Engineering Commons^™

Event Sampled Optimal Adaptive Regulation Of Linear And A Class Of Nonlinear Systems, Avimanyu Sahoo

Doctoral Dissertations

In networked control systems (NCS), wherein a communication network is used to close the feedback loop, the transmission of feedback signals and execution of the controller is currently carried out at periodic sampling instants. Thus, this scheme requires a significant computational power and network bandwidth. In contrast, the event-based aperiodic sampling and control, which is introduced recently, appears to relieve the computational burden and high network resource utilization. Therefore, in this dissertation, a suite of novel event sampled adaptive regulation schemes in both discrete and continuous time domain for uncertain linear and nonlinear systems are designed.

Event sampled Q-learning and …

Resistance Switching Of Electrodeposited Cuprous Oxide, Sanaz Yazdanparast

Doctoral Dissertations

In this work, the resistance switching behavior of electrodeposited cuprous oxide (Cu₂O) thin films in Au/Cu₂O/top electrode (Pt, Au-Pd, Al) cells was studied. After an initial FORMING process, the fabricated cells show reversible switching between a low resistance state (16.6 Ω) and a high resistance state (0.4 x 10⁶ Ω). Changing the resistance states in cuprous oxide films depends on the magnitude of the applied voltage which corresponds to unipolar resistance switching behavior of this material. The endurance and retention tests indicate a potential application of the fabricated cells for nonvolatile resistance switching random access …

Localization And Tracking Of Electronic Devices With Their Unintended Emissions, Nurbanu Guzey

Doctoral Dissertations

"The precise localization and tracking of electronic devices via their unintended emissions has a broad range of commercial and security applications. Active stimulation of the receivers of such devices with a known signal generates very low power unintended emissions. This dissertation presents localization and tracking of multiple devices using both simulation and experimental data in the form of five papers.

First the localization of multiple emitting devices through active stimulation under multipath fading with a Smooth MUSIC based scheme in the near field region is presented. Spatial smoothing helps to separate the correlated sources and the multipath fading and results …

Quartz-Mems: Wet Chemical Etching Assisted By Electromagnetic Energy Sources For The Development Of Quartz Crystal To Be Used For Microelectromechanical Systems, William J. Clower

Doctoral Dissertations

Quartz crystal resonators have been the most commonly used timing devices to date. Today's timing market requires devices to be as small as possible and consume smaller amounts of energy. Because of the market demand, many startup companies have formed to develop silicon resonators as timing devices. Silicon resonators have poor noise and temperature performance (due to its linear temperature versus frequency coefficient). At the moment the only advantage that silicon resonators have over quartz crystal resonators is a small form factor. The photolithography processing method currently being used in industry is a very tedious task, requiring multiple etching steps …

Computational Study Of Sodium Magnesium Hydride For Hydrogen Storage Applications, Fernando Antonio Soto Valle

Doctoral Dissertations

Hydrogen offers considerable potential benefits as an energy carrier. However, safe and convenient storage of hydrogen is one of the biggest challenges to be resolved in the near future. Sodium magnesium hydride (NaMgH 3) has attracted attention as a hydrogen storage material due to its light weight and high volumetric hydrogen density of 88 kg/m3. Despite the advantages, hydrogen release in this material occurs at approximately 670 K, which is well above the operable range for on-board hydrogen storage applications. In this regard, hydrogen release may be facilitated by substitution doping of transition-metals. This dissertation describes first-principles computational methods that …

Applications Of Halloysite Nanocontainers For Functional Protective Coating, Anupam Ramesh Joshi

Doctoral Dissertations

In this study we have explored the applications of halloysite clay nanotubes as a nanocontainer. Halloysite nanotubes are used as a storage unit for anticorrosion agents, flame retardants, and a dopant to extend the curing time for geopolymer composites. Halloysite is a naturally occurring clay mineral with a chemical formula of Al2Si2O 5(OH)4 · 2 H2O and is identical to kaolinite with the exception that it holds an additional water monolayer in its interlayered spaces. Upon heating at higher temperatures, halloysite loses the additional water monolayer, and this variant known colloquially as "meta-halloysite" has a chemical formula of Al2Si2O5(OH) 4 …

