Engineering Commons^™

Thermal And Mechanical Properties Of Novel Carbide Materials, Evan Charles Schwind

Doctoral Dissertations

"This research focuses on studying the thermal and mechanical properties of novel carbide materials at room and elevated temperatures. The novel carbide materials investigated include zeta phase tantalum carbide (ζ-Ta₄C_3-x) and a high entropy (Ta,Hf,Nb,Zr)C carbide. The electrical resistivity and thermal conductivity of zeta phase tantalum carbide (~96 wt.%) were measured as 160 ± 4.2 μΩ-cm and 9.6 W/m•K. These are higher and lower (respectively) than for cubic tantalum carbide, most likely due to planes of carbon vacancies present in the ζ-Ta₄C_3-x crystal structure. The thermal conductivity of (Ta,Hf,Nb,Zr)C was lower than any …

Prediction Of Battery Health Dynamics, Damola Martins Ajiboye

Doctoral Dissertations

"The successful market penetration of lithium-ion batteries in the last 30 years has ushered in a new dawn in energy applications. Notwithstanding their widespread use, lithium-ion batteries are affected by a plethora of fundamental issues — safety, cycle life, performance, and cost. In this work, advanced modeling techniques are developed to tackle some of these issues. This dissertation is subdivided into four parts, the first is introduction while the remaining are dedicated to the development of computational techniques for predicting battery health dynamics.

In the second part of this work, we developed fast and accurate algorithms for modeling essential battery …

Assessment Of Rib Failure Mechanisms Using Discontinuum Mechanics Based Modeling Approach, Maurice Nuonituo Sunkpal

Doctoral Dissertations

"Coal mine rib failures are major safety and health challenge for coal mines worldwide. The need for clear procedures to evaluate mine rib behavior and to provide an efficient, reliable, and consistent rib control protocol is needed. Understanding coal rib geomechanics is essential for improving rib stability and eliminating fatality and injury trends due to rib failures. This knowledge is also vital to determine support requirements.

The rib control practices used in the 21st Century in most countries originated in roof control techniques. Understandably, applying roof control methods to coal rib does not yield desirable results. The geology of structures …

Studying The Effects Of New Additive Materials For The Improvement Of The Capacity And Cycle Life Performance Of The Lead-Acid Battery, Julian Kosacki

Doctoral Dissertations

"Lead-acid batteries are an established technology with nearly 99% recyclability; however, lead-acid batteries produce only 40% of their theoretical capacity due to poor active mass utilization and PbSO4 pore blockage, and the longevity of the batteries is hampered by secondary reactions during the cycle life such as corrosion and gassing.

Lead-acid batteries were investigated and improved through several different approaches: an alternative electrolyte to mitigate secondary reactions, graphite additives to improve positive active mass (PAM) utilization, and dispersant additives to help the industrial pasting process.

The thermodynamics and chemical reactions of a commercial electrolyte replacement called Tydrolyte^TM were investigated …

Hydromechanical Stress And Internal Erosion Under Earthen Structures, Kerry Allen Magner

Doctoral Dissertations

"Dam failures by seepage and internal erosion have reportedly been attributed to up to 40% of all dam failures in the United States. Backwards piping erosion either through the embankment or foundation soils has been reported to be the major contributing method to seepage and internal erosion dam failures. This proposed research is motivated by the lack of understanding of the complex stress regimes associated with internal erosion in cohesionless soils under earthen structures. The overall goal of this research is to provide a fundamental understanding of internal erosion and the hydromechanical stress conditions necessary for the initiation and continuation …

Sources Of Quality Uncertainty In Laser Powder Bed Fusion Metal Additive Manufacturing, Zachary Young

Doctoral Dissertations

"Powder based additive manufacturing (AM) exhibits tremendous uncertainties, where variations in build quality is present despite utilizing similar build processing parameters. First, this work reports the features and formation mechanisms of five unique types of spatter during the LPBF process by in-situ high-speed, high-energy x-ray imaging. The unique physical characteristics of spatter are determined. The effect of laser scan speed and laser power on spatter formation, ejection, and mitigation are determined. Second, this work addresses the uncertainty challenge by identifying the sources of uncertainty in SLM by in-situ characterization due to variations from the additive manufacturing processing parameters needed for …

