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- Electrocatalysis (75)
- Oxygen reduction reaction (65)
- Cyclic voltammetry (64)
- Electrodeposition (64)
- Lithium ion battery (58)
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- Electrochemistry (48)
- Supercapacitor (45)
- Corrosion (41)
- Cathode material (38)
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- Lithium-ion batteries (35)
- Lithium-ion battery (34)
- Fuel cell (33)
- Electrochemical impedance spectroscopy (30)
- Modified electrode (27)
- Lithium ion batteries (26)
- Carbon nanotubes (23)
- Oxygen evolution reaction (22)
- Anode (21)
- Fuel cells (21)
- Anode materials (20)
- Cathode (20)
- Electrolyte (20)
- Anode material (19)
- Electrocatalyst (19)
- Hydrogen evolution reaction (19)
- Lithium-sulfur batteries (19)
- Polyaniline (19)
- Li-ion battery (18)
- EIS (17)
- Publication Year
Articles 1501 - 1530 of 2026
Full-Text Articles in Engineering
Study On The Electrochemical Impedance Spectroscopy (Eis) Of Al-Bronze At Different Anodic Potentials, Hui Yu, Sa-Ying Dong, Hai-Bo Xu, Ming-Xian Sun
Study On The Electrochemical Impedance Spectroscopy (Eis) Of Al-Bronze At Different Anodic Potentials, Hui Yu, Sa-Ying Dong, Hai-Bo Xu, Ming-Xian Sun
Journal of Electrochemistry
The corrosion dissolution mechanism of Al-bronze has been investigated by Electrochemical Impedance Spectroscopy (EIS) at different anodic potentials. In the active region, the corrosion products are complex compounds of cupreous chloride and the diffusion of CuCl2- is the control process of electrochemical reaction. In the transition region, there exhibits two capacitance loops on EIS because CuCl and cupreous oxides films deposit on the electrode surface. In the limiting current region, an inductance loop appears on the EIS because the breakdown of the oxides film leads to serious pit corrosion.
Substrates Made By Electrodeposition For Measuring Electrical Properties Of One Dimensional Nanomaterials, Jin-Xuan Liu, Juan Xiang, Zhong-Qun Tian, Bing-Wei Mao
Substrates Made By Electrodeposition For Measuring Electrical Properties Of One Dimensional Nanomaterials, Jin-Xuan Liu, Juan Xiang, Zhong-Qun Tian, Bing-Wei Mao
Journal of Electrochemistry
A method to prepare alternating conducting/insulating substrates by electrodeposition-oxidation was established to facilitate I-E measurements of one-dimensional nanomaterial by CT-AFM. The prepared Au/CuO and HOPG/CuO substrates showed low roughness as well as high uniformity of the alternating conducting/insulating structure, Qualitative I-E measurements were performed on a single carbon nanotube attached to the two above-mentioned substrates, both showing metallic characteristics at room temperature and in air.
Studies On The Mechanism Of Electroreduction Of Oxalic Acid, Yu-Zhan Li, Xin Liu, Rui-Sheng Hu, Deng-Ping Gu
Studies On The Mechanism Of Electroreduction Of Oxalic Acid, Yu-Zhan Li, Xin Liu, Rui-Sheng Hu, Deng-Ping Gu
Journal of Electrochemistry
The electroreduction mechanism of oxalic acid on Pb electrode in Na2SO4 solution were investigated using high scan rate cyclic voltammetry and chronoamperometry. The dynamic parameters for the first step electron transter reaction of oxalic acid electroreduction by were determined. The corresponding reduction peak potentials of oxalic acid, glyoxylic acid and glycolic acid in the cyclic voltammogranis obtained in the same condition were compared, and the intermediate reduction products of oxalic acid were suggested. The results showed that oxalic acid is weakly absorbed on the lead electrode.
