Engineering Commons^™

Assessing Corrosion Damage In Post -Tensioned Concrete Structures Using Acoustic Emission & A Preliminary Investigation Of Biopolymer Doped Cement Mortar For Use In Structural Restoration, Aditya Appalla

Theses and Dissertations

A sizeable portion of the civil infrastructure is made from concrete. An estimate shows that about 7 billion cubic meters of concrete is made annually worldwide. With the deterioration of the infrastructure due to aging or external factors, significant monetary and technological investment is needed for condition evaluation, maintenance and repair. Two areas that account for a considerable portion of this investment are condition evaluation for maintenance of corroded concrete structures and mortar patching for repair and rehabilitation.

The primary method of evaluation of a structure is by visual inspection. But this method is limited as some crucial areas in …

Assessment Of Damage In Concrete Structures Using Acoustic Emission, Marwa Abdelrahman

Theses and Dissertations

Evaluating the integrity of concrete structures is an essential procedure to ensure structural safety and durability. Non-destructive testing (NDT) is needed for localizing and characterizing the growing damage in existing structures and also for quality control of new structures. Visual inspection is a commonly used method; however it is not suitable for early detection of damage and very dependent on the experience of the inspector. More research is needed to establish advanced methods for structural health diagnosis such as acoustic emission (AE). Acoustic emission is notably sensitive to active damage in concrete structures. This thesis includes three studies that mainly …

Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov

Faculty Publications

A new Zn-Ni-Cd plating process was developed which offers a unique way of controlling and optimizing the Ni and Cd contents in the final deposit. Zinc-nickel-cadmium alloy was deposited from a 0.5 M NiSO₄ + 0.2 M ZnSO₄ bath in the presence of 0.015 M CdSO₄ and 1 g/L nonyl phenyl polyethylene oxide. Using this process a Zn-Ni-Cd ternary alloy, with a higher nickel content as compared to that obtained from conventional Zn-Ni baths, was synthesized. The Zn-Ni-Cd alloy coatings deposited from an electrolyte containing 0.015 M (0.3%) CdSO₄ has a Zn to Ni ratio of …

Characterization Of Hydrogen Permeation Through Zinc-Nickel Alloys Under Corroding Conditions: Mathematical Model And Experimental Study, M. Ramasubramanian, Branko N. Popov, Ralph E. White

Faculty Publications

A mathematical model was developed for the characterization of hydrogen permeation into metals and alloys under corroding conditions. The model requires a knowledge of the corrosion rate of the given metal or alloy in solutions of various H⁺ concentrations. It provides quantitative values of rate constants of the hydrogen discharge, recombination, and adsorption reactions. This model can serve as a diagnostic criterion for determining the effectiveness of various metals and alloys as hydrogen permeation inhibitors and can be used for evaluation of hydrogen entry inhibition efficiency. Experiments were carried out to study the effectiveness of thin layers of electrodeposited …

Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin

Faculty Publications

Electrochemical impedance spectroscopy (EIS) was used to evaluate the degree of delamination of the epoxy primer Uniprime ED-4¹ electrocoated on phosphate-treated cold-rolled steel in 3.5% NaCl exposed to air. Specimens with coating thicknesses of 20.3 and 20.8 µm and surface areas of 78.5 cm² were used. Coating parameters were obtained using a circuit-analog model. The area of delamination was estimated using several EIS parameters, including the pore resistance and the break point frequency. These values were compared to the corroded area determined visually. All methods considered exhibited a strong correlation over some or all of the range of …

A Mathematical Model For The Initial Corrosion Rate Of A Porous Layer On A Rotating Disk Electrode, William E. Ryan, Ralph E. White, S. L. Kelly

Faculty Publications

A mathematical model is presented for the initial corrosion rate of a porous layer on a rotating disk electrode. The model is used to predict the corrosion potential and corrosion current density for a porous electrode made of pure iron in aerated caustic solutions. The dependence of these predictions on some of the properties of the porous layer is presented. It is shown that the corrosion rate depends significantly on the specific surface area of the porous electrode.