Investigating The Impact Of Rock Bridges On The Mechanical Behavior Of Jointed Rock Mass Using Lattice Spring-Based Synthetic Rock Mass (Ls-Srm) Approach, Mariam Salem Alebayat

Doctoral Dissertations

"Rock bridges were defined as a segment of intact rock that separates from discontinuities. Numerous studies are focused on developing methods to quantify their significance in rock mass strength and deformability behavior. This thesis aimed to enhance understanding of the effect of rock bridges on jointed rock masses in both laboratory and slope scales. For this purpose, the lattice spring base Synthetic Rock Mass (LS-SRM) method was adopted to conduct the numerical models, distinguished in computational efficiency, and simulates the brittle failure and roughness of discontinuities.

A robust approach was developed to optimize the calibration procedure to avoid the complex …

Novel Piezo Actuators For Surface Cleaning, Yezad H. Anklesaria

Doctoral Dissertations

"Optical cameras are becoming increasingly common and are used in a variety of applications. With recent progress and transition toward more autonomous systems, the usage of optical systems will be common and widespread. Applications of the optical systems range from autonomous vehicles, home security systems, aviation, extraterrestrial vehicles, spacecraft, and satellites. Imaging systems are used in decision-making in many of these applications. Fouling of the field of view of the imaging system can impede the decision process. An active autonomous cleaning method for the optical surface of the optical systems reliably would be advantageous. The research work focuses on developing …

Convective-Diffusive Transport In Krogh Cylinders: A Model For Pharmacokinetics, Xianjie Qiu

Doctoral Dissertations

"Drug delivery to inside of the tumor is the important problem. The dynamics of drug delivery is presented here. Previously and particularly for directed delivery, a stirred tank model has been used, which appears to have worked well when compared to experiments. However, the stirred tank models do not include all the mass transfer resistances and towards that end we have used a distributed system called Krogh cylinder. This study focuses on the Krogh cylinder model simulation, both on the fluid flow and the mass transfer. The capillary network is broken down into cylindrical cells, each containing a capillary and …

Information-Based Methods And Models For Particle Flow Filtering, Kari Catherine Ward

Doctoral Dissertations

"Recursive estimation methodologies, such as Kalman and Bayesian filters, typically require models of some kind to perform the estimation. This filtering process seeks to improve knowledge surrounding some quantities of interest, or states, over time by incorporation of imperfect observations. The models required pertain to the state dynamics, sensors from which measurements are obtained, and probabilistic models of the underlying stochastic processes. In addition to any number of necessary models, real-world application of a filter is normally accompanied by at least one, if not several, techniques to promote better performance. These methods vary in purpose from expanding the kinds of …

Instrumentation, Modeling, And Sound Metamodeling Foundations For Complex Hybrid Systems, Natasha Amelia Jarus

Doctoral Dissertations

Many of our critical infrastructures, from power grids to water distribution networks, are complex hybrid systems that use software to control their non-trivial physical dynamics. These systems must be able to capably serve their purpose, while also being reliable, dependable, safe, secure, and efficient. Representation and analysis of these features requires the creation of several distinct models. These models may encode design goals or be derived from collected instrumentation data, reflecting both how a system ought to operate and how it does operate. It is essential to ensure that all of these models consistently and accurately describe the same system. …

Prediction Of Deflection Of Helical Anchors Under Load, Andre Stephen Hawks

Doctoral Dissertations

”As the sophistication of modern structural design methods has improved over time, the ability to accurately predict and model foundation stiffness has become increasingly more important. In complicated structural systems with deep foundations, correct calculation of the distribution of load and serviceability requires proper modeling of axial load-deflection characteristics. To keep pace with advances in structural analysis, there is much need for more practical and scientific work on the load-deflection prediction of deep foundations including Helical Anchors.