Preparation, Structure And Electrochemical Hydrogenation Of Carbon Nanotubes Supported Platinum Catalysts, Qing-Gang He, Xiao-Zi Yuan, Xian-Xia Yuan, Zi-Feng Ma
Preparation, Structure And Electrochemical Hydrogenation Of Carbon Nanotubes Supported Platinum Catalysts, Qing-Gang He, Xiao-Zi Yuan, Xian-Xia Yuan, Zi-Feng Ma
Journal of Electrochemistry
In this paper, Pt/CNTs catalyst was prepared and its electrocatalytic property was studied by obtaining cycling voltammetry curves (C-V) and Tafel curves. In addition, the XRD,XPS and TEM tests were carried out to determine the structure and composition of the catalysts. It can be found that the platinum loading has been increased significantly using a carbon nanotubes support. Dispersion of Platinum was better and gave more active sites. The electrochemical characteristic of Pt/CNTs was also more desirable than that of Pt/C catalys t(Johnson Matthey). In conclusion, carbon nanotubes can played a conspicuous role in "electrogenerative" processes of PEMFC hydrogenation reactor.
Electrochemical Character Of Water Containing Gel Electrolyte And Its Preliminary Examination In Lithium Water Cell, Jing-Dong Liu, Wen-Ji Wang, Xin-Zheng Yi
Electrochemical Character Of Water Containing Gel Electrolyte And Its Preliminary Examination In Lithium Water Cell, Jing-Dong Liu, Wen-Ji Wang, Xin-Zheng Yi
Journal of Electrochemistry
AC impedance technique has been used to characterize the system of poly(methyl acrylic acid)-poly(methyl acrylic lithiumate)-glycerol (referred to as GPE).The results showed that the conductivity of GPE increased with increasing both temperature and its water content.The glass transition temperature of GPE polymer could be lowered by water. Its conducting characteristic was just like liquid electrolyte,The electrolysis of GPE was almost the same as the electrolysis of water. Its composition voltage was about 1.50V. The GPE has been used to manufacture lithium water cell. When the graphite was used as cathode, the cell could discharge continuously for 2 hours under constant …
Preparation And Characterization Of Y-Type Carbon Nanotubes By Using Anodized Alumina Oxide (Aao) Template, Jing Zhang, Quan-Yong Gao, Yong Yang
Preparation And Characterization Of Y-Type Carbon Nanotubes By Using Anodized Alumina Oxide (Aao) Template, Jing Zhang, Quan-Yong Gao, Yong Yang
Journal of Electrochemistry
In this work, potential-modulation method was used in two-step anodization process to make an AAO template with Y-type nanochannels. Then Y-type carbon nanotubes with controlled length and branch angle were prepared in the template based on chemical vapor decomposion (CVD) method with Co particles as catalyst and C2H2 as carbon source. The Y-type nanotube branches exhibit the angle distribution ranging from 20° to 120°. The results demonstrated that the oxidation potential should be responsible for the angles and length of the branches. Short pulse and high oxidation potential will result in the short and dense nanotube branches.
Study On The Gas Generation In Different Charging Voltage During Formation Process In Polymer Lithium-Ion Battery, Li Huang, Ming-Gang Jin, Hui-Qun Cai, Ming-Sen Zheng, Quan-Feng Dong, Jin-Kua You, Zu-Geng Lin
Study On The Gas Generation In Different Charging Voltage During Formation Process In Polymer Lithium-Ion Battery, Li Huang, Ming-Gang Jin, Hui-Qun Cai, Ming-Sen Zheng, Quan-Feng Dong, Jin-Kua You, Zu-Geng Lin
Journal of Electrochemistry
The gases of polymer lithium-ion battery (PLI) generated under different voltages during the first charging process were examined by means of gas chromatography (GC), and the mechanism of the gas generation was discussed. The electrolyte used in batteries was 1 mol/L LiPF6-EC～DMC～EMC=1∶1∶1(in volume). The results showed that when the charging voltage is less than 2.5 V, the main component of generated gases are H2 and CO2, and when the charging voltage is 2.5 V, EC begins to decompose. Due to the decomposition of EC, the main generated gas is C2H4 when the …
Electrochemical And In-Situ Scanning Tunneling Microscopy Studies On The Sb Underpotential Deposition On Cu Single Crystal Electrodes, Ji-Hong Wu, Jia-Wei Yan, Jing Tang, Wen-Yun Hu, Bing-Wei Mao
