Engineering Commons^™

Functionalization Of Nanoclays Through Exchange Reactions, Jin Uk Ha

Theses

A cationic clay (sodium-montmorillonite, MMT) and an anionic clay (hydrotalcite, HT) were treated with two phosphonium based ionic liquids (ILs) and a commercial corrosion inhibitor. Clay modification was examined by TGA, FTLR and WXRD. The cationic clay modified with both ILs had similar thermal stabilities since they contained the same cation although the original anions were different. The thermal stability of the modified clays was higher than that of a commercial organoclay and of clays modified in our group with smaller MW pyridinium and imidazolium based cations. 10 wt% of interchanged cation was found under selected time/temperature treatment conditions.

Clays …

Multi-Degree Of Freedom Telemanipulation In An Unstructured Environment, Diego Ramirez

Theses

Two approaches to 6-degrees-of-freedom telemanipulation that will accommodate different needs and skills of potential users with congenital amputation, arthrogryposis, muscular dystrophy and cerebral palsy were developed. One method uses scalable movements (i.e. position and orientation), and the second employs isometric forces and torques without movement. The scalable position approach employs a 6-degress-of-freedom electromechanical stylus whose joint orientations are used by the controlling computer to determine the position and orientation of the robot's end effector via inverse kinematics or by one-to-one matching of the stylus joint angles with those of the manipulator. The isometric method uses the measured forces and torques …

Numerical Analysis Of The Operation Of A Water Cannon, Teymuraz G. Bitadze

Theses

This study was designed to investigate the operational process of a launcher for generation of high speed water projectiles, and it involved the optimization of the geometry of a launcher body. The objective of the optimization of the internal geometry was to increase the effective momentum of the projectile while the optimization of the external geometry resulted in the reduction of the mass of the launcher.

In the course of the optimization of the internal geometry the exit velocity variation was determined, and used to compute an effective projectile momentum, which actually affects a workpiece. In this research, it was …

Burmester Curve And Numerical Motion Generation Of Grashof Mechanisms With Perimeter And Transmission Angle Optimization In Mathcad, Peter J. Martin

Theses

An infinite number of planar four-bar mechanism solutions exist for a series of prescribed rigid-body positions. Given a set of Burmester curves or numerically-generated fixed and moving pivot curves, sorting through the limitless number of possible mechanism solutions to find one that ensures full link rotatibility, satisfies compactness criteria and produces feasible transmission angles can be a daunting task. In this work, two algorithms are developed and presented by which the user can select optimum planar four-bar motion generators (optimum with respect to Grashof criteria, mechanism perimeter criteria and transmission angle criteria) from a set of all mechanism solutions produced …

Determining Continual Improvement Process Methods Within Quality Management Systems, Diane M. Bové

Theses

Institutionalized standards require organizations to actively define and implement quality management systems, which includes active participation in continual improvement efforts. Interpretations and practices vary on implementation methodology.

Traditional views of quality do not integrate the technical disciplines into a defined science which would support a standardized approach for continual improvement implementation.

In order to optimize improvement efforts, a conceptual hypothesis is proposed to integrate quality through combining and collaborating implementation efforts of engineering, control, assurance, improvement and costs. The purpose of this thesis is to establish a roadmap to assist in choosing effective quality improvement methodologies and toolsets that assist …

Channel-Predictive Link Layer Arq Protocols In Wireless Networks, Huseyin Dogukan Cavdar

Theses

Communication performance over a wireless channel should be considered according to two main parameters: energy and throughput. The reliable data transfer is a key to these goals. The reliable node-to-node data transfer is performed by link layer protocols. One prominent approach is Automatic Repeat Request (ARQ) protocol. The traditional ARQ protocols attempt to recover the erroneously transmitted frames by retransmitting those frames, regardless of the channel state. Since this channel state unaware behaviour may cause unnecessary retransmissions, traditional ARQ protocols are expected to be energy inefficient. Some ideas have been proposed such as stochastic learning automaton based ARQ, and channel …

