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Articles 2851 - 2880 of 3294

Full-Text Articles in Engineering

Multilevel Coded Modulation For Unequal Error Protection And Multistage Decoding—Part I: Symmetric Constellations, Robert H. Morelos-Zaragoza, Marc P. C. Fossorier, Shu Lin, Hideki Imai Feb 2000

Multilevel Coded Modulation For Unequal Error Protection And Multistage Decoding—Part I: Symmetric Constellations, Robert H. Morelos-Zaragoza, Marc P. C. Fossorier, Shu Lin, Hideki Imai

Faculty Publications

In this paper, theoretical upper bounds and computer simulation results on the error performance of multilevel block coded modulations for unequal error protection (UEP) and multistage decoding are presented. It is shown that nonstandard signal set partitionings and multistage decoding provide excellent UEP capabilities beyond those achievable with conventional coded modulation. The coding scheme is designed in such a way that the most important information bits have a lower error rate than other information bits. The large effective error coefficients, normally associated with standard mapping by set partitioning, are reduced by considering nonstandard partitionings of the underlying signal set. The …

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Selective Area Deposited Blue Gan-Ingan Multiple-Quantum Well Light Emitting Diodes Over Silicon Substrates, J. W. Yang, A. Lunev, Grigory Simin, A. Chitnis, M. Shatalov, M. Asif Khan, Joseph E. Van Nostrand, R. Gaska Jan 2000

Selective Area Deposited Blue Gan-Ingan Multiple-Quantum Well Light Emitting Diodes Over Silicon Substrates, J. W. Yang, A. Lunev, Grigory Simin, A. Chitnis, M. Shatalov, M. Asif Khan, Joseph E. Van Nostrand, R. Gaska

Faculty Publications

We report on fabrication and characterization of blue GaN–InGaN multi-quantum well (MQW)light-emitting diodes(LEDs) over (111) silicon substrates. Device epilayers were fabricated using unique combination of molecular beam epitaxy and low-pressure metalorganic chemical vapor depositiongrowth procedure in selective areas defined by openings in a SiO2mask over the substrates. This selective area deposition procedure in principle can produce multicolor devices using a very simple fabrication procedure. The LEDs had a peak emission wavelength of 465 nm with a full width at half maximum of 40 nm. We also present the spectral emission data with the diodes operating up to 250 …

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On The Error Performance Of 8-Vsb Tcm Decoder For Atsc Terrestrial Broadcasting Of Digital Television, Dojun Rhee, Robert H. Morelos-Zaragoza Jan 2000

On The Error Performance Of 8-Vsb Tcm Decoder For Atsc Terrestrial Broadcasting Of Digital Television, Dojun Rhee, Robert H. Morelos-Zaragoza

Faculty Publications

The error performance of various 8-VSB TCM decoders for reception of terrestrial digital television is analyzed. In previous work, 8-state TCM decoders were proposed and implemented for terrestrial broadcasting of digital television. In this paper, the performance of a 16-state TCM decoder is analyzed and simulated. It is shown that not only a 16-state TCM decoder outperforms one with 8-states, but it also has much smaller error coefficients.

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Modeling The Effect Of Plasticizer On The Viscoelastic Response Of Crosslinked Polymers Using The Tube-Junction Model, P. P. Simon, Harry J. Ploehn Jan 2000

Modeling The Effect Of Plasticizer On The Viscoelastic Response Of Crosslinked Polymers Using The Tube-Junction Model, P. P. Simon, Harry J. Ploehn

Faculty Publications

Plasticizers modify the mechanical properties of polymericmaterials. The effects of plasticizers on glass transition temperatures can be most clearly observed in isochronal temperature sweep profiles of viscoelastic dynamic moduli. However, no simple mathematical models of plasticization are available to those who wish to design and employ plasticized materials in specific applications. We extend a phenomenological, molecular-level model (known as the tube–junction model) for crosslinked polymers to describe the effect of plasticizers on dynamic moduli. We show that the increase in free volume fraction due to the presence of the plasticizer can account for the shift in the glass transition in …

