Engineering Commons^™

High Temperature Proton Exchange Membranes With Enhanced Proton Conductivities At Low Humidity And High Temperature Based On Polymer Blends And Block Copolymers Of Poly(1,3-Cyclohexadiene) And Poly(Ethylene Glycol), Shawn Deng, Mohammad K. Hassan, Amol Nalawade, Kelly A. Perry, Karren L. More, Kenneth A. Mauritz, Marshall T. Mcdonnell, David J. Keffer, Jimmy W. Mays

Faculty Publications

Hot (at 120 °C) and dry (20% relative humidity) operating conditions benefit fuel cell designs based on proton exchange membranes (PEMs) and hydrogen due to simplified system design and increasing tolerance to fuel impurities. Presented are preparation, partial characterization, and multi-scale modeling of such PEMs based on cross-linked, sulfonated poly(1,3-cyclohexadiene) (xsPCHD) blends and block copolymers with poly(ethylene glycol) (PEG). These low cost materials have proton conductivities 18 times that of current industry standard Nafion at hot, dry operating conditions. Among the membranes studied, the blend xsPCHD-PEG PEM displayed the highest proton conductivity, which exhibits a morphology with higher connectivity of …

Application Of A Coated Film Catalyst Layer Model To A High Temperature Polymer Electrolyte Membrane Fuel Cell With Low Catalyst Loading Produced By Reactive Spray Deposition Technology, Timothy D. Myles, Siwon Kim, Radenka Maric, William E. Mustain

Faculty Publications

In this study, a semi-empirical model is presented that correlates to previously obtained experimental overpotential data for a high temperature polymer electrolyte membrane fuel cell (HT-PEMFC). The goal is to reinforce the understanding of the performance of the cell from a modeling perspective. The HT-PEMFC membrane electrode assemblies (MEAs) were constructed utilizing an 85 wt. % phosphoric acid doped Advent TPS® membranes for the electrolyte and gas diffusion electrodes (GDEs) manufactured by Reactive Spray Deposition Technology (RSDT). MEAs with varying ratios of PTFE binder to carbon support material (I/C ratio) were manufactured and their performance at various operating temperatures was …

Ash Formation And Deposition During Oxy-Coal Combustion In A 100 Kw Laboratory Combustor With Various Flue Gas Recycle Options, Zhonghua Zhan, Andrew R. Fry, Danxi Yu, Minghou Xu, Jost O.L. Wendt

Faculty Publications

Fouling and slagging processes are important in oxy-coal combustion processes because they greatly influence heat transfer and boiler performance. Ash partitioning processes are precursors to deposition processes and so in order to predict the latter one must have a good understanding of the former. This work involves a 100 kW rated down-fired oxy-fuel combustor outfitted with sophisticated ash aerosol and ash deposit sampling equipment. The work differs from that previously published, in that here we focus on the effects of changes in the composition and amounts of actual recycled flue gas (RFG) streams used in oxy-coal combustion, not using once …

Modeling Napl Dissolution From Pendular Rings In Idealized Porous Media, Junqi Huang, John A. Christ, Mark N. Goltz, Avery H. Demond

Faculty Publications

The dissolution rate of nonaqueous phase liquid (NAPL) often governs the remediation time frame at subsurface hazardous waste sites. Most formulations for estimating this rate are empirical and assume that the NAPL is the nonwetting fluid. However, field evidence suggests that some waste sites might be organic wet. Thus, formulations that assume the NAPL is nonwetting may be inappropriate for estimating the rates of NAPL dissolution. An exact solution to the Young‐Laplace equation, assuming NAPL resides as pendular rings around the contact points of porous media idealized as spherical particles in a hexagonal close packing arrangement, is presented in this …

Hybrid Dynamic Optimization Methods For Systems Biology With Efficient Sensitivities, Nicholas Lewis, John Hedengren, Eric Haseltine

Faculty Publications

In recent years, model optimization in the field of computational biology has become a prominent area for development of pharmaceutical drugs. The increased amount of experimental data leads to the increase in complexity of proposed models. With increased complexity comes a necessity for computational algorithms that are able to handle the large datasets that are used to fit model parameters. In this study the ability of simultaneous, hybrid simultaneous, and sequential algorithms are tested on two models representative of computational systems biology. The first case models the cells affected by a virus in a population and serves as a benchmark …

Rigidly Foldable Origami Gadgets And Tessellations, Thomas A. Evans, Robert J. Lang, Spencer P. Magleby, Larry L. Howell

Faculty Publications

Rigidly foldable origami allows for motion where all deflection occurs at the crease lines and facilitates the application of origami in materials other than paper. In this paper, we use a recently discovered method for determining rigid foldability to identify existing flat-foldable rigidly foldable tessellations, which are also categorized. We introduce rigidly foldable origami gadgets which may be used to modify existing tessellations or to create new tessellations. Several modified and new rigidly foldable tessellations are presented.

