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Articles 2851 - 2880 of 2901
Full-Text Articles in Engineering
Electrodeposition Of Copper Indium Sulfide Films From Organic Solutions, Arif Raza, Robert Engelken, Brandon Kemp, Imran Khan, Wasim Aleem, Chris Barber
Electrodeposition Of Copper Indium Sulfide Films From Organic Solutions, Arif Raza, Robert Engelken, Brandon Kemp, Imran Khan, Wasim Aleem, Chris Barber
Journal of the Arkansas Academy of Science
We report on organic solutions ofCuCl 2 ,InClg, and elemental sulfur for electrodepositing CuIn x Sv films. CuInS 2 and CuInSe 2 are promising solar cellmaterials; our work on CuInSg prefaces planned work on plating CuInSe 2 from nonaqueous solvents. Two promising solvent systems are (1) mixed propylcne carbonate and water and (2) mixed ethylene glycol, propionic acid, and water (Engelken et al., 1988). Gray-brown films ofCuInx Sy (nominally GuInS2 ) have been plated from both baths. Major problems include (1) reduction ofCu+2 to Cu and Cu x S by the solvent at high temperatures (T>l()0°C), hence depleting Cu+2,(2) …
Characterization Of Cadmium Sulfide Films Deposited By Chemical Bath Method, Quazi Galib Samdami, Hameed A. Naseem, W. D. Brown
Characterization Of Cadmium Sulfide Films Deposited By Chemical Bath Method, Quazi Galib Samdami, Hameed A. Naseem, W. D. Brown
Journal of the Arkansas Academy of Science
Thin filmcadmium sulfide is a leading candidate in the fabrication of large area solar cells. The chemical bath deposition method is one of the least expensive sources for the fabrication of device quality cadmium sulfide thin films.Inthe present work, the deposition of CdS films on glass substrate from an aqueous solution containing cadmium acetate, ammonia, ammonium acetate, and thiourea are investigated. The structural properties of CdS films are characterized. Good quality thin films within 0.1 - o.5 |im thickness were obtained in30 minute deposition time, and at 70*-90*C. The films show preferential orientations. The optical transmittance of the films are …
Molten Salt Electrolytes For Electrodeposition Of Cdte Films, Arif Raza, Robert Engelken, Brandon Kemp, Arees Siddiqui, Omer Mustafa
Molten Salt Electrolytes For Electrodeposition Of Cdte Films, Arif Raza, Robert Engelken, Brandon Kemp, Arees Siddiqui, Omer Mustafa
Journal of the Arkansas Academy of Science
We report preliminary investigation of several molten salt electrolytes containing CdCl2 and TeCl4 for the electrodeposition of CdTe films at temperatures well above (>250 °C) those used with aqueous and organic electrolytes. These high temperatures have potential todramatically increase the crystallite size (Poole, Engelken, et al., 1994), as is important for optoelectronic device applications of CdTe, a leading II-VIsemiconductor. This paper willsurvey the results obtained withelectrolytes such as B2O,/HBO2 (m.p. - 230'C), NaCH3COO (m.p. » 324°C), ZnCl2 (m.p. - 283*C), and LiCl/KCl (m.p. * 350 °C), with an emphasis on the latter two. Key material to be presented includes …
Polishing Of Cvd-Diamond Substrates Using Reactive Ion Etching, Gopi M.R. Sirineni, Hameed A. Naseem, W. D. Brown, A. P. Malshe
Polishing Of Cvd-Diamond Substrates Using Reactive Ion Etching, Gopi M.R. Sirineni, Hameed A. Naseem, W. D. Brown, A. P. Malshe
Journal of the Arkansas Academy of Science
Multichip modules (MCM)have proved to be a viable packaging technology for achieving small size and high performance. By their nature, MCMs typically integrate multiple bare die into a module that can be the plastic or ceramic package. As a result, the MCMrequires an efficient mechanism for removing excess heat. Diamond with its excellent thermal conductivity, is the ideal choice as a substrate material for these applications. Chemical vapor deposited (CVD) diamond substrates makes possible the practical realization of a novel diamond based 3-D MCM. However, the diamond films grown by CVD technique are polycrystalline and have non-uniform filmroughness and randomly …
Diagnostics Of Cdte Electrodeposition By Rest Potential Voltammetry, Brandon Kemp, Robert Engelken, Arif Raza, Arees Siddiqui, Omer Mustafa
Diagnostics Of Cdte Electrodeposition By Rest Potential Voltammetry, Brandon Kemp, Robert Engelken, Arif Raza, Arees Siddiqui, Omer Mustafa
Journal of the Arkansas Academy of Science
