Engineering Commons^™

Measurement Of Peptoid Concentration Using Uv Spectroscopy, Katie Holland

Chemical Engineering Undergraduate Honors Theses

The goal of this research is to establish a relationship between ultraviolet adsorption and peptiod concentration to be used to determine the concentration of an unknown peptoid sample. This will allow for the measurement of concentration differences of peptoid samples before and after incubation with membrane surfaces. Samples were prepared nine know concentrations and diluted 50 fold. The UV absorbances of each sample was measured using a UV spectrophotometer at wavelengths from 200 to 450 nanometers. This process was repeated, and the maximum absorbance of each replicate was averaged to yield an absorbance value for each concentration of peptoid. …

A Risk-Based Method For Estimating The Carbon Sequestration Budget For A Mixed Hardwood Forest, Erin Cooper

Chemical Engineering Undergraduate Honors Theses

Carbon Dioxide (CO₂) levels in the atmosphere have risen from approximately 310 ppm in the 1950’s to over 400 ppm as of 2015. This rise in CO₂ has likely resulted in the observed warming trend of the earth’s atmosphere in the same time frame, causing significant concern in the scientific community. Several mitigation strategies have arisen to combat the upward trend of CO₂ emissions in recent decades, among them being carbon sequestration- the process of capturing CO₂ from the atmosphere and holding it for an extended period of time. This study used the U.S. Forest …

Tailings Dust Emissions, Emily Degner, Sam Horn, Zakary Galligan, Ryan Bernard, Julie Jameson, Josh Mueller, Natalie Tucker, Joe Griffin

Chemical Engineering Undergraduate Honors Theses

Fugitive dust emissions from the storage and handling of mine tailings presents environmental and safety concerns, which must be addressed to promote the land sustainability and the health and safety of individuals around a tailings storage facility (TSF). The investigated dust control methods were agglomeration, binder slurry injection, and topical spray.

The Dust Busters determined that pelletizing was the most practical method of agglomeration. In order to produce durable pellets from the mine tailings, which consist primarily of silica, a binder must be added. A variety of binders were considered including magnesium and calcium chloride, bentonite, barite, cement, vinyl polymers, …

Proposal To Build Nylon 6,6 Plant: A Grassroots Economic Analysis, Caleb M. Woodall

Chemical Engineering Undergraduate Honors Theses

This report analyzes the profitability of building a grass roots Nylon 6,6 plant in Calvert City, Kentucky. A rigorous process simulation was produced, equipment prices were estimated, utility usage was assessed, and a plan for the plant organization was developed. The calculations yielded values for fixed capital investment ($10.5 million), working capital ($101 million) and revenue ($114 million). The discounted cash flow rate of return was calculated to be 8.94%. The conclusion drawn from these calculated values is that the current plan for the plant would not be profitable on a 10 year project life basis. However, recommendations are presented …

Life Cycle Assessment Of Sweet Sorghum As Feedstock For Second-Generation Biofuel Production, Karla Morrissey

Chemical Engineering Undergraduate Honors Theses

There exist few life cycle assessments (LCAs) in the literature that focus on the second-generation biofuel production from sweet sorghum, a non-food-source feedstock that offers several advantages in terms of farming requirements compared to corn or sugarcane. The objective of this LCA study was to evaluate biofuels produced from sweet sorghum to determine the potential environmental benefits of producing sweet sorghum biofuel compared to conventional fossil fuels. The biofuel production process used for this study differed from other LCAs in that, in parallel to stalk juice extraction and fermentation, residual bagasse and vinasse was pyrolyzed and upgraded to a diesel …

An Industrial Process For The Production Of Nylon 6 6 Through The Step-Growth Reaction Of Adipic Acid And Hexamethylenediamine, David Wallace Jacobson

Chemical Engineering Undergraduate Honors Theses

A continuous, two stage, four reactor system process is presented here for the proposed purpose of nylon 6 6 manufacture at the rate of 85 million lbs per year. Report components include: process descriptions, simulation methods and results, economic analysis, EH&S considerations, process control descriptions, and a general recommendation for how to proceed with plans enclosed. The general design of the plant is a two stage system composed of one PFR used for the formation of nylon salt and low molecular weight nylon chains, followed by three CSTR’s used for increasing nylon molecular weight. The overall process has been found …

Feasibility Analysis Of Recycled-Paper Fueled Agricultural Desalination Process: Design Of Recycling And Desalination Processes, Sean M. Street

Chemical Engineering Undergraduate Honors Theses

While recycled-paper-briquettes have lower BTU ratings than wood, and fresh water is typically a low cost to agricultural entities, situations exist where economic and/or environmental factors may allow a recycled-paper-fueled desalination process to be viable for some specific agricultural entities. This document begins with a discussion of how water is priced throughout India before analyzing trends in the Maize futures market. By tying the two together, an opportunity is created for solution which the remainder of the document presents. Paper waste in India makes-up 50% of its solid waste country-wide; however, only a quarter of that waste is recycled - …

Passive Solar Distillation Of Acid Rock Drainage, Stephanie Shreve, Luke Galuska, Anna Stoller, Alex Raney, Agustin Caceres, Caitlyn Chambers, Chris Graham, Devin Hazlett

Chemical Engineering Undergraduate Honors Theses

Arkansas Razorback Distillers (A.R.D.) has developed a passive solar distillation system for treating acid rock drainage (ARD) from legacy (i.e., abandoned) mines. The solar still addresses the need to reduce both the metal sulfate contaminants as well as the acidity of acid rock drainage. During the design phase, A.R.D. addressed the need for the system to be low cost, simple, and effective for general use as well as a specified location. To demonstrate the applicability of the solar still, A.R.D. used the Freeport McMoRan Inc. Copper Queen legacy mine in Bisbee, Arizona, as a base case scenario. The mine was …

Evaluation Of Phosphorous Removals By Biochar Supported Nano-Scale Zero-Valent Iron, Maria S. Rossetti

Chemical Engineering Undergraduate Honors Theses

This study evaluated the effectiveness of biochar-supported nano-scale zero-valent iron (nZVI/BC) in removing phosphorus (P) from water. Samples of nZVI/BC were prepared using aqueous nanoparticles synthesis techniques, and were mixed with a stock phosphorus solution. To determine P reductions water samples were tested for P content using the ascorbic acid method. This procedure was repeated for samples of stock P solution, zero-valent iron (ZVI), biochar, and ZVI/BC. nZVI/BC reduced P content by 86% whereas ZVI, biochar, and ZVI/BC removed 6%, -23%, and 17% respectively. This suggests that nZVI/BC has the potential to be an effective method of stormwater remediation.