Engineering Commons^™

Supported Metal Bifunctional And Bimetallic Catalysts With Precisely Controlled Structures And Properties, Anhua Dong

Theses and Dissertations

In heterogenous catalysis, metallic nanomaterials play vital roles in numerous chemical processes. However, monofunctional catalysts are greatly impeded in their applications especially in the systems including tandem and/or sequential reaction steps. Besides, the catalytic performance can also be greatly influenced by the particle size, morphology, and geometry of the surface metal atoms.

The goal of this work is to synthesize bifunctional or bimetallic nanoparticles with high metal dispersion and homogenous alloys by rational synthetic strategies to facilitate the catalyst function. Strong electrostatic adsorption (SEA) is an effective and facile methodology to produce well dispersed and uniform nanoparticles. Metal-acid bifunctional catalysts …

Hydrodeoxygenation Of Biomass Derived Sugar Alcohols To Platform Chemicals Using Heterogeneous Catalysts, Blake Macqueen

Theses and Dissertations

This work set out to investigate biomass derived sugar alcohol upgrading via the removal of oxygen and hydroxyl groups via the hydrodeoxygenation reaction utilizing heterogeneous catalysts. The importance of reaction conditions, catalyst meal loadings, catalyst structure and properties were probed using techniques such as design of experiments, and spectroscopic techniques including Raman and DRIFTS. The state of the art simultaneous hydrodeoxygenation (S-HDO) catalyst ReO_x-Pd/CeO₂ was investigated and optimized for various sugar alcohol substrates. The kinetics and associated mass transfer were also investigated to give further insight into the reaction over the ReO_xPd/CeO₂ catalyst.

First, …

Design, Synthesis, And Characterization Of Monometallic And Bimetallic Catalysts, Sonia Eskandari

Theses and Dissertations

Supported catalysts are used extensively in a variety of heterogeneously catalyzed reactions for industrial processes. Techniques for preparing supported noble metal catalysts are typically chosen to achieve high metal dispersions in order to obtain high activity for a given metal loading. Enhancing the catalytic performance of heterogeneous catalysts can be done by increasing active site count as well as modification of the physico-chemical characteristics of the catalyst material. For supported metal nanoparticles this can be achieved by decreasing particle size, thus increasing dispersion or metal utilization on the surface of the particles, while modification of metal properties can be attained …

Characterization Of Evaporation/Condensation During Pool Boiling And Flow Boiling, Mostafa Mobli

Theses and Dissertations

Present dissertation has investigated pool and flow boiling and their characteristics via numerical means. A code was developed to investigate and enhance heat transfer performance during different modes of phase change phenomena. Multiphase heat transfer has proven to be one of the most effective means of heat transfer in different industries, therefore, there have been numerous experimental and numerical studies on the subject of phase change phenomena in a wide range of conditions and setups; yet there are complex bubble dynamics and heat transfer characteristics that remain unresolved. To have a more detailed look at and a better understanding of …

Characterization Of Subgrade Resilient Modulus For Mepdg And The Effects On Pavement Rutting, Md Mostaqur Rahman

Theses and Dissertations

In 2008, the American Association of State Highway and Transportation Officials (AASHTO) released a modified pavement design method (i.e., the Mechanistic Empirical Pavement Design Guide (MEPDG)) based on Long Term Pavement Performance (LTPP) data from all over the United States. The MEPDG default design parameters developed from the LTPP database are expected to be significantly different than those for South Carolina material, traffic and weather conditions, thus the default design parameters may not be accurate for South Carolina. Therefore, the new pavement design method should be calibrated for South Carolina conditions by performing MEPDG local calibration.

Different input variables should …

Characterization, Synthesis And Stabilization Of Au Based Bimetallic Catalysis For The Hydrochlorination Of Acetylene, Kerry Charles O'Connell

Theses and Dissertations

Polyvinyl chloride (PVC) is the third most-produced plastic polymer world-wide by volume after polypropylene and polyethylene. Vinyl chloride monomer, which is polymerized into PVC, is produced via mercuric chloride catalysts that deactivate as mercury sublimes into the atmosphere from the catalyst surface, resulting in substantial environmental concerns.

