Engineering Commons^™

Opportunistic Scheduling And Cooperative Relaying In Wireless Networks, Yufeng Wang

USF Tampa Graduate Theses and Dissertations

The demand for ever larger, more efficient, reliable and cost effective communication networks necessitates new network architectures, such as wireless ad hoc networks, cognitive radio, relaying networks, and wireless sensor networks. The study of such networks requires a fundamental shift from thinking of a network as a collection of independent communication pipes, to a multi-user channel where users cooperate via conferencing, relaying, and joint source-channel coding.

The traditional centralized networks, such as cellular networks, include a central controller and a fixed infrastructure, in which every node communicates with each other via a centralized based station (BS). However, for a decentralized …

Analysis And Optimization Of Broadband Measurement Cells For The Characterization Of Dielectric Polymer Films, Scott Skidmore

USF Tampa Graduate Theses and Dissertations

The current techniques and methodologies used in the field of material characterization are well documented and widely accepted as reliable and accurate. However, literature describing these techniques focuses on the algorithms used during material characterization; few studies have reposted on the design of, and the selection criteria for, the test fixtures themselves. This research focuses on the measurement cell with the goal of determining the sensitivity of the measurement cell to the addition of a thin film material.

Microstrip and coplanar waveguide were chosen for the analysis, which included three configurations of each transmission line geometry: a reference with no …

The Electronic Structure Of Biomolecular Self-Assembled Monolayers, Matthaeus Anton Wolak

USF Tampa Graduate Theses and Dissertations

The studies presented here address the characterization of the electronic structure of various self-assembled monolayers (SAMs) of peptide nucleic acid (PNA) and tetraphenylporphyrin (TPP) SAMs and arrays, formed on gold substrates.

PNA is a promising alternative to DNA for bio-sensing applications, as well as for strategies for self-assembly based on nucleic acid hybridization. In recent years charge transfer through PNA molecules was a focus of research due to possible applications in self-assembled molecular circuits and molecular tools. In light of this research it is interesting to investigate the electronic structure of PNA interfaces to gold, a potential electrode material.

TPP …

Development Of A Bi-Directional Electronics Platform For Advanced Neural Applications, Luca Abbati

USF Tampa Graduate Theses and Dissertations

This work presents a high-voltage, high-precision bi-directional multi-channel system capable of stimulating neural activity through bi-phasic pulses of amplitude up to ∓50 V while recording very low-voltage responses as low as tens of microvolts. Most of the systems reported from the scientific community possess at least one of the following common limitations: low stimulation voltages, low gain capabilities, or insufficient bandwidth to acquire a wide range of different neural activities.

While systems can be found that present remarkable capabilities in one or more specific areas, a versatile system that performs over all these aspects is missing. Moreover, as many novel …

Improving The Throughput And Reliability Of Wireless Sensor Networks With Application To Wireless Body Area Networks, Gabriel Arrobo

USF Tampa Graduate Theses and Dissertations

This dissertation will present several novel techniques that use cooperation and diversity to improve the performance of multihop Wireless Sensor Networks, as measured by throughput, delay, and reliability, beyond what is achievable with conventional error control technology.

We will investigate the applicability of these new technologies to Wireless Body Area Networks (WBANs) an important emerging class of wireless sensor networks. WBANs, which promise significant improvement in the reliability of monitoring and treating people's health, comprise a number of sensors and actuators that may either be implanted in vivo or mounted on the surface of the human body, and which are …

Basal Graph Structures For Geometry Based Organization Of Wide-Baseline Image Collections, Aveek Shankar Brahmachari

USF Tampa Graduate Theses and Dissertations

We propose algorithms for organization of images in wide-area sparse-view datasets. In such datasets, if the images overlap in scene content, they are related by wide-baseline geometric transformations. The challenge is to identify these relations even if the images sparingly overlap in their content. The images in a dataset are then grouped into sets of related images with the relations captured in each set as a basal (minimal and foundational) graph structures. Images form the vertices in the graph structure and the edges define the geometric relations between the images. We use these basal graphs for geometric walkthroughs and detection …

Design Of A Reversible Alu Based On Novel Reversible Logic Structures, Matthew Arthur Morrison