Nanotechnology And Additive Manufacturing Platforms For Clinical Medicine: An Investigation Of 3d Printing Bioactive Constructs And Halloysite Nanotubes For Drug Delivery And Biomaterials, Jeffery A. Weisman

Doctoral Dissertations

Personalized medicine requires the development of new technologies for controlled or targeted drug delivery. Three-dimensional (3D) printing and additive manufacturing techniques can be used to generate customized constructs for bioactive compound delivery. Nanotechnology in the form of nanoparticles, used as a stand-alone construct or for material enhancements, can significantly improve established biomaterials such as PMMA based bone cements or enable new technology to have enhanced capabilities. Combinations of the technologies can be used in such applications as infectious disease treatments, chemotherapeutic targeted drug delivery or targeted delivery of nearly any bioactive compound.

Chemotherapeutic or antibiotic enhanced 3D printing filaments were …

Quantum Levitation Using Metamaterials, Venkatesh K. Pappakrishnan

Doctoral Dissertations

The emergence of an attractive vacuum force (Casimir force) between two purely dielectric materials can lead to an increase in the friction and the stiction effects in nanoscale devices, resulting in degradation or decreased performance. Thus, it is of high practical importance that the conditions for the reversal of the Casimir force from attractive to repulsive are identified. Although the repulsive Casimir force has been considered for high dielectric materials as an intermediate (between the plates) medium, so far no realistic system has been proposed that can demonstrate quantum levitation with air/vacuum as a host medium. Since air is the …

On Electromagnetic And Quantum Invisibility, Pattabhiraju Chowdary Mundru

Doctoral Dissertations

The principle objective of this dissertation is to investigate the fundamental properties of electromagnetic wave interactions with artificially fabricated materials i.e., metamaterials for application in advanced stealth technology called electromagnetic cloaking. The main goal is to theoretically design a metamaterial shell around an object that completely eliminates the dipolar and higher order multipolar scattering, thus making the object invisible.

In this context, we developed a quasi-effective medium theory that determines the optical properties of multi-layered-composites beyond the quasi-static limit. The proposed theory exactly reproduces the far-field scattering/extinction cross sections through an iterative process in which mode-dependent quasi-effective impedances of the …

A Knowledge Discovery Approach For The Detection Of Power Grid State Variable Attacks, Nathan Wallace

Doctoral Dissertations

As the level of sophistication in power system technologies increases, the amount of system state parameters being recorded also increases. This data not only provides an opportunity for monitoring and diagnostics of a power system, but it also creates an environment wherein security can be maintained. Being able to extract relevant information from this pool of data is one of the key challenges still yet to be obtained in the smart grid. The potential exists for the creation of innovative power grid cybersecurity applications, which harness the information gained from advanced analytics. Such analytics can be based on the extraction …

Hybrid Nanomaterial And Its Applications: Ir Sensing And Energy Harvesting, Yi-Hsuan Tseng

Doctoral Dissertations

In this dissertation, a hybrid nanomaterial, single-wall carbon nanotubes-copper sulfide nanoparticles (SWNTs-CuS NPs), was synthesized and its properties were analyzed. Due to its unique optical and thermal properties, the hybrid nanomaterial exhibited great potential for infrared (IR) sensing and energy harvesting.

The hybrid nanomaterial was synthesized with the non-covalent bond technique to functionalize the surface of the SWNTs and bind the CuS nanoparticles on the surface of the SWNTs. For testing and analyzing the hybrid nanomaterial, SWNTs-CuS nanoparticles were formed as a thin film structure using the vacuum filtration method. Two conductive wires were bound on the ends of the …

Thermoelectric Elisa For Quantification Of 8ohdg In A Microfluidic Device, Gergana Nestorova

Doctoral Dissertations

This research demonstrates the feasibility of a novel method for performing thermoelectric enzyme-linked immunosorbent assay (ELISA) in a microfluidic device. The feasibility of the thermoelectric ELISA is demonstrated by measuring the concentration of 8-hydroxy 2-deoxyguanosine (8OHdG) in urine samples from amyloid precursor protein (APP) transgenic mice. The detection method is based on formation of a complex between 8OHdG and anti-8OHdG capture antibody conjugated to biotin. The complex is immobilized over the measuring junctions of a thermopile via biotin streptavidin interaction. The concentration of the analyte is determined by using enzyme linked secondary IgG antibody specific to the primary one. The …