A Dynamic Supine Stander For Subjects With Disabilities Leading To Prolonged Immobility, Luis Alberto Espina

Theses

Bone tissue needs to be exposed to loading in order to stimulate the osteogenic response of the body. Disabilities that lead to prolonged immobility will result in a decrease of the osteogenic processes and an increase in resorption of bone by osteoclast cells. This disuse modeling can lead to osteopenia, osteoporosis, and subsequent non-traumatic fractures. These disabilities are varied in nature and duration, and can include load bearing bone fracture, excessive obesity, spinal cord injury, and cerebral palsy.

The following describes the concept and design of a novel dynamic supine stander that will provide loads simulating ambulation to the lower …

A Kinematic Analysis Of Sign Language, Chemuttaai C. Koech

Theses

Signed languages develop among deaf populations and employ manual communication instead of voiced communication. Stokoe attributes classify individual signs in American Sign Language (ASL) and include handshape, hand location, movement, orientation, and facial expression. Signed and oral languages are not mutually understood, and many deaf individuals live in linguistic isolation. This research addresses computer translation between signing and speech, investigating sign duration in sentence context versus in isolation and identifying kinematic sign markers. To date, there has been little study of continuous signing kinematics; it was previously unknown if kinematic markers existed.

Kinematic data were collected from a proficient signer …

Jet Assisted Fluidization Of Nanoparticle Agglomerates, Ayokunle O. Omosebi

Theses

Fluidization serves as a primary operation used to disperse, handle and process nanoparticles, but due to the complications involved with achieving homogenous fluidization of the agglomerates of nanoparticles, several methods have been developed to assist their conventional mode of fluidization.

In this work, the conventional mode of fluidization was coupled with secondary gas flow emerging from a micro jet nozzle. The effect of the jet on the fluidization behavior of various APF and ABF nanopowders was studied and compared with the pure conventional fluidization mode. Generally, experiments were conducted to find the optimal operation of the jet by varying parameters …

Inverse Solid-Liquid Fluidization Of Aerogel Granules And Its Application In Removing Oil From Water, Gaurav Babubhai Patel

Theses

Fluidization is a very well known unit operation used in the chemical industry for various purposes. Inverse solid-liquid fluidization, where the solid particles to be fluidized are less dense than the fluid, is one of the several different kinds of fluidization being studied for its potential in industrial applications. The present work focuses on finding the hydrodynamic characteristics (minimum fluidization velocity, bed expansion and pressure drop) of an inverse fluidized bed of aerogel granules and using this system to remove oil from an oil-water mixture. The solid particles employed for this study are low density (100 kg/m³) surface …

Implementation Of Stereo Correspondence Algorithms For Multi-Baseline Vision System, Navaneetha Shivram

Theses

The purpose of this study is to determine the impact of varying camera baselines on correspondence and depth estimation. As the baseline increases the resolution of depth increases but finding correspondences is very tedious. On the other hand when cameras are placed close to each other and thereby reducing the baseline distance points in the images are easily matched however depth resolution deteriorates. This problem is solved by using a multi-camera system is used in which the cameras are spaced close to each other along a straight line. Calculating the correspondence along successive camera pairs is relatively easy. These respondences …

Non-Repudiation Secure File Transfer Protocol (Nrsftp), Jerry Chen

Theses

Non Repudiation Secure File Transfer Protocol (NRSFTP) is designed to resolve three main concerns for today's electronic file transfer methodology. The three main concerns are Non-Repudiation, Secure, and Non-Real Time file transfer. Non-repudiation is to assure the receiver that the sender of the document is not an imposter. Secure document transfer is to assure the sender that only the intended receiver will be able to read the document. Non-real-time file transfer is to provide convenient and low cost transportability of the encrypted data from one party to another. With the above three concerns addressed, the NRSFTP protocol can be widely …

Inverse Dynamic Modeling For Characterization Of Spasticity, Katharine Markel Swift

Theses

Spasticity affects subjects with cerebral palsy, stroke, multiple sclerosis, and traumatic brain injury. The need to develop a deeper understanding of spasticity is driven by the existing limited understanding and the lack of satisfactory interventions for this disabling phenomenon.