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Diffusion Of Water In Nafion 115 Membranes, Sathya Motupally, Aaron J. Becker, John W. Weidner Jan 2000

Diffusion Of Water In Nafion 115 Membranes, Sathya Motupally, Aaron J. Becker, John W. Weidner

Faculty Publications

In this paper, experimental and simulated data for the diffusion of water across Nafion membranes as a function of the water activity gradient are presented. The gradient in the activity of water across the membrane was varied by changing the flow rate and pressure of nitrogen gas on one side of the membrane. The other side of the membrane was equilibrated with liquid water. It was found that the model predictions are very sensitive to the value of the diffusion coefficient of water in Nafion. Using the Fickian diffusion coefficient extracted from self-diffusion measurements reported in the literature, the model …

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Modeling The Effects Of Ion Association On Direct-Current Polarization Of Solid Polymer Electrolytes, Changqing Lin, Ralph E. White, Harry J. Ploehn Jan 2000

Modeling The Effects Of Ion Association On Direct-Current Polarization Of Solid Polymer Electrolytes, Changqing Lin, Ralph E. White, Harry J. Ploehn

Faculty Publications

Considerable experimental evidence indicates that ion association occurs in solid polymer electrolytes. This work provides a thorough theoretical analysis of the effect of ion association on the conductivity, general current-potential behavior, and limiting current density in a solid polymer electrolyte. The model employs dilute solution theory to describe the fluxes of cations, anions, and ion pairs in a motionless continuum but neglects higher order association. The predictions of the model highlight the effects of the relative diffusion coefficients and dimensionless association constant on concentration distributions of simple ions and ion pairs, the limiting current density, and the potential drop required …

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Oxygen Diffusion Coefficient And Solubility In A New Proton Exchange Membrane, Andrew T. Haug, Ralph E. White Jan 2000

Oxygen Diffusion Coefficient And Solubility In A New Proton Exchange Membrane, Andrew T. Haug, Ralph E. White

Faculty Publications

No abstract provided.

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Self‐Discharge Model Of A Nickel‐Hydrogen Cell, B. Wu, Ralph E. White Jan 2000

Self‐Discharge Model Of A Nickel‐Hydrogen Cell, B. Wu, Ralph E. White

Faculty Publications

No abstract provided.

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An Agent-Based Global Economy, Michael N. Huhns Jan 2000

An Agent-Based Global Economy, Michael N. Huhns

Faculty Publications

Many people are buying music CDs over the Web, but with multiple retail sites offering the same CDs, how do you decide which retailer to buy from? Typically, you visit a few sites and choose the one with the lowest price. Shopbotsshopping agents that automatically search the Internet to obtain information about prices and other attributes of goods and servicesare ideal helpers for such a task.1 The better ones can visit hundreds of sites, giving price-conscious consumers a powerful tool that could work to the detriment of some retailers.

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The Emergence Of Language Among Autonomous Agents, Piotr Gmytrasiewicz, Michael N. Huhns Jan 2000

The Emergence Of Language Among Autonomous Agents, Piotr Gmytrasiewicz, Michael N. Huhns

Faculty Publications

Suppose some autonomous shopbot agents had been representing us by dealing with a vendor's pricebot, and suppose they didn't share an agent communication language (ACL). What should they know at a fundamental level, what could each point to, and how could they establish a common language? Recent research at the University of Texas at Arlington has shown that agents first establish a common vocabulary, progress to a primitive language similar to human pidgin, then enrich the language's grammar to develop a creole, and eventually arrive at a full-blown ACL. During this process, the vocabulary and grammatical structures most important to …

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Sensors + Agents + Networks = Aware Agents, Michael N. Huhns, Sreenath Seshadri Jan 2000

Sensors + Agents + Networks = Aware Agents, Michael N. Huhns, Sreenath Seshadri

Faculty Publications

Software agents are being deployed in increasing numbers to help users find and manage information, particularly in open environments such as the Internet. For the most part, they operate independently and are typically designed to be aware only of their users and the environment in which they perform their tasks. Thus, they fail to take advantage of each other's abilities or results. For example, a shopping agent might periodically access several online databases to find the best price for a music CD and then purchase it if the price falls below its user's threshold. Other agents might be tracking prices …

