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Articles 3151 - 3180 of 3292

Full-Text Articles in Engineering

Heterogeneity Of Intergranular Damage In Copper Crept In Plane-Strain Tension, Brent L. Adams, David P. Field Sep 1992

Heterogeneity Of Intergranular Damage In Copper Crept In Plane-Strain Tension, Brent L. Adams, David P. Field

Faculty Publications

The authors wish to acknowledge support of this work by the Office of Basic Energy Sciences of the U. S. Department of Energy. An interface damage function (IDF), which statistically describes the area fraction of interface damage as a function of up to eight parameters defining crystallite interfaces, was determined for commercial purity copper specimens crept in plane strain tension. The IDF was determined from stereological parameters measured on plane sections cut through damaged specimens. The eight-dimensional space of the function was investigated by analyzing two-dimensional projections of the complete domain. Certain special interfaces were observed to damage preferentially. A …

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Interface Cavitation Damage In Polycrystalline Copper, Brent L. Adams, David P. Field Jun 1992

Interface Cavitation Damage In Polycrystalline Copper, Brent L. Adams, David P. Field

Faculty Publications

The authors acknowledge the support of the Office of Basic Energy Sciences of the United States Department of Energy. Determination of an interface damage function (IDF) from a stereological procedure similar to that presented by Hilliard is described. The mathematical and experimental simplicity of the method is utilized in measuring an IDF for polycrystalline copper crept at 0.6T sub m under uniaxial tension. Whereas previous work focused on a five parameter description of the local state of a grain boundary, the domain of the IDF is increased to eight degrees of freedom in the present study to include the complete …

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Experimental Measurement Of Rov Tether Tension, Tim W. Mclain, S M. Rock Jun 1992

Experimental Measurement Of Rov Tether Tension, Tim W. Mclain, S M. Rock

Faculty Publications

In the undersea operation of a tethered ROV system, the pilot's ability to control precisely the ROV is often limited by disturbance forces generated by drag due to currents that act either directly on the ROV or indirectly on the ROV through the tether. The objective of this research, which was conducted at the Monterey Bay Aquarium Research Institute (MBARI), was to characterize the magnitude and dynamics of tether forces by measuring them during operation. To achieve this, a tether tension sensor and data logging system were developed. This system was used to measure the forces in the tether of …

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Note On The Number Dependence Of Nonequilibrium Molecular Dynamics Simulations Of The Viscosity Of Structured Molecules, Richard L. Rowley, James F. Ely Mar 1992

Note On The Number Dependence Of Nonequilibrium Molecular Dynamics Simulations Of The Viscosity Of Structured Molecules, Richard L. Rowley, James F. Ely

Faculty Publications

Nonequilibrium molecular dynamics simulations have been performed for a system of 512 four-site models representing n-butane molecules. The results are compared to simulations previously reported for 125 molecules to check a recently reported number dependence in such simulations. A small system size dependence was observed at low shear rates, but the rheological behavior is not affected. Considerably greater certainty is obtained using larger systems.

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Effect Of Co2 On The Processing Of Y-Ba-Cu-O Superconductors, C. Zhang, Guna S. Selvaduray Feb 1992

Effect Of Co2 On The Processing Of Y-Ba-Cu-O Superconductors, C. Zhang, Guna S. Selvaduray

Faculty Publications

The superconducting properties of YBa2Cu3O6+x reacted with various known ratios of O2/CO2 gas mixtures during sintering at different temperatures were studied. Jc was found to decrease drastically upon reaction with CO2, becoming zero at certain CO2 activities. The stability region for the 123 superconductor, as a function of CO2 activity and temperature, was empirically formulated as follows: log pCO2 < (−45,000)/T + 33.4. The grain boundaries in sintered samples with Jc = 0 were investigated with HRTEM in conjunction with EDS. Two distinct types of grain boundaries were observed. Approximately 10% of the grain boundaries were wet by a thin layer of a second phase, deduced to be BaCuO2. The remaining boundaries were sharp grain boundaries. The grain structure near the sharp grain boundaries was tetragonal. These two types of grain boundaries are thought to be responsible for Jc being zero.

