through Electron Beam Lithography Process And Its Application To Electron – Optical Systems, Jihoon Kim

Doctoral Dissertations

Today’s semiconductor industry has been significantly changing in its techniques and processes for the fabrication of devices and accordingly, there has been dramatic increase in performance and a reduction in cost. To obtain still higher device performances and still further cost reduction, the dimensions of patterns in integrated circuits should be as small as possible and the 3-dimensional accuracy of multidimensional semiconductor structures should be also achieved as well. The manufacturing of smaller feature dimensions and 3-dimensional devices has been enabled by developments in lithography – the technology which transfers designed patterns onto the silicon wafer. Especially, electron beam lithography …

Guidelines For The Application Of Recycled Concrete Aggregate In The Egyptian Construction Industry, Ahmed Moustafa Essam Aly Kamel

Archived Theses and Dissertations

Construction industry is one of the most important fractions of economy worldwide. This industry consumes enormous amounts of raw materials and produces considerable waste. The optimization of construction material usage not only saves costs but also can significantly contribute towards sustainable development. The concept of recycling the construction and demolition rubble is being addressed in this study as a solution. The recycling of concrete, resulting from both the construction activities and the demolition activities, in order to be used as a source of aggregate is being focused upon in this study. Although the idea of using recycled concrete has been …

Rational Design And Investigation Of Polypeptide Multilayer Films And Capsules, Ling Zhang

Doctoral Dissertations

Three major concerns in the science of materials today are control over structure and function at the molecular level, biodegradability, and scalability of production. Polymeric materials, notably polyelectrolyte multilayer films, have shown considerable promise in all these areas, and for rational development of multifunctionality. Polypeptides constitute an especially interesting class of polyelectrolyte, given their inherent biodegradability, means of control over structure, methods of large-scale synthesis, and ability to encode biological information. Relatively little is known, however, about polypeptide multilayer films, despite recent advances in the general area.

In this dissertation, ten heteropolypeptides were designed and synthesized by Fmoc chemistry. These …

Self-Assembly And Characterization Of Germanium Quantum Dots On Silicon By Pulsed Laser Deposition, Mohammed S. Hegazy

Electrical & Computer Engineering Theses & Dissertations

Self-assembled Ge quantum dots (QD) are grown on Si(100)-(2×1) by pulsed laser deposition (PLD). In situ reflection-high energy electron diffraction (RHEED) and post-deposition atomic force microscopy (AFM) are used to study the growth dynamics and morphology of the QDs. Several films of different thicknesses were grown at a substrate temperature of 400°C using a Q-switched Nd:YAG laser (λ = 1064 mu, 40 ns pulse width, 23 J/cm2 fluence, and 10 Hz repetition rate). At low film thicknesses, but clusters that are faceted by different planes, depending on their height, are observed after the completion of the wetting layer. With increasing …

Properties Of Light Transmitting Concrete, Dina Abdel Mohsen Abou Alia

Archived Theses and Dissertations

No abstract provided.

The Effect Of Cold Work On The Mechanical Behavior Of Niti Shape Memory Alloys, Mohamed Elwi Mitwally

Archived Theses and Dissertations

No abstract provided.

High Temperature Degradation Of 5250-4 Polymer Resin, Patrick E. Link

Theses and Dissertations

5250-4 bismaleimide resin is used in high performance polymer matrix composites with high temperature aeronautical applications. This thesis investigated the thermal and oxidative degradation of 5250-4 neat resin powder in argon, air, and oxygen environments. The powder was aged at 163 deg. C, 177 deg. C, and 190 deg. C in all environments for at least 250 hours. Isothermal thermo-gravimetric analysis demonstrated that weight loss was negligible for aging in the argon environment, indicating weight loss is the result of an oxidative process at these temperatures. The 5250-4 powder exhibited an initial period of weight gain before eventually losing weight …

Experimental Investigation And Numerical Modeling Of Hybrid Glass/Carbon Frp Section Combined With Concrete Slab, Stephen Craig Raynor

Theses

No abstract provided.

Effect Of Prior Aging On Fatigue Behavior Of Im7/Bmi 5250-4 Composite At 191°C, Christine G. Ladrido

Theses and Dissertations

IM7/BMI 5250-4 with carbon fiber orientations [± 45] and [0/90] were aged in air at 191 °C for up to 1000 hours. The weight loss was analyzed during the aging process. Tension to failure tests were performed on both the unaged and aged specimens to establish a baseline for the Ultimate Tensile Strengths and Young's Modulus. Tension-tension cyclic load fatigue testing was conducted on the specimen to determine the effect of prior aging on the fatigue response of the composite. Cyclic strain accumulation was not influenced by prior aging, but it was influenced by the stress levels applied. [± 45] …

Development Of Knowledge Base Of Concrete Bridge Maintenance System, Bahre Karam

Masters Theses

Bridges are the key elements of any transportation system of a country. Bridges are expensive structures and therefore, it's essential to maintain and repair them on regular basis. Almost one third of the bridges in United States are reported to be in some what deteriorated conditions. This Research presents the development of knowledge base for decision support system for concrete bridges.

During this research various concrete bridge problems are investigated including COlTosion, delamination, cracks, spalling and scour etc. The inspection tools and techniques are addressed in order to identify these problems both for above and below water surface. The various …

Formation Of Rdx Nanoparticles By Rapid Expansion Of Supercritical Solution : In Situ Characterization By Laser Scattering, Takuya Matsunaga

Dissertations

Cyclo-1,3,5-trimethylene-2,4,6-trinitramine (RDX), a well-known energetic material, is highly explosive. Reduction of the sensitivity of RDX is desired for safe handling and

storage in military applications. Data on the sensitivity of RDX in the 10-1000 µm crystal size range suggested that the impact sensitivity could be further reduced by reduction of the crystal size to the sub-micron or nano-scale (Armstrong, 1990). Recent research with nano-RDX obtained using Rapid Expansion of Supercritical Solutions (RESS) confirmed these expectations (Stepanov, 2005).

RESS process appeared to be one out of a few techniques of production of nanoscale energetic materials free of the risk of explosion. …

Development And In Vitro Examination Of Materials For Osseointegration, Sahil Jalota

All Dissertations

Bone is a connective tissue with nanosized particles of carbonated apatitic calcium phosphate dispersed in a hydrated collagen matrix. With the ageing of the baby boomer population, an increasing number of people sustain bone fractures and defects. Hence, efforts are underway to develop materials to hasten the healing and repairing of such defects. These materials are termed as artificial bone substitutes.
This study represents innovative techniques for development of bone implant materials and improving the existing substitute materials. Emphasis was on three different kinds of materials: Metals (titanium and alloys), Ceramics (calcium phosphates), and Polymers (collagen). The bioactivity of titanium …

Plastic Deformation And Annealing Of Zr- And Cu- Based Bulk Metallic Glasses, Sujing Xie

Doctoral Dissertations

Plastic deformation in crystalline metals occurs by the motion and multiplication of lattice defects called dislocations, resulting in strain hardening. Metallic glasses, in contrast, lack long-range order; therefore, dislocation-mediated plasticity is not possible in these materials. Metallic glasses undergo plastic deformation through the nucleation and propagation of defects called shear bands, which cause strain softening.

This strain softening can be recovered after annealing, i.e., annealing makes the plastically strained metallic glasses harder, in sharp contrast to the annealing-induced softening typically observed in crystalline metals. During annealing, hardness initially recovers more rapidly in heavily deformed specimens than in lightly deformed ones, …