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Articles 61 - 65 of 65
Full-Text Articles in Engineering
Engineered Nanoparticles For Site-Specific Bioorthogonal Catalysis: Imaging And Therapy, Riddha Das
Engineered Nanoparticles For Site-Specific Bioorthogonal Catalysis: Imaging And Therapy, Riddha Das
Doctoral Dissertations
Bioorthogonal catalysis offers a strategy for chemical transformations complementary to bioprocesses and has proven to be a powerful tool in biochemistry and medical sciences. Transition metal catalysts (TMCs) have emerged as a powerful tool to execute selective chemical transformations, however, lack of biocompatibility and stability limits their use in biological applications. Incorporation of TMCs into nanoparticle monolayers provides a versatile strategy for the generation of bioorthogonal nanocatalysts known as “nanozymes”. We have fabricated a family of nanozymes using gold nanoparticles (AuNPs) as scaffolds featuring diverse chemical functional groups for controlled localization of nanozymes in biological environments, providing unique strategies for …
Molecular Design Of Organic Semiconductors For Interfacial And Emissive Material Applications, Marcus David Cole
Molecular Design Of Organic Semiconductors For Interfacial And Emissive Material Applications, Marcus David Cole
Doctoral Dissertations
This dissertation describes the synthesis and characterization of functional optoelectronically active materials. Synthetic techniques were used to prepare polymers containing perylene diimide (PDI) or tetraphenylethylene (TPE) moieties in the polymer backbone. PDI-based structures were prepared with embedded cationic or zwitterionic moieties intended to tailor organic/inorganic interfaces in thin film photovoltaic devices. The aggregation-induced emission (AIE)-active TPE polymers were synthesized to study how AIE properties evolve in π-conjugated polymers. The syntheses discussed here focused on modulation of molecular architecture to give rise to materials with tailored optoelectronic properties. Chapter 1 provides a brief overview of the field of organic electronics and …
Bandwidth Bounds Of Infinite Planar Array Elements, Hsieh-Chi Chang
Bandwidth Bounds Of Infinite Planar Array Elements, Hsieh-Chi Chang
Doctoral Dissertations
For elements of an infinite planar phased array in free space and an infinite conductor-backed free standing planar phased array, fundamental bandwidth bounds are derived from the optical theorem for periodic scatterers. The bounds are based on Gustafsson’s theory of fundamental bandwidth limits for electrically small antennas of arbitrary shape, but extended to periodic configurations. The element bandwidth bound is found to be a function of the strengths of the induced static dipole moments in constant background fields as well as the unit-cell dimensions and the scan angle. Explicit bandwidth bound expressions are found for narrowband and ultrawideband array cases. …
Qoe-Aware Content Distribution Systems For Adaptive Bitrate Video Streaming, Divyashri Bhat
Qoe-Aware Content Distribution Systems For Adaptive Bitrate Video Streaming, Divyashri Bhat
Doctoral Dissertations
A prodigious increase in video streaming content along with a simultaneous rise in end system capabilities has led to the proliferation of adaptive bit rate video streaming users in the Internet. Today, video streaming services range from Video-on-Demand services like traditional IP TV to more recent technologies such as immersive 3D experiences for live sports events. In order to meet the demands of these services, the multimedia and networking research community continues to strive toward efficiently delivering high quality content across the Internet while also trying to minimize content storage and delivery costs. The introduction of flexible and adaptable technologies …
Computational Modeling Of Laminated Veneer Bamboo (Lvb) Dowel Joints, Niloufar Khoshbakht
Computational Modeling Of Laminated Veneer Bamboo (Lvb) Dowel Joints, Niloufar Khoshbakht
Doctoral Dissertations
Laminated veneer bamboo (LVB) is a sustainable building material that has been gaining interest in the construction industry of late. As a relatively new product, little is known about its connection performance, specifically, its failure behavior in dowel type joints and possible similarities it may have to engineered wood products in terms of failure mechanisms. Research is needed to aid in the understanding of LVB dowel connection failure behavior and to quantify the failure mechanism and key factors associated with LVB dowel connection strength. Modeling, as conducted in this research, is a valuable tool to help devise safe standards and …