Morphology Of Nanoporous Carbon-Binder Domains In Li-Ion Batteries—A Fib-Sem Study, Severin Vierrath, Lukas Zielke, Riko Moroni, Andrew Mordon, Dean R. Wheeler, Roland Zengerle, Simon Thiele

Faculty Publications

FIB-SEM tomography is used to reconstruct the carbon-binder domain (CBD) of a LiCoO2 battery cathode (3.9 × 5 × 2.3 μm3) with contrast enhancement by ZnO infiltration via atomic layer deposition. We calculate the porosity inside the CBD (57.6%), the cluster-size distribution with a peak at 54 nm, and the pore-size distribution with a peak at 64 nm. The tortuosities of the pore space (1.6–2.0) and the CBD (2.3–3.5) show a mild anisotropy, which is attributed to the fabrication process. A comparison to a modeled homogenous CBD reveals that clustering in the CBD decreases its electronic conductivity while increasing …

An Improved Statistical Analysis For Predicting The Critical Temperature And Critical Density With Gibbs Ensemble Monte Carlo Simulation, Richard A. Messerly, Richard L. Rowley, Thomas A. Knotts Iv, W Vincent Wilding

Faculty Publications

A rigorous statistical analysis is presented for Gibbs ensemble Monte Carlo simulations. This analysis reduces the uncertainty in the critical point estimate when compared with traditional methods found in the literature. Two different improvements are recommended due to the following results. First, the traditional propagation of error approach for estimating the standard deviations used in regression improperly weighs the terms in the objective function due to the inherent interdependence of the vapor and liquid densities. For this reason, an error model is developed to predict the standard deviations. Second, and most importantly, a rigorous algorithm for nonlinear regression is compared …

Sediment Loss And Its Cause In Puerto Rico Watersheds, Y. Yuan, Y. Jiang, E. V. Taugas, Eric G. Mbonimpa

Faculty Publications

A major environmental concern in the Commonwealth of Puerto Rico is increased sediment load to water reservoirs, to estuaries, and finally to coral reef areas outside the estuaries. Sediment deposition has significantly reduced the storage capacity of reservoirs, and sediments, with their associated contaminants and nutrients that are adsorbed, can stress corals and negatively impact reef health. To prevent and manage sediment loss it is therefore important to understand local soil erosion and sediment transport processes. The main objective of this study was to determine the influence of landscape characteristics on sediment loss. We analyzed available precipitation and sediment data …

A Numerical Comparison Of Precipitating Turbulent Flows Between Large-Eddy Simulation And One-Dimensional Turbulence, Alex W. Abboud, Ben B. Schroeder, Tony Saad, Sean T. Smith, Derek D. Harris, David O. Lignell

Faculty Publications

This study presents the results of computational fluid dynamics simulations of a multiphase, reacting, turbulent mixing layer in an idealized geometry. The purpose is to compare large-eddy simulation (LES) to one-dimensional turbulence (ODT) and examine the trends of the flow under differing mixing conditions. Aqueous streams are mixed together to precipitate polymorphs of calcium carbonate. The polymorphs of calcium carbonate are tracked numerically using population balance equations (PBE). Each PBE contains all of the relevant physical models to track the particle evolution including nucleation, growth, and aggregation. A simple subgrid mixing model that is convenient for use with PBEs was …

Communication: Antibody Stability And Behavior On Surfaces, Derek B. Bush, Thomas A. Knotts Iv

Faculty Publications

Antibody microarrays have the potential to revolutionize molecular detection in scientific, medical, and other biosensor applications, but their current use is limited because of poor reliability. It is hypothesized that one reason for their poor performance results from strong antibody-surface interactions that destabilize the antibody structure and create steric interference for antigen recognition. Using a recently developed coarse-grain protein-surface model that has been parameterized against experimental data, antibody-surface interactions for two antibody orientations on two types of surfaces have been investigated. The results show that regardless of attachment geometry, antibodies tend to collapse onto hydrophobic surfaces and exhibit lower overall …

Hydrocarbon-Based Fuel Cell Membranes: Sulfonated Crosslinked Poly(1,3-Cyclohexadiene) Membranes For High Temperature Polymer Electrolyte Fuel Cells, Suxiang Deng, Mohammad K. Hassan, Kenneth A. Mauritz, Jimmy W. Mays