Electrochemical And In-Situ Scanning Tunneling Microscopy Studies On The Sb Underpotential Deposition On Cu Single Crystal Electrodes, Ji-Hong Wu, Jia-Wei Yan, Jing Tang, Wen-Yun Hu, Bing-Wei Mao
Journal of Electrochemistry
We report electrochemical and in-situ STM studies on Sb UPD onto Cu(111) and Cu(100) electrode surfaces in HClO4 and H2SO4 solutions. The results indicate that the electrode surface structure as well as anion can considerably influence Sb UPD. Sb UPD on Cu(100) forms open adlayer structures, which is accompanied by surface alloying due to the more open structure of the (100) surface, On Cu(111), a more compact Sb adlayer is formed instead. Anion adsorption influences the dynamics as well as the adlayer structure of Sb UPD. Owing to the strong adsorption of SO42-, …
Application Of Hydrogen-Storage Alloy Electrode In Electrochemical Reduction Of Glucose, Hui Chen, You-Gen Tang, Zheng Tang
Application Of Hydrogen-Storage Alloy Electrode In Electrochemical Reduction Of Glucose, Hui Chen, You-Gen Tang, Zheng Tang
Journal of Electrochemistry
Electrolysis of glucose was performed at constant potential using hydrogen-storage alloy as catalytic reduction electrode. It was found that the superficial treatment and activation of hydrogen-storage alloy powder had obvious effects on improving the current efficiency of sorbitol. Under the optimums, current efficiency of sorbitol by electrolyzing glucose was over 94%. The yield of sorbitol was over 80%, the lifespan of electrode was tested and analyzed, the ways of regeneration were discussed.
Study On Electrochemical Behavior Of Sus316l Stainless Steel After Surface Modification, Cheng-Hao Liang, Liang Guo, Wan Chen, Jing-Xiao Liu
Study On Electrochemical Behavior Of Sus316l Stainless Steel After Surface Modification, Cheng-Hao Liang, Liang Guo, Wan Chen, Jing-Xiao Liu
Journal of Electrochemistry
The surface modification for SUS316L stainless steel was carried out by electroplating Rh, ion beam assisted deposition Ta2O5 and sol-gel-derived TiO2. In Tyrode's stimulated body fluid, the surface modified samples had been investigated with electrochemical techniques. The results indicated that the electrochemical stability and dissolution were improved significantly after surface modification. Moreover, as to ion beam assisted deposition Ta2O5 and Sol-gel-derived TiO2 film, the metal's d orbit electron holes filled up by the oxygen electrons made against the adsorption of hydrogen. Thus the cathode process, which is controlled by the hydrogen …
Pitting Characteristics Of Cu-50/60ni Alloys In Nacl Solution, Jie Li, Yan Niu, Shi-Zhe Song
Pitting Characteristics Of Cu-50/60ni Alloys In Nacl Solution, Jie Li, Yan Niu, Shi-Zhe Song
Journal of Electrochemistry
The pitting behavior of nanocrystalline Cu-50/60Ni and cast Cu-50/60Ni alloys in different concentration of NaCl solutions has been investigated using various electrochemical methods. A logarithmic dependence of the passive breakdown potential (Eb), which is established using dynamic potential scan technic, on the chloride concentration was obtained for both alloys. The study on pitting propagation of both alloys was carried out using potential step chronocurrent method. As long as pits initiate on both alloys, the pits on nanocrystalline Cu-Ni alloys develop faster than those on cast alloys.
Preparation And Properties Of The Composite Microporous Pvdf-Hfp/Sio2 Based Polymer Electrolytes, Bao-Wen Zhang, Lu Qi, Hui Hen, Xiao-Hui Zhu, Li-Yan Liu, Yun-Xiang Ci
Preparation And Properties Of The Composite Microporous Pvdf-Hfp/Sio2 Based Polymer Electrolytes, Bao-Wen Zhang, Lu Qi, Hui Hen, Xiao-Hui Zhu, Li-Yan Liu, Yun-Xiang Ci
Journal of Electrochemistry
Microporous PVDF-HFP/SiO2 film were prepared using a solvent/nonsolvent method-phase inversion method and the volatile plasticizers DMC, DEC or PC. The conductivity of the films increased pore volume measured by a nonsolvent uptake method. The conductivity of 1.86×10-3 S⋅m-1 were obtained using the liquid electrolyte LiPF6(1 M) in EC/DMC (1:1).
