Engineering Commons^™

Novel Endohedral Derivatives Of Sc3n@C2n (N = 34, 40) And Unique Tether Controlled Bis-Functionalization Of Fullerenes, Maira Raquel Ceron Hernandez

Open Access Theses & Dissertations

Since the discovery of fullerenes in 1985, their exohedral functionalization has been necessary to increase their solubility and explore their properties and potential applications in materials science and medicinal chemistry. This Thesis provides a short overview of the importance of electronic, size and shape complementarity in determining the structures of specific endohedral fullerene compounds. This is followed by a description of a new method for the separation of scandium nitride endohedral fullerenes Sc3N@C2n (n = 34, 39 and 40), and their monofunctionalization.

We also present the regioselective synThesis of easily isolable bis-derivatives of C60, C70, and M3N@Ih-C80 (M = Sc, …

Study Of A Directly Heated Oxy-Fuel Supercritical Power Generation System, A S M Arifur Rahim Chowdhury

Open Access Theses & Dissertations

The Directly heated supercritical oxy-fuel gas turbines have the potential to become an important addition to current power generation systems. They provide a higher thermal efficiency and more effective carbon capture techniques than existing gas turbines. Due to the higher density of the working fluids, the turbomachinery size in these systems can be reduced significantly; this will facilitate to minimize the operational cost. To achieve supercritical working fluid at the turbine inlet combustion needs to be conducted under enormous amounts of pressure; these values are is about 10 times those found in the present gas turbines. Additionally, existing material operational …

Re-Examining Resistance: Fan-Produced Queer Readings And Teen Wolf, Joshua J. Espinoza

Open Access Theses & Dissertations

MTV's popular television series, Teen Wolf (2011), has amassed a large online following of fans that create their own queer narratives through fan-fiction, subverting the show's hegemonic heteronormativity. Through a textual thematic analysis of Teen Wolf, this case study illustrates how online fandoms can subvert hegemony through queer readings of literary characters, resisting the dominant heteronormativity on network television. This article argues that rearticulating the showâ??s narratives into queer readings functions as a form of LGBT resistance, effectively counteracting the heteronormativity and hegemony portrayed on screen. This study examines how Teen Wolf approaches queer content, including homoeroticism and LGBT themes …

Transition States And Modeling For Co9s8/Mos2 Catalysis, Gabriel Angel Gonzalez

Open Access Theses & Dissertations

Transition state computational studies of the sulfur removal from dibenzothiophene (DBT) molecule have herein been performed considering the Co9S8/MoS2 interface existing on unsupported Co/MoS2 catalysts. The linear synchronous transit (LST) and quadratic synchronous transit (QST) methods integrated in a density functional theory (DFT) program such as Dmol3 were used for the calculations of energy barriers of the transition states. Three different configurations present on the Co9S8/MoS2 interface have been envisaged as possible catalytic sites: sulfur-sulfur (S, S) sites, and molybdenum-sulfur (Mo, S) and molybdenum-molybdenum (Mo, Mo) edge sites. This study revealed that the (Mo, Mo) edge site is the most …

An Improved Sin-Hyperbolic Constitutive Model For Creep Deformation And Damage, Mohammad Shafinul Haque

Open Access Theses & Dissertations

Inspection and maintenance of industrial gas turbines (IGTs) cost millions of dollars. Growing demand of obtaining higher IGT efficiency leads to higher temperature and pressure operating conditions. Long exposure of turbine components at elevated temperature and pressure

makes creep damage critically important to consider during planning, designing and operating conditions. Effective and economic maintenance requires accurate creep deformation, damage

evolution and rupture life prediction information. Creep prediction models are used to determine the state of the turbine components and to schedule the inspection, maintenance and replacement time periods. The more accurate the prediction model, the less is the overall cost …

High Temperature Helical Tubular Receiver For Concentrating Solar Power System, Nazmul Hossain