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Unequal Error Protection Qpsk Modulation Codes, Robert H. Morelos-Zaragoza, Shu Lin Jan 1992

Unequal Error Protection Qpsk Modulation Codes, Robert H. Morelos-Zaragoza, Shu Lin

Faculty Publications

The authors use binary linear UEP (LUEP) codes, in combination with a QPSK signal set and Gray mapping, to obtain new efficient block QPSK modulation codes with unequal minimum squared Euclidean distances. They give several examples of codes that have the same minimum squared Euclidean distance as the best QPSK modulation codes of the same rate and length. A new suboptimal two-stage soft-decision decoding is applied to LUEP QPSK modulation codes.

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Thermal Mathematical Modeling Of A Multicell Common Pressure Vessel Nickel-Hydrogen Battery, Junbom Kim, T. V. Nguyen, Ralph E. White Jan 1992

Thermal Mathematical Modeling Of A Multicell Common Pressure Vessel Nickel-Hydrogen Battery, Junbom Kim, T. V. Nguyen, Ralph E. White

Faculty Publications

A two-dimensional and time-dependent thermal model of a multicell common pressure vessel (CPV) nickel-hydrogen battery was developed. A finite element solver called PDE/Protran was used to solve this model. The model was used to investigate the effects of various design parameters on the temperature profile within the cell. The results were used to help find a design that will yield an acceptable temperature gradient inside a multicell CPV nickel-hydrogen battery. Steady-state and unsteady-state cases with a constant heat generation rate and a time-dependent heat generation rate were solved.

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Comparison Of Heat-Fin Materials And Design Of A Common-Pressure-Vessel Nickel-Hydrogen Battery, Junbom Kim, Ralph E. White Jan 1992

Comparison Of Heat-Fin Materials And Design Of A Common-Pressure-Vessel Nickel-Hydrogen Battery, Junbom Kim, Ralph E. White

Faculty Publications

A two-dimensional, axisymmetric, and time-dependent thermal model was developed to study the temperature behavior of the cylindrically shaped common-pressure-vessel nickel-hydrogen cell. A differential-energy-balance equation was used as the governing equation. A finite-element software package called PDE/Protran was used to solve this model. Different materials such as copper, copper beryllium, silver, and sterling silver were compared as heat-fin materials. The heat-fin geometry (thickness and height) and spacing were tested to find a design that yielded an acceptable temperature gradient inside a nickel-hydrogen cell. Pulse heat-generation rates were tested and correlated with the time-dependent heat-generation cases.

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Mathematical Modeling Of A Primary Zinc/Air Battery, Z. Mao, Ralph E. White Jan 1992

Mathematical Modeling Of A Primary Zinc/Air Battery, Z. Mao, Ralph E. White

Faculty Publications

The mathematical model developed by Sunu and Bennion has been extended to include the separator, precipitation of both solid ZnO and K2Zn(OH)4, and the air electrode, and has been used to investigate the behavior of a primary Zn-Air battery with respect to battery design features. Predictions obtained from the model indicate that anode material utilizationis predominantly limited by depletion of the concentration of hydroxide ions. The effect of electrode thickness on anode material utilization is insignificant, whereas material loading per unit volume has a great effect on anode material utilization; a higher loading lowers both the …

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Removal Of Mercury From Waste Water: Large-Scale Performance Of An Ion Exchange Process, James A. Ritter, J. P. Bibler Jan 1992

Removal Of Mercury From Waste Water: Large-Scale Performance Of An Ion Exchange Process, James A. Ritter, J. P. Bibler

Faculty Publications

Duolite™ GT-73 ion exchange resin routinely reduces the mercury content of a waste water stream to less than the permitted level of 10 ppb. Effluent concentrations from the ion exchange facility (IEF) are consistently between 1 to 5 ppb, even though the feed contains a varying concentration of mercury (0.2 to 70 ppm). Two operational problems have been encountered at that facility, however. Firstly, the stated capacity of the resin for mercury was not being achieved. The abnormally low capacity was traced to analytical laboratory waste which was intermittently treated by the resin. That waste contained hydrochloric acid, stannous chloride, …