Due to the extreme sensitivity of the partial elemental currents (i.e.,iCd, iTe) and, hence, stoichiometry to deposition voltage, temperature, mass transport, and ambient light intensity during electrodeposition of semiconductor films, it is important to implement in-situ methods for monitoring the stoichiometry and related semiconductor efficacy of the growing film. We report investigation of open circuit rest potential (Eoc) voltammetry as one such method during electrodeposition of CdTe from aprotic electrolytes such as ethylene glycol. Plots of transient open circuit potential versus sweep voltage exhibit distinct transition and plateau structures corresponding to Te, CdTe, and Cd phases and correlating with the …
Construction Resource Allocation Using A Genetic Algorithm, Siripong Malasri, Jennifer R. Martin
Construction Resource Allocation Using A Genetic Algorithm, Siripong Malasri, Jennifer R. Martin
Journal of the Arkansas Academy of Science
A proper allocation of limited resources (men, machines, materials, and money) is critical in a construction project. Traditionally, resource allocation problems have been solved using methods in operations research (OR), such as mathematical programming. In recent years, genetic algorithms (GA) have emerged as an effective optimization methodology. One major advantage of the GA approach over the OR approach is that the GA approach is universal for various types of optimization problems, unlike the OR approach which varies depending on the types of problems at hand. This paper shows an application of GA to a resource allocation problem in the construction …
Retrieval Of Atmospheric Turbidity Coefficiant And Water Column Density Fro Solar Irradiance Data, Felix Tendeku
Retrieval Of Atmospheric Turbidity Coefficiant And Water Column Density Fro Solar Irradiance Data, Felix Tendeku
Journal of the Arkansas Academy of Science
Ground-based measurement of solar irradiance has been made using a spectroradiometer at wavelengths inapx-water absorption band. An algorithm is formulated to retrieve simultaneously the atmospheic water column density and Angstrom's turbidity coefficient. The transmission models used to account for the contribution from diverse atmospheic absorbing and scattering elements are presented.
Concrete Beam Design Optimization With Genetic Algorithms, Siripong Malasri, D. A. Halijan, M. L. Keough
Concrete Beam Design Optimization With Genetic Algorithms, Siripong Malasri, D. A. Halijan, M. L. Keough
Journal of the Arkansas Academy of Science
This paper demonstrates an application of the natural selection process to the design of structural members. Reinforced concrete beam design is used as the example to show how various chromosomes representing a design solution can be formulated. Fitter chromosomes (or better solutions) have a better chance of being selected for cross over; this in turn creates better generations. Random mutation is used to enhance the diversity of the population. The evolution progresses through several generations, and the best solution is then used in the design. The method gives reasonable results, but sometimes a local (as opposed to the global) optimized …
Application Of Machine Learning Principles To Modeling Of Nonlinear Dynamic Systems, Murray R. Clark
Application Of Machine Learning Principles To Modeling Of Nonlinear Dynamic Systems, Murray R. Clark
Journal of the Arkansas Academy of Science
A method for the development of mathematical models for dynamic systems with arbitrary nonlinearities from measured data is described. The method involves the use of neural networks as embedded processors in dynamic system simulation models. The technique is demonstrated through generation of models for anharmonic oscillators described by the Duffing Equation and the Van der Pol Equation from measured input/output data. It is shown that high quality models of these systems can be developed using this technique which are efficient in terms of model size. Using neural networks as embedded processors, accurate models of the Duffing Oscillator and the Van …
Method For Determining Atmospheric Aerosol Optical Depth Using Solar Transmission Measurements, Felix Tendeku
Method For Determining Atmospheric Aerosol Optical Depth Using Solar Transmission Measurements, Felix Tendeku
Journal of the Arkansas Academy of Science
A multiple wavelength radiometer instrumentation has been developed and used to measure solar irradiance in a water vapor absorption band in the near-infrared region. From these measurements the total atmospheric optical depth at each wavelength of observation is deduced using a linear least-squares fitting method. An iteration technique, based on a power law wavelength dependence of aerosol optical depth, is employed to retrieve aerosol optical depth from the total optical depth data. The technique permits simultaneous determination of precipitable water vapor amount.
