Engineering Commons^™

Optical Investigations Of Ingan Heterostructures And Gesn Nanocrystals For Photonic And Phononic Applications: Light Emitting Diodes And Phonon Cavities, Shopan D. Hafiz

Theses and Dissertations

InGaN heterostructures are at the core of blue light emitting diodes (LEDs) which are the basic building blocks for energy efficient and environment friendly modern white light generating sources. Through quantum confinement and electronic band structure tuning on the opposite end of the spectrum, Ge_1−xSn_x alloys have recently attracted significant interest due to its potential role as a silicon compatible infra-red (IR) optical material for photodetectors and LEDs owing to transition to direct bandgap with increasing Sn. This thesis is dedicated to establishing an understanding of the optical processes and carrier dynamics in InGaN heterostructures for achieving …

The Modification Of Silica Aerogel Materials For Contemporary Use, Lauren White

Theses and Dissertations

Aerogel materials have had limited utility due to their fragility, geometrical limitations, fabrication costs and protracted fabrication times. The objective of this project was to eliminate these limitations. Native, cross-linked and hybrid aerogel monoliths have been fabricated using a newly developed one-pot method without the need for solvent exchange. The key to this technique is the use of an ethanol–water azeotrope mixture, which contains 4.4% water by volume, as both a gelation and supercritical drying solvent. The small water content allows for drying at temperatures close to the supercritical temperature of the dry solvent, where reactions such as silica dissolution …

Hybrid Straintronics-Spintronics: Energy-Efficient Non-Volatile Devices For Boolean And Non-Boolean Computation, Ayan K. Biswas

Theses and Dissertations

Research in future generation computing is focused on reducing energy dissipation while maintaining the switching speed in a binary operation to continue the current trend of increasing transistor-density according to Moore’s law. Unlike charge-based CMOS technology, spin-based nanomagnetic technology, based on switching bistable magnetization of single domain shape-anisotropic nanomagnets, has the potential to achieve ultralow energy dissipation due to the fact that no charge motion is directly involved in switching. However, switching of magnetization has not been any less dissipative than switching transistors because most magnet switching schemes involve generating a current to produce a magnetic field, or spin transfer …

Novel Small Airway Model Using Electrospun Decellularized Lung Extracellular Matrix, Bethany M. Young

Theses and Dissertations

Chronic respiratory diseases affects many people worldwide with little known about the mechanisms diving the pathology, making it difficult to find a cure. Improving the understanding of smooth muscle and extracellular matrix (ECM) interaction is key to developing a remedy to this leading cause of death. With currently no relevant or controllable in vivo or in vitro model to investigate diseased and normal interactions of small airway components, the development of a physiologically relevant in vitro model with comparable cell attachment, signaling, and organization is necessary to develop new treatments for airway disease. The goal of this study is to …

Direct L2 Support Vector Machine, Ljiljana Zigic

Theses and Dissertations

This dissertation introduces a novel model for solving the L2 support vector machine dubbed Direct L2 Support Vector Machine (DL2 SVM). DL2 SVM represents a new classification model that transforms the SVM's underlying quadratic programming problem into a system of linear equations with nonnegativity constraints. The devised system of linear equations has a symmetric positive definite matrix and a solution vector has to be nonnegative.

Furthermore, this dissertation introduces a novel algorithm dubbed Non-Negative Iterative Single Data Algorithm (NN ISDA) which solves the underlying DL2 SVM's constrained system of equations. This solver shows significant speedup compared to several other state-of-the-art …

Electrochemical Studies Of Cerium And Uranium In Licl-Kcl Eutectic For Fundamentals Of Pyroprocessing Technology, Dalsung Yoon

Theses and Dissertations

Understanding the characteristics of special nuclear materials in LiCl-KCl eutectic salt is extremely important in terms of effective system operation and material accountability for safeguarding pyroprocessing technology. By considering that uranium (U) is the most abundant and important element in the used nuclear fuel, measurements and analyses of U properties were performed in LiCl-KCl eutectic salt. Therefore, the electrochemical techniques such as cyclic voltammetry (CV), open circuit potential (OCP), Tafel, linear polarization (LP), and electrochemical impedance spectroscopy (EIS) were conducted under different experimental conditions to explore the electrochemical, thermodynamic, and kinetic properties of U in LiCl-KCl eutectic. The ultimate goal …