Open Access Theses & Dissertations

In the field of conventional cleaner power generation technology, concentrating solar power systems have introduced remarkable opportunity. In a solar power tower, solar energy concentrated by the heliostats at a single point produces very high temperature. Falling solid particles or heat transfer fluid passing through that high temperature region absorbs heat to generate electricity. Increasing the residence time will result in more heat gain and increase efficiency. A novel design of solar receiver for both fluid and solid particle is approached in this paper which can increase residence time resulting in higher temperature gain in one cycle compared to conventional …

Study Of Materials And Machines For 3d Printed Large-Scale, Flexible Electronic Structures Using Fused Deposition Modeling, Seyeon Hwang

Open Access Theses & Dissertations

The 3 dimensional printing (3DP), called to additive manufacturing (AM) or rapid prototyping (RP), is emerged to revolutionize manufacturing and completely transform how products are designed and fabricated. A great deal of research activities have been carried out to apply this new technology to a variety of fields. In spite of many endeavors, much more research is still required to perfect the processes of the 3D printing techniques especially in the area of the large-scale additive manufacturing and flexible printed electronics.

The principles of various 3D printing processes are briefly outlined in the Introduction Section. New types of thermoplastic polymer …

Design Of A High Intensity Turbulent Combustion System, Mohammad Arif Hossain

Open Access Theses & Dissertations

In order to design next generation gas turbine combustor and rocket engines, a systematic study of flame structure at high intensity turbulent flow is necessary. The fundamental study of turbulent premixed combustion has been a major research concern for decades. The work is focused on the design and development of a high intensity turbulent combustion system which can be operated at compressible (0.3 < M < 0.5), preheated (T0=500K) and premixed conditions in order to investigate the 'Thickened Flame' regime. An air-methane mixture has been used as the fuel for this study. An optically accessible backward-facing step stabilized combustor has been designed for a maximum operating pressure of 6 bar. A grid has been introduced with different blockage ratios (BR = 54%, 61% & 67%) in order to generate turbulence inside the combustor for the experiment. Optical access is provided via quartz windows on three sides of the combustion chamber. Finite Element Analysis (FEA) is done in order to verify the structural integrity of the combustor at rated conditions. In order to increase the inlet temperature of the air, a heating section was designed to use commercially available in-line heaters. Separate cooling subsystems have been designed for chamber cooling and exhaust cooling. The LabVIEW software interface has been selected as the control mechanism for the experimental setup. A 10 kHz Time Resolved Particle Image Velocimetry (TR-PIV) system and a 3 kHz Planer Laser Induced Fluorescence (PLIF) system have been integrated with the system in order to diagnose the flow field and the flame respectively. The primary understanding of the flow field inside the combustor was achieved through the use of Detached Eddy Simulation (DES) by using commercially available software package ANSYS FLUENT. Preliminary validation is done by 10 kHz TR-PIV technique. Both qualitative and quantitative analysis have been done for CFD and experiment. Major flow parameters such as average velocity, fluctuation of velocity, kinetic energy, and turbulent intensity have been calculated for two distinct Reynolds number (Re = 815 & 3500). PIV results are compared with CFD results which show significant agreement with each other.

Wind Farm Optimization Using Evolutionary Algorithms, Carlos Marco Ituarte-Villarreal

Open Access Theses & Dissertations

In recent years, the wind power industry has focused its efforts on solving the Wind Farm Layout Optimization (WFLO) problem. Wind resource assessment is a pivotal step in optimizing the wind-farm design and siting and, in determining whether a project is economically feasible or not. In the present work, three (3) different optimization methods are proposed for the solution of the WFLO: (i) A modified Viral System Algorithm applied to the optimization of the proper location of the components in a wind-farm to maximize the energy output given a stated wind environment of the site. The optimization problem is formulated …

Transition Metal Carbide (Tmc) Novel Materials For Novel Catalytic Applications, Svetlana Lagoykina

Open Access Theses & Dissertations

Transition metal carbides (TMC) constitute a diverse class of materials and traditionally have many technological applications. TMC became a subject of extensive research since 1973, when their platinum -like properties were discovered. They demonstrated high catalytical activity and selectivity in a variety of chemical reaction and have potential for some novel catalytic application.