Nanostructured Aluminum Oxide (Nao): Enhanced Fluorescence Imaging And Sensing, Xiang Li

Doctoral Dissertations

A new fluorescence enhancement technical platform based on nanostructured aluminum oxide (NAO) has been discovered. Experiments reveal that this new platform can enhance the fluorescence signals up to two or three orders of magnitude compared to a traditional glass substrate platform. In order to realize a large-scale arrayed fluorescence biosensing platform for high throughput applications, a rapid and cost-effective process has been developed to fabricate the micropatterned NAO of a variety of shapes. An optical characterization technology, by introducing UV light irradiance, has been found for the first time to determine if the NAO has been formed from Al and …

Micro And Nano Technology Platforms: From Cell Viability Monitoring To Fet Based Biosensing, Pushparaj D. Pathak

Doctoral Dissertations

Nanotechnology is a multidisciplinary field that combines science and engineering to design, synthesize, characterize and explore applications for materials and devices whose smallest functional organization in at least one dimension is on the nanometer scale. Nanotechnology is undergoing an explosive development and the extent of potential application is vast and widely diverse. In the field of human health care, nanotechnology is helping to develop novel materials and structures, which have made it possible to miniaturize many of the tools used in conventional assays. Smart biochips constructed out of these novel materials and structures are now capable of performing limited in …

Study And Development Of Sulfated Zirconia Based Proton Exchange Fuel Cell Membranes, Brittany Wilson Kemp

Doctoral Dissertations

With the increasing consumption of energy, fuel cells are among the most promising alternatives to fossil fuels, provided some technical challenges are overcome. Proton exchange membrane fuel cells (PEMFCs) have been investigated and improvements have been made, but the problem with Nafion®, the main membrane for PEMFCs, has not been solved. Nafion® restricts the membranes from operating at higher temperatures, thus preventing them from working in small electronics. The problem is to develop a novel fuel cell membrane that performs comparably to Nafion® in PEMFCs.

The membranes were fabricated by applying sulfated zirconia, via template wetting, to porous alumina membranes. …

Selected Durability Studies Of Geopolymer Concrete With Respect To Carbonation, Elevated Temperature, And Microbial Induced Corrosion, Mohammad Sufian Badar

Doctoral Dissertations

This thesis reports a comprehensive study related to the experimental evaluation of carbonation in reinforced geopolymer concrete, the evaluation of geopolymer concretes at elevated temperature, and the resistance of geopolymer concrete to microbial induced corrosion (MIC).

Carbonation: Reinforced concretes, made of geopolymer, prepared from two class F fly ashes and one class C fly ash, were subjected to accelerated carbonation treatment for a period of 450 days. Electrochemical, microstructure and pore structure examinations were performed to evaluate the effect of corrosion caused due to carbonation. GPC specimens prepared from class F fly ash exhibited lower corrosion rates by a factor …

Multiscale Modeling Study Of Methanol Oxidation By Ion-Modified Mdh Enzymes, Purnima Kharidehal

Doctoral Dissertations

Enzymes have been considered as molecular electrocatalysts due to their extraordinary characteristics such as their ability to accelerate reactions enormously, to operate under physiological conditions, and to produce fewer by-products during a catalytic reaction. However, enzyme based fuel cells have been reported to have power output and stability limitations, which are restricting the use of this kind of fuel cell to small electronic devices. Methanol dehydrogenase (MDH) is one such enzyme, which oxidizes methanol and other primary alcohols to their corresponding aldehydes. The active site of MDH contains a divalent cation (Ca2+), a co-factor pyrrolo-quinoline quinone (PQQ), several amino acids, …

Sparse Nonlinear Optimization For Signal Processing And Communications, Zengli Yang

Doctoral Dissertations

"This dissertation proposes three classes of new sparse nonlinear optimization algorithms for network echo cancellation (NEC), 3-D synthetic aperture radar (SAR) image reconstruction, and adaptive turbo equalization in multiple-input multiple-output (MIMO) underwater acoustic (UWA) communications, respectively.

For NEC, the proposed two proportionate affine projection sign algorithms (APSAs) utilize the sparse nature of the network impulse response (NIR). Benefiting from the characteristics of l₁-norm optimization, affine projection, and proportionate matrix, the new algorithms are more robust to impulsive interferences and colored input than the conventional adaptive algorithms.