Solid State Nmr Of Hydrogen In Thin Film Synthetic Diamond, G. Burnside, Roger M. Hawk, Richard A. Komoroski, W. D. Brown
Solid State Nmr Of Hydrogen In Thin Film Synthetic Diamond, G. Burnside, Roger M. Hawk, Richard A. Komoroski, W. D. Brown
Journal of the Arkansas Academy of Science
Thin film synthetic diamond promises to be the next semiconductor material, if the manufacturing processes which produce it can be controlled. Solid state nuclear magnetic resonance (NMR) using magic angle spinning (MAS) is used to measure the content of hydrogen in diamond which controls the resistivity of the diamond thin films. Spectral results are presented for proton NMR of thin film synthetic diamond. Experimental calibration techniques using BaF2 as the hydrogen standard will be discussed, as well as acquisition times, pulsing sequences, spinning rates, and rotor composition.
Comparison Of High-Temperature Superconductors In Multi-Chip Module Applications, D. E. Ford, S. S. Scott, S. S. Ang, W. D. Brown
Comparison Of High-Temperature Superconductors In Multi-Chip Module Applications, D. E. Ford, S. S. Scott, S. S. Ang, W. D. Brown
Journal of the Arkansas Academy of Science
In the application of high-temperature superconductors (HTSCs) in multi-chip module (MCM) technology, it is first necessary to investigate the advantages and disadvantages of the various HTSC compounds. The standard criteria for comparing the suitability of HTSCs in electronics applications has been critical temperature (Tc )and critical current density (Jc ). It is also necessary to consider the physical properties of HTSCs in relation to the various processing techniques required in fabrication of MCMs. These techniques can be grouped into four main areas: deposition, patterning, packaging, and characterization. The four main HTSC materials, Y-Ba-Cu-O, Bi-Sr-Ca-Cu-O, Tl,Ba-Ca-Cu-O and Hg-Ba-Ca-Cu-O, will be compared …
Using The Cern Program-Library Graphics And Interactive Data Display, Morgan T. Burks, Wilson H. Howe, Christine A. Byrd, Wilfred J. Braithwaite
Using The Cern Program-Library Graphics And Interactive Data Display, Morgan T. Burks, Wilson H. Howe, Christine A. Byrd, Wilfred J. Braithwaite
Journal of the Arkansas Academy of Science
Small scale Monte Carlo programming is growing rapidly due to the ease with which complex problems may be formulated by any programmer. These programmers may choose to exploit graphics and interactive displays available in the program library developed and maintained by CERN (the Center for European Nuclear Research). This paper outlines the use of graphics and interactive data display features of the CERN program library, developed for visualizing simulated data events in particle detectors. One example uses GEANT, CERN's Monte Carlo modeling program, to simulate 300 MeV/c protons incident on a silicon slab. Display packages for GEANT are available both …
Reaction Of Titanocene Dichloride With Acetylenedicarboxylate, Tanya L. Hagler, Mark Draganjac, Paul M. Nave, J. Ed Bennett, Farooq Kahn, Robert Engelken, Gerard Williams, Chris Poole, Kwok Fai Yu
Reaction Of Titanocene Dichloride With Acetylenedicarboxylate, Tanya L. Hagler, Mark Draganjac, Paul M. Nave, J. Ed Bennett, Farooq Kahn, Robert Engelken, Gerard Williams, Chris Poole, Kwok Fai Yu
Journal of the Arkansas Academy of Science
The reaction of Cp2TiCl2 with either the mono- or dipotassium salt of acetylenedicarboxylic acid (ADC) gives high yields of an insoluble orange product. The insoluble compound shows potential semiconductor behavior, as evidenced by an apparent bandgap in the orange region of the visible spectrum. Under N2 ,the compound decomposes at 238° C, eventually losing approximately 46% total mass up to 1350° C. The exothermic decomposition in air, beginning at 235° C, results in the formation of titanium oxides.