This research is an effort to design new high effective, selective and stable bimetal or alkali promoted TMC catalyst. After extensive theoretical research a wide range of TMC, including bimetal and alkali promoted carbides, were synthesized by different methods. All solids were characterized by XRD and microscopy. …

Thermal Shock Studies On Carbon-Carbon Composites: Experimentation And Analysis, Alma Lucia Leanos

Open Access Theses & Dissertations

The oxidation behavior of C/C composites under thermal shock conditions in air is understood and predicted experimentally and by computational efforts. In Chapter. 1, both compressive properties and oxidation behavior of pristine and thermal shock exposed 2D C/C composite specimens were examined. Pristine test specimens were exposed to thermal shock conditions with temperatures ranging from 400°C to 1000°C in an oxidizing environment, followed by compression tests on pristine and thermal shock exposed specimens to obtain their compressive responses.

Similarly, in Chapter. 2, the influence of thermal shock conditions on both, the extent of carbon materials decomposition and the through-thickness compressive …

Computation Offloading Decisions For Reducing Completion Time, Salvador Melendez

Open Access Theses & Dissertations

Mobile devices are being widely used in many applications such as image processing, computer vision (e.g. face detection and recognition), wearable computing, language translation, and battlefield operations. However, mobile devices are constrained in terms of their battery life, processor performance, storage capacity, and network bandwidth. To overcome these issues, there is an approach called Computation Offloading, also known as cyber-foraging and surrogate computing. Computation offloading consists of migrating computational jobs from a mobile device to more powerful remote computing resources. Upon completion of the job, the results are sent back to the mobile device. However, a decision must be made; …

Effect Of Si Substrate Orientation On The Quality Of Cdte Selective Growth On Si(111) And Si(211) Substrates Via Closed-Space Sublimation (Css) Witout The Use Of A Mask., Aryzbe Najera

Open Access Theses & Dissertations

The material, fabrication and operation parameters for mercury cadmium telluride (HgCdTe) detectors require high sensitivity, small pixel size, low defect density, long-term thermal-cycling reliability and large area substrates. The focus of this work is on the epitaxial growth of CdTe thin films on Si(111) and Si(211) for the purpose of using the resulting material as a substrate for the subsequent growth of HgCdTe thin films. Currently, there is an interest to improve the quality of epitaxial thin films associated with the fabrication of HgCdTe infrared and X-ray imaging using the close-spaced sublimation (CSS) technique. The CSS technique is proven to …

Reliability And Sensitivity Analysis For Micro-Meteoroids And Orbital Debris Protection Models Using First-Order Reliability Methods (Form)., Levi Pereda

Open Access Theses & Dissertations

Abstract This Thesis provides a probabilistic assessment of the micro-meteoroids and orbital debris (MMOD) impact protection structures. The assessment is based on first-order reliability methods that use Ballistic Limit equations traditionally used by NASA for the design of shields. The research demonstrates how the structural reliability methods can be implemented into the aeronautics and astronautics field. NASA is continuously developing new techniques that allow the consideration of the uncertainty that exists in the design of their space structures. Nevertheless, some of their design approaches are still deterministic. For example MMOD ballistic limit equations used for the design of the MMOD …

Fluid Flow Characterization Of High Turbulent Intensity Compressible Flow Using Particle Image Velocimetry, Marco Efrain Quiroz