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Chemical Percolation Model For Devolatilization: Ii. Temperature And Heating Rate Effects On Product Yields, Thomas H. Fletcher, Alan R. Kerstein, Ronald J. Pugmire, David M. Grant Jan 1992

Chemical Percolation Model For Devolatilization: Ii. Temperature And Heating Rate Effects On Product Yields, Thomas H. Fletcher, Alan R. Kerstein, Ronald J. Pugmire, David M. Grant

Faculty Publications

The chemical percolation devolatilization (CPD) model describes the devolatilization behavior of rapidly heated coal based on the chemical structure of the parent coal. Percolation lattice statistics are employed to describe the generation of tar precursors of finite size based on the number of cleaved labile bonds in the infinite lattice. The chemical percolation devolatilization model described here includes treatment of vapor-liquid equilibrium and a cross-linking mechanism. The cross-linking mechanism permits reattachment of metaplast to the infinite char matrix. A generalized vapor pressure correlation for high molecular weight hydrocarbons, such as coal tar, is proposed based on data from coal liquids. …

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Characterizations Of Antimony Tri‐Sulfide Chemically Deposited With Silicotungstic Acid, O. Savadogo, K. C. Mandal Jan 1992

Characterizations Of Antimony Tri‐Sulfide Chemically Deposited With Silicotungstic Acid, O. Savadogo, K. C. Mandal

Faculty Publications

No abstract provided.

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Parameter Sensitivity And Optimization Predictions Of A Hydrogen/Oxygen Alkaline Fuel Cell Model, Michael C. Kimble, Ralph E. White Jan 1992

Parameter Sensitivity And Optimization Predictions Of A Hydrogen/Oxygen Alkaline Fuel Cell Model, Michael C. Kimble, Ralph E. White

Faculty Publications

A mathematical model is used to predict parameter sensitivities and optimal design parameters for a hydrogen/oxygen alkaline fuel cell. A sensitivity analysis of the various transport and electrode kinetic parameters indicates which parameters have the most influence on the predicted current density and over which range of potentials these parameters affect the fuel-cell performance the most. This information can be used to decide which parameters should be optimized or determined more accurately through further modeling or experimental studies. The effect of various design parameters on the limiting current density are investigated to determine if optimal values exist for the parameters. …

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The Self-Discharge Of The Niooh/Ni(Oh)2 Electrode Constant Potential Study, Z. Mao, Ralph E. White Jan 1992

The Self-Discharge Of The Niooh/Ni(Oh)2 Electrode Constant Potential Study, Z. Mao, Ralph E. White

Faculty Publications

Hydrogen oxidation currents at a NiOOH/Ni(OH)2 electrode were measured directly at constant potentials for various hydrogen pressures and states of charge. It was found that the hydrogen oxidation current is linearly proportional to the hydrogen pressure at all electrode potentials and that the logarithm of the anodic current is a linear function of electrode potential. It was also found that hydrogen oxidation on the nickel substrate material was strongly inhibited by the presence of nickel hydroxide on the substrate surface. By comparing the currents for hydrogen oxidation and oxygen evolution on the NiOOH/Ni(OH)2 electrode and on a nickel …

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Mathematical Modeling Of Cathodic Protection Using The Boundary Element Method With A Nonlinear Polarization Curve, J. F. Fan, S. N. R Pakalapati, T. V. Nguyen, Ralph E. White, R. B. Griffin Jan 1992

Mathematical Modeling Of Cathodic Protection Using The Boundary Element Method With A Nonlinear Polarization Curve, J. F. Fan, S. N. R Pakalapati, T. V. Nguyen, Ralph E. White, R. B. Griffin