Gamma Ray Emissions From Binary Pulsar Systems, Tony A. Hall, Andrew T. Sustich
Gamma Ray Emissions From Binary Pulsar Systems, Tony A. Hall, Andrew T. Sustich
Journal of the Arkansas Academy of Science
A method is developed for estimating the gamma ray flux impinging upon the earth from production in binary pulsar systems. We calculate production of the 6.13 MeV gamma ray line characteristic of 16O. These are produced by protons emitted by the pulsar interacting with 16O atoms at the surface of the companion. We examine different types of companion stars and estimate the gamma ray flux at the earth as a function of proton emission from the pulsar and distance from the earth. Prospects for detection from earth are discussed.
Tetraethylene Gycol-Based Electrolytes For High Temperature Electrodeposition Of Compound Semiconductors, Chris Poole, Robert Engelken, Brandon Kemp, Jason Brannen
Tetraethylene Gycol-Based Electrolytes For High Temperature Electrodeposition Of Compound Semiconductors, Chris Poole, Robert Engelken, Brandon Kemp, Jason Brannen
Journal of the Arkansas Academy of Science
We report an investigation of tetraethylene glycol (TEG) solutions of chloride salts (CdCl2 ,TeCl4 ,and HgCl2 ) for electrodeposition of films of CdTe and Hg1.xCdxTe, leading II-VI semiconductors. The high boiling point (314°C), below-room temperature (T) (-6°C) melting point, adequate metal chloride solubilities, and low toxicity of TEG make it a good candidate for electrodeposition at T > 200°C. Such temperatures tend to activate growth of larger crystallites than with aqueous electrolytes at T< 100 °C, as are advantageous in optoelectronic applications. Initial results do, indeed, indicate a dramatic increase in crystallinity with deposition temperature, especially for the CdTe films which are nearly amorphous when grown at room temperature. Hg1.xCdxTe films (x< 0.5) are marginally polycrystalline when grown at room temperature but also improve in crystallinity at higher growth temperatures. There appears to be a strong decrease in film adherence and uniformity as growth temperature increases for both materials probably because the greatly increased carrier concentrations at higher temperatures increase film conductivity which, in turn, supports easy electroplating of protruding loose dendritic and/or columnar crystallites, instead of the monolayer-by monolayer growth of lower conductivity material as occurs at lower temperatures, especially in the higher bandgap/lower conductivity CdTe. The same increase in film conductivity with temperature is responsible for the decrease in the relative photosensitivity of both the CdTe and Hg1.x CdxTe with temperature. At all temperatures, the inferior adherence, uniformity, and photosensitivity as well as the superior crystallinity of Hg1.xCd xTe over that of the CdTe are also explained by its lower bandgap and higher conductivity. On balance, however, the initial results prove the utility of high temperature TEG electrolytes for electrodepositing CdTe and Hg1.xCdxTe films with much better crystallinity than for those grown at lower temperatures, notably in aqueous baths.
Evaluation Of Photodiode Arrays For Use In Rocket Plume Monitoring And Diagnostics, Dallas Snider, M. Keith Hudson, Robert B. Shanks, Reagan Cole
Evaluation Of Photodiode Arrays For Use In Rocket Plume Monitoring And Diagnostics, Dallas Snider, M. Keith Hudson, Robert B. Shanks, Reagan Cole
Journal of the Arkansas Academy of Science
The spectroscopic analysis of plume emissions is a non-intrusive method which has been used to check for fatigue and possible damage throughout the pumps and other mechanisms in a rocket motor or engine. These components are made of various alloys. Knowing the composition of the alloys and for which parts they are used, one can potentially determine from the emissions in the plume which component is failing. Currently, Optical Multichannel Analyzer systems are being used which utilize charge coupled devices, cost tens of thousands of dollars, are somewhat delicate, and usually require cooling. We have developed two rugged instruments using …
Multiple Sample Cryostat For The Determination Of Superconductor Properties, G. Burnside, Roger M. Hawk, Paul C. Mcleod
Multiple Sample Cryostat For The Determination Of Superconductor Properties, G. Burnside, Roger M. Hawk, Paul C. Mcleod
Journal of the Arkansas Academy of Science
Cryostats which are currently used to characterize the properties of superconductors between 4 K and 100 K are primarily single sample devices. The purpose of this paper is to present an instrument design which can hold up to five (5) one cm. diameter samples at a stable temperature (+ /-0.1K) within the above range specified while measurements of the sample properties are made.