USF Tampa Graduate Theses and Dissertations

Programmable reversible logic is emerging as a prospective logic design style for implementation in modern nanotechnology and quantum computing with minimal impact on circuit heat generation. Recent advances in reversible logic using and quantum computer algorithms allow for improved computer architecture and arithmetic logic unit designs. In this paper, a 2*2 Swap gate which is a reduced implementation in terms of quantum cost and delay to the previous Swap gate is presented. Next, a novel 3*3 programmable UPG gate capable of calculating the fundamental logic calculations is presented and verified, and its advantages over the Toffoli and Peres gates are …

Model Estimation Of Electric Power Systems By Phasor Measurement Units Data, Yasser Wehbe

USF Tampa Graduate Theses and Dissertations

This dissertation tackles the online estimation of synchronous machines' power subsystems electromechanical models using the output based Phasor Measurements Units (PMUs) data while disregarding any inside data. The research develops state space models

and estimates their parameters and states. The research tests the developed algorithms against models of a higher and of the same complexity as the estimated models.

The dissertation explores two estimations approaches using the PMUs data: i)non-linear Kalman filters namely the Extended Kalman Filter (EKF) and then the Unscented

Kalman Filter (UKF) and ii) Least Squares Estimation (LSE) with Finite Differences (FN) and then with System Identification. …

Zno Nanostructures: Growth, Characterization And Applications, Mikhail Ladanov

USF Tampa Graduate Theses and Dissertations

ZnO nanostructures have been investigated for quite a long time. However, only recently they triggered much interest due to advances in materials synthesis and characterization, as well as emerging demand for new nanostructured materials in novel device implementations.

A large part of the work was devoted to exploring new methodology for patterning growth sites and controlling nanowires morphology using the deposition methods that are compatible with integrated circuits (IC) processing. Microcontact printing was used to pattern the seeding layer, and, subsequently, ZnO nanowires through a resistless soft lithography process.

When considering hydrothermal growth of ZnO nanowires in the framework of …

Development Of A Reliable Metal-Insulator-Metal Bilayer Tunnel Junction For Wideband Detectors, Rudraskandan Ratnadurai

USF Tampa Graduate Theses and Dissertations

Detectors and sensors are an integral part of modern electronics and are crucial to highly sensitive applications. Metal-Insulator-Metal (MIM) tunnel junctions have been explored for the past five decades and are still being investigated due to its wide use of applications such as mixers, capacitors, detectors, rectifiers and energy conversion devices. In this research, various designs of thin film based tunnel junctions have been investigated and the optimum one picked for the purpose of a wide band detector up to 10GHz based on their sensitivities. A modified design with an isolation layer incorporating a self-aligning method to increase fabrication throughput …

Multistable Shape-Shifting Surfaces (Mssss), Paul Joseph Montalbano

USF Tampa Graduate Theses and Dissertations

This paper presents designs for Multistable Shape-Shifting Surfaces (MSSS) by introducing bistability into the Shape-Shifting Surface (SSS). SSSs are defined as surfaces that retain their effectiveness as a physical barrier while undergoing changes in shape. The addition of bistability to the SSS gives the surface multiple distinct positions in which it remains when shifted to, i.e. by designing bistability into a single SSS link, the SSS unit cell can change into multiple shapes, and stabilize within the resulting shape, while maintaining integrity against various forms of external assaults normal to its surface. Planar stable configurations of the unit cell include, …

Encapsulation Of High Temperature Phase Change Materials For Thermal Energy Storage, Rupa Nath

USF Tampa Graduate Theses and Dissertations

Thermal energy storage is a major contributor to bridge the gap between energy demand (consumption) and energy production (supply) by concentrating solar power. The utilization of high latent heat storage capability of phase change materials is one of the keys to an efficient way to store thermal energy. However, some of the limitations of the existing technology are the high volumetric expansion and low thermal conductivity of phase change materials (PCMs), low energy density, low operation temperatures and high cost. The present work deals with encapsulated PCM system, which operates at temperatures above 500°C and takes advantage of the heat …

Volume-Phase Transitions In Responsive Photo-Cross-Linked Polymer Network Films, Leena Patra