Faculty Publications

The distributions of potential and current density around a cathodically protected pipeline in seawater were determined using the boundary element technique. A nonlinear polarization curve for a low carbon steel in artificial sea water was obtained from dc-potentiodynamic measurements and was fitted for use as the boundary condition on the pipe. The program was used to evaluate cases in which one or two aluminum sacrificial anodes are used to protect a low carbon steelpipe in seawater. The results show that the number of anodes, the sizes of the anodes, and the distance between the anodes and the cathode are of …

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Hydrogen Diffusion, Solubility, And Water Uptake In Dow's Short-Side-Chain Perfluorocarbon Membranes, Yu-Min Tsou, M. C. Kimble, Ralph E. White Jan 1992

Hydrogen Diffusion, Solubility, And Water Uptake In Dow's Short-Side-Chain Perfluorocarbon Membranes, Yu-Min Tsou, M. C. Kimble, Ralph E. White

Faculty Publications

Hydrogen gas diffusion coefficients and solubilities as well as water uptake values are reported for Dow's short-side-chain perfluoro-sulfonic and -carboxylic membranes of different equivalent weight (EW). The diffusion coefficients and solubilities were determined with an electrochemical test cell. Hydrogen solubility decreases with increasing EW in the lower EW range and tends to level off at higher EWs for both types of membranes. Both hydrogen solubility and diffusion coefficients of a sulfonic membrane with EW higher than 800 are higher than the corresponding values of a carboxylic membrane of similar EW. An unusual maximum is observed in the diffusion coefficient-EW plot …

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Calorimetric Determination Of The Thermoneutral Potential Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy Jan 1992

Calorimetric Determination Of The Thermoneutral Potential Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy

Faculty Publications

Through a continuous recording of the cell voltage, heat flow, and current, the effective thermoneutral potential, Eetpof Li/BCX and Li/SOCl2 cells were determined in the temperature range, 0–60°C. The depth of discharge (DOD), temperature (T), and cell type (cell chemistry) affect the effective thermoneutral potential. The effective thermoneutral potential, Eetp differs from the classical thermoneutral potential of a cell because it takes into account the heat flow due to non-faradaic processes. The average effective thermoneutral potential at 25°C (determined by selecting the most constant region of Eetp vs. time of discharge) was 4.0 …

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Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin Jan 1992

Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin

Faculty Publications

Electrochemical impedance spectroscopy (EIS) was used to evaluate the degree of delamination of the epoxy primer Uniprime ED-41 electrocoated on phosphate-treated cold-rolled steel in 3.5% NaCl exposed to air. Specimens with coating thicknesses of 20.3 and 20.8 µm and surface areas of 78.5 cm2 were used. Coating parameters were obtained using a circuit-analog model. The area of delamination was estimated using several EIS parameters, including the pore resistance and the break point frequency. These values were compared to the corroded area determined visually. All methods considered exhibited a strong correlation over some or all of the range of …

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Reduction Of Chromium (Vi) When Solar Selective Black Chromium Is Deposited In The Presence Of Organic Additive, Branko N. Popov, Ralph E. White, D. Slavkov, Z. Koneska Jan 1992

Reduction Of Chromium (Vi) When Solar Selective Black Chromium Is Deposited In The Presence Of Organic Additive, Branko N. Popov, Ralph E. White, D. Slavkov, Z. Koneska

Faculty Publications

Electrochemical dc methods were used to study the reduction of chromium (VI) in the presence of organic additives. It is shown that F–, thiourea, and citric acid are essential to enable deposition of black chrome from concentrated chromic acid solutions. A new formulation of the plating bath is defined. The optimum operating conditions under which spectrally selective surface of black chrome is deposited have been determined.