An inverse model is implemented to describe the motion in the pendulum knee drop test. Inverse kinematic modeling is implemented to investigate the pathophysiology of spasticity.

Using the equilibrium point hypothesis as a conceptual framework to explain disabled and non-disabled neuromuscular control, it has been demonstrated that the equilibrium point of the passive knee is dynamic and exhibits a pseudo-exponential trajectory …

Personal Information Management. A Framework For Development Of Personalisable Web Based Services, Christopher Fuchs

Theses

The thesis research proposed herein will model, analyse and implement strategies for the development of personalised services. The goal of the research work is to design and implement a framework which supports developers by minimising the effort required in implementing personalised services. This includes the ability to react to localisation changes and to present proper information. An overall design goal is the independency of most components from each other which will be attained through the use of standard technologies and protocols and the consistent use of a component model. The result will include the proposed framework and the analyses of …

Thermo-Mechanical Design Of A 100 Ghz Mmic Power Amplifier Using Flip Chip Technology, Sean Cremin

Theses

This thesis is concerned with the thermo-mechanical design, thermal modelling and temperature profile measurement of a 100 GHz flip chip bump bonded MMIC medium power amplifier.

Flip chip mounting offers superior RF performance in terms of output power, gain, noise figure and bandwidth. The thermal challenge was to dissipate approximately two watts of DC power from the GaAs MMIC (monolithic microwave integrated circuit) through Au (gold) stud bumps which equates to less then 7% of the total surface area of the die. Infrared thermographic images confirmed that the flip chip MMIC amplifier was functional with all eight FET stages on …

Anaerobic Digestion: Decision Support Software, Marco Poliafico

Theses

Ireland has significant quantities of livestock; meat exportation is a vibrant sector of the economy. Environmental management of animal wastes has therefore become an important concern. On the other hand in the last decade, national and EU policy debate has highlighted the need to investigate alternative energy: in particular energy for transport.

This study investigates the quantities of animal wastes produced in Ireland and their potential treatment using Anaerobic Digestion technologies. In 2005 Ireland had over 8 millions animals (cattle and pigs) and the annual slaughter accounted for over 4.2 million of these creatures. These animals have been responsible for …

The Potential For Ch4-Enriched Biogas As A Transport Fuel In Ireland, Niamh Power

Theses

Ireland needs a biofuel industry- to aid compliance with the Kyoto Protocol, the Biofuels Directive and to secure its energ>' supply. The overall aim of this work is to assess the potential of CH4-enriched biogas as a transport fuel in Ireland. Biogas is produced during the anaerobic digestion of biomass. This work investigates biogas production from two different feedstocks; biodegradable municipal waste and agricultural crops. To assess the potential for biogas as a transport fuel the alternatives to biogas are investigated and compared. Thus digestion and composting of biodegradable municipal waste, and biogas and ethanol production from agricultural crops …

The Smart Helmet, Michael Walsh

Theses

This thesis addresses the design, development and testing of a wireless sensor network for a sports helmet. The objective is to monitor an athlete's physiology and also physical impacts using a sensor network. A detailed literature review is presented addressing currently available appropriate wireless technologies, sensors and their operation, packaging, interconnections and applications. It gives a brief introduction to each sensor used in the smart helmet, accelerometers, temperature sensors, heart rate and blood oxygen sensors, along with a review of possible sensors which could be added at a later stage. The specific sensors and other related components for the helmets …

A Service Provisioning Platform For Beyond 3g - The Telecommunication Service Exchange, Donna Griffin

