Engineering Commons^™

Mixed Surfactant Systems: Thermodynamics And Applications In Metal Oxide Imprinting, Suvid Joshi

Theses and Dissertations--Chemical and Materials Engineering

In this work we study mixtures of cationic surfactant (CTAB) and sugar based surfactant(s) (octyl beta-D-glucopyranoside (C8G1), dodecyl maltoside (C12G2) and octyl beta-D-xylopyranoside (C8X1)) to understand the non-ideal thermodynamic behavior of the mixtures of cationic and non-ionic surfactants in water and synthesis of imprinted materials. The thermodynamics of micellization, mixing and dilution of these systems are studied using Isothermal Titration Calorimetry (ITC) and the experimental data obtained are modeled with a pseudo-phase separation model with non-ideal mixing described by regular solution theory. It is shown that a model accounting for enthalpy of demicellization and enthalpy of dilution based on McMillan-Mayer …

Experimental And Modelling Evaluation Of Slagging Behaviour Of German Lignite, Martin Kaiser, Alexander Ilyushechkin

Coal Combustion and Gasification Products Journal Archive

The behaviour of mineral matter is important for the characterisation of coal for use in entrained-flow gasification technologies. We investigated four behavioural characteristics—ash fusion temperatures (AFT), slag viscosity versus temperature profiles, temperatures of critical viscosity (TCV), and slag phase compositions—of Rhenish lignite coal ash using laboratory and modelling tools. Our modelling of AFT using coal ash composition provided a wide range of data, with only one (modified) model demonstrating agreement with experimental data. Experimental slag viscosity data were obtained over a temperature range from 1200uC to 1500uC. Where relevant, TCV was also measured. Comparison of these data to the calculated …

Investigation Of Cardiac Electrophysiology In Human Ventricular Tissue, Kathleen Brownson

Theses and Dissertations--Biomedical Engineering

Individuals with cardiomyopathy are at higher risk to die from sudden cardiac arrest than those with non-failing (NF) hearts. This study examined the differences in electrical properties of failing and NF human hearts in terms of cardiac memory through explicit control of diastolic intervals in a sinusoidal fashion, restitution of action potential duration (APD) through standard and dynamic pacing protocols, maximum rate of depolarization and APD alternans. Recordings of transmembrane potentials were made in tissues extracted from patients with heart failure and one donor NF heart. Computational simulations were performed using the O’Hara Rudy model for generating surrogates of control …

Active Current Injection Method For Limiting Ground Fault Current Harmonics In Underground Coal Mines, Yigong Zhang

Theses and Dissertations--Mining Engineering

Current practice in U.S. underground coal mine high-voltage distribution systems is to attempt to limit ground fault current to 25 Amperes and de-energize the circuit at 10 Amperes. However, the significant amount of system capacitance due to the use of shielded cables can cause ground fault current to be two or three times the intended ground fault limit. Consequently, this practice can cause several issues such as ground fault currents significantly exceeding the neutral grounding resistor current limit, loss of relay selectivity in the distribution system, and transient overvoltages in certain ground fault situations. These issues are solved to some …

Tacot V3.0, Jean Lachaud, Tom Van Eekelen, Daniele Bianchi, Alexandre Martin

Ablation Workshop: Code Comparison

No abstract provided.

The Effects Of Body Armor On Lower Back And Knee Biomechanics During Basic And Military Inspired Tasks, Megan P. Phillips

Theses and Dissertations--Biomedical Engineering

With increased military personal protection equipment, body armor, comes the addition of carried load. Such person protection in recent history has been instrumental in combating the imminent threats (e.g., improvised explosive devices) of hostile environments, preventing otherwise lethal injuries. However, body armor has been suggested to degrade warfighters’ performance and compound the risk of musculoskeletal injuries. Both performance and risk of injury are intensely related to joint biomechanics. Therefore the objective of this project was set to determine the immediate and prolonged effects of wearing body armor on biomechanics of the lower back and knee. A randomized cross-over study design, …

Fly Ash As A Potential Scrubber Of Acidic Wastes From The Phosphate Industries In Israel, Roy Nir Lieberman, Eli Lederman, Ithamar Pelly, Haim Cohen