For 3-D SAR image reconstruction, the proposed two compressed sensing (CS) approaches exploit the …

Far-Field Prediction Using Only Magnetic Near-Field Scanning And Modeling Delay Variations In Cmos Digital Logic Circuits Due To Electrical Disturbances In The Power Supply, Xu Gao

Doctoral Dissertations

"The first topic of this dissertation is far-field prediction using only magnetic near-field scanning. Near-field scanning has been used extensively for the far-field estimation of antennas. Applied to electromagnetic compatibility (EMC) problems, near-field scanning has been used to estimate emissions from both integrated circuits (ICs) and printed circuit boards (PCBs). Interest in applying far-field predictions using near-field to EMI/EMC problems has recently grown. To predict the far-field emissions from a PCB in the top half space, the near-field data on a planar surface above PCB usually is sufficient. However, near-field measurement on only one planar surface may not be enough …

Energy Deposition Into Heavy Gas Plasma Via Pulsed Inductive Theta-Pinch, Ryan Alan Pahl

Doctoral Dissertations

"The objective of this research is to study the formation processes of a pulsed inductive plasma using heavy gases, specifically the coupling of stored capacitive energy into plasma via formation in a theta pinch coil. To aid in this research, the Missouri Plasmoid Experiment Mk. I (and later Mk. II) was created.

In the first paper, the construction of differential magnetic field probes are discussed. The effects of calibration setup on B-dot probes is studied using a Helmholtz coil driven by a vector network analyzer and a pulsed-power system. Calibration in a pulsed-power environment yielded calibration factors at least 9.7% …

Bioactive Glass/Polymer Composites For Bone And Nerve Repair And Regeneration, Ali Mohammadkhah

Doctoral Dissertations

"Bioactive glasses have several attractive properties in hard and soft tissue repair but their brittleness limited their use, as scaffolding materials, for applications in load- bearing hard tissue repair. At the same time, because of their bioactive properties, they are being studied more often for soft tissue repair. In the present work, a new glass/polymer composite scaffold was developed for the repair of load-bearing bones with high flexural strength and without brittle behavior. The new composites have 2.5 times higher flexural strength and ~100 times higher work of fracture (without catastrophic failure) compared to a similar bare glass scaffold.

Also …

Dissolution Behavior Of Phosphate Glasses, Li Na Ma

Doctoral Dissertations

"The solubility of phosphate glasses in aqueous solutions can be tailored through compositional control to obtain a wide range of ion release rates required for a variety of applications. The principal objective of this dissertation is to advance the understanding of the dissolution behavior of phosphate glasses in aqueous environments.

Two families of glasses, sodium-iron phosphate (NFP) glasses and sodium-calcium phosphate (NCP) glasses, were evaluated. The dissolution behavior depends on the phosphate anions that constitute the glass structure and the associated metal (Me) cations. The phosphate glass structure, defined by the distribution and average size of phosphate anions and depending …

Sustainability Analysis In Integrated Inventory Control And Transportation Systems, Brian Joseph Schaefer

Doctoral Dissertations

"Due to the importance of costs as well as environmental effects of logistical activities throughout supply chains, such as inventory holding, freight transportation, and warehousing activities, this dissertation models and analyzes four integrated inventory control and transportation problems that account for economic and environmental aspects of a supply chain agents related decisions.

The first model presents an integrated inventory control and transportation problem in a single item deterministic demand setting. A supply chain agents inventory control and transportation mode selection problem is solved under carbon cap, carbon cap and trade, carbon cap and offset, and carbon tax regulations. The second …

Two New Families Of High-Gain Dc-Dc Power Electronic Converters For Dc-Microgrids, Venkata Anand Kishore Prabhala

Doctoral Dissertations

"Distributing the electric power in dc form is an appealing solution in many applications such as telecommunications, data centers, commercial buildings, and microgrids. A high gain dc-dc power electronic converter can be used to individually link low-voltage elements such as solar panels, fuel cells, and batteries to the dc voltage bus which is usually 400 volts. This way, it is not required to put such elements in a series string to build up their voltages. Consequently, each element can function at it optimal operating point regardless of the other elements in the system. In this dissertation, first a comparative study …

Performance Assessment Of Capture Zones Generated By Pv-Powered Pump And Treat Systems, Yovanna Cortes Di Lena