Theses

From the inception of mobile communications one of the most important factors contributing to its success has been a good understanding of user requirements. In the first generation, mobile networks offered subscribers the freedom to communicate regardless of their locations and the joy of instant access to voice telephony services. This provided a competitive edge over wire line communication networks and resulted in large revenue streams. However over the past decade, mobile network operators have been faced with a number of factors that have incurred significant costs and resulting reduced revenue. These factors include deregulation, increased competition and technological progress …

The Effect Of The Size Of Pinning Centres On The Critical Current Density In High-Temperature Superconductors, Salama Bakhit Sowaidan Al-Neaimi

Theses

Superconductor materials that have no resistance to the flow of electricity are one of the last great frontiers of scientific discovery.

Superconductivity in these materials occurs particularly in the copper-oxide (CuO₂) planes. However, since these materials are type-II superconductors, magnetic fields can penetrate these materials in quantized amounts of flux called vortices without completely destroying superconductivity, but producing some resistance, due to vortex motion. In order to overcome the resistance problem, vortices must be pinned to prevent their motion and hence eliminate the resistance.

In this work study we have performed extensive numerical simulations to study the effect …

Investigation Of The Band Structures And Optical Properties Of Super Lattices, Sheikha Ahmed Awad Alnaeme

Theses

Group III nitrides are highly attractive materials because of their great potential for the development of optoelectronic devices in short wavelength, semiconductor lasers and optical light-emitters and detectors. GaN, AlN and InN are considered as the most important compounds in this class of materials. In this work, we present a theoretical investigation of the electronic properties (band structure, density of state and contour maps of the charge density distribution) and optical properties (refractive index, absorption and dielectric constants). Also, we investigate the band structures and optical properties of AlN/GaN and InN/GaN super lattices. A full-potential linearized plane-wave (FPLAPW) method is …

A Wireless Method For Monitoring Medication Compliance, Jeffrey Scott Jonas

Theses

There are many devices on the market to help remind patients to take their pills, but most require observation by a caregiver to assure medication compliance. This project demonstrates three modes to detect pill removal from a pillbox: a switch under the pills, a reflective type photointerrupter and a transmissive "electric eye" photosensor. Each mode exhibited blind spots or other failures to detect pill presence, but by combining modes with complementary characteristics, the accuracy of pill detection is greatly increased.

Two methods of caregiver notification are demonstrated: text messages transmitted via an attached cellular phone, or the status is collected …

Fpga-Based Implementation Of Parallel Graph Partitioning, Mohammad Kharashgeh

Theses

Graph partitioning is a very important application that can be found in numerous areas, from finite element methods to data processing and VLSI circuit design. Many algorithms have been developed to solve this problem. Of special interest is multilevel graph partitioning that provides a very efficient solution. This method can also be parallelized and implemented on various multiprocessor architectures. Unfortunately, the target of such implementations is often unavailable high-end multiprocessor systems. Here a parallel version of this method for an in-house developed multiprocessor system is implemented on an FPGA. The system designed provides a cost-effective solution.

The design is based …

Characterization Of Thermally Diffused Bordie Layers On Aisi 1018 Steel : Residual Stresses (By Synchrotron Radiation) And Microhardness, Joel A. Payne

Theses

Boronization is a thermal diffusion process in which needle like boride layers are formed at the surface of the metallic substrate. The boride coatings formed by the diffusion process have high hardness and strong ware and corrosion resistance. In order for coatings of this nature to be industrially successful, their service life should be long and characterization should be extensive. Measuring the residual stresses of the coatings caters to each of these aspects.