Coal Combustion and Gasification Products Journal Archive

Fly ash (FA) is produced in Israeli utilities via bituminous coal combustion. It is used as a cement additive or in concrete production, and its economic value is low. The FA produced in Israel is very basic (defined as class F) owing to ambient air quality standards that impose low sulfur content in the imported coals. Because the lime content is high (in the South African coal, ,10 wt%), it is a good potential chemical scrubber to acidic wastes. The phosphate industry in Israel produces mainly phosphate fertilizers and water-treatment products as well as phosphoric acid. The production methods rely …

Geochemistry And Mineralogy Of Coal-Fired Circulating Fluidized Bed Combustion Fly Ashes, Luis F.O. Silva, Marcos L.S. Oliveira, Rubens M. Kautzmann, Claudete G. Ramos, Maria Izquierdo, Shifeng Dai, Jennifer Wilcox, Jeremy Hoffman, James C. Hower

Coal Combustion and Gasification Products Journal Archive

The fuel, bed ash, and fly ash were sampled from a circulating fluidized bed combustion (CFBC) unit at two times. The first sampling was a high-sulfur (S) coal-only run, and the second sampling coincided with an experimental burn of up to 10% switchgrass (Panicum virgatum) pressed pellets mixed with a high-S coal. The latter blend had a higher moisture content and a lower heating value than the coal-only fuel. Given the time between the samplings and the special needs for the experimental run, unavoidable changes in the coal and limestone complicate comparisons of the bed ash and fly ash chemistry …

Kentucky Water Resources Research Institute Annual Technical Report Fy 2013, Kentucky Water Resources Research Institute, University Of Kentucky

KWRRI Annual Technical Reports (USGS’s 104b Grant Program)

The FY 2013 Annual Technical Report for Kentucky consolidates reporting requirements of the Section 104(b) base grant award into a single document that includes: 1) a description of Kentucky Information Transfer activities, 2) citations for related publications, 3) a summary of student support during the reporting period, 4) notable awards and achievements during the year, and 5) publications from prior year projects.

No funds were requested for general program administration activities. However, travel funds were provided to support the participation of the Director and the Associate Director in the annual meeting of the National Institutes for Water Resources in Washington, …

A Tutorial On Learning Human Welder's Behavior: Sensing, Modeling, And Control, Y. K. Liu, W. J. Zhang, Yu Ming Zhang

Electrical and Computer Engineering Faculty Publications

Human welder's experiences and skills are critical for producing quality welds in manual GTAW process. Learning human welder's behavior can help develop next generation intelligent welding machines and train welders faster. In this tutorial paper, various aspects of mechanizing the welder's intelligence are surveyed, including sensing of the weld pool, modeling of the welder's adjustments and this model-based control approach. Specifically, different sensing methods of the weld pool are reviewed and a novel 3D vision-based sensing system developed at University of Kentucky is introduced. Characterization of the weld pool is performed and human intelligent model is constructed, including an extensive …

Transition Zone Design Final Report, Nikiforos Stamatiadis, Adam J. Kirk, Andrea Cull, Austin Dahlem

Kentucky Transportation Center Research Report

The purpose of this report is to document the activities of the research effort and present the findings of the work accomplished. Transition zone is the area in which it is communicated to drivers that the roadway environment is changing (i.e., from rural to built-up) and that their speed should change as well. This study evaluated treatments that could advise drivers to this. Based on the study findings, it is recommended to add additional speed warning sites to such transition zones.

Ultra Clean Coal Production Using Dense Medium Separation For The Silicon Market, Seyed Hassan Amini

Theses and Dissertations--Mining Engineering

The production of high quality silicon requires the use of ultraclean coal containing less than 1.5% ash. The magnetite used to clean the coal in a dense medium process is a contaminant that seriously impacts the quality of the final silicon product. As such, research has been conducted to evaluate the potential to substitute the magnetite with fine silica–based alternative material generated during the silicon production process. Dense medium cyclone tests were performed based on a statistically designed program to determine the optimum conditions that maximize organic efficiency and minimize probable error and low–density bypass. The results revealed that a …

Status Of Communication And Tracking Technologies In Underground Coal Mines, Alexander D. Douglas