USF Tampa Graduate Theses and Dissertations

The overall thrust of this project is to gain an insight into a class of surface-tethered cross-linked thin films of poly(N-alkylacrylamides) that display a lower critical solution temperature (LCST).The structure of the alkyl group and the modification of the amide groups determine the LCST and resultant volume-phase transition behavior. The aim of this study involves synthesis and characterization of thin films and to correlate the volume-transition behavior to the structure of the alkyl group. For better understanding the volume-transition behavior, the polymer films are perturbed by the Hofmeister salt series to examine trends between different alkyl groups. While most of …

Field And Laboratory Comparison Of The Hydraulic Performance Of Two Ceramic Pot Water Filters, Duncan Peabody

USF Tampa Graduate Theses and Dissertations

Currently 884 million people worldwide are living without access to an improved source of drinking water (WHO/UNICEF, 2011). Piped-water on premises is the ultimate goal of World Health Organization (WHO) due to the ability to treat all of the water and distribute it safely in pressurized pipes. However, Household Water Treatment and Safe Storage (HWTS) is an option for improving the quality of drinking water where that infrastructure is not yet developed, especially where there is a risk of recontamination between point of collection and point of use (Clasen, 2006).

This study analyzed one such HWTS, the ceramic pot water …

Estimation Of The Impact Of Single Airport And Multi-Airport System Delay On The National Airspace System Using Multivariate Simultaneous Models, Nagesh Nayak

USF Tampa Graduate Theses and Dissertations

Airline delays lead to a tremendous loss of time and resources and cost billions of dollars every year in the United States (U.S.). At certain times, individual airports become bottlenecks within the National Airspace System (NAS). To explore solutions for reducing the delay, it is essential to understand factors causing flight delay and its impact on airports in the NAS. Major causal factors of flight delay at airports include over-scheduling, en-route convective weather, reduced ceiling and visibility around airports, and upstream delay propagation. Delay at one airport can be passed on to other airports in the NAS, in another word, …

Cell Adhesion And Migration On Ndga Cross-Linked Fibrillar Collagen Matrices For Tendon Tissue Engineering, Ana Ysabel Rioja

USF Tampa Graduate Theses and Dissertations

Tendons, essential tissues that connect muscles to bones, are susceptible to rupture/degeneration due to their continuous use for enabling movement. Often surgical intervention is required to repair the tendon; relieving the pain and fixing the limited mobility that occurs from the damage. Unfortunately, post-surgery immobilization techniques required to restore tendon properties frequently lead to scar formation and reduced tendon range of motion. Our ultimate goal is to create an optimal tendon prosthetic that can stabilize the damaged muscle-bone connection and then be remodeled by resident cells from the surrounding tissues over time to ensure long-term function. To achieve this, we …

Macroencapsulation Of Phase Change Materials For Thermal Energy Storage, Swetha Pendyala

USF Tampa Graduate Theses and Dissertations

The use of a latent heat storage system using phase change materials (PCMs) is an effective way of storing thermal energy. Latent heat storage enables high-energy storage density which reduces the footprint of the system and the cost. However, PCMs have very low thermal conductivities making them unsuitable for large-scale use without enhancing the effective thermal conductivity. In order to address, the low thermal conductivity of the PCMs, macroencapsulation of PCMs has been adopted as an effective technique. The macroencapsulation not only provides a self-supporting structure of PCM and separates the PCM from thermal fluids but also enhances the heat …

A Statically Balanced Shape-Shifting Surface, Joseph Eugene Pishnery

USF Tampa Graduate Theses and Dissertations

ABSTRACT

This paper presents a concept for producing a Statically Balanced Shape-Shifting Surface (SB-SSS). In this context, an SB-SSS is a surface that can require near-zero magnitude force changes to accomplish a change in shape while retaining effectiveness as a physical barrier. This paper focuses on how to statically balance a specifically-designed compliant mechanism and how to incorporate this mechanism into a polygonal cell.