Faculty Publications

High temperature fuel cell membranes based on poly(1,3-cyclohexadiene) were prepared by a Polymerization-Crosslinking-Sulfonation (PCS) approach, and a broad range of membrane compositions were achieved using various sulfonating reagents and reaction conditions. Membranes were characterized for their proton conductivity and thermal degradation behavior. Some of the membranes showed up to a 68% increase in proton conductivity as compared to Nafion under the same conditions (100% relative humidity and 120 °C). Thermogravimetric analysis revealed that these membranes are thermally stable up to 200 °C. High proton conductivity and thermal stability, combined with much lower cost as compared to Nafion®, make these materials …

Improved Terahertz Modulation Using Germanium Telluride (Gete) Chalcogenide Thin Films, Alexander H. Gwin, Christopher H. Kodama, Tod V. Laurvick, Ronald Coutu Jr., Philip F. Taday

Faculty Publications

We demonstrate improved terahertz (THz) modulation using thermally crystallized germanium telluride (GeTe) thin films. GeTe is a chalcogenide material that exhibits a nonvolatile, amorphous to crystalline phase change at approximately 200 °C, as well as six orders of magnitude decreased electrical resistivity. In this study, amorphous GeTe thin films were sputtered on sapphire substrates and then tested using THz time-domain spectroscopy (THz-TDS). The test samples, heated in-situ while collecting THz-TDS measurements, exhibited a gradual absorbance increase, an abrupt nonvolatile reduction at the transition temperature, followed by another gradual increase in absorbance. The transition temperature was verified by conducting similar thermal …

Optimum 3d Matrix Stiffness For Maintenance Of Cancer Stem Cells Is Dependent On Tissue Origin Of Cancer Cells, Esmaiel Jabbari, Samaneh K. Sarvestani, Leily Daneshian, Seyedsina Moeinzadeh

Faculty Publications

Introduction

The growth and expression of cancer stem cells (CSCs) depend on many factors in the tumor microenvironment. The objective of this work was to investigate the effect of cancer cells’ tissue origin on the optimum matrix stiffness for CSC growth and marker expression in a model polyethylene glycol diacrylate (PEGDA) hydrogel without the interference of other factors in the microenvironment.

Methods

Human MCF7 and MDA-MB-231 breast carcinoma, HCT116 colorectal and AGS gastric carcinoma, and U2OS osteosarcoma cells were used. The cells were encapsulated in PEGDA gels with compressive moduli in the 2-70 kPa range and optimized cell seeding density …

Connecting Self-Efficacy And Nature Of Science Shifts In Undergraduate Research Experiences, Gina Quan

Faculty Publications

Undergraduate research can support students’ more central participation in physics. We present analysis of one way this participation may shift: changes in their beliefs about the Nature of Science coupled to changes in a sense of ability to contribute to authentic research. Students in the study worked with faculty and graduate student research mentors on research projects and also participated in a seminar where they learned about research and reflected on their experiences. In videotaped interviews, we asked students to describe their experiences in research. Students developed nuanced views about how the research process works coupled to shifts in their …

Reliability-Based Selection Of Standard Steel Beams, Edward Osakue

Faculty Publications

A reliability-based design approach using sensitivity analysis is presented for the selection of standard steel beams subjected to concentrated and or distributed loads, assuming lognormal probability density function. Serviceability criteria of bending stress, transverse deflection, and web maximum shear stress are considered. The load, strength, and geometric parameters are considered to be log normal in distribution. Equations are developed for the coefficients of variation for the mentioned serviceability criteria so as to determine design reliability. Deterministic design equations are transformed into probabilistic ones by replacing the traditional “safety factor” with a “reliability factor”. The reliability factor is determined from a …

Impacts Of Large-Scale Stormwater Green Infrastructure Implementation And Climate Variability On Receiving Water Response In The Salt Lake City Area, Chris York, Erfan Goharian, Steven J. Burian

Faculty Publications

This study evaluated impacts of Green Infrastructure (GI) as a stormwater management practice on return flows and the further Implications of climate variability. The goal was to create a model to explore the impacts that bioretention and Rainwater Harvesting (RWH) representing GI had using goldsim and Stormwater Management Modeling (SWMM) software. The software was used to represent impacts that climate variability individually and combined, may have on downstream stakeholders and receiving water systems in Salt Lake city, Utah, USA. Primary stakeholders included downstream water rights users, Farmington Bay waterfowl management area and the migratory birds that rely on Farmington Bay …