Theses and Dissertations--Mining Engineering

In 2006, Congress passed the MINER Act requiring mine operators to submit an emergency response plan that included post-accident communications and tracking systems to MSHA within three years of the Act. These systems were required to be designed for maximum survivability after a catastrophic event, such as a fire or explosion, and to be permissible (meets MSHA criteria for explosion-proof). At that time, no commercially available systems existed that met these standards. Several companies undertook developing new, or enhancing existing, technologies to meet these requirements. This research presents the results of a study that was conducted to determine the present …

The Effect Of Various Pathologies On Bone Quality, Daniel S. Porter

Theses and Dissertations--Biomedical Engineering

Bone’s ability to resist fracture is often ignored until a low-energy fracture occurs. Patients with Chronic Kidney Disease (CKD) or osteoporosis are at an increased risk of low-energy fracture. Generally, fracture risk is evaluated by using a bone mineral density (BMD) test. BMD values; however, do not fully predict bone’s ability to resist fracture. This suggests that other parameters may be involved. Bone quality is the term used to describe these parameters, which are categorized into three groups: structural, material, and microdamage. The aim of this dissertation research was to examine whether bone quality was altered in patients who: 1) …

Trends In Coal Utilization And Coal Combustion Product Production In Kentucky: Results Of The 2012 Survey Of Power Plants, James C. Hower, Gerald A. Thomas, Shelley G. Hopps

Coal Combustion and Gasification Products Journal Archive

The University of Kentucky Center for Applied Energy Research has conducted a survey of Kentucky’s utility coal-fired power plants every 5 years since 1992. The survey includes a collection of the feed coal and the coal combustion products (CCPs). The latest collection was in 2012, with the accompanying information survey covering trends in 2011. Overall coal-fired energy production decreased, and the nature of the CCPs changed for a number of reasons, including but not limited to, increased gas production in the Appalachians, a series of warm winters, energy conservation, depletion of Appalachian coal reserves, and utility responses to regulations. From …

Modification Of Plasmonic Nano Structures' Absorption And Scattering Under Evanescent Wave Illumination Above Optical Waveguides Or With The Presence Of Different Material Nano Scale Atomic Force Microscope Tips, Gazi Mostafa Huda

Theses and Dissertations--Electrical and Computer Engineering

The interaction of an evanescent wave and plasmonic nanostructures are simulated in Finite Element Method. Specifically, the optical absorption cross section (C_abs) of a silver nanoparticle (AgNP) and a gold nanoparticle (AuNP) in the presence of metallic (gold) and dielectric (silicon) atomic force microscope (AFM) probes are numerically calculated in COMSOL. The system was illuminated by a transverse magnetic polarized, total internally reflected (TIR) waves or propagating surface plasmon (SP) wave. Both material nanoscale probes localize and enhance the field between the apex of the tip and the particle. Based on the absorption cross section equation the author …

Quantifiying The Effectiveness Of A Grout Curtain Using A Laboratory-Scale Physical Model, Elliot N. Magoto

Theses and Dissertations--Civil Engineering

In the past decade, the grouting industry has made significant technological advancements in real-time monitoring of flow rate and pressure of pumped grout, stable grout mix design, and with grout curtain concepts dealing with placement and orientation. While these practices have resulted in improved construction practices in the grouting industry, current design guidelines for grout curtains are still predominately based on qualitative measures such as engineering judgment and experience or are based on proprietary methods. This research focused on the development of quantitative guidelines to evaluate the effectiveness of a grout curtain in porous media using piezometric and hydraulic flow …

Pretreatment Of Scenedesmus Sp. Biomass As A Potential Anaerobic Digestion Substrate, Xinyi E, Czarena Crofcheck

Biosystems and Agricultural Engineering Faculty Publications

Algal biomass can be a potential substrate for anaerobic digestion. However, raw algae cells show a resistance to biological degradation, resulting in a slower methane production rate. Varying thermal and chemical pretreatments of algal biomass were investigated in an attempt to increase soluble organic matter (SOM) yield, which would result in enhanced methane production during subsequent anaerobic digestion. Scenedesmus sp. was harvested using three different procedures: with flocculation, with flocculation and drying, and without flocculation or drying. For all pretreatments and algae types, fluorescence micrographs were obtained to visually confirm the degradation of the algal cell walls. A complete 2 …

Human Cardiovascular Responses To Artificial Gravity Variables: Ground-Based Experimentation For Spaceflight Implementation, Mark Howarth

Theses and Dissertations--Biomedical Engineering

One countermeasure to cardiovascular spaceflight deconditioning being tested is the application of intermittent artificial gravity provided by centripetal acceleration of a human via centrifuge. However, artificial gravity protocols have not been optimized for the cardiovascular system, or any other physiological system for that matter. Before artificial gravity protocols can be optimized for the cardiovascular system, cardiovascular responses to the variables of artificial gravity need to be quantified.