Optimizing Catalyst Layer Composition Of Pemfc By Orthogonal Method, Ming-Hua Wang, Xin-Jian Zhu, Guang-Yi Cao, Sheng Sui, Qing-Chun Yu, Ming-Ruo Hu, Zheng-Yu Fan
Optimizing Catalyst Layer Composition Of Pemfc By Orthogonal Method, Ming-Hua Wang, Xin-Jian Zhu, Guang-Yi Cao, Sheng Sui, Qing-Chun Yu, Ming-Ruo Hu, Zheng-Yu Fan
Journal of Electrochemistry
The optimal composition of catalyst layer in a PEMFC electrode was studied through orthogonal method. It was showed that the performance of hydrophilic electrodes, in which there is no PTFE in the catalyst layer, were more favorable than that of hydrophobic electrodes. According to this condition, the power density of PEMFC attained 0.37 w·cm-2 when the Nafion loading was 1.4 mg·cm-2, and the Pt loading was 0.4 mg·cm-2 in the catalyst layer, using H2 as fuel and air as oxidant both at atmospheric pressure. Additionally, the results showed that increasing Pt loading in Pt/C catalyst …
Study On Degradation Of Phenol By Electrochemical Oxidation, Yue-Li Liu, Hong-Hua Ge
Study On Degradation Of Phenol By Electrochemical Oxidation, Yue-Li Liu, Hong-Hua Ge
Journal of Electrochemistry
Electrochemical oxidation of phenol was carried out by the Dimensionally Stable Anodes (DSA) electrode, which has been discarded as waste by alkali chloride factory. The result indicates that a good phenol removal can be obtained under certain phenol concentration by the DSA electrode. The key factor in effecting phenol removal of electrochemical oxidation is applied current density, the following factors are pH, electrolyte concentration and phenol concentration. After experiments, the optimal test conditions are 30 mA/cm2, pH 10, electrolyte concentration 10 mg/L, phenol concentration 10 mg/L.67% CODcr removal and 90% absorbance removal are gained by electrochemical oxidation for …
Adsorption And Oxidation Of Phenol Electrode Processes, Bao-Cheng Wang, Yan-Ping Sun, Jin-Hua Zhu
Adsorption And Oxidation Of Phenol Electrode Processes, Bao-Cheng Wang, Yan-Ping Sun, Jin-Hua Zhu
Journal of Electrochemistry
The electrochemical behaviors of platinum electrode were studied by cyclic voltammetry in 1mol/L sulfuric acid solution and 1mol/L sulfuric acid solution contained phenol. The adsorption characteristics of phenol and the intermediat on electrode surface have been discussed. The reactive reversibility and oxidation mechanism of phenol on electrode process have been investigated.The potential of characteristic adsorption was suggested. The various products woud be formed when the electrode potential was greater than the one of characteristic adsorption.
The Study Of Green Corrosion Inhibitors For Mild Steel 907 In Natural Seawater Environment, Ping Gong, Min Du, Qing-Zhang Wang, Zhen-Jun Mu
The Study Of Green Corrosion Inhibitors For Mild Steel 907 In Natural Seawater Environment, Ping Gong, Min Du, Qing-Zhang Wang, Zhen-Jun Mu
Journal of Electrochemistry
Nine green compounds, including calcium gluconate, zinc gluconate, zinc sulfate, garlic, ACUSOL 445N, OS-15, APG, OCTA and STPP were selected according to the methods of molecule design and function groups prune. The functions of combined corrosion inhibitors mixed by the compounds mentioned above for mild steel in seawater were studied in this work using the methods of polarization curve and weight-loss.The best weight ratio and distinct synergistic effect of calcium gluconate, zinc sulfate and OCTA were studied by Latin experiment. The afgereffects of the best weight ratio corrosoin inhibitor were studied by subsection experiment. In this way, a kind of …
The Study On Carbon Nanotube-Loaded Pt Catalysts For Proton Exchange Membrane Fuel Cells, Hong Zhu, Feng-Juan Ge, Xiao-Hong Kang, Yu-Guo Yang, Yun-Hua Xu
The Study On Carbon Nanotube-Loaded Pt Catalysts For Proton Exchange Membrane Fuel Cells, Hong Zhu, Feng-Juan Ge, Xiao-Hong Kang, Yu-Guo Yang, Yun-Hua Xu
Journal of Electrochemistry
Carbon nanotube-supported-platinum (Pt/CNTs) and carbon-supported-platinum (Pt/C) catalysts were synthesized by in-situ chemical reduction. They were analyzed using TEM and XRD, then made into electrodes to be part of assemable PEMFC for the performence tests. The resulted show that Pt clusters in both catalysts are of small particle size (about 4nm), and Pt/CNTs exhibits a higher catalytic activity than Pt/C.