Solving Nonlinear Heat Transfer Problems Using Variation Of Parameters, Travis J. Moore, Matthew R. Jones

Faculty Publications

Nonlinear problems arise in many heat transfer applications, and several analytical and numerical methods for solving these problems are described in the literature. Here, the method of variation of parameters is shown to be a relatively simple method for obtaining solutions to four specific heat transfer problems: 1. a radiating annular fin, 2. conduction-radiation in a plane-parallel medium, 3. convective and radiative exchange between the surface of a continuously moving strip and its surroundings, and 4. convection from a fin with temperature-dependent thermal conductivity and variable cross-sectional area. The results for each of these examples are compared to those obtained …

Investigating The Impact Of Cryogenic Carbon Capture On Power Plant Performance, Seyed M. Safdarnejad, L. Kennington, Larry Lin Baxter, John Hedengren

Faculty Publications

Cryogenic Carbon Capture (CCC) is a CO2 mitigation process that can be integrated into existing baseline and load following fossil-fueled power plants. This process consumes less energy than conventional chemical absorption and includes energy storage capability. The CCC process has a fast response time to load changes to allow higher utilization of intermittent renewable power sources to be used at a grid-scale level in the power sector. The impact of the CCC process on the performance and operating profit of a single fossil-fueled power generation unit is studied in this paper. The proposed system (power production from wind, coal, and …

Comparison Of Two Wake Models For Use In Gradient-Based Wind Farm Layout Optimization, Jared Thomas, Eric Tingey, Andrew Ning

Faculty Publications

Wind farm layout has a significant impact on the productivity of a wind farm. To ensure that the turbines are placed in the most advantageous arrangement, optimization algorithms are often used during the layout design process. Depending on the wake model used for the optimization, optimizing the layout can be time intensive or potentially inaccurate. In this paper we present a comparison of optimization results using two simple wake models, the FLORIS model and the Jensen model. Results highlight some of the key similarities and differences of layout optimization results when different wake models are used.

Plant-Level Dynamic Optimization Of Cryogenic Carbon Capture With Conventional And Renewable Power Sources, Seyed M. Safdarnejad, John Hedengren, Larry Lin Baxter

Faculty Publications

Increasing competitiveness of renewable power sources due to tightening restrictions on CO₂ emission from fossil fuel combustion is expected to cause a shift in power generation systems of the future. This investigation considers the impact of the Cryogenic Carbon Capture™ (CCC) process on transitional power generation. The CCC process consumes less energy than chemical and physical absorption processes and has an energy storage capability that shifts the parasitic loss of the CCC process away from peak hours. The CCC process responds rapidly to the variation of electricity demand and has a time constant that is consistent with the intermittent …

Effect Of Airfoil And Composite Layer Thicknesses On An Aerostructural Blade Optimization For Wind Turbines, Ryan Barrett, Ian Freeman, Andrew Ning

Faculty Publications

The purpose of this research is to enhance the performance of wind turbine blades by exploring the effect of adding airfoil and material layer thicknesses to the optimization design process. This is accomplished by performing an aerostructural blade optimization to minimize mass over annual energy production and thereby reduce the cost of energy. Changing airfoil thickness allows the airfoil shape to evolve as part of the optimization. The airfoil thicknesses are allowed to vary within two airfoil families, the TU-Delft and NACA 64-series, that are used in the NREL 5-MW reference turbine. Both experimental wind tunnel and computational data are …

Wind Farm Layout Optimization Using Sound Pressure Level Constraints, Eric Tingey, Jared Thomas, Andrew Ning

Faculty Publications

This project explored wind farm layout optimization using turbine acoustic and wake models. For two existing wind farms, the position of each wind turbine was optimized to maximize power output while constraining noise. Semi-empirical calculations were used for both the acoustic and wake models to predict how the turbine noise and wake disturbances propagated downstream. Turbine layout was optimized using a sequential quadratic programming optimizer called SNOPT. The optimization was able to constrain the noise level of the wind farms with a small impact on power output.