The research presented in this document is intended to determine how the artificial gravity variables, radius (gravity gradient) and lower limb exercise, affect cardiovascular responses during centrifugation. Net fluid (blood) shifts between body …

Development Of A Moldable Composite Bone Graft Substitute Releasing Antibacterial And Osteogenic Drugs, Matthew E. Brown

Theses and Dissertations--Biomedical Engineering

Large infected bone defects (IBD) are very complicated to treat due to their high variability; they often require multiple procedures. Bone autografts are the gold standard for treatment but have several drawbacks, such as a need for a second surgery site, limited grafting material, and donor site morbidity. The objective of this research was to develop a moldable synthetic bone grafting material capable of releasing both antimicrobial and osteogenic drugs over a clinically relevant time course for the treatment of IBDs. Current treatment methods for large IBDs require two separate procedures to treat the bone defect and the infection.

This …

Control Of The Surficial Fine-Grained Laminae Upon Stream Carbon And Nitrogen Cycles, William I. Ford Iii

Theses and Dissertations--Civil Engineering

This dissertation investigated the impact of the Surficial Fine-Grained Laminae (SFGL) upon stream biogeochemical cycles to constrain stream C and N budgets. Collection and analysis of 8 years of transported sediment elemental and isotopic signatures, weekly, from a SFGL dominated stream, a novel dissolved C and N dataset, statistical and time-series analysis of sediment and dissolved data, and development of a comprehensive modeling framework that couples hydrodynamics, sediment, C and N biogeochemistry, and stable isotope sub-models to simulate fluvial C and N budgets was used. SFGL C modeling suggests benthic particulate C stocks and transport vary seasonally and annually but …

Deformation And Shear Behaviors Of Weathered Compacted Shale, Xu Zhang

Theses and Dissertations--Civil Engineering

As an abundant sedimentary rock, shale is widely used as construction material around the world. However, shale is a fissile and laminated material and is therefore subject to deterioration due to environmental and chemical forces (i.e., weathering), which is possible to cause high maintenance cost on associated structures and failures of earth slopes and embankments. However, currently, there is lack of efficient method to monitor the weathering process of shale. This thesis uses several shale samples collected from the commonwealth of Kentucky to study the deformation and shear behaviors of weathered compacted shale. A new electrical approach was developed to …

Development Of Indirect Ring Tension Test For Fracture Characterization Of Asphalt Mixtures, Alireza Zeinali Siavashani

Theses and Dissertations--Civil Engineering

Low temperature cracking is a major distress in asphalt pavements. Several test configurations have been introduced to characterize the fracture properties of hot mix (HMA); however, most are considered to be research tools due to the complexity of the test methods or equipment. This dissertation describes the development of the indirect ring tension (IRT) fracture test for HMA, which was designed to be an effective and user-friendly test that could be deployed at the Department of Transportation level. The primary advantages of this innovative and yet practical test include: relatively large fracture surface test zone, simplicity of the specimen geometry, …

The Study Of Trunk Mechanical And Neuromuscular Behaviors, Brian D. Koch

Theses and Dissertations--Biomedical Engineering

Low back pain (LBP) is a common ailment in the United States, affecting up to 80% of adults at least once in their lifetime. Although 90% of LBP cases are considered nonspecific, recent studies show that abnormal mechanics of the lower back can be a major factor. One method of assessing the lower back mechanical environment is through perturbation experiments. An intensive literature review of perturbation systems was used to select and develop a system for the Human Musculoskeletal Biomechanics Lab (HMBL). Following construction, individuals with high/low exposure to day-long physical activity were assessed to quantify daily changes in their …

Stabilization Of Extended Diffuse Optical Spectroscopy Measurements On In Vivo Human Skeletal Muscle During Dynamic Exercise, Brad A. Henry