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Agent Teams: Building And Implementing Software, Michael N. Huhns Jan 2000

Agent Teams: Building And Implementing Software, Michael N. Huhns

Faculty Publications

Agents will become fundamental building blocks for general-purpose Internet-based software. The software may not display any explicitly agent-like characteristics, but it will exhibit the benefits of tolerance to errors, ease of maintenance, adaptability to change, and speed of construction that agents provide. Moreover, an agent-based approach to software development can lead to new types of software solutions that might not otherwise be obvious. The author considers how an approach based on teams of active, cooperative, and persistent software components, that is agents, shows special promise in enabling the rapid construction of robust and reusable software.

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Studies On The Capacitance Of Nickel Oxide Films: Effect Of Heating Temperature And Electrolyte Concentration, Venkat Srinivasan, John W. Weidner Jan 2000

Studies On The Capacitance Of Nickel Oxide Films: Effect Of Heating Temperature And Electrolyte Concentration, Venkat Srinivasan, John W. Weidner

Faculty Publications

Nickel oxide films were prepared by electrochemically precipitating the hydroxide and heating it in air to form the oxide. The resulting oxide films behave as a capacitor. The capacitance of the oxide depends on the heating temperature, showing a maximum at 300°C. The mechanism of charge storage was studied by measuring the capacitance and surface area as a function of heating temperature, and the capacitance in different electrolytes and potential windows. The charge-storage mechanism is believed to be a surface redox reaction involving adsorbed hydroxyl ions.

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Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov Jan 2000

Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov

Faculty Publications

A new Zn-Ni-Cd plating process was developed which offers a unique way of controlling and optimizing the Ni and Cd contents in the final deposit. Zinc-nickel-cadmium alloy was deposited from a 0.5 M NiSO4 + 0.2 M ZnSO4 bath in the presence of 0.015 M CdSO4 and 1 g/L nonyl phenyl polyethylene oxide. Using this process a Zn-Ni-Cd ternary alloy, with a higher nickel content as compared to that obtained from conventional Zn-Ni baths, was synthesized. The Zn-Ni-Cd alloy coatings deposited from an electrolyte containing 0.015 M (0.3%) CdSO4 has a Zn to Ni ratio of …

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Ni-Composite Microencapsulated Graphite As The Negative Electrode In Lithium-Ion Batteries Ii: Electrochemical Impedance And Self-Discharge Studies, P. Yu, James A. Ritter, Ralph E. White, Branko N. Popov Jan 2000

Ni-Composite Microencapsulated Graphite As The Negative Electrode In Lithium-Ion Batteries Ii: Electrochemical Impedance And Self-Discharge Studies, P. Yu, James A. Ritter, Ralph E. White, Branko N. Popov

Faculty Publications

Electrochemical impedance and self-discharge studies were carried out to investigate lithium intercalation into bare and Ni-coated KS10 graphite. Values of the charge-transfer resistances, exchange current densities, surface film resistances, and lithium-ion diffusion coefficients as functions of the state of charge (SOC) all favored the 10 wt % Ni composite KS10 graphite over bare KS10 graphite when these materials were used as the negative electrode in a Li-ion cell with mixed organic electrolyte. The charge-transfer resistances were always lower and gave rise to between 26 and 27% larger exchange current densities, which increased from 137 to 614 mA/g as the SOC …

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Structural And Electrical Characterization Of A Novel Mixed Conductor: Ceo2 - Sm2O3 - Zro2 Solid Solution, W. Huang, P. Shuk, M. Greenblatt, M. Croft, Fanglin Chen, M. Liu Jan 2000

Structural And Electrical Characterization Of A Novel Mixed Conductor: Ceo2 - Sm2O3 - Zro2 Solid Solution, W. Huang, P. Shuk, M. Greenblatt, M. Croft, Fanglin Chen, M. Liu

Faculty Publications

solid solutions were synthesized for the first time by the hydrothermal method. The electrical properties of the solid solutions have been studied in air and under reducing conditions. Solid solutions with the fluorite structure were formed in all of the studied range of substitution after calcination at 1500°C. With increasing substitution up to 30 mol %, the electronic conductivity increases under a reducing atmosphere. The solid solution has good mixed electronic and ionic conductivity; the total conductivity is 0.42 S/cm at and 700°C with an estimated ionic conductivity of ca. .