In this study, AISI 1018 steel samples were boronized by a powder-pack process for four hours at 850°C in an argon atmosphere. Characterization techniques included coating thickness, …

Submicron Patterning Using Laser Interference Lithography, Luigi Pollara Verdoni

Theses

In this thesis, the theory, fabrication protocol, and initial results of an alternative nanopatterning technique called Interferometric Lithography (IL) are presented. Comprised of the identical process attributes of traditional projection photolithography, IL mirrors the wafer preparation and development procedures of our existing clean room capabilities. The main departure is solely in means of pattern delineation. IL is a "mask less" technique that employs the interference fringe pattern of two coherent beams, and can therefore be generated with a commercial laser. Due to its simplicity, Interferometric Lithography provides an attractive supplement to existing methods of nano-patterning.

Utilizing a 325 nm HeCd …

Dem Simulated Floor Pressure Induced By A Granular Column, Shawn A. Chester

Theses

At the end of the 19th century, H. A. Janssen discovered that the bottom floor pressure in a cylindrical container of granular material asymptotes exponentially to a value less than the weight of the material i.e., the pressure becomes independent of the fill height of the column. This phenomenon is investigated using discrete element simulations of inelastic, frictional spheres in a cylindrical vessel having a particle-to-cylinder diameter ratio at approximately 13.3 or 26.6, with varying bed heights in both cases. The axial pressure profile and the load experienced by a piston that is supporting the granular column are computed. In …

Individual Cell Pressure Control In An Air Mattress For The Prevention Of The Pressure Sores, Kapilchandra Anand

Theses

Many kinds of pressure-relieving mattresses have been developed to prevent pressure sores in patients with spinal cord injuries (SCIs) and obesity. Current technology uses alternating air pressure mattress, foam and low pressure mattress for reducing the incidence of pressure sores in SCI and obesity patients. These mattresses do not have control of pressure in individual air chambers. They are open loop system and they do not receive any feedback from the system. They have at the most control of two different pressures. The purpose of this study is to improve the current assistive technology in reducing pressure sores and to …

In-Vitro Characterization Of Boronized Titanium Alloy By Means Of Corrosion And Electrochemical Impedance Spectroscopy Methods In Simulated Body Fluids, David Anthony Panus

Theses

Titanium and titanium alloys are becoming the backbone of medical implants and prosthetics. Titanium alloys are used because of its high biocompatibility and similarity to bone. However, titanium and titanium alloys have a low wear resistance. Titanium and titanium alloys are susceptible to particle erosion, which can cause inflammation, infection, and even implant rejection. Boronizing titanium alloy improves titanium's wear resistance and also improves corrosion resistance.

The target of this research was to characterize the corrosion characteristics of both unboronized and boronized titanium using both electrochemical corrosion methods and Electrochemical Impedance Spectroscopy (ELS) in simulated body fluid. Using electrochemical methods …

Fabrication Of Hydroxyapatite-Biodegradable Polymer Scaffolds By Electrospinning For Potential Bone Tissue Application, Satomi Suzuki

Theses

The purpose of this study is to determine the potential of combining hydroxyapatite (HA) and polymers to form synthetic composite materials used for bone tissue engineering applications. In this study, ceramic-biodegradable polymer composites are fabricated by electrospinning method. The biodegradable polymers used are poly(L-lactic acid) (PLLA), and poly(lactide-co-glycolide) (PLGA). Two types of HA-polymer solutions are first prepared to achieve HA weight percentage of 0, 10, and 25%of the total combined weight of HA and PLLA, and HA and PLGA. The solutions are electrospun to form nanofibrous mats incorporated with HA powder. A biomimetic process was also conducted as a …

Fabrication And Characterization Of Back Illuminated Cmos Photodiode Array, Amitra Banerjee

Theses

With the rapid development in low-cost CMOS technology, silicon photodiodes are currently recognized as promising choice for the imager core. In this research, the arrays of back illuminated photodiodes were designed, fabricated and demonstrated with CMOS imager fabrication process on silicon wafers. The main purpose of this work was to improve the contribution of these arrays on the imaging systems before committing their design on the chips.

In this CMOS process, first the n-well, p-well, n+and p+ regions were simulated and fabricated by several implantation processes. The n-well region was implanted by phosphorus at an energy of 170 keV and …