In an effort to rationally synthesize non-mercuric catalysts, strong electrostatic adsorption (SEA) was used to prepare highly dispersed and active gold nanoparticles over low point of zero charge (PZC) carbon to increase the active metal surface area. The use of <1.5nm gold clusters did not lead to large increases in activity as there was an increased degree of particle coalescence during reaction for activated carbon supported samples. A pronounced support effect was observed in which oxide supports completely prevented Au sintering, but was virtually inactive. This suggests that the active site for the hydrochlorination reaction involves the carbon surface.

The stabilization of carbon supported gold nanoparticles in the HCl-rich reaction environment was …

A Mechanical Approach To The Characterization Of Material Failure Of Atherosclerotic Lesions, Lindsey A. Davis

Theses and Dissertations

Failure of atherosclerotic plaques can lead to potentially life threatening clinical events such as myocardial infarction (MI), stroke, or transient ischemic attack (TIA). The most frequently described plaque failure mechanism is tensile rupture of the fibrous cap; however, often during angioplasty another plaque failure mechanism occurs in which the atherosclerotic plaque separates from the internal elastic lamina (IEL). This study aims assess the material strength of atherosclerotic lesions using mechanical concepts.

To assess likelihood of plaque dissection at the vessel wall, adhesion strength was assessed in both mouse and human specimens using plaque delamination experiments. Measuring plaque adhesion in transgenic …

Characterization Of Human-Induced Vibrations, Benjamin Thomas Davis

Theses and Dissertations

In the US alone, 20% of citizens will be over the age of 65 by the year 2030, and the largest challenge facing this growing demographic is not a new disease but a simple motion - the fall. These events are the premier cause of fatal and nonfatal injuries. In fact, a fall is so common that every 17 seconds an older adult is treated for fall-related injuries, and every 30 minutes, an older adult dies from fall complications. Research has shown a positive outcome of a fall event is largely dependent on the immediate response (<30 minutes) and rescue of the person.

This work explores …

Fabrication And Characterization Of Graphene Based Biocompatible Ion-Sensitive Field Effect Transistor (Isfet), Rina Patel

Theses and Dissertations

Graphene, a two-dimensional material with a high surface to volume ratio, has drawn extensive research enthusiasm for applications in the field of electronic sensors. The special material properties that make graphene a highly promising material include its biocompatibility, very high mobility, low 1/f and thermal noise, modulation of carrier concentration and fermi level by electrical, optical, and chemical means. To exploit these properties for practical applications a large area high quality graphene, transferred on appropriate substrates, is required. In this work, high quality single monolayer graphene (determined from Raman spectroscopy) has been synthesized by chemical vapor deposition (CVD) technique for …

Growth, Fabrication And Characterization Of Cu2Znsn(SXSe1-X)4 Photovoltaic Absorber And Thin-Film Heterojunction Solar Cells, Sandip Das

Theses and Dissertations

Current thin-film solar cell technologies based on CuIn_xGa1_-xSe₂ (CIGS) and CdTe photo-absorber materials use rare and expensive elements, such as In, Te, Ga, and toxic Cd which severely limit the mass production and deployment of these solar cells. Thus, a major research effort is focused toward the development of new photovoltaic (PV) absorber materials comprising of earth-abundant, low-cost, and environmentally benign constituent elements that can support terawatt (TW)-scale PV generation in the near future and be economically sustainable. Cu-based I₂-II-IV-VI₄ quaternary kesterite compound Cu₂ZnSn(S_xSe_1-x)4 (CZTSS_{e …}

Characterization Of Two Ods Alloys: 18cr Ods And 9cr Ods, Julianne Kay Goddard

Theses and Dissertations

ODS alloys, or oxide dispersion strengthened alloys, are made from elemental or pre-alloyed metal powders mechanically alloyed with oxide powders in a high-energy attributor mill, and then consolidated by either hot isostatic pressing or hot extrusion causing the production of nanometer scale oxide and carbide particles within the alloy matrix; crystalline properties such as creep strength, ductility, corrosion resistance, tensile strength, swelling resistance, and resistance to embrittlement are all observed to be improved by the presence of nanoparticles in the matrix. The presented research uses various methods to observe and characterize the microstructural and microchemical properties of two experimental ODS …