Engineering Commons^™

Synthesis And Structure Of Li6Y(Bo3)3 As A Neutron Scintillator, Emily Ann Sheats

Masters Theses

Single phase polycrystalline Li₆Y(BO₃)₃:Ce has been produced with substitutions of Ca, Sc, La, Sr, Gd, and Lu substituting for Y. Samples included isotopes of 6-Li and 11-B through isotopically enriched Li₂CO₃ and H₃BO₃. X-ray powder diffraction was used to verify the phase(s) present, while Rietveld refinements provided lattice parameters. Photoluminescence data were collected to verify Ce activation and proper location within the crystal structure. The amount of Ce and Ca were then varied to survey the best composition for scintillation properties within Li₆Y(BO₃) …

Correlating Grain Boundary Microstructure And Ductility Loss On Aging In Haynes® 25, Darryl Britt Glanton

Masters Theses

Haynes® 25 is a cobalt-base superalloy known for its excellent high temperature strength and corrosion resistance. However, this alloy undergoes severe embrittlement on aging at elevated temperatures. Historical research associated this ductility loss with the formation of a Co₂W Laves phase, but more recent studies have challenged the existence of this phase after prolonged aging at temperatures above 600°C. In this study, scanning and transmission electron microscopy were used to characterize the chemistry and location of precipitates in the alloy after aging at temperatures of 675 and 850°C for times up to 12,000 hours. These data were compared …

Development Of Knowledge Base Of Concrete Bridge Maintenance System, Bahre Karam

Masters Theses

Bridges are the key elements of any transportation system of a country. Bridges are expensive structures and therefore, it's essential to maintain and repair them on regular basis. Almost one third of the bridges in United States are reported to be in some what deteriorated conditions. This Research presents the development of knowledge base for decision support system for concrete bridges.

During this research various concrete bridge problems are investigated including COlTosion, delamination, cracks, spalling and scour etc. The inspection tools and techniques are addressed in order to identify these problems both for above and below water surface. The various …

The Study Of Crack Closure Phenomenon Following One Tensile Overload, Yinan Sun

Masters Theses

During the load-controlled high-cycle fatigue test, when the overload was applied, it is shown that from the crack-growth rate (da/dN) versus stress-intensity-factor range (K) curve, the crack-growth rate decreased, following the overload, which indicated the crack-closure phenomenon. The crack-growth-retardation period was observed after the overload. The goal of this study is to investigate the deformation evolution during tensile loading and unloading cycles using neutron diffraction.

Neutron diffraction is used to investigate the crack-closure phenomenon by measuring the changes in the elastic-lattice-strain profiles around the fatigue-crack tip in a compact-tension (CT) specimen during tensile loading and unloading cycles. Spatially-resolved-strain measurements were …

Traceable Standard For Sub - 100nm Metrology, Sachin Jayant Deo

Masters Theses

As we approach the 65nm technological node, transistor gates with dimensions of the order of 40nm are being manufactured. As the device performance is directly related to the dimensions of the gate, critical dimension (CD) control becomes an important part of the fabrication process. Characterization of these small feature size, generally referred to as Metrology, is an indispensable ingredient of the semiconductor manufacturing processes. Metrology relies not only on the precision, but also the accuracy of commercially used metrology tools like the CD-SEM. To facilitate the magnification calibration of the CD-SEM, an easy access to standard reference artifact traceable …

Friction Stir Processing Of Cast Magnesium Alloys, Timothy A. Freeney

Masters Theses

"This thesis investigates the feasibility and benefits of using friction stir processing as a thermo-mechanical microstructural modification tool for local property enhancement or casting repair of magnesium alloys, specifically high strength EV31A and WE43"--Abstract, page iv.

Process Development And Applications Of A Dry Film Photoresist, Phaninder R. Kanikella

Masters Theses

"In this study, dry film photoresist was patterned using UV lithography and the sidewall profile was optimized to achieve vertical sidewalls. Sidewall verticality of dry film is very important for better pattern transfer"--Abstract, page iv.

Age Strengthening Of Gray Cast Iron: Alloying Effects And Kinetics Study, Thottathil Viswanathan Anish

Masters Theses

"Age strengthening of gray cast iron has become a critical issue with metal casters trying to optimize their process for the closest conformance to properties. This necessitated more robust and precise methods to predict age strengthening. Most foundries use age strengthening behavior to cast at hight carbon equivalents to facilitate smaller gating systems. Also, it is well known in the casting industry that the tool life improves with aging. Hence these foundries require a model to predict aging behavior and accelerate the mechanism from days to hours. This research focuses on the methods of composition adjustments to control aging properties, …

Properties Of Alkaline-Resistant Calcium-Iron-Phosphate Glasses, Jiawanjun Shi

Masters Theses

"The physical properties and alkaline corrosion resistant properties of calcium-iron-phosphate glasses were studied. The addition of Fe₂O₃ decreases the thermal expansion coefficient and increases the glass fiber's Young's modulus in comparison with the addition of CaO. Bulk glass dissolution behavior in alkaline Lawrence solution was studied by weight loss experiments, Raman spectroscopy, and analytical scanning electron microscopy. The corrosion of glass powder in NaOH solution was studied by X-ray diffraction, infrared spectroscopy and high pressure liquid chromatography. The results show that the dissolution rate decreases when the phosphate chain length decreases. Calcium oxide can improve the glass durability in high …