Effect Of Dspp Al2O3 On Electrical Properties Of Polymer Electrolyte, Hai-Fen Xie, Xiao-Xiang Sun, Yi-Pin Wang, Guang-Yuan Li
Effect Of Dspp Al2O3 On Electrical Properties Of Polymer Electrolyte, Hai-Fen Xie, Xiao-Xiang Sun, Yi-Pin Wang, Guang-Yuan Li
Journal of Electrochemistry
The PEO-NaSCN polymer solid electrolytes by adding dispersed second phase particles (DSPP) of Al2O3 were studied. The characteristics of solid electrolytes and conductivity values are dependent on DSPP Al2O3 sizes and its contents. It was found that when the Al2O3 sizes are less than 1 μm, which is a criticle size, the sample conductivities were larger than those of the pure PEO-NaSCN samples and when the Al2O3 sizes are larger than 1 μm then the sample conductivities are less then those of the pure samples. The maximum conductivity …
The Current Fluctuations Of Carbon Steel In Nano2-Nacl Solutions, Yu-Ming Tang, Yu Zuo
The Current Fluctuations Of Carbon Steel In Nano2-Nacl Solutions, Yu-Ming Tang, Yu Zuo
Journal of Electrochemistry
The characteristics of current fluctuations of A3 carbon steel in NaNO2-NaCl solutions were studied with potentiostatic and potentiodynamic polarization methods. The steel remained stable passivation in 0.1 mol/L NaNO2 solution without Cl-. After NaCl was added in to the solution, current fluctuations with a characteristic of quick increase and slow decrease occurred, indicating quick dissolution and slow re-passivation of the metastable pits. The metastable pitting may cause accumulated corrosion damage around certain area and result in observable pits. With the increase of chloride concentration, the occurring potential for metastable pits Em rised, and peak values …
Synthesis And Electrochemical Properties Of K2Feo4, Ning Zhou, Shi-Hai Ye, Yong-Long Wang, Xue-Ping Gao, Dong-Feng Lin, Zuo-Xiang Zhou, De-Ying Song
Synthesis And Electrochemical Properties Of K2Feo4, Ning Zhou, Shi-Hai Ye, Yong-Long Wang, Xue-Ping Gao, Dong-Feng Lin, Zuo-Xiang Zhou, De-Ying Song
Journal of Electrochemistry
The K2FeO4 used for new positive electrode materials was prepared. The primary batteries were used in different concentration of electrolyte and different currents. In 9 mol/L KOH , the capacity was the best. The higher the concentration of electrolyte, the lower the electric potential was. When the batteries discharged in 0.4 C , the capacity reached 521.3 mAh/g. By XRD, we gave the reasonable explanations for the discharge products of K2FeO4. Possible mechanism of discharge is discussed.