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A Semianalytical Method For Predicting Primary And Secondary Current Density Distributions: Linear And Nonlinear Boundary Conditions, Dhanwa Thirumalai, Ralph E. White Jan 2000

A Semianalytical Method For Predicting Primary And Secondary Current Density Distributions: Linear And Nonlinear Boundary Conditions, Dhanwa Thirumalai, Ralph E. White

Faculty Publications

No abstract provided.

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Development Of A New Electrodeposition Process For Plating Of Zn‐Ni‐X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn‐Ni‐Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko Popov Jan 2000

Development Of A New Electrodeposition Process For Plating Of Zn‐Ni‐X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn‐Ni‐Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko Popov

Faculty Publications

No abstract provided.

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Computational Fluid Dynamics Modeling Of A Lithium/Thionyl Chloride Battery With Electrolyte Flow, W. B. Gu, C. Y. Wang, John W. Weidner, Rudolph G. Jungst, Ganesan Nagasubramanian Jan 2000

Computational Fluid Dynamics Modeling Of A Lithium/Thionyl Chloride Battery With Electrolyte Flow, W. B. Gu, C. Y. Wang, John W. Weidner, Rudolph G. Jungst, Ganesan Nagasubramanian

Faculty Publications

A two-dimensional model is developed to simulate discharge of a lithium/thionyl chloride primary battery. As in earlier one-dimensional models, the model accounts for transport of species and charge, and electrode porosity variations and electrolyte flow induced by the volume reduction caused by electrochemical reactions. Numerical simulations are performed using a finite volume method of computational fluid dynamics. The predicted discharge curves for various temperatures show good agreement with published experimental data, and are essentially identical to results published for one-dimensional models. The detailed two-dimensional flow simulations show that the electrolyte is replenished from the cell head space predominantly through the …

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Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: Permeation Characteristics Of Zn-Ni-Cd Ternary Alloys, A. Durairajan, B. S. Haran, Ralph E. White, Branko N. Popov Jan 2000

Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: Permeation Characteristics Of Zn-Ni-Cd Ternary Alloys, A. Durairajan, B. S. Haran, Ralph E. White, Branko N. Popov

Faculty Publications

It is shown that an electrodeposited Zn-Ni-Cd alloy coating produced from sulfate electrolyte inhibits the discharge of hydrogen on carbon steel. The newly developed ternary alloys have approximately ten times higher corrosion resistance when compared to a Zn-Ni alloy. Hydrogen permeation characteristics of Zn-Ni-Cd alloy coatings were studied and compared with those of a bare and a Zn-Ni alloy coated steel. The transfer coefficient, a, exchange current density, io, thickness dependent adsorption-absorption rate constant, k0, recombination rate constant, k3, surface hydrogen coverage, θH, were obtained by applying a mathematical model to experimental results. Alloys obtained from baths containing higher concentration …

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Modeling Lithium Intercalation Of A Single Spinel Particle Under Potentiodynamic Control, Dong Zhang, Branko N. Popov, Ralph E. White Jan 2000

Modeling Lithium Intercalation Of A Single Spinel Particle Under Potentiodynamic Control, Dong Zhang, Branko N. Popov, Ralph E. White

Faculty Publications

A mathematical model is presented for the lithium intercalation of a single spinel particle as a microelectrode under the stimulus of a cyclic linear potential sweep. The model includes both lithium diffusion within the particle and kinetics at the particle/electrolyte interface. The model is used to predict that peak current densities depend linearly on the scan rate to a certain power with a constant term, which is different from the predicted peak current density for a conventional redox system.