Open Access Theses & Dissertations

A high turbulent intensity combustion chamber has been designed in order to operate with compressible (0.3 < M < 0.5) and preheated (T=500K) air-methane combustion. These conditions will allow the investigation of different flame regimes; most notably the proposed "Thickened Flame" regime. Initial design and flow validation has been completed in order to begin further experimentation. A 10 kHz Time Resolved Particle Image Velocimetry (TR-PIV) system and a 3 kHz Planer Laser Induced Fluorescence (PLIF) system have been integrated with the system in order to diagnose the flow field and the flame respectively. The exhaust and chamber cooling subsystems were designed to comply with safety regulations, and the control systems were set up in a way that allows automated (LabVIEW) and user controlled sequencing. This work's main purpose is to characterize and map the flow properties at maximum flow conditions (M > 0.3) in order to map the following; flow structures, kinetic energy at different length scales, velocity fluctuations and turbulent intensity. PIV measurements are carried out for three different volumetric flow rates (ð???Ì? = 25 scfm, 55 scfm, and 115 scfm) and three different grid geometries for each (BR= 67%, 61%, and 54%). Upon finding that the main flow structure consisted of jets caused by the grid at higher flowrates, experiments were done with a grid BR = 67% which was thinner (50% of original …

Design And Development Of The Portable Build Platform And Heated Travel Envelope For The Multi3d Manufacturing System, Steven Daniel Ambriz

Open Access Theses & Dissertations

The final product functionality of parts produced by Additive Manufacturing (AM) can, in part, be improved by the inclusion of multi-material capabilities. The “Multi3D system” that is under development at The University of Texas at El Paso uses material extrusion printing (or fused deposition modeling), solid conductor wire embedding, direct-write, component placement, and micromaching to enable multi-material fabrication. The Multi3D was designed to transport a workpiece between manufacturing stations via a six-axis robot, portable build platform (PBP), and a controlled temperature environment or chamber that travels to each manufacturing station. The heated travel envelope (HTE) was included to mitigate thermal …

Solar Pv Power Generation Forecasting Using Hybrid Intelligent Algorithms And Uncertainty Quantification Based On Bootstrap Confidence Intervals, Donna Alhakeem

Open Access Theses & Dissertations

This Thesis focuses on short-term photovoltaic forecasting (STPVF) for the power generation of a solar PV system using probabilistic forecasts and deterministic forecasts. Uncertainty estimation, in the form of a probabilistic forecast, is emphasized in this Thesis to quantify the uncertainties of the deterministic forecasts. Two hybrid intelligent models are proposed in two separate chapters to perform the STPVF. In Chapter 4, the framework of the deterministic proposed hybrid intelligent model is presented, which is a combination of wavelet transform (WT) that is a data filtering technique and a soft computing model (SCM) that is generalized regression neural network (GRNN). …

3d Printing Technology Using High Viscous Materials-Synthesis Of Functional Materials And Fabrication Of 3d Metal Structure, Seongik Hong

Open Access Theses & Dissertations

In the 3D printing technology, the research for using various materials has been performing. In this research work, 3D printable high viscous materials are suggested as one of the solutions for problems in the traditional 3D printing technology.

First, Cu-Ag coreshell was synthesized as a functional material. In terms of the reaction rate, reaction rate limiting step was defined as a fundamental research, and then prepared Cu-Ag coreshell was printed and analyzed. Second, the high viscous Cu paste was prepared and then metal 3D printed structure was fabricated by using new printing method.

In the synThesis of Cu-Ag coreshell, different …

Fused Deposition Modeling (Fdm) Fabricated Part Behavior Under Tensile Stress, Thermal Cycling, And Fluid Pressure, Mohammad Shojib Hossain

Open Access Theses & Dissertations

Material extrusion based additive manufacturing (AM) technology, such as fused deposition modeling (FDM), is gaining popularity with the numerous 3D printers available worldwide. FDM technology is advancing from exclusively prototype construction to achieving production-grade quality. Today, FDM-fabricated parts are widely used in the aerospace industries, biomedical applications, and other industries that may require custom fabricated, low volume parts. These applications are and were possible because of the different production grade material options (e.g., acrylonitrile butadiene styrene (ABS), polycarbonate (PC), polyphenylsulfone (PPSF), etc.) available to use in FDM systems. Recent researchers are exploring other material options including polycaprolactone (PCL), polymethylmethacrylate (PMMA), …

