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Chemical Engineering

2012

Chemical and Materials Engineering Faculty Publications

Articles 1 - 5 of 5

Full-Text Articles in Engineering

Novel Platform Development Using An Assembly Of Carbon Nanotube, Nanogold And Immobilized Rna Capture Element Towards Rapid, Selective Sensing Of Bacteria, Elizabeth I. Maurer, Kristen K. Comfort, Saber M. Hussain, John J. Schlager, Sharmila M. Mukhopadhyay Jun 2012

Novel Platform Development Using An Assembly Of Carbon Nanotube, Nanogold And Immobilized Rna Capture Element Towards Rapid, Selective Sensing Of Bacteria, Elizabeth I. Maurer, Kristen K. Comfort, Saber M. Hussain, John J. Schlager, Sharmila M. Mukhopadhyay

Chemical and Materials Engineering Faculty Publications

This study examines the creation of a nano-featured biosensor platform designed for the rapid and selective detection of the bacterium Escherichia coli. The foundation of this sensor is carbon nanotubes decorated with gold nanoparticles that are modified with a specific, surface adherent ribonucleic acid (RNA) sequence element. The multi-step sensor assembly was accomplished by growing carbon nanotubes on a graphite substrate, the direct synthesis of gold nanoparticles on the nanotube surface, and the attachment of thiolated RNA to the bound nanoparticles.

The application of the compounded nanomaterials for sensor development has the distinct advantage of retaining the electrical behavior …


Biomedical Properties And Preparation Of Iron Oxide-Dextran Nanostructures By Maple Technique, Carmen Steluta Ciobanu, Simona Liliana Iconaru, Eniko Gyorgy, Mihaela Radu, Marieta Costache, Anca Dinischiotu, Philippe Le Coustumer, Khalid Lafdi, Daniela Predoi Mar 2012

Biomedical Properties And Preparation Of Iron Oxide-Dextran Nanostructures By Maple Technique, Carmen Steluta Ciobanu, Simona Liliana Iconaru, Eniko Gyorgy, Mihaela Radu, Marieta Costache, Anca Dinischiotu, Philippe Le Coustumer, Khalid Lafdi, Daniela Predoi

Chemical and Materials Engineering Faculty Publications

Background: In this work the chemical structure of dextran-iron oxide thin films was reported. The films were obtained by MAPLE technique from composite targets containing 10 wt. % dextran with 1 and 5 wt.% iron oxide nanoparticles (IONPs). The IONPs were synthesized by co-precipitation method. A KrF* excimer laser source (λ = 248 nm, τFWHM≅25 ns, ν = 10 Hz) was used for the growth of the hybrid, iron oxide NPs-dextran thin films.

Results: Dextran coated iron oxide nanoparticles thin films were indexed into the spinel cubic lattice with a lattice parameter of 8.36 Å. The particle sized calculated was …


Carbon Nanotubes Grown On Glass Fiber As A Strain Sensor For Real Time Structural Health Monitoring, Matthew Boehle, Qiong Jiang, Lingchuan Li, Alexandre Lagounov, Khalid Lafdi Feb 2012

Carbon Nanotubes Grown On Glass Fiber As A Strain Sensor For Real Time Structural Health Monitoring, Matthew Boehle, Qiong Jiang, Lingchuan Li, Alexandre Lagounov, Khalid Lafdi

Chemical and Materials Engineering Faculty Publications

In order to more effectively monitor the health of composite structures, a fuzzy fiber sensor has been developed. The fuzzy fiber is a bundle of glass fibers with carbon nanotubes or nanofibers (CNTs or CNFs) grown on the surface. The nanotube coating makes the fiber bundle conductive while the small conductive path increases sensitivity. The fuzzy fiber sensor can replace conventional metal foil strain gauges in composite applications. The electrical response of the sensor is monitored in real time to measure strain, vibration, cracking and delamination. Continuous monitoring provides instant notification of any problems. Implementation of this sensor network in …


Design Mixers To Minimize Effects Of Erosion And Corrosion Erosion, Julian B. Fasano, Eric E. Janz, Kevin J. Myers Jan 2012

Design Mixers To Minimize Effects Of Erosion And Corrosion Erosion, Julian B. Fasano, Eric E. Janz, Kevin J. Myers

Chemical and Materials Engineering Faculty Publications

A thorough review of the major parameters that affect solid-liquid slurry wear on impellers and techniques for minimizing wear is presented. These major parameters include (i) chemical environment, (ii) hardness of solids, (iii) density of solids, (iv) percent solids, (v) shape of solids, (vi) fluid regime (turbulent, transitional, or laminar), (vii) hardness of the mixer's wetted parts, (viii) hydraulic efficiency of the impeller (kinetic energy dissipation rates near the impeller blades), (ix) impact velocity, and (x) impact frequency. Techniques for minimizing the wear on impellers cover the choice of impeller, size and speed of the impeller, alloy selection, and surface …


Limited Thermal Conductance Of Metal-Carbon Interfaces, Jaime J. Gengler, Sergei V. Shenogin, John E. Bultman, Ajit K. Roy, Andrey A. Voevodin, Christopher Muratore Jan 2012

Limited Thermal Conductance Of Metal-Carbon Interfaces, Jaime J. Gengler, Sergei V. Shenogin, John E. Bultman, Ajit K. Roy, Andrey A. Voevodin, Christopher Muratore

Chemical and Materials Engineering Faculty Publications

The thermal conductance for a series of metal-graphite interfaces has been experimentally measured with time-domain thermoreflectance (TDTR). For metals with Debye temperatures up to ∼400 K, a linear relationship exists with the thermal conductance values. For metals with Debye temperatures in excess of ∼400 K, the measured metal-graphite thermal conductance values remain constant near 60 MW m−2 K−1. Titanium showed slightly higher conductance than aluminum, despite the closeness of atomic mass and Debye temperature for the two metals. Surface analysis was used to identify the presence of titaniumcarbide at the interface in contrast to the aluminum and gold-carbon interfaces (with …