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Shrinking Core Model For The Discharge Of A Metal Hydride Electrode, Venkat R. Subramanian, Harry J. Ploehn, Ralph E. White Jan 2000

Shrinking Core Model For The Discharge Of A Metal Hydride Electrode, Venkat R. Subramanian, Harry J. Ploehn, Ralph E. White

Faculty Publications

A shrinking core model is presented for the galvanostatic discharge of a metal hydride particle. A quantitative criterion for when the shrinking core can be completely neglected or approximated by a pseudosteady-state solution is presented. The effect of shrinking of the core on the discharge behavior of a metal hydride particle is also studied.

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Improved Resolution Backscatter Measurements With The Seawinds Pencil-Beam Scatterometer, David G. Long, Michael W. Spencer, Chialin T. Wu Jan 2000

Improved Resolution Backscatter Measurements With The Seawinds Pencil-Beam Scatterometer, David G. Long, Michael W. Spencer, Chialin T. Wu

Faculty Publications

The SeaWinds scatterometer was launched on the NASA QuikSCAT spacecraft in June 1999 and is planned for the Japanese ADEOS-II mission in 2000. In addition to generating a global Ku-band backscatter data set useful for a variety of climate studies, these flights will provide ocean-surface wind estimates for use in operational weather forecasting. SeaWinds employs a compact "pencil-beam" design rather than the "fan-beam" approach previously used with SASS on Seasat, NSCAT on ADEOS-I, and the AMI scatterometer on ERS-1, 2. As originally envisioned and reported, the resolution of the SeaWinds backscatter measurements were to be antenna-beamwidth limited. In order to …

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Solid-State 13c Nmr Characterization Of Matched Tars And Chars From Rapid Coal Devolatilization, Steven T. Perry, Eric M. Hambly, Thomas H. Fletcher, Mark S. Solum, Ronald J. Pugmire Jan 2000

Solid-State 13c Nmr Characterization Of Matched Tars And Chars From Rapid Coal Devolatilization, Steven T. Perry, Eric M. Hambly, Thomas H. Fletcher, Mark S. Solum, Ronald J. Pugmire

Faculty Publications

Matched tar/char sets were prepared by pyrolysis of a lignite and a bituminous coal in two entrained flow reactors at temperatures between 900 K and 1650 K and heating rates of 104–105 K/s. Detailed chemical structural characterization of these tars and chars was performed using elemental analysis and solid-state 13C NMR. This is the first set of detailed solid-state 13C nuclear magnetic resonance (NMR) data on coal tar samples. The average aromatic cluster sizes of the primary tars from these experiments are quite similar to those of their parent coals, confirming an assumption often made …

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Modeling High Pressure Char Oxidation Using Langmuir Kinetics With An Effectiveness Factor, Jianhui Hong, William C. Hecker, Thomas H. Fletcher Jan 2000

Modeling High Pressure Char Oxidation Using Langmuir Kinetics With An Effectiveness Factor, Jianhui Hong, William C. Hecker, Thomas H. Fletcher

Faculty Publications

The global nth order rate equation has been criticized for lack of theoretical basis and has been shown to be inadequate for modeling char oxidation rates as a function of total gas pressure. The simple Langmuir rate equation is believed to have more potential for modeling high pressure char oxidation. The intrinsic Langmuir rate equation is applied to graphite flake oxidation data and agrees well with reaction rates at three temperatures over the entire range of oxygen pressure (1–64 atm). It also explains the change of reaction order with temperature. In this work, the intrinsic Langmuir rate equation is combined …

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Modeling Nitrogen Evolution During Coal Pyrolysis Based On A Global Free-Radical Mechanism, Steven T. Perry, Thomas H. Fletcher Jan 2000

Modeling Nitrogen Evolution During Coal Pyrolysis Based On A Global Free-Radical Mechanism, Steven T. Perry, Thomas H. Fletcher