The load-settlement mechanism of an axially loaded helical pile is a complex soil-structure interaction problem influenced by helical pile dimensions, installation method, and …

Using Strontium Coated Clay Nanoparticles For Bone Regeneration And Other Biomedical Applications, Anusha Elumalai

Doctoral Dissertations

The aim of this project is to coat halloysite nanotubes (HNTs) with strontium in an ecofriendly, simple, and non-expensive process. These particles, when doped in calcium phosphate cements (CPC), are predicted to increase the osteoconductive and antibacterial properties of three dimensional (3D) printed bone scaffolds.

The purpose of the 3D printed bone scaffolds is to assume the same function as the bones they are replacing but with several additional functionalities. These biomaterials will have the ability to be resorbed as new bone is formed. Due to inherent osteogenic factors and antibiotics released from doped HNTs during the reparative process, it …

Social Media Based Algorithmic Clinical Decision Support Learning From Behavioral Predispositions, Radhika V. Medury

Doctoral Dissertations

Behavioral disorders are disabilities characterized by an individual’s mood, thinking, and social interactions. The commonality of behavioral disorders amongst the United States population has increased in the last few years, with an estimated 50% of all Americans diagnosed with a behavioral disorder at some point in their lifetime. AttentionDeficit/Hyperactivity Disorder is one such behavioral disorder that is a severe public health concern because of its high prevalence, incurable nature, significant impact on domestic life, and peer relationships. Symptomatically, in theory, ADHD is characterized by inattention, hyperactivity, and impulsivity. Access to providers who can offer diagnosis and treat the disorder varies …

Nanoengineered Core-Shell Structures Using Tubile Halloysite Clay, Yusuf A. Darrat

Doctoral Dissertations

Halloysite nanotubes are a versatile nanomaterial that can be used in a wide variety of applications. They have a unique structure which could be described as a flat material that consists of silica on one side and alumina on the other; this structure is rolled up in a way naturally forming an internal 10-15 nm lumen and interlayer spacing. This could lead to many potential applications for example incorporating halloysite as a template material or as a support structure. They are an inexpensive clay material that is available in large quantities (thousands of tons), so they may be practically used …

Time- And Space-Dependent Uncertainty Analysis And Its Application In Lunar Plasma Environment Modeling, Xinpeng Wei

Doctoral Dissertations

”During an engineering system design, engineers usually encounter uncertainties that ubiquitously exist, such as material properties, dimensions of components, and random loads. Some of these parameters do not change with time or space and hence are time- and space-independent. However, in many engineering applications, the more general time- and space-dependent uncertainty is frequently encountered. Consequently, the system exhibits random time- and space-dependent behaviors, which may result in a higher probability of failure, lower average lifetime, and/or worse robustness. Therefore, it is critical to quantify uncertainty and predict how the system behaves under time- and space- dependent uncertainty. The objective of …

Computational Model For Neural Architecture Search, Ram Deepak Gottapu

Doctoral Dissertations

"A long-standing goal in Deep Learning (DL) research is to design efficient architectures for a given dataset that are both accurate and computationally inexpensive. At present, designing deep learning architectures for a real-world application requires both human expertise and considerable effort as they are either handcrafted by careful experimentation or modified from a handful of existing models. This method is inefficient as the process of architecture design is highly time-consuming and computationally expensive.

The research presents an approach to automate the process of deep learning architecture design through a modeling procedure. In particular, it first introduces a framework that treats …

Understanding The Deformation Mechanisms In Ni-Based Superalloys With Using Crystal Plasticity Finite Element Method, Tianju Chen

Doctoral Dissertations

“Ni-based superalloy is considered as a good candidate due to its excellent resistance to elevated temperature deformation for long term period application. Understanding the deformation and failure mechanisms of Ni-Based superalloys is very helpful for providing design guidelines for processing Ni-based superalloys. Experimental characterization indicates that the deformation mechanisms of Ni based superalloy is strongly microstructure dependent. Besides, damage transform from the void nucleation to the macro cracks by voids growth leading to the failure of the Ni-based superalloys are also showing strong microstructure sensitivity. Therefore, this work focuses on the prediction and comprehension of the deformation and void growth …

Operation And Analysis Of High-Voltage-Gain Dc-Dc Converters With Voltage Multipliers, Mohammad Rashed M. Altimania