Sputter Deposition And Thallination Of Ti-Ba-Ca-Cu-O Superconducting Thin Films, T. H. Dhayagude, S. S. Ang, W. D. Brown
Sputter Deposition And Thallination Of Ti-Ba-Ca-Cu-O Superconducting Thin Films, T. H. Dhayagude, S. S. Ang, W. D. Brown
Journal of the Arkansas Academy of Science
Thallination techniques used for the fabrication of sputter-deposited TI2Ba2CaCu 2Ox and TI2Ba2Ca2Cu3Ox superconducting thin films were investigated. Differences in elemental composition of precursor Ba-Ca-Cu-O sputtering targets were found to yield different superconducting phases. Thallination conditions which yielded transition temperatures as high as 122 K for samples annealed in air are described. Finally, reactive ion etching of films using a mixture of chlorine and argon gases is discussed.
Computer Model For Predicting Aids Among Intravenous Drug Users, Daniel Berleant, R. Ron Goforth, Jun Yuan
Computer Model For Predicting Aids Among Intravenous Drug Users, Daniel Berleant, R. Ron Goforth, Jun Yuan
Journal of the Arkansas Academy of Science
Intravenous drug abuse (IVDA) is an important cause of HIV transmission. Computer simulation is one way to understand and predict the spread of HIV infection among IVDAs. We design and simulate HIV infection among IVDAs and the impact of AIDS on this community, and thereby predict future IVDA population, HIV levels, AIDS levels, and AIDS deaths in this group. The HIV to AIDS, and AIDS to Death latencies are described by probability density functions (PDFs) in this model. Factors such as the recruit, quit, and normal death rate of IVDAs, are considered, as well as the infection and removal rates …
Semi-Insulating Polysilicon Hetero- And Isotype Junctions On Silicon, R. M. Ranade, S. S. Ang, W. D. Brown
Semi-Insulating Polysilicon Hetero- And Isotype Junctions On Silicon, R. M. Ranade, S. S. Ang, W. D. Brown
Journal of the Arkansas Academy of Science
The effects of nitrogen trifluorideinthe gas stream during deposition of semi-insulating polysilicon (SIPOS) on the electrical characteristics of undoped (SIPSO)/p-Si, and n+-SIPOS/n-Si isotype junctions were investigated. The current-voltage characteristics of undoped SIPOS/p-Si heterojunctions exhibit a strong dependence on the oxygen content of the SIPOS film and depart from a hyperbolic sine behavior as the refractive index of the SIPOS increases.. The addition of nitrogen trifluoride decreases the current density of these undoped SIPOS/p-Si heterojunctions due presumably to the oxidation/hydrolysis of SiF species intoSiO2. The n+-SIPOS formed a rectifying isotype junction o n-Si. The forward current voltage characteristics exhibit two distinct …
Documented Aids Cases As The Basis For Projections Of Adolescence Hiv Infections In The Us, R. Ron Goforth, S. A. Goforth
Documented Aids Cases As The Basis For Projections Of Adolescence Hiv Infections In The Us, R. Ron Goforth, S. A. Goforth
Journal of the Arkansas Academy of Science
Twenty percent of AIDS cases in the U.S. occur in individuals in the age range 20 to 29. The mean incubation time, the time from infection to the onset of AIDS, is in the order of 8 years. Therefore, most of these AIDS cases represent HIV infections that occurred during mid- to late-adolescence. About 800 officially reported cases in the age group 13 to 19 have occurred in the U.S. This low occurrence of AIDS should not be a source of complacency in assessing the need to provide education and behavioral alternatives to this age group. As the predominate mode …
Application Of Stable Operating Criterion To Grating Tuned Strong External Feedback Semiconductor Lasers, Haiyin Sun, Malay K. Mazumder
Application Of Stable Operating Criterion To Grating Tuned Strong External Feedback Semiconductor Lasers, Haiyin Sun, Malay K. Mazumder
Journal of the Arkansas Academy of Science
Stability analysis is done by applying criterion dnQ((o)/cfco>0 for grating tuned strong external feedback semiconductor lasers. The resulting stable and unstable operating ranges agree well with experiment results.