Doctoral Dissertations

"Pump and treat (P&T) is a technology that has been extensively used to remove and/or contain contaminated groundwater. Hydraulic containment of contaminants is accomplished by generating capture zones through pumping of groundwater. An appropriate delineation of capture zones is necessary to design an effective P&T system. P&T systems conventionally operate continuously to achieve steady-state capture zones, which require significant amounts of energy. The use of renewable energies to meet power demands of remedial systems may reduce a project's carbon dioxide emissions. The hydraulic effectiveness of a photovoltaic (PV) powered P&T system without energy storage was characterized using data collected at …

Preformed Particle Gel Transport Through Fractures, Hao Zhang

Doctoral Dissertations

"Polymer gel treatment is one of the most cost-effective methods to control water production in mature oil fields. The main objective of gel treatments is to reduce water or gas flow through high-permeability channels or fractures without damaging productive zones. Preformed particle gels (PPGs) have been applied for conformance control because they can overcome some potential drawbacks inherent in an in-situ gelation system.

In this study, lab experiments were performed to quantify PPG propagation through fractures and fracture-like channels by using screen models and open fracture models. The main findings in these experiments can guide the selection of best particle …

Synthesis Of Radioactive And Nonradioactive Nanostructures Through Radiolytic And Wet Chemistry, Jessika Viviana Rojas Marin

Doctoral Dissertations

"In this work the synthesis of non radioactive and radioactive nanoparticles (NPs) through radiolytic and wet chemistry was studied. Non radioactive NPs of rhenium, iridium, and rhodium were synthesized from aqueous solutions containing the metal salt precursors by gamma irradiation. The solutions were irradiated to generate reducing species that led to the nucleation and growth of the nanoparticles. Amorphous rhenium oxide nanoparticles with average sizes ranging from 10 nm to 55 nm were obtained. Metallic iridium and rhodium nanoparticles were produced in polyvinyl-pyrrolidone (PVP) having narrow particle size distributions and average particle sizes from 2 nm to 6 nm. The …

The Structure And Properties Of Ternary Zinc Phosphate Glasses For Optical Applications, Charmayne Elizabeth Smith

Doctoral Dissertations

"This dissertation focuses on the properties and structures of ternary zinc phosphate glasses that have recently been investigated as substrates for femto-second (fs) laser writing. Although these glasses have potential for use as optical substrates, their poor chemical properties limit their applications. In this work, ternary zinc phosphate glasses were studied to find compositions with enhanced chemical durability and the properties and structures of the investigated glasses are reported.

Paper 1 and Paper 2 include the first systematic studies of the properties, structures of zinc aluminophosphate (ZAP) glasses and phase relationships in the ZnO-Al₂O₃-P₂O₅ system, respectively. Adding alumina to a …

Turbo Equalization For Multiple-Input Multiple-Output (Mimo) Wireless Communication Systems, Longbao Wang

Doctoral Dissertations

"This dissertation investigates both of the frequency domain and time domain turbo equalization with multiple-input multiple-output (MIMO) fading channels for radio frequency and underwater acoustic communications. First, a low complexity frequency domain turbo equalization (FDTE) is proposed for the MIMO systems with zero padding (ZP) or cyclic prefix (CP) inserted between the transmitted data blocks and its performance is tested on the real-world UWA communications experiments.

Second, as high speed communication system requires efficient bandwidth usage and power consumption, CP or ZP is not transmitted as auxiliary information. An inter-block interference cancelation and CP reconstruction algorithm is developed to re-arrange …

Rapid Repair Of Severely Damaged Rc Columns Under Combined Loading Of Flexure, Shear, And Torsion With Externally Bonded Cfrp, Ruili He

Doctoral Dissertations

"This research aimed to develop a technique to rapidly repair reinforced concrete (RC) bridge columns for emergency service restoration after severe earthquake damage has occurred. Experimental and analytical studies were conducted to study the performance and effectiveness of the proposed repair method. The experimental study included a series of 1/2-scale RC square bridge columns originally tested to failure under constant axial and increasing cyclic lateral loadings resulting in combined flexure, shear, and torsion with different torsional-to-flexural moment ratios. Using externally bonded carbon fiber reinforced polymer (CFRP) sheets, each column was repaired over a 3-day period and then retested under the …