Faculty Publications

A global free-radical mechanism and an associated rate equation for the evolution of light gas nitrogen during coal devolatilization are presented. The light gas nitrogen rate equation was used to modify an existing nitrogen model so that only a network devolatilization model and coal-specific chemical structural input data are required to adequately predict light gas nitrogen release at a variety of pyrolysis conditions. Model predictions show good agreement with nitrogen release data from pyrolysis of coals of rank from lignite to low volatile bituminous at heating rates from 0.5 to 105 K/s, temperatures as high as 2300 K, and …

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Improving The Accuracy Of Predicting Effectiveness Factors For Mth Order And Langmuir Rate Equations In Spherical Coordinates, Jianhui Hong, William C. Hecker, Thomas H. Fletcher Jan 2000

Improving The Accuracy Of Predicting Effectiveness Factors For Mth Order And Langmuir Rate Equations In Spherical Coordinates, Jianhui Hong, William C. Hecker, Thomas H. Fletcher

Faculty Publications

Char oxidation is often modeled using an mth order intrinsic reaction rate in conjunction with an effectiveness factor to account for intraparticle diffusion of gas species. This approach involves the use of a general modulus (MT) and using the first-order curve of effectiveness factor vs MT. This method was originally referred to as the general asymptotic solution. It has been suggested that a simple Langmuir rate equation is more suitable for modeling the effects of pressure on char reactivity. Therefore, several methods of developing general moduli for the Langmuir rate expression are shown. The general asymptotic …

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Measurement Of Soot And Char In Pulverized Coal Fly Ash, John M. Veranth, Thomas H. Fletcher, David W. Pershing, Adel F. Sarofim Jan 2000

Measurement Of Soot And Char In Pulverized Coal Fly Ash, John M. Veranth, Thomas H. Fletcher, David W. Pershing, Adel F. Sarofim

Faculty Publications

The unburned carbon in the fly ash produced by low-NOx pulverized coal combustion has been shown by electron microscopy to be a mixture of porous coal char particles and aggregates of submicron particles, which are thought to be soot. The carbon is bimodally distributed with large soot aggregates mixed with the char in the particles larger than 10 microns and dispersed soot found with the submicron particles. A method for determining the mass of soot and char by liquid-suspension gravity separation was used with both laboratory-scale and power plant fly ash samples. For low-NOx, staged, pilot-scale combustion of bituminous coal …

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The Use Of Two Mixture Fractions To Treat Coal Combustion Products In Turbulent Pulverized-Coal Flames, Daniel V. Flores, Thomas H. Fletcher Jan 2000

The Use Of Two Mixture Fractions To Treat Coal Combustion Products In Turbulent Pulverized-Coal Flames, Daniel V. Flores, Thomas H. Fletcher

Faculty Publications

Previous coal combustion models using assumed-shape PDF's to treat turbulence-chemistry interactions have used only one progress variable to treat products from coal reactions. This assumes that the products of all coal reactions have the same composition. However. the composition of the combustion products of coal particles is known to vary with burnout, especially between devclatilization and char oxidation. In this work, two progress variables were implemented which distinguish between the products of devolatilization and those of char oxidation. This new approach requires as input the specified volatile content and elemental release during devolatilization. The values for these parameters were estimated …

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Simulation And Density Functional Study Of A Simple Membrane Separating Two Restricted Primitive Model Electrolytes, Richard L. Rowley, Dezso Boda, Douglas Henderson, Stefan Sokolowski Nov 1999

Simulation And Density Functional Study Of A Simple Membrane Separating Two Restricted Primitive Model Electrolytes, Richard L. Rowley, Dezso Boda, Douglas Henderson, Stefan Sokolowski

Faculty Publications

A simple membrane, supporting charge densities on its inner and outer surfaces, is considered. In addition to the electrostatic potential, the membrane interacts with the surrounding fluid by a short range van der Waals-like potential. The fluid beyond the outer surface is a three-component restricted primitive electrolyte consisting of two cations and one anion. The membrane is impermeable to one of the cations so that the fluid in the membrane and beyond the inner surface is a two-component restricted primitive electrolyte. We use Monte Carlo simulations and density functional theory to study the density profiles of the electrolyte and the …

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