Techniques For Efficiency Calibration Of Photon Detectors For X-Rays And Low Energy Gamma Rays, Rahul Mehta
Techniques For Efficiency Calibration Of Photon Detectors For X-Rays And Low Energy Gamma Rays, Rahul Mehta
Journal of the Arkansas Academy of Science
No abstract provided.
Measurement Of The Coefficient Of Thermal Expansion Of Superconducting Thin Films Using Powder X-Ray Diffraction, Biju Chandran, R. Calvin Goforth, S. Nasrazadani
Measurement Of The Coefficient Of Thermal Expansion Of Superconducting Thin Films Using Powder X-Ray Diffraction, Biju Chandran, R. Calvin Goforth, S. Nasrazadani
Journal of the Arkansas Academy of Science
The High Density Electronics Center (HiDEC) at the University of Arkansas, Fayetteville is developing the technology for High Temperature Superconductor Multi-Chip Modules (HTSC-MCM's). As part of this work, we are looking at the mechanical properties of HTSC materials. An important mechanical property which influences the mechanical integrity of the hybrid MCMis the coefficient of thermal expansion (CTE) of the HTSC films. As a first step in developing a procedure for the determination of the CTE of HTSC materials, the lattice parameters and the CTE of an alpha-alumina substrate have been determined by powder x-ray diffraction technique. An extension of this …
Properties Of Ruthenium Oxide Coatings, Roger M. Hawk, Kamesh V. Gadepally, David N. Patangia
Properties Of Ruthenium Oxide Coatings, Roger M. Hawk, Kamesh V. Gadepally, David N. Patangia
Journal of the Arkansas Academy of Science
Ruthenium oxide coatings have been deposited on titanium substrates using a flood coating process. These films were heat treated for varying times and temperatures. The resulting films subsequently were characterized by performing resistivity and SEM analyses. Resistivity of the ruthenium oxide coating was found to be extremely dependent upon the firing temperature. Effect of the process conditions and formulations of the coatings on the morphology with respect to their electrical characteristics is presented. Capacitors were fabricated using plates coated with ruthenium oxide coatings. Capacitance versus heat treatment temperatures are discussed and at one firing temperature (480'C), the capacitance was 50 …
Simple Synchronous Detector For Spectroscopic Studies, Mokhtar Mofidi, M. Keith Hudson, Reagan Cole, James D. Wilson
Simple Synchronous Detector For Spectroscopic Studies, Mokhtar Mofidi, M. Keith Hudson, Reagan Cole, James D. Wilson
Journal of the Arkansas Academy of Science
Lock-in-amplifiers are used in many applications for signal processing and offer the ability to discriminate high levels of noise. While these instruments are very powerful and offer many features, they are not portable and are expensive. An economical and easy to use alternative circuit is presented which incorporates pre-amplification, reference, and synchronous detection on one circuit board. The design can be used in laboratory or process control situations where its small size and low cost are advantageous. The circuit was successfully applied to moderate and high level signals as seen in flame infrared emission detection and in a portable radiometer …
Radiometer For The Investigation Of Infrared Emissions From Flames And Rocket Plumes, Kathy Underhill, M. Keith Hudson, Jason Willis, Mokhtar Mofidi, Matthew J. Russo
Radiometer For The Investigation Of Infrared Emissions From Flames And Rocket Plumes, Kathy Underhill, M. Keith Hudson, Jason Willis, Mokhtar Mofidi, Matthew J. Russo
Journal of the Arkansas Academy of Science
A prototypical radiometer using standard one inch interference filters and a lead selenide detector was constructed for use in flame and rocket plume studies. This radiometer was designed to employ a 600 Hz chopper and chopper frequency/phase reference circuit for signal processing. Bandpass filters centered for either 2.7 mum or 4.45 mum were placed in the optical path. The passed carbon dioxide or water vapor band energy irradiated the lead selenide detector, resulting in an output voltage. This signal was then fed into a dedicated synchronous detector. The signal was then recorded by a computer system equipped with an analog-to-digital …
Homogenous Functions In Thermodynamics, Stephen R. Addison
Homogenous Functions In Thermodynamics, Stephen R. Addison
Journal of the Arkansas Academy of Science
No abstract provided.
Data Acquisition And Control Program For Chromatography, M. Keith Hudson, William G. Hood
Data Acquisition And Control Program For Chromatography, M. Keith Hudson, William G. Hood
Journal of the Arkansas Academy of Science
No abstract provided.