Measurement Of Rare Earth And Uranium Elements Using Laser-Induced Breakdown Spectroscopy (Libs) In An Aerosol System For Nuclear Safeguards Applications, Ammon N. Williams

Theses and Dissertations

The primary objective of this research is to develop an applied technology and provide an assessment for remotely measuring and analyzing the real time or near real time concentrations of used nuclear fuel (UNF) elements in electrorefiners (ER). Here, Laser-Induced Breakdown Spectroscopy (LIBS) in UNF pyroprocessing facilities was investigated. LIBS is an elemental analysis method, which is based on the emission from plasma generated by focusing a laser beam into the medium. This technology has been reported to be applicable in solids, liquids (includes molten metals), and gases for detecting elements of special nuclear materials. The advantages of applying the …

Optimizing Virtual Machine I/O Performance In Cloud Environments, Tao Lu

Theses and Dissertations

Maintaining closeness between data sources and data consumers is crucial for workload I/O performance. In cloud environments, this kind of closeness can be violated by system administrative events and storage architecture barriers. VM migration events are frequent in cloud environments. VM migration changes VM runtime inter-connection or cache contexts, significantly degrading VM I/O performance. Virtualization is the backbone of cloud platforms. I/O virtualization adds additional hops to workload data access path, prolonging I/O latencies. I/O virtualization overheads cap the throughput of high-speed storage devices and imposes high CPU utilizations and energy consumptions to cloud infrastructures. To maintain the closeness between …

Improved Capability Of A Computational Foot/Ankle Model Using Artificial Neural Networks, Ruchi D. Chande

Theses and Dissertations

Computational joint models provide insight into the biomechanical function of human joints. Through both deformable and rigid body modeling, the structure-function relationship governing joint behavior is better understood, and subsequently, knowledge regarding normal, diseased, and/or injured function is garnered. Given the utility of these computational models, it is imperative to supply them with appropriate inputs such that model function is representative of true joint function. In these models, Magnetic Resonance Imaging (MRI) or Computerized Tomography (CT) scans and literature inform the bony anatomy and mechanical properties of muscle and ligamentous tissues, respectively. In the case of the latter, literature reports …

Characterization Of Poly(Dimethylsiloxane) Blends And Fabrication Of Soft Micropillar Arrays For Force Detection, Thomas J. Petet Jr

Theses and Dissertations

Diseases involving fibrosis cause tens of thousands of deaths per year in the US alone. These diseases are characterized by a large amount of extracellular matrix, causing stiff abnormal tissues that may not function correctly. To take steps towards curing these diseases, a fundamental understanding of how cells interact with their substrate and how mechanical forces alter signaling pathways is vital. Studying the mechanobiology of cells and the interaction between a cell and its extracellular matrix can help explain the mechanisms behind stem cell differentiation, cell migration, and metastasis. Due to the correlation between force, extracellular matrix assembly, and substrate …

Design And Development Of A High-Temperature High-Pressure Rolling Ball Viscometer/Densimeter And Evaluation Of Star Polymer-Solvent Mixtures, Matthew Stanton Newkirk

Theses and Dissertations

Modern automotive applications such as transmission clutch plates, combustion chambers, diesel fuel injector tips, and axle gears and friction plates operate at temperatures that can exceed 250°C and pressures of 40,000 psia. Industrial practice is to add homopolymers and copolymers to base oils to modify bulk fluid viscosity and frictional properties for these demanding applications. However, designing polymeric additives for lubricants and predicting their performance is limited by the lack of available high-temperature high-pressure (HTHP) viscosity and density data needed to test contemporary lubricity models. Thus, a major objective of this thesis is the design, development, and commissioning of a …

An Investigation Of Kinetic Visual Biofeedback On Dynamic Stance Symmetry, Trisha J. Massenzo

Theses and Dissertations

The intent of the following research is to utilize task-specific, constraint-induced therapies and apply towards dynamic training for symmetrical balance. Modifications to an elliptical trainer were made to both measure weight distributions during dynamic stance as well as provide kinetic biofeedback through a man-machine interface. Following a review of the background, which includes research from several decades that are seminal to current studies, a design review is discussed to cover the design of the modified elliptical (Chapter 2).