Virtual Peer Teams: Connecting Students With The Online Work Environment, Thalia Anagnos, Alicia Lyman-Holt, Sean Brophy

Faculty Publications

This study examined the potential of online collaboration tools to develop team cohesiveness and research skills of undergraduates participating in Virtual Peer Teams (VPTs) in a geographically distributed research experience for undergraduates (REU). The VPTs mimic geographically dispersed virtual teams that are now common in industry. VPTs consisted of four to six students from multiple REU sites around the United States who were asked to experiment with various collaboration and social network technologies to complete specified research-based and social tasks. Surveys were used to collect formative and summative feedback. Students agreed their VPT experiences were significant in their professional development …

Tensions In The Productivity In Design Task Tinkering – Fundamental, Gina Quan, Ayush Gupta

Faculty Publications

Tensions in the Productivity in Design Task TinkeringTinkering is an ad-hoc approach to a problem and involves the practice of manipulating objectsto characterize and build knowledge about a particular system in an exploratory way, often withthe goal of getting some product/idea to produce desired behavior (e.g. Turkle & Papert, 1991;Berland, 2013; Roth, 1996). Tinkering thus contrasts with more deliberate activity towardsunderstanding how some phenomenon works or towards achieving conceptual understanding.Some researchers have argued that tinkering is an unproductive process because it does notalways lead to progress and/or conceptual learning (Law, 1998; Yeshno & Ben-Ari, 2001).Others view it as productive for …

Curved-Folding-Inspired Deployable Compliant Rolling-Contact Element (D-Core), Todd Nelson, Robert Lang, Spencer P. Magleby, Larry L. Howell

Faculty Publications

This work describes a deployable compliant rolling-contact element joint (DCORE joint) that employs curved-folding origami techniques to enable transition from a flat to deployed state. These deployable joints can be manufactured from a single sheet of material. Two fundamental configurations of the D-CORE are presented. The first configuration allows for motion similar to that of a Jacob’s ladder when the joint is in a planar state while achieving the motion of a CORE when in the deployed state. The second configuration constrains all degrees of freedom to create a static structure when the joint is in the planar state and …

Advances In Catalyst Deactivation And Regeneration, Calvin H. Bartholomew, Morris D. Argyle

Faculty Publications

Catalyst deactivation, the loss over time of catalytic activity and/or selectivity, is a problem of great and continuing concern in the practice of industrial catalytic processes. Costs to industry for catalyst replacement and process shutdown total tens of billions of dollars per year. While catalyst deactivation is inevitable for most processes, some of its immediate, drastic consequences may be avoided, postponed, or even reversed through regeneration.

Morphology And Magnetic Properties Of Sulfonated Poly[Styrene-(Ethylene/Butylene)-Styrene]/Iron Oxide Composites, Sateesh K. Peddini, Huy N. Pham, Leonard Spinu, James L. Weston, David E. Nikles, Kenneth A. Mauritz

Faculty Publications

α-Fe₂O₃ structures were initiated in the sulfonated polystyrene block domains of poly[styrene–(ethylene/butylene)–styrene] (SEBS) block copolymers via a domain-targeted in-situ chemical precipitation method. The crystal structure of these particles was determined using wide-angle X-ray diffraction and selected area electron diffraction using a transmission electron microscope (TEM). TEM revealed that for less sulfonated SEBS (10 mole%), nanoparticles were aggregated with aggregate size range of 100–150 nm whereas for high sulfonation (16 and 20 mole% sSEBS) there were needle-like structures with length and width of 200–250 nm and 50 nm, respectively. Dynamic mechanical analyses suggest that initial iron oxide nanoparticle …

What Does The Time Constant Of The Pulmonary Circulation Tell Us About The Progression Of Right Ventricular Dysfunction In Pulmonary Arterial Hypertension?, Alessandro Bellofiore, Z. Wang, Naomi Chesler

Faculty Publications

Compliance (C) and resistance (R) maintain a unique, inverse relationship in the pulmonary circulation, resulting in a constant characteristic time that has been observed in healthy subjects as well as patients with pulmonary arterial hypertension (PAH). However, little is known about the dependence of right ventricular (RV) function on the coupled changes in R and C in the context of this inverse relationship. We hypothesized three simple dependencies of RV ejection fraction (RVEF) on R and C. The first model (linear-R) assumes a linear RVEF-R relation; the second (linear-C) assumes a linear RVEF-C relation; and the third one combines the …

Unmanned Aircraft Systems: Air-Ground Channel Characterization For Future Applications, David W. Matolak, Ruoyu Sun

Faculty Publications

Unmanned aircraft systems (UASs) are being used increasingly worldwide. These systems will operate in conditions that differ from conventional piloted aircraft, and this implies that the airground (AG) channel for UASs can differ significantly from the traditional, simple, AG channel models. After providing some background and motivation, we describe the AG channel features and our efforts in measuring and modeling the AG channel. Some example measurement and model results-for the path loss and the Ricean K-factor-are provided to illustrate some of the interesting AG channel characteristics that are still being investigated.