Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Engineering
Fabrication, Magnetic, And Ferroelectric Properties Of Multiferroic Bifeo3 Hollow Nanoparticles, Yi Du, Zhenxiang Cheng, S X. Dou, Darren J. Attard, Xiaolin Wang
Fabrication, Magnetic, And Ferroelectric Properties Of Multiferroic Bifeo3 Hollow Nanoparticles, Yi Du, Zhenxiang Cheng, S X. Dou, Darren J. Attard, Xiaolin Wang
Faculty of Engineering - Papers (Archive)
Hollow BiFeO3 nanoparticles were synthesized by an electrospray route for the first time. The phase purity and structure have been investigated by x-ray diffraction and Raman spectroscopy. Transmission and scanning electron microscope investigations revealed that the as-obtained BiFeO3 hollow spheres were polycrystalline, with a shell thickness of 35 nm. The formation mechanism can be possibly explained by Ostwald ripening. Raman spectra have verified decreased vibrational frequencies in BiFeO3 nanoparticles. These hollow and core-shell multiferroic nanoparticles exhibit significantly enhanced ferromagnetism from 5 to 600 K due to a broken spiral spin structure. The ferroelectricity of hollow BiFeO3 …
Magnetic And Ferroelectric Properties Of Multiferroic Bi2nimno6 Nanoparticles, Yi Du, Zhenxiang Cheng, Xiaolin Wang, Peng Liu, S. X. Dou
Magnetic And Ferroelectric Properties Of Multiferroic Bi2nimno6 Nanoparticles, Yi Du, Zhenxiang Cheng, Xiaolin Wang, Peng Liu, S. X. Dou
Faculty of Engineering - Papers (Archive)
Multiferroic Bi2NiMnO6 nanoparticles were synthesized by a simple electrospray method. Bi2NiMnO6 nanoparticles crystallize in the monoclinic structure with space group C121. The particles show a uniform spherical shape with a diameter of 100 nm to 300 nm. The ferromagnetic transition of Bi2NiMnO6 is confirmed at 122 K. The room temperature ferroelectricity of the Bi2NiMnO6 nanoparticles is verified by Kelvin probe force microscopy.
Improved Reversible Dehydrogenation Of 2libh4+Mgh2 System By Introducing Ni Nanoparticles, Jianfeng Mao, Zaiping Guo, Xuebin Yu, Hua-Kun Liu
Improved Reversible Dehydrogenation Of 2libh4+Mgh2 System By Introducing Ni Nanoparticles, Jianfeng Mao, Zaiping Guo, Xuebin Yu, Hua-Kun Liu
Faculty of Engineering - Papers (Archive)
We report that the hydrogen de/resorption of the 2LiBH4+MgH2 system was modified by introducing Ni nanoparticles. Dehydrogenation analysis revealed that the first-step dehydrogenation, i.e., the decomposition of MgH2, can be significantly promoted by adding a small amount of Ni because of the catalytic effect. However, the improvement of the second-step dehydrogenation, corresponding to the decomposition of LiBH4, needs the addition of a large amount of Ni, resulting in the formation of a Mg–Ni–B ternary alloy. Furthermore, the presence of the Mg–Ni–B ternary alloy allowed an increased reversible H-capacity, in which about 5.3 wt% …