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Measurements Of The Fundamental Thermodynamic Parameters Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy Jan 1992

Measurements Of The Fundamental Thermodynamic Parameters Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy

Faculty Publications

The thermodynamic data needed to estimate the heat generation characteristics of Li/BCX and Li/SOCl2 cells were determined using two experimental techniques, equilibrium or reversible cell discharge and measurement of open circuitpotential as a function of temperature. The results obtained showed that the reversible cell potential (Er), the temperature dependence of the reversible cell potential (dEr/dT) and thermoneutral potential (Eh) of the BCX cell were respectively, Er,25oc = 3.74 V, dEr/dT = –0.857 ± 0.198 mV/K and Eh = 3.994 …

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A Mathematical Model Of A Cuo/Cu Vaporvolt Cell, Makoto Kawanami, Trung V. Nguyen, Ralph E. White Jan 1992

A Mathematical Model Of A Cuo/Cu Vaporvolt Cell, Makoto Kawanami, Trung V. Nguyen, Ralph E. White

Faculty Publications

A new battery named "Vaporvolt"b cell is in the early stage of its development. A mathematical model of a CuO/CuVaporvolt cell is presented that can be used to predict the potential and the transport behavior of the cell during discharge.A sensitivity analysis of the various transport and electrokinetic parameters indicates which parameters have the mostinfluence on the predicted energy and power density of the Vaporvolt cell. This information can be used to decide whichparameters should be optimized or determined more accurately through further modeling or experimental studies. Theoptimal thicknesses of electrodes and separator, the concentration of the electrolyte, and …

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Chemical Structure Of Char In The Transition From Devolatilization To Combustion, Thomas H. Fletcher, Mark S. Solum, David M. Grant, Ronald J. Pugmire Jan 1992

Chemical Structure Of Char In The Transition From Devolatilization To Combustion, Thomas H. Fletcher, Mark S. Solum, David M. Grant, Ronald J. Pugmire

Faculty Publications

Coal devolatilization experiments are generally conducted separately from char oxidation experiments, and the relationship between the chars generated in the two types of research is often ignored. However, char is one of the most important products of coal devolatilization and must be characterized as a function of temperature and heating rate in a manner similar to that for gaseous devolatilization products. The chemical structure of the parent coal directly affects devolatilization behavior. In this work, the chemical structure of chars from five coals of different rank are examined, and implications on char reactivity are discussed. Chars were obtained as a …

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Resource Integration Using A Large Knowledge Base In Carnot, Christine Collet, Michael N. Huhns, Wei-Min Shen Dec 1991

Resource Integration Using A Large Knowledge Base In Carnot, Christine Collet, Michael N. Huhns, Wei-Min Shen

Faculty Publications

A method for integrating separately developed information resources that overcomes incompatibilities in syntax and semantics and permits the resources to be accessed and modified coherently is described. The method provides logical connectivity among the information resources via a semantic service layer that automates the maintenance of data integrity and provides an approximation of global data integration across systems. This layer is a fundamental part of the Carnot architecture, which provides tools for interoperability across global enterprises.

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A Note On Repeated-Root Cyclic Codes, Robert H. Morelos-Zaragoza Nov 1991

A Note On Repeated-Root Cyclic Codes, Robert H. Morelos-Zaragoza

Faculty Publications

In papers by Castagnoli et al. and Van Lint, cyclic codes with repeated roots are analyzed. Both papers fail to acknowledge a previous work by Chen, dating back to 1969, which includes an analysis of even, length binary cyclic codes. Results from Chen’s study are presented.

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Spaceborne Radar Measurement Of Wind Velocity Over The Ocean-An Overview Of The Nscat Scatterometer System, David G. Long, F. M. Naderi, Michael H. Freilich Jun 1991

Spaceborne Radar Measurement Of Wind Velocity Over The Ocean-An Overview Of The Nscat Scatterometer System, David G. Long, F. M. Naderi, Michael H. Freilich

Faculty Publications

Scatterometry and scatterometer design issues are reviewed. The design of the NASA Scatterometer (NSCAT) to be flown on the Japanese ADEOS mission is presented. Building on Seasat experience, the NSCAT system includes several enhancements, such as three antenna azimuths in each of two swaths, and an onboard digital Doppler processor to allow backscatter measurements to be colocated everywhere within the orbit. These enhancements will greatly increase the quality of the NSCAT wind data. The ground processing of data is discussed, and scatterometers of the next decade are briefly described.