Doctoral Dissertations

"This research analyzes and investigates the steady-state operations of four different high-voltage-gain step-up dc- dc converters to achieve a high gain. These topologies consist of a two-phase interleaved boost stage with three various voltage multiplier (VM) stages. The first stage of the first three topologies is the same, which is a two-phase interleaved boost stage implemented by using inductors. The first family used in this research is based on a modified Dickson charge pump voltage multiplier stage, and this family has been studied in discontinuous conduction mode (DCM). The second family relies on a non-inverting or inverting diode-capacitors voltage multiplier …

Forming And Processing Of Advanced Fiber Reinforced Polymer Composites, Robert Meinders

Doctoral Dissertations

“Composite materials are commonly used in industry to manufacture strong and lightweight structures. Composites feature a large degree of flexibility in materials selection and manufacturing processes to tailor the strength of manufactured parts. This study examines different manufacturing aspects of composites. In Part I, the fabrication of composite parts using the compression forming process is examined. During compression forming, metal dies are used to apply large deformations to prepreg material to fabricate composite parts. The high stresses and deformations of this process can yield manufacturing defects. T650/5320-1 prepreg is subjected to material characterization to develop simulations of large deformation forming …

Exploring Wellbore And Reservoir Temperature Profiles In Fluid Circulation And Production Operations, Ahmed Qasim Al Saedi

Doctoral Dissertations

"The wellbore heat flow occurs during different well operations resulting from any temperature differences between the wellbore fluid and the adjacent formation. Understanding the direction and mechanism of heat flow whether it is conduction or convection help to represent this heat exchange mathematically. However, the only available factor used to understand the heat flow behavior is the measured wellbore temperature which can be obtained from the direct measurement while drilling or circulation operations, well logging, well test, or from the production operations. Also, the initial geothermal formation temperature resulting from the geothermal gradient will help to understand the undistributed formation …

Experimental Investigation Of Ionic Liquid Mixtures For Electrospray Propulsion, Mitchell J. Wainwright

Doctoral Dissertations

"In recent years, there has been a dramatic increase in the number of small satellites (namely MicroSats, NanoSats, and CubeSats) in earth orbit; many of these are launched without propulsion systems. Multi-mode propulsion systems, capable of operating in either chemical or electric mode, have been proposed as attractive candidates for use in small satellites. Such systems are mass and volume optimal and flexible in terms of thrust requirements. Most previous work on multi-mode systems has focused on chemical mode performance.The work in this dissertation focuses on the electric mode performance of these propulsion systems.

The work in this research is …

Application Of Geophysics And Remote Sensing Techniques For Economic Mineral Exploitation In Libya, Awad Abdussalam Henish Lemnifi

Doctoral Dissertations

“This study investigates crustal thickness and properties within the north central Africa region. Results obtained from 15 seismic stations belonging to the Libyan Center for Remote Sensing and Space Science are reported, in addition to 3 seismic stations publically available, using receiver functions, the first P-to-S receiver function investigation of the 410 km and 660 km depth discontinuities bounding the mantle transition zone (MTZ), and P wave tomography methods. The results from the first method show crustal thicknesses ranging from 24 km to 36 km (with uncertainties ranging between ±0.10 km and ±0.90 km). More specifically, crustal thickness ranges from …

Optimal Adaptive Control Of Time-Delay Dynamical Systems With Known And Uncertain Dynamics, Rohollah Moghadam

Doctoral Dissertations

"Delays are found in many industrial pneumatic and hydraulic systems, and as a result, the performance of the overall closed-loop system deteriorates unless they are explicitly accounted. It is also possible that the dynamics of such systems are uncertain. On the other hand, optimal control of time-delay systems in the presence of known and uncertain dynamics by using state and output feedback is of paramount importance. Therefore, in this research, a suite of novel optimal adaptive control (OAC) techniques are undertaken for linear and nonlinear continuous time-delay systems in the presence of uncertain system dynamics using state and/or output feedback. …