The mechanism consists of a compliant Peaucellier-Lipkin linkage layered with a pre-stressed link as the balancer. Previous work is presented that can show how a polygonal cell can be incorporated into a surface via a tiling …

Novel Blends Of Sulfur-Tolerant Water-Gas Shift Catalysts For Biofuel Applications, Timothy Michael Roberge

USF Tampa Graduate Theses and Dissertations

As traditional sources of energy become depleted, significant research interest has gone into conversion of biomass into renewable fuels. Biomass-derived synthesis gas typically contains concentrations of approximately 30 to 600 ppm H2S in stream. H2S is a catalyst poison which adversely affects downstream processing of hydrogen for gas to liquid plants. The water-gas shift reaction is an integral part of converting CO and steam to H2 and CO2. Currently, all known water-gas shift catalysts deactivate in sulfur concentrations typical of biomass-derived synthesis gas. Novel catalysts are needed to remain active in the presence of sulfur concentrations in order to boost …

Analysis And Remediation Of Chlorinated Hydrocarbons In Environmental Media, Jonathan Ticknor

USF Tampa Graduate Theses and Dissertations

The two objectives of this work were to develop a simplified method for the analysis of chlorinated organics in water samples and to improve an existing soil remediation technology. The contaminants considered for these studies were chlorinated hydrocarbons because of their relative frequency of appearance at contaminated sites. The first half of this study involved the analysis of chlorinated ethenes by gas chromatography with flame ionization detection (GC-FID). I tested the hypothesis that the FID response factor is the same for all chlorinated ethene compounds. The rationale for this investigation is that if the hypothesis is correct, a single calibration …

Experimental And Numerical Investigation Of An Electrospray Rf Ion Funnel, Eric Miguel Tridas

USF Tampa Graduate Theses and Dissertations

Using experimental techniques along with computational fluid dynamics and electrodynamic simulations the performance of the first of three focusing elements in an electrospray macromolecular patterning system was assessed. The performance of this element, the ion funnel, was analyzed by varying the parameters and electric field applied to the system including electrospray emitter to atmosphere-vacuum interface capillary distance, temperature of the desolvating heater, injection rate of solution and the voltage applied to the jet disruption element. Results indicated that processes involved in injecting larger droplets into the chamber resulted in a less effective transmission of the ions through the funnel. Droplet …

On The Development Of The Extradosed Bridge Concept, Steven Lynn Stroh

USF Tampa Graduate Theses and Dissertations

The Extradosed Prestressed Bridge represents a relatively new bridge type. The first of this type bridge was constructed in Japan in 1994, and Japan has since built at least 29 examples of this bridge type. Throughout the rest of the world, another 34 of this bridge type have been built, with most countries having only one, or at most a few, examples. A broader application of this bridge type has been hampered by lack of design information and in particular lack design criteria for the stay cables. The purpose of this dissertation is to progress the understanding and application of …

Shelf-Scale Mapping Of Fish Distribution Using Active And Passive Acoustics, Carrie Christy Wall

USF Tampa Graduate Theses and Dissertations

Fish sound production has been associated with courtship and spawning behavior. Acoustic recordings of fish sounds can be used to identify distribution and behavior. Passive acoustic monitoring (PAM) can record large amounts of acoustic data in a specific area for days to years. These data can be collected in remote locations under potentially unsafe seas throughout a 24-hour period providing datasets unattainable using observer-based methods. However, the instruments must withstand the caustic ocean environment and be retrieved to obtain the recorded data. This can prove difficult due to the risk of PAMs being lost, stolen or damaged, especially in highly …

Catalytic Tri-Reforming Of Biomass-Derived Syngas To Produce Desired H2:Co Ratios For Fuel Applications, Devin Mason Walker

USF Tampa Graduate Theses and Dissertations

This study focuses on upgrading biomass derived syngas for the synthesis of liquid fuels using Fischer-Tropsch synthesis (FTS). The process includes novel gasification of biomass via a tri-reforming process which involves a synergetic combination of CO2 reforming, steam reforming, and partial oxidation of methane. Typical biomass-derived syngas H2:CO is 1:1 and contains tars that deactivate FT catalyst. This innovation allows for cost-effective one-step production of syngas in the required H2:CO of 2:1 with reduction of tars for use in the FTS. To maximize the performance of the tri-reforming catalyst, an attempt to control oxygen mobility, thermal stability, dispersion of metal, …

Smart Packaging: A Novel Technique For Localized Drug Delivery For Ovarian Cancer, Eva Christabel Williams

USF Tampa Graduate Theses and Dissertations

Localized drug delivery is emerging as an effective technique due to its ability to administer therapeutic concentrations and controlled release of drugs to cancer sites in the body. It also prevents the contact of harsh chemotherapy drugs to healthy regions in the body that otherwise would become exposed to current treatments.