An initial study was conducted in a healthy sample population in order to determine the best visual biofeedback representation by comparing different …

Joint Detection-State Estimation And Secure Signal Processing, Mengqi Ren

Theses and Dissertations

In this dissertation, joint detection-state estimation and secure signal processing are studied. Detection and state estimation are two important research topics in surveillance systems. The detection problems investigated in this dissertation include object detection and fault detection. The goal of object detection is to determine the presence or absence of an object under measurement uncertainty. The aim of fault detection is to determine whether or not the measurements are provided by faulty sensors. State estimation is to estimate the states of moving objects from measurements with random measurement noise or disturbance, which typically consist of their positions and velocities over …

A Reused Distance Based Analysis And Optimization For Gpu Cache, Dongwei Wang

Theses and Dissertations

As a throughput-oriented device, Graphics Processing Unit(GPU) has already integrated with cache, which is similar to CPU cores. However, the applications in GPGPU computing exhibit distinct memory access patterns. Normally, the cache, in GPU cores, suffers from threads contention and resources over-utilization, whereas few detailed works excavate the root of this phenomenon. In this work, we adequately analyze the memory accesses from twenty benchmarks based on reuse distance theory and quantify their patterns. Additionally, we discuss the optimization suggestions, and implement a Bypassing Aware(BA) Cache which could intellectually bypass the thrashing-prone candidates.

BA cache is a cost efficient cache design …

Collecting Unsolicited User-Generated Change Requests, Joseph W. Goldsmith

Theses and Dissertations

Unlike aircrew directly associated with acquisitions, line operators are not fully engaged in the methods to push materiel hardware or software change requests up the chain, to a decision maker, and then to the engineers. The Air Force trains these end users to logically apply expert systems knowledge to execute the mission but has not fully leveraged this resource for properly identifying and correcting operational shortfalls in an aircraft's design. Focusing on the Remotely Piloted Aircraft (RPA) community, the research goal is to determine if the Air Force should establish a formal program for collecting and prioritizing unsolicited user change …

Demonstration Of Inexact Computing Implemented In The Jpeg Compression Algorithm Using Probabilistic Boolean Logic Applied To Cmos Components, Christopher I. Allen

Theses and Dissertations

Probabilistic computing offers potential improvements in energy, performance, and area compared with traditional digital design. This dissertation quantifies energy and energy-delay tradeoffs in digital adders, multipliers, and the JPEG image compression algorithm. This research shows that energy demand can be cut in half with noisesusceptible16-bit Kogge-Stone adders that deviate from the correct value by an average of 3 in 14 nanometer CMOS FinFET technology, while the energy-delay product (EDP) is reduced by 38 . This is achieved by reducing the power supply voltage which drives the noisy transistors. If a 19 average error is allowed, the adders are 13 times …

Comparison Of Novel Carboneous Structures To Treat Nitroaromatic Impacted Water, Benjamin M. Doane

Theses and Dissertations

Carboneous materials such as carbon nanotube (CNT), granular activated carbon (GAC), and biochar are promising materials for the removal of organic contaminants from aqueous phase solutions. CNTs have astonishing mechanical strength, chemical and thermal stability and high surface area. While biochar, similar to GAC, having an extremely porous structure and high surface area, can be produced in more austere conditions with native materials. In this study, novel CNT-Hybrid structures (CNT-HS), hardwood pellet (HWP) Biochar and standard GAC (F-600 GAC) were used as adsorbents to treat water contaminated by a model nitroaromatic compound, 2,4-dinitrotoluene (DNT).