Theses and Dissertations--Biomedical Engineering

This research investigates various applications of diffuse correlation spectroscopy (DCS) on in-vivo human muscle tissue, both at rest and during dynamic exercise. Previously suspected muscle tissue relative blood flow (rBF) baseline shift during extended measurement with DCS and DCS-Near infrared spectroscopy (NIRS) hybrid optical systems are verified, quantified, and resolved by redesign of optical probe and alteration in optical probe attachment methodology during 40 minute supine bed rest baseline measurements. We then translate previously developed occlusion techniques, whereby rBF and relative oxygen consumption rV̇O₂ are calibrated to initial resting absolute values by use of a venous occlusion (VO) and …

Calibration Of Non-Nuclear Devices For Construction Quality Control Of Compacted Soils, Joshua E. R. Wells

Theses and Dissertations--Civil Engineering

Inadequate compaction of a soil subgrade can lead to detrimental outcomes that are not only costly but dangerous to the general public. To avoid this, quality control (QC) devices such as the nuclear density gauge (NDG) are currently being used to monitor the compaction and moisture content of soil subgrades. However, regulatory concerns associated with the NDG have encouraged federal and state agencies, as well as the heavy civil construction industry to consider non-nuclear devices for QC testing of compacted soils. One such non-nuclear device is the Soil Density Gauge (SDG), which utilizes electromagnetic wave propagation to obtain soil properties …

Bioerodible Calcium Sulfate Bone Grafting Substitutes With Tailored Drug Delivery Capabilities, Bryan R. Orellana

Theses and Dissertations--Biomedical Engineering

Bone regeneration or augmentation is often required prior to or concomitant with implant placement. With the limitations of many existing technologies, a biologically compatible synthetic bone grafting substitute that is osteogenic, bioerodible, and provides spacing-making functionality while acting as a drug delivery vehicle for bioactive molecules could provide an alternative to ‘gold standard’ techniques.

In the first part of this work, calcium sulfate (CS) space-making synthetic bone grafts with uniformly embedded poly(β-amino ester) (PBAE) biodegradable hydrogel particles was developed to allow controlled release of bioactive agents. The embedded gel particles’ influence on the physical and chemical characteristics of CS was …

Development Of Cementitious Materials For Adhesion Type Applications Comprising Calcium Sulfoaluminate (Csa) Cement And Latex Polymer, Joshua V. Brien

Theses and Dissertations--Civil Engineering

The objective of this research was to develop high performing polymer modified calcium sulfoaluminate (CSA) cement materials for use in applications requiring superior adhesion characteristics. Little information is available describing interactions of CSA cement containing minor phase tri-calcium aluminate (C₃A) with commonly used admixtures. Given the scarcity of information, a basic approach for developing cementitious materials was followed. The basic approach consisted of four tasks: cement design, admixture design, polymer design and testing developed materials. The iterative, time consuming process is necessary for understanding the influence of specific constituent components on overall system behavior. Results from the cement …

Mucoadhesive Films For Treatment Of Local Oral Disorders: Development, Characterization And In Vivo Testing, Sandeep K. Ramineni

Theses and Dissertations--Biomedical Engineering

Mucoadhesive drug delivery systems which are being used from 1980’s to avoid first pass metabolism of drugs, commercially exist for only systemic drug delivery with fast erosion times (15-60 min), that may not be appropriate for local oral disorders. The goal of this research was to develop and characterize mucoadhesive films with flexibility of carrying different drugs and proteins and provide sustained release for local treatment of oral disorders.

Mucoadhesive films composed of polyvinylpyrrolidone (PVP) and carboxymethlycellulose (CMC) were formulated with imiquimod, an immune response modifier. Problems such as solubilization of imiquimod to increase drug loading, uniformity in films and …

Precise Control Of Carbon Nanotube Membrane Structure For Enzyme Mimetic Catalysis, Nicholas W. Linck

Theses and Dissertations--Chemical and Materials Engineering

The ability to fabricate a charge-driven water pump is a crucial step toward mimicking the catalytic ability of natural enzyme systems. The first step towards making this water pump a reality is the ability to make a carbon nanotube (CNT) membrane with uniform, 0.8 nm pore diameter. Proposed in this work is a method for synthesizing these carbon nanotubes via VPI-5 zeolite templated, transition metal catalyzed pyrolysis. Using a membrane composed of these CNTs, it is possible to get water molecules to flow single file at a high flow rate, and to orient them in such a way that would …