Safety Measures For Trucks: A Comparison Between Eu And U.S., Jan Kapusta

Open Access Theses & Dissertations

Road transportation is playing an important role in almost all of the freight movements and contributes to the economy. It has the highest share in the modal division of transported goods. This situation is not about to change in next years to come. Therefore, it is necessary to change the current situation and create rules and regulations that would lead to decrease in number of accidents either in EU or in U.S. The goal of this research is to analyze selected parameters related to the safety of truck transportation in EU and in U.S. This thesis also identifies and compares …

Water Recovery From Silica Saturated Ro Concentrate By The Concentrate Enhanced Reverse Osmosis Process, Gautam Patwardhan

Open Access Theses & Dissertations

Membrane fouling due to silica precipitation during reverse osmosis (RO) continues to be documented as the most common challenge in attaining stable continuous operation of RO systems across water treatment plants (1). Silica scale precipitation is time dependent and involves multiple steps leading to aqueous polymerization, condensation of polymers to form colloids, and deposition onto a solid surface (2). Exceeding the solubility of silica, widely considered to be in the range of 100-140 ppm, under a pH of 8 at 25 °C by various researchers, results in the precipitation of silica on the membranes, thereby limiting water recovery. Once the …

Inkjet Bioprinting Of Solid Peroxides For Constructing Oxygen Generating Scaffolds To Improve Cells Viability And Growth Under Hypoxic Environment, Daniel Reyna Soriano

Open Access Theses & Dissertations

Tissue engineering has emerged as an interdisciplinary field to overcome current challenges for tissue repair or replacement in the human body. In essence, it proposes new medical therapies customized to match the biology of specific patients. The potential benefits offered by tissue engineering have driven scientific inquiry to make it a clinical reality.

One of the current challenges in tissue engineering is to provide oxygen supply to thick tissues as oxygen diffusion is limited to 100 - 200 µm layer of viable tissue. Engineered vascular conduits are applied in vitro, providing pre-vascularization to tissues; however, host anastomosis is still a …

Characterization Of High-Purity Niobium Structures Fabricated Using The Electron Beam Melting Process, Cesar Adrian Terrazas

Open Access Theses & Dissertations

Additive Manufacturing (AM) refers to the varied set of technologies utilized for the fabrication of complex 3D components from digital data in a layer-by-layer fashion. The use of these technologies promises to revolutionize the manufacturing industry. The electron beam melting (EBM) process has been utilized for the fabrication of fully dense near-net-shape components from various metallic materials. This process, catalogued as a powder bed fusion technology, consists of the deposition of thin layers (50 - 120µm) of metallic powder particles which are fused by the use of a high energy electron beam and has been commercialized by Swedish company Arcam …

Numerical Prediction Of Collection Efficiency Of A Personal Sampler Based On Cyclone Principle, Antara Badhan

Open Access Theses & Dissertations

A personal bioaerosol sampler is a self-contained, operation flexible, high-efficient device for indoor air quality (IAQ) and health risk exposure monitoring and measurement. Bio-aerosols such germ-laden viruses, microbial species, airborne microorganisms and volatile organic compounds (VOC) are sucked into the sampler and are deposited on the inner wall surface based on cyclone principal. The major concern with bio-aerosol samplers is the collection efficiency. In this study, we used computational fluid dynamics (CFD) tools to evaluate key design parameters, specifically the inlet tube angle and collection tube inner wall roughness. 3D incompressible turbulent flow was simulated using commercial software ANSYS FLUENT. …

The Study Of The Dielectric Properties Of The Endohedral Fullerenes, Shusil Bhusal