Design And Implementation Of A Unified Command And Control Architecture For Multiple Cooperative Unmanned Vehicles Utilizing Commercial Off The Shelf Components, Jeremy Gray

Theses and Dissertations

Small unmanned systems provide great utility to military applications due to their portable and expendable design. These systems are, however, costly to develop, produce, and maintain, making it desirable to integrate available commercial off the shelf (COTS) components. This research investigates the integration of COTS components through the development of a modular unified command and control (C2) architecture for heterogeneous and homogeneous vehicle teams to accomplish formation flocking and communication relay scenarios. A vehicle agnostic architecture was developed to be applied across different vehicle platforms, different vehicle combination, and different cooperative missions. COTS components consisting primarily of open source hardware …

Continuous Decision Support, Jeremy P. Hendrix

Theses and Dissertations

Organizations are often faced with portfolio construction efforts that require them to select one or more alternatives, subject to resource constraints, with the aim of achieving the maximum value possible. This is a well-defined problem with a number of analytically defensible approaches, provided the entire set of alternatives is known when the decision event takes place. Less well treated in the literature is how to approach this problem when the entire set of alternatives is unknown, as when the alternatives arrive over time. This change in the availability of data shifts the problem from one of identifying an optimal subset …

Application Of Executable Architectures In Early Concept Evaluation, Ryan M. Pospisal

Theses and Dissertations

This research explores use of executable architectures to guide design decisions in the early stages of system development. Decisions made early in the system development cycle determine a majority of the total lifecycle costs as well as establish a baseline for long term system performance and thus it is vital to program success to choose favorable design alternatives. The development of a representative architecture followed the Architecture Based Evaluation Process as it provides a logical and systematic order of events to produce an architecture sufficient to document and model operational performance. In order to demonstrate the value in the application …

Investigation Of Electromagnetic Signatures Of A Fpga Using An Aprel Em-Isight System, Karynn A. Sutherlin

Theses and Dissertations

Large military platforms have encountered major performance and reliability issues due to an increased number of incidents with counterfeit electronic parts. This has drawn the attention of Department of Defense (DOD) leadership making detection and avoidance of counterfeit electronic parts a top issue for national defense. More defined regulations and processes for identifying, reporting, and disposing of counterfeit electronic parts are being revised to raise awareness for this aggregating issue, as well as enhance the detection of these parts. Multiple technologies are currently employed throughout the supply chain to detect counterfeit electronic parts. These methods are often costly, time-consuming, and …

Creep And Oxidation Of Hafnium Diboride-Based Ultra High Temperature Ceramics At 1500°C, Anthony J. Degregoria

Theses and Dissertations

Ultra high temperature ceramics (UHTCs) are leading candidates for aerospace structural applications in high temperature environments, including the leading edges of hypersonic aircraft and thermal protection systems for atmospheric re-entry vehicles. Before UHTCs can be used in such applications, their structural integrity and environmental durability must be assured, which requires a thorough understanding and characterization of their creep and oxidation behavior at relevant service temperatures.

Optimal Attitude Control Of Agile Spacecraft Using Combined Reaction Wheel And Control Moment Gyroscope Arrays, Cole C. Doupe

Theses and Dissertations

This dissertation explores the benefits of combined control moment gyroscope (CMG) and reaction wheel array (RWA) actuation for agile spacecraft. Agile spacecraft are capable of slewing to multiple targets in minimum time. CMGs provide the largest torque capability of current momentum exchange actuation devices but also introduce singularity events in operation. RWAs produce less torque capability than CMGs but can achieve greater pointing accuracy. In this research, a combined RWA and CMG (RWCMG) system is evaluated using analytical simulations and hardware experiments. A closed-loop control scheme is developed which takes advantage of the strengths of each actuator set.The CMGs perform …

Optimal Uas Assignments And Trajectories For Persistent Surveillance And Data Collection From A Wireless Sensor Network, Nidal M. Jodeh

Theses and Dissertations

This research developed a method for multiple Unmanned Aircraft Systems (UAS) to efficiently collect data from a Wireless Sensor Networks (WSN). WSN are composed of any number of fixed, ground-based sensors that collect and upload local environmental data to over flying UAS. The three-step method first uniquely assigns aircraft to specific sensors on the ground. Second, an efficient flight path is calculated to minimize the aircraft flight time required to verify their assigned sensors. Finally, sensors reporting relatively higher rates of local environmental activity are re-assigned to dedicated aircraft tasked with concentrating on only those sensors. This work was sponsored …

Feature Selection And Classifier Development For Radio Frequency Device Identification, Trevor J. Bihl