Deep Learning For Digitized Histology Image Analysis, Sudhir Sornapudi

Doctoral Dissertations

“Cervical cancer is the fourth most frequent cancer that affects women worldwide. Assessment of cervical intraepithelial neoplasia (CIN) through histopathology remains as the standard for absolute determination of cancer. The examination of tissue samples under a microscope requires considerable time and effort from expert pathologists. There is a need to design an automated tool to assist pathologists for digitized histology slide analysis. Pre-cervical cancer is generally determined by examining the CIN which is the growth of atypical cells from the basement membrane (bottom) to the top of the epithelium. It has four grades, including: Normal, CIN1, CIN2, and CIN3. In …

Catalytic Utilization Of Carbon Dioxide As Renewable Feedstock For Production Of Chemicals And Fuels, Abbas Alaa Jawad

Doctoral Dissertations

"The utilization of CO₂ as a renewable feedstock for producing commodity chemicals and fuels is an interesting challenge to explore new concepts and opportunities in catalysis and industrial chemistry. This sustainable approach not only leads to production of useful chemicals, but also has the potential to mitigate anthropogenic CO₂ emissions to the atmosphere. CO₂ itself is a sustainable and inexhaustibly available carbon source, however, it is inextricably linked to its inherent inertness. It is a thermodynamically stable molecule (ΔG_f = -394.01 kJ.mol^-1) with high oxidation state, hence, reactions of CO₂ must be combined …

Thermodynamic Investigations Of Pure And Blended Cement Mixtures, Jonathan Lapeyre

Doctoral Dissertations

” This research is made up of several studies. The first study focused on understanding the reaction kinetics of Ca₃SiO₅ and metakaolin (MK) mixtures compared to Ca₃SiO₅ and silica fume (SF) mixtures. It was shown that MK was a more effective additive than SF at small replacement levels (i.e. ≥ 10% by mass) while higher replacement levels of MK became a detriment due to excess (Al(OH)₄¯) ions preventing the nucleation and growth of C-S-H. In a follow-up study where the MK particle size distribution (PSD) was modified, similar effects were observed but …

Polymeric Nanoparticle As A New Platform For High Removal Of Endotoxins From Biopharmaceutical Solutions, Sidharth Razdan

Doctoral Dissertations

"Presently, approximately one-third of all biopharmaceutical drugs are derived from biological sources like gram-negative bacteria. Gram-negative bacteria like E.coli are much cheaper to cultivate and provide higher biotherapeutic yield compared to mammalian cells. On extracting the useful biotherapeutics from the gram-negative bacterial cells (E.coli), endotoxin present in the bacteria is released in the surrounding media thus contaminating the lifesaving biotherapeutics. Application of the endotoxin-contaminated therapeutics to humans or animals can cause serious health issues like septic shock, tissue injury and ultimately death. Hence, thorough purification of biotherapeutics before parenteral application is necessary. Although there are multiple methods for …

Characterization Of Neutron Irradiated Accident Tolerant Nuclear Fuel Cladding Silicon Carbide & Radiation Detector Deadtime, Bader Almutairi

Doctoral Dissertations

“In part I, the pulse shape characteristics generated by a Geiger Muller (GM) detector and recorded by an oscilloscope manually, were investigated. The objective of part I was (1) to find a correlation between pulse shape and the operating voltage; and (2) to assess if pulse shape properties followed distinct patterns comparable to detector deadtime findings reported by a previous study. It was observed that (1) there is a strong correlation between pulse shape and operating voltage, and (2) pulse shape falls in three distinct regions similar to detector deadtime. Furthermore, parts II and III are companions and share the …

Effect Of Turbulence Model Closure Coefficient Uncertainty On Scramjet Flow Field Analysis, Martin Albert Di Stefano

Doctoral Dissertations

“The numerical modeling of supersonic combustion ramjet (scramjet) engine flow paths plays an important role in the design of hypersonic air-breathing propulsion systems. Due to the complexity of the flow field physics and limited experimental data, numerical models possess uncertainties which should be addressed to improve the prediction accuracy of the simulations. In this study, the effect of turbulence model closure coefficient uncertainty on the Reynolds-averaged Navier-Stokes solution of a scramjet isolator and scramjet strut fuel injector flow field is investigated with an uncertainty quantification and sensitivity analysis study for commonly used turbulence models. Turbulence models considered in this work …