Corrosion Fatigue And Dynamic Strain Aging Of Duplex Stainless Steel In Aqueous Solution, Chuan-Ming Tseng, I-Hsuang Lo, Wen-Ta Tsai
Corrosion Fatigue And Dynamic Strain Aging Of Duplex Stainless Steel In Aqueous Solution, Chuan-Ming Tseng, I-Hsuang Lo, Wen-Ta Tsai
Journal of Electrochemistry
The corrosion fatigue and dynamic strain aging behaviors of 22%Cr duplex stainless steel (DSS) in sodium chloride solutions were investigated. Austenitic 316L SS and ferrtic 430 SS were also used in this study for a comparison. The experimental results showed that no stress corrosion cracking (SCC) occurred in all these SSs tested in 3.5wt% NaCl solution at 80 ℃. However, dynamic strain aging (DSA) occurred in 316L austenitic SS and 22%Cr DSS during slow strain rate testing (SSRT) in this solution.The occurrence of DSA was dependent on solution temperature,strain rate and the presence of austenitic phase. The corrosion rate of …
Synthesis Of Polyunit Vapor Phase Inhibitor And Its Volatile Corrosion Inhibition Performance, Da-Quan Zhang, Li-Xin Gao, Guo-Ding Zhou
Synthesis Of Polyunit Vapor Phase Inhibitor And Its Volatile Corrosion Inhibition Performance, Da-Quan Zhang, Li-Xin Gao, Guo-Ding Zhou
Journal of Electrochemistry
A Mannich Base derivative (BMMCH), containing two morpholinum moieties and one cyclohexylamnonium moiety, was synthesized through aminomethy1 reaction. Its configuration was verified by IR and 1H-NMR. Its volatile rustproofing effect was appraised by volatile rustproofing sieve test and vapor inhabitability test. The result shows that BMMCH has good protection effect for carbon steel. BMMCH has lower volatility compared with dicyclohexylamnonium nitrite (DICHAN) via closed space volatile weight-loss test. The inhibition mechanism was studied by potentiodynamic polarization electrochemistry technique in ASTM simulated atmospheric water. The corrosion potential of carbon steel electrode shifted to a negative direction when BMMCH was joined …
Effect Of Heat Laminating Aggregation Status Of Polymer Lithium-Ion Battery Cathode On Battery Performance, Ming-Gang Jin, Quan-Feng Dong, Ming-Sen Zheng, Li Huang, Hui-Qun Cai, Jin-Qua You, Zu-Geng Lin
Effect Of Heat Laminating Aggregation Status Of Polymer Lithium-Ion Battery Cathode On Battery Performance, Ming-Gang Jin, Quan-Feng Dong, Ming-Sen Zheng, Li Huang, Hui-Qun Cai, Jin-Qua You, Zu-Geng Lin
Journal of Electrochemistry
Multi-layer heat laminated polymer lithium ion battery was made, the effect of temperature of cathode laminating on battry performance was also investigated. It was discovered that suitable temperature of cathode laminating is critical to battery performance and is a key parameter to manufacture process control of polymer lithium ion battery.
Influence Of Marine Organisms Upon Corrosion Of Steel Piling Systems, Jiunn-Shyong Luo, Cliff Rau, Kuei-Ching Chen
Influence Of Marine Organisms Upon Corrosion Of Steel Piling Systems, Jiunn-Shyong Luo, Cliff Rau, Kuei-Ching Chen
Journal of Electrochemistry
To study the influence of marine organisms upon corrosion of ASTM A36 steel piling sysems, specimens were immersed in both natural and synthetic seawater. Electrochemical techniques such as linear polarization resistance and electrochemical impedance scan(EIS) were applied to evaluate corrosion of the steel. The results indicated that attachment of marine organisms to form fouling layers on the steel surface reduced general corrosion, but localized corrosion occurred underneath marine organisms. An equivalent circuit model was established to simulate attachment of marine organisms upon carbon carbon steel surfaces.
Severe Corrosivity And Its Eletrochemical Mechanism Of Seawater In Xiamen Sea Area To Al-Mg Alloys, Le-Yun Lin, Yue-Hong Zhao
Severe Corrosivity And Its Eletrochemical Mechanism Of Seawater In Xiamen Sea Area To Al-Mg Alloys, Le-Yun Lin, Yue-Hong Zhao
Journal of Electrochemistry
The surface layer seawater of different sea areas in China exhibit different corrosivity to Al-Mg alloys according to the experiment results of 16 years exposure in seawater. The seawater in Xiamen sea area possesses severe corrosivity while seawater in Qingdao possesses the mildest corrosivity to Al-Mg alloys with better regularity of corrosion behavior. The present paper illustrates by experiment data that the strongest corrosivity of Xiamen seawater to Al-Mg alloys is owing to the low salinity of the seawater and the “electrolyte effect” come from it. The 16 year corrosion data and corrosion morphology of the typical Al-Mg alloys from …
