Engineering Commons^™

Coal Fires: An Environmental Disaster, Lidsay Hoggatt

Chemical Engineering Undergraduate Honors Theses

The mission of the Coal Fire Gang (CFG) is to spread awareness about the global issue of uncontrolled coal fires, and to highlight them as a low-hanging fruit of immediate emissions reduction. This report summarizes CFG’s research for the WERC competition, for which this topic was chosen as an open task. Beyond raising awareness, CFG modeled, developed and built an experimentation apparatus meant to prove the validity of a relatively cheap extinguishing method which was also novel to the regions in which it could be employed. The apparatus, which simulated an underground coal fire, was used to test a sand …

Coal Fires - An Environmental Disaster, Nicholas Kordsmeier

Chemical Engineering Undergraduate Honors Theses

The mission of the Coal Fire Gang (CFG) is to spread awareness about the global issue of uncontrolled coal fires, and to highlight them as a low-hanging fruit of immediate emissions reduction. This report summarizes CFG’s research for the WERC competition, for which this topic was chosen as an open task. Beyond raising awareness, CFG modeled, developed and built an experimentation apparatus meant to prove the validity of a relatively cheap extinguishing method which was also novel to the regions in which it could be employed. The apparatus, which simulated an underground coal fire, was used to test a sand …

Expression, Purification, And Large-Scale Production Of The Human Recombinant Annexin-V Protein, Gayatri Suresh Kumar

Chemical Engineering Undergraduate Honors Theses

Annexin-V is a cytosolic protein involved in many significant physiological roles including stabilization of the phospholipid membrane, regulation of blood coagulation, and cell apoptosis or programmed cell death. Though the exact mechanism of Annexin-V in the human body is not fully understood, its wide range of applications in the medical field cannot be denied. Annexin-V can be applied in cancer therapy as a diagnostic to detect cell apoptosis and determine the effectiveness of chemotherapeutic drugs. Furthermore, Annexin-V could even be used as a drug delivery vehicle in the treatment of cancer. Commercially useful proteins like Annexin-V are in high demand, …

Water System For Developing Countries / Disaster Relief Made With Local Materials, Dong Joon Lee

Chemical Engineering Undergraduate Honors Theses

As the equipment builder of the team, I was responsible for building the treadle pump, the sand filter tank, the hand pump, and generating the instructions for each equipment. Each team member was responsible for certain parts of the water purification system, but everyone worked cohesively on all parts of the design when assistance was necessary. The original design for the treadle pump was a two-man powered pump which discharged water at 15 gallons per minute. Since our system only required less than half of the flow rate, and required another person to operate the bicycle, the pump was redesigned …

Water System For Developing Countries / Disaster Relief Made With Local Materials, Florencio Serrano Castillo

Chemical Engineering Undergraduate Honors Theses

The objective of this project was to design a water purification system that can be constructed from easily available materials, common to the particular country, and is capable of the complete water purification process. The designed system consisted of a treadle pump (built from wood or bamboo) to pull the water from its source, a filter (made of readily available materials such as sand) to remove contaminants and improve palatability of water, an electrolysis system to allow chlorination from salt water (using locally sourced salt), and a car battery (which could be sourced from a scrapped car) that could be …

Coal Fires: An Environmental Disaster, Turner Tomlinson

Chemical Engineering Undergraduate Honors Theses

The mission of the Coal Fire Gang (CFG) is to spread awareness about the global issue of uncontrolled coal fires, and to highlight them as a low-hanging fruit of immediate emissions reduction. This report summarizes CFG’s research for the WERC competition, for which this topic was chosen as an open task. Beyond raising awareness, CFG modeled, developed and built an experimentation apparatus meant to prove the validity of a relatively cheap extinguishing method which was also novel to the regions in which it could be employed. The apparatus, which simulated an underground coal fire, was used to test a sand …

Coal Fires: An Environmental Disaster, Daniel Robert Miskin

Chemical Engineering Undergraduate Honors Theses

The mission of the Coal Fire Gang (CFG) is to spread awareness about the global issue of uncontrolled coal fires, and to highlight them as a low-hanging fruit of immediate emissions reduction. This report summarizes CFG’s research for the WERC competition, for which this topic was chosen as an open task. Beyond raising awareness, CFG modeled, developed and built an experimentation apparatus meant to prove the validity of a relatively cheap extinguishing method which was also novel to the regions in which it could be employed. The apparatus, which simulated an underground coal fire, was used to test a sand …

Water System For Developing Countries / Disaster Relief Made With Local Materials, Lauren E. Cole