Open Access Theses & Dissertations

Dielectric response of the metal nitride fullerenes is studied using the density functional theory at the all-electron level using generalized gradient approximation. The dielectric response is studied by computing the static dipole polarizabilities using the finite field method, i.e. by numerically differentiating the dipole moments with respect to electric field. The endohedral fullerenes studied in this work are Sc3N@C68(6140), Sc3N@C68(6146), Sc3N@C70(7854), Sc3N@C70(7960), Sc3N@C76(17490), Sc3N@C78(22010), Sc3N@C80(31923), Sc3N@C80(31924), Sc3N@C82(39663), Sc3N@C90(43), Sc3N@C90(44), Sc3N@C92(85), Sc3N@C94(121), Sc3N@C96(186), Sc3N@C98(166). Using the Voronoi and Hirschfield approaches as implemented in our NRLMOL code, we determine the atomic contributions to the total polarizability. The site-specific contributions to the polarizability …

Evaluation Of A Torch Ignition System For Propulsion, Robert Ellis

Open Access Theses & Dissertations

In recent years NASA has had a renewed interest in oxygen and methane as propellants for propulsion. The drive for this combination comes from several factors including ease of land- based storage, handling safety, in situ resource utilization, and a relatively clean burning process when compared with the widely used hypergolic propellants. This project is part of a larger goal of the Center for Space Exploration Technology Research (cSETR) to better understand all aspects of using LOX/CH4 propellants to create future hardware that is specially optimized for these propellants. This paper discusses the literature background and reasons that led to …

Why Ricker Wavelets Are Successful In Processing Seismic Data: Towards A Theoretical Explanation, Afshin Gholamy Salehabady

Open Access Theses & Dissertations

In many engineering applications ranging from engineering seismology to petroleum engineering and civil engineering, processing seismic data plays a key role. In processing seismic data, it turns out to be very efficient to describe the signal's spectrum as a linear combination of Ricker wavelet spectra.

In this Thesis, we provide a possible theoretical explanation for this empirical efficiency. Specifically, signal propagation through several layers is discussed, and it is shown that the Ricker wavelet is the simplest non-trivial solution for the corresponding data processing problem, under the condition that the described properties of the approximation family are satisfied.

Experimental Evaluation Of Flame Stability And Pollutant Emissions From A Multi-Tube Fuel Injector, Sarzina Hossain

Open Access Theses & Dissertations

According to US Energy Information Administration coal is predicted to be the dominant source of power production in the United States until 2035. With fifty percent of the electricity generated in the United States originating from coal, the US produces close to 2 billion tons of CO2 per year from coal-burning power plants. The Integrated Gasification Combined Cycle (IGCC) offers a cleaner way to generate electricity-using coal. IGCC is a process where the feedstock is gasified and converted into to syngas (CO-H2) which can then be used as a fuel source to power energy-generating gas turbines. Compared to other hydrocarbons, …

3d Printed Electromagnetic Transmission And Electronic Structures Fabricated On A Single Platform Using Advanced Process Integration Techniques, Paul I. Deffenbaugh

Open Access Theses & Dissertations

3D printing has garnered immense attention from many fields including in-office rapid prototyping of mechanical parts, outer-space satellite replication, garage functional firearm manufacture, and NASA rocket engine component fabrication. 3D printing allows increased design flexibility in the fabrication of electronics, microwave circuits and wireless antennas and has reached a level of maturity which allows functional parts to be printed. Much more work is necessary in order to perfect the processes of 3D printed electronics especially in the area of automation. Chapter 1 shows several finished prototypes of 3D printed electronics as well as newly developed techniques in fabrication. Little is …

Experimental Studies Of Lox/Ch4 Uni-Element Shear Coaxial Injector Geometry, Vanessa Dorado-Martinez

Open Access Theses & Dissertations

The Center for Space Exploration Technology Research (cSETR) has developed a set of shear coaxial injectors as part of a system-level approach to study LOX/CH4 combustion. This Thesis describes the experimental studies involved in the characterization of the effects produced by two design injection face plate variables: post thickness and recession length. A testing program was developed to study the injectors' atomization process using LN2 as a substitute for LOX in cold flow and the flame anchoring mechanisms in hot firings. The cold flow testing stage was conducted to obtain liquid core measurements and compare its behavior between the different …