Discussion On Factors Of Unstable 304 Stainless Steel Stress Corrosion Cracking, Xin-Sheng Zhang, Chun-Chun Xu, Gang Hu
Discussion On Factors Of Unstable 304 Stainless Steel Stress Corrosion Cracking, Xin-Sheng Zhang, Chun-Chun Xu, Gang Hu
Journal of Electrochemistry
The 304 stainless steels were stretched at low temperatures to get different martensite phase transformation. Ferrmagnetometer was used to measure the martensite phase content. It was found that the dislocation density of 304 stainless sted was increased unavoidably with increase of deformation. Transmission electron microscope (TEM) was used to study the distribution of the dislocation. The influence of microstructure change on SCC of 304 stainless steel was discussed by slow strain rate testing (SSRT) in 42% MgCl2 boiling solution,metallurgical microscope and scanning electron microscope (SEM).The results showed that martensite phase and dislocation flaw act together on the SCC susceptibility …
The Electroless Plating Ni-Fe-P Alloy And Its Voltammetric Behavior, Sen-Lin Wang, Hui-Huang Wu
The Electroless Plating Ni-Fe-P Alloy And Its Voltammetric Behavior, Sen-Lin Wang, Hui-Huang Wu
Journal of Electrochemistry
Electroless Ni-Fe-P alloy deposition from an alkaline bath, containing sodium hypophosphite as reducer, boric acid as buffer agent and sodium citrate as complexing agent, was investigated. To increase the plating rate and to inprove the bath stability, the deposition parameters were optimized. The effects of process parameters (pH, temperature and mole ratio of [Fe2+]/([Ni2+]+[Fe2+]) on the plating rate and deposit composition were examined and it was found that the presence of ferrous sulfate in the bath has an inhibitory effect on the alloy deposition. As a consequence, the percentage of iron in the electroless …
The Mechanism Of Electrocatalytic Reduction Of Oxygen On Manganese Dioxide, Yu-Liang Cao, Han-Xi Yang, Xin-Ping Ai, Li-Fen Xiao
The Mechanism Of Electrocatalytic Reduction Of Oxygen On Manganese Dioxide, Yu-Liang Cao, Han-Xi Yang, Xin-Ping Ai, Li-Fen Xiao
Journal of Electrochemistry
The oxygen electroreduction on the MnO2 electrode was investigated by analysis of the polarzation properties of oxygen reduciton and its dependence on MnO2 discharge state, in combination with the characterization of discharge intermediate and the kinetic parameters of the oxygen reduction. Based on the experimental observation and mechanistic analysis, it was suggested that the reduction of oxygen was closely related to the discharge behaviors of MnO2. When MnO2 was electrochimically reduced to MnOOH, it was immediately oxidized by oxygen molecules. Thus the oxygen reduction proceeds through continuous oxidation of the discharge product of MnO2 …
The Technique Of Rare-Earth Conversion Coatings On Aluminum Alloy, Jun-Tao Wang, Jian-Hua Wu, Guang-Zhang Chen
The Technique Of Rare-Earth Conversion Coatings On Aluminum Alloy, Jun-Tao Wang, Jian-Hua Wu, Guang-Zhang Chen
Journal of Electrochemistry
The orthogonal design was used to screen the film_forming technique on LY12 aluminum alloy using quadrivalent cerium salt, and the corrosion-resistance performance of the coating was studied. The results revealed that: after LY12 aluminum alloy was treated by cerium salt, its pitting potential shifts to positive direction while the corrosion potential slightly decreases, showing that the alloy becomes less sensitive to pitting corrosion was greatly improved, comparable to that after chromate treatment; in addition, by combining the results of electrochemical measurements with surface analysis, the mechanism of corrosion-resistance on the race-earth conversion coating of the aluminum alloy was also discussed.
Comparison Of Thermal Cyclic Oxidation Of The Pvd Ni-Al And Hvof-Mcraly Coatings, J-T Chang, C-H Yeh, J-L He, K-C Chen
Comparison Of Thermal Cyclic Oxidation Of The Pvd Ni-Al And Hvof-Mcraly Coatings, J-T Chang, C-H Yeh, J-L He, K-C Chen
Journal of Electrochemistry
A PVD process-cathodic arc plasma ion plating was used to deposit Ni-Al films on Inconel 600 superalloy. The oxidation behaviors of PVD Ni-Al coating and the thermal sprayed CoCrAlY coatings were revealed and compared by performing cyclic thermal oxidation test at 1100 ℃ to evaluate its feasibility. Experimental results showed that the films with different compositions of Ni62Al38, Ni63Al37 and Ni69Al31 could be obtained when using Ni52Al48, Ni60Al40 and Ni70Al30 as targets, respectively. During the cyclic thermal oxidation test, the …