Theses and Dissertations

The proliferation of simple and low-cost devices, such as IEEE 802.15.4 ZigBee and Z-Wave, in Critical Infrastructure (CI) increases security concerns. Radio Frequency Distinct Native Attribute (RF-DNA) Fingerprinting facilitates biometric-like identification of electronic devices emissions from variances in device hardware. Developing reliable classifier models using RF-DNA fingerprints is thus important for device discrimination to enable reliable Device Classification (a one-to-many looks most like assessment) and Device ID Verification (a one-to-one looks how much like assessment). AFITs prior RF-DNA work focused on Multiple Discriminant Analysis/Maximum Likelihood (MDA/ML) and Generalized Relevance Learning Vector Quantized Improved (GRLVQI) classifiers. This work 1) introduces a …

Effects Of Automation On Aircrew Workload And Situation Awareness In Tactical Airlift Missions, David R. Meyer

Theses and Dissertations

In tactical aviation, decision superiority brought upon by high situation awareness remains the arbiter of combat effectiveness. The advancement of sophisticated avionics and highly automated cockpits has allowed for the reduction of aircrew size, and in certain platforms, removal of the crew from the aircraft entirely. However, these developments have not reduced the complex and dynamic interaction between situation awareness and crew workload. While many predictive and experimental methods of evaluating workload exist, situation awareness can only be measured by conducting trials with human operators in a functional prototype. This thesis proposes an innovative methodology to predicatively determine situation awareness …

Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 800°C In Air And In Silicic Acid-Saturated Steam, Scott J. Robertson

Theses and Dissertations

A facility was demonstrated that successfully resolved problems highlighted by previous attempts to study SiC fibers in steam. Monotonic tension and creep tests were conducted to characterize the fibers. The tensile strength of the fibers showed little dependence on applied stress rate, indicating a resistance to environmentally assisted crack growth. Climb-controlled diffusion in air and grain boundary sliding in silicic acid-saturated steam were the dominant damage mechanisms. Silicic acid-saturated steam had a degrading effect on the mechanical performance of the fibers, but much less than unsaturated steam environments. The Monkman-Grant relationship was demonstrated for Hi-NicalonTM S fibers and may be …

Nd − Pdpa: N Dimensional Probability Density Profile Analysis, Arjang Fahim

Theses and Dissertations

Proteins are often referred as working molecule of a cell, performing many structural, functional and regulatory processes. Revealing the function of proteins still remains a challenging problem. Advancement in genomics sequence projects produces large protein sequence repository, but due to technical difficulty and cost related to structure determination, the number of identified protein structure is far behind. Novel structures identification are particularly important for a number of reasons: they generate models of similar proteins for comparison; identify evolutionary relationships; further contribute to our understanding of protein function and mechanism; and allow for the fold of other family members to be …

In Situ Ir Spectroscopic Investigation Of Noble Metal Catalysts Related To The Reduction Of Automotive Exhaust Emissions, Zhiyong Wang

Theses and Dissertations

The reduction of automotive exhaust emissions has been one of the hottest topics in catalysis community since 1970s. Thanks to the development of three-way catalysts, main auto-exhaust pollutants, such as carbon monoxide, nitrogen oxides and unburned hydrocarbons, can be removed simultaneously. Nowadays, diesel engines and lean-engines become more and more popular due to their high fuel-efficiency and low CO2 emissions. Unfortunately, conventional three-way catalysts are not effective at reducing the NOx emissions from these engines due to the excess oxygen in the exhaust stream. Platinum catalysts were found to be highly active for selective NO reduction with hydrocarbons in excess …

A Multiphysics Modeling Of Solid Oxide Metal-Air Redox Battery, Md Ahsan Uddin

Theses and Dissertations

Cost-effective and large scale energy storage is essential for the growth of the future’s ‘‘green energy’’ infrastructure. Among the energy storage technologies currently being used, rechargeable batteries represent a class of advanced electrical energy storage (EES) mechanisms that can be valuable for the future renewable integration and smart grid. Rechargeable batteries have innumerous advantages over the conventional pumped hydro and compressed-air energy storage system. Now days, There are various types of rechargeable batteries available to work as an energy storage device in a smart grid but it still needs many breakthroughs to become commercially viable for stationary energy storage. First …