This study reports on a model chemotherapy drug delivery system comprising non-ionic surfactant vesicles (niosomes) packaged within a temperature-sensitive chitosan network. This smart packaging, or package-within-a package system, provides two distinct advantages. First, the gel prevents circulation of the niosomes and maintains delivery in the vicinity of a tumor. …

Effects Of Random Cross-Sectioned Distributions, Fiber Misalignment And Interphases In Three-Dimensional Composite Models On Transverse Shear Modulus, Jarrett Zitko

USF Tampa Graduate Theses and Dissertations

Finite element analysis was implemented to evaluate the transverse shear modulus of a unidirectional glass/epoxy fiber-matrix composite based on pure shear displacement boundary conditions. Unit cells consisting of three-dimensional glass cylinders surrounded in square-cuboid epoxy matrices were modeled to represent "Representative Volume Element" (RVE) configurations in periodic and random-periodic square cell arrangements of variable size. Three RVEs were constructed and analyzed: A single unit cell, a 9-cell (3 x 3) array, and a 25-cell (5 x 5) array. Additionally, the unit cell was modeled to include an interphase. Three sets of cell arrangements were constructed and evaluated: a periodic square …

Corrosion Evaluation And Durability Estimation Of Aluminized Steel Drainage Pipes, Mersedeh Akhoondan

USF Tampa Graduate Theses and Dissertations

Aluminized steel pipes are expected to have a long service life, e.g. 75 years. Spiral ribbed aluminized pipes (SRAP) have been widely specified and used by the Florida Department of Transportation (FDOT) for drainage of runoff water. Confidence in the long term durability of SRAP has been challenged by recent unexpected early corrosion failures in various Florida locations. SRAP premature corrosion incidents have occurred in two modalities. Mode A has taken place in near-neutral soil environments and has often been associated with either gross manufacturing defects (i.e. helical cuts) or corrosion concentration at or near the ribs. Mode B took …

Theory And Modeling Of Graphene And Single Molecule Devices, Lyudmyla Adamska

USF Tampa Graduate Theses and Dissertations

This dissertation research is focused on first principles studies of graphene and single organic molecules for nanoelectronics applications. These nanosized objects attracted considerable interest from the scientific community due to their promise to serve as building blocks of nanoelectronic devices with low power consumption, high stability, rich functionality, scalability, and unique potentials for device integration. Both graphene electronics and molecular electronics pursue the same goal by using two different approaches: top-down approach for graphene devices scaling to smaller and smaller dimensions, and bottom-up approach for single molecule devices. One of the goals of this PhD research is to apply first-principles …

Synthesis And Physical Properties Of Group 14 Intermetallic Clathrates, Stevce Stefanoski

USF Tampa Graduate Theses and Dissertations

The search of materials relevant for thermoelectric and magnetocaloric applications, as well as materials that interact with light, is an important aspect of the materials science. Such materials can be used for solid-state power generation and refrigeration, as light sources, detectors, or controllers. Intermetallic clathrates have long been of interest for the materials science research. The promise these materials hold for useful applications ranges from thermoelectrics to photovoltaics and optoelectronics to potentially ultra-hard materials and magnetic cooling applications. Their unique physical properties are intimately related to their intriguing structural properties. Thus a fundamental understanding of the chemistry and physics of …

Chemical Mechanical Planarization Of Electronic Materials, Fnu Atiquzzaman

USF Tampa Graduate Theses and Dissertations

In the modern semiconductor manufacturing processes, chemical mechanical planarization (CMP) has attained important processing step because of its ability to provide global planarization. CMP is the planarization technique which is used for the removal of excess material, as left over from the previous processing steps. In addition, CMP offers a uniform surface that is essential for subsequent processing steps, especially for the high resolution photolithography processes. In simpler notation, CMP is a process where a chemical reaction enhances in obtaining a planar surface through removal of the mechanical materials from a wafer.

In this study, CMP performance of three electronic …