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Identifiability In Wind Estimation From Scatterometer Measurements, David G. Long, Jerry M. Mendel Mar 1991

Identifiability In Wind Estimation From Scatterometer Measurements, David G. Long, Jerry M. Mendel

Faculty Publications

The problem of identifiability of a wind vector that is estimated from wind scatterometer measurements of the radar backscatter of the ocean's surface is addressed. The traditional wind estimation approach produces multiple estimates of the wind direction. A second processing step, known as dealiasing or ambiguity removal, is used to select a single wind estimate from these multiple solutions. Dealiasing is typically based on various ad hoc considerations. The traditional wind estimation approach results in multiple solutions associated with local minima in an objective function formed from the noisy backscatter measurements. The authors discuss the question of the uniqueness of …

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Set-Valued Filtering And Smoothing, Wynn C. Stirling, Darryl Morrell Feb 1991

Set-Valued Filtering And Smoothing, Wynn C. Stirling, Darryl Morrell

Faculty Publications

A theory of discrete-time optimal filtering and smoothing based on convex sets of probability distributions is presented. Rather than propagating a single conditional distribution as does conventional Bayesian estimation, a convex set of conditional distributions is evolved. For linear Gaussian systems, the convex set can be generated by a set of Gaussian distributions with equal covariance with means in a convex region of state space. The conventional point-valued Kalman filter is generated to a set-valued Kalman filter consisting of equations of evolution of a convex set of conditional means and a conditional covariance. The resulting estimator is an exact solution …

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Convex Bayes Decision Theory, Wynn C. Stirling, Darryl Morrell Feb 1991

Convex Bayes Decision Theory, Wynn C. Stirling, Darryl Morrell

Faculty Publications

The basic concepts of Levi's epistemic utility theory and credal convexity are presented. Epistemic utility, in addition to penalizing error as is done with traditional Bayesian decision methodology, permits a unit of informational value to be distributed among the hypotheses of a decision problem. Convex Bayes decision theory retains the conditioning structure of probability-based inference, but addresses many of the objections to Bayesian inference through relaxation of the requirement for numerically definite probabilities. The result is a decision methodology that stresses avoiding errors and seeks decisions that are likely to be highly informative as well as true. By relaxing the …

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A Median-Filter-Based Ambiguity Removal Algorithm For Nscat, David G. Long, Scott J. Shaffer, R. Scott Dunbar, S. Vincent Hsiao Jan 1991

A Median-Filter-Based Ambiguity Removal Algorithm For Nscat, David G. Long, Scott J. Shaffer, R. Scott Dunbar, S. Vincent Hsiao

Faculty Publications

A description is given of the baseline NSCAT (the NASA scatterometer) ambiguity removal algorithm and the method used to select the set of optimum parameter values. An extensive simulation of the NSCAT instrument and ground data processor provides a means of testing the resulting tuned algorithm. This simulation generates the ambiguous wind-field vectors expected from the instrument as it orbits over a set of realistic mesoscale wind fields. The ambiguous wind field is then de-aliased using the median-filter-based ambiguity removal algorithm. Performance is measured by comparison of the selected wind fields with the true wind fields. Results have shown that …

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A Mathematical Model Of A Sealed Nickel-Cadmium Battery, Deyuan Fan, Ralph E. White Jan 1991

A Mathematical Model Of A Sealed Nickel-Cadmium Battery, Deyuan Fan, Ralph E. White

Faculty Publications

A mathematical model for the charge and discharge of a sealed nickel-cadmium (Ni-Cd) battery is presented. The model is used to study the effect of transport properties of the electrolyte and kinetic parameters of the electrode reactions on the cell performance during the charge and discharge period. The model can also be used to demonstrate the changes of cell performance during cycling. Some comparisons between model predictions and experimental results indicate that the model predictions appear to fit the experimental data well. Sensitivity analyses illustrate that the sealed nickel-cadmium battery operates under activation control. It is also shown theoretically that …

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