Chemical Engineering Undergraduate Honors Theses

At the beginning of this project, I elected to focus mainly on the electrolysis portion. I completed a lot of research on electrolysis in general, and then specifically on brine electrolysis, which is transforming a salt water solution into a sodium hypochlorite solution, or bleach. I researched all of the different types of electrode materials and purchased several electrodes in order to perform experiments. I researched several methods of electrolysis in use today. I performed several calculations about the electrolysis reaction, including the electric potential required to drive the reaction (approximately 1.0 volt), as well as what concentration of salt …

Water System For Developing Countries/Disaster Relief Made With Local Materials, Cayla Tichy

Chemical Engineering Undergraduate Honors Theses

The United Nations estimates that water-borne illness accounts for 80% of deaths in developing nations and that nearly 1 in 6 do not have access to clean water (1). However, despite the ability to produce water in the developed world from complex streams such as wastewater or seawater, challenges remain in providing this basic resource in the developing world. Too often the approach has been to apply a high-tech solution, which requires significant technical expertise to run and significant financial resources to repair. Furthermore, as every developing nation faces different challenges, a new solution must be provided for each situation. …

Solid State Synthesis Of The Srtio3 Nano-Particle, Spencer S. Coonrod

Mechanical Engineering Undergraduate Honors Theses

Recent studies have shown the ability to synthesize peroviskite materials through solid state chemical reaction. In previous work at the University Annamalai Naga, a specific peroviskite SrTiO3 (STO) was created through solid state reaction between strontium carbonate and, titanium dioxide powders that were homogenously mixed and then sintered until completion of the reaction. The sintered powder was characterized by X-ray diffraction (XRD) and shown to be a perovskite structure without evidence of additional phases. This work specifically reports on the reproducible solid state reaction procedure developed at the University of Arkansas for the production of STO powder, characterization of formed …

Properties Of Multiferroic Bifeo3 From First Principles, Dovran Rahmedov

Graduate Theses and Dissertations

In this dissertation, a first-principle-based approach is developed to study magnetoelectric effect in multiferoic materials. Such approach has a significant predictive power and might serve as a guide to new experimental works. As we will discuss in the course of this work, it also gives an important insight to the underlying physics behind the experimentally observed phenomena.

We start by applying our method to investigate properties of a generic multiferroic material. We observe how magnetic susceptibility of such materials evolves with temperature and compare this evolution with the characteristic behavior of magnetic susceptibility for pure magnetic systems. Then we focus …

Radiation-Hardened Delay-Insensitive Asynchronous Circuits For Multi-Bit Seu Mitigation And Data-Retaining Sel Protection, John Davis Brady

Graduate Theses and Dissertations

Radiation can have highly damaging effects on circuitry, especially for space applications, if designed without radiation-hardening mechanisms. Delay-insensitive asynchronous circuits inherently have promising potentials in mitigating the effects of radiation due to their delay insensitivity. This thesis proposes the use of two delay-insensitive asynchronous logic architectures to mitigate the effects of up to two single-event upsets (SEU) and a single-event latch-up (SEL). The multi-bit SEU mitigation with SEL protection architecture improves the original design by providing more integrity against data corruption and lock-ups caused by multi-bit SEUs, and it is expanded to simultaneously provide protection against SEL. The multi-bit SEU …

Synthesis And Characterization Of Nanocrystals And Their Application For Photodetectors, Ahmad Nusir

Graduate Theses and Dissertations

Room temperature operation is considered one of the essential restrictions in the design of electronic devices. Photodetectors are unable to detect light efficiently at room temperature due to high dark currents. Semiconductor nanocrystals possess unique optical and electrical properties which make them ideal for fabricating uncooled photodetectors. In this project, nanocrystals were synthesized and implemented in devices that detect light at room temperature.

Nanocrystalline I-III-VI2 and II-VI semiconductors (CuInS2 and CdSe) were grown by a wet chemical method, and characterized using: optical absorption, photoluminescence, Raman scattering, and x-ray diffraction. The optical absorption and photoluminescence spectra of the nanocrystals were recorded …

Time-Driven Activity-Based Costing For Healthcare Provider Supply Chain Processes, Martha Isaura Gonzalez

Graduate Theses and Dissertations

In a time when healthcare costs continue to rise, nearly a third of hospital operating expenses are related to supplies, and the healthcare supply chain is complex, it is pertinent for healthcare providers to have a clear understanding of their healthcare supply chain process costs. Having a clear picture into how these costs are driven and where opportunities for cost reductions exist can support supply chain efficiencies. In this research, we develop a Time-Driven Activity-Based Costing (TDABC) supply chain cost management tool for healthcare providers. A TDABC management system can provide healthcare providers with valuable product and process supply chain …

Poisson Distributed Individuals Control Charts With Optimal Limits, Negin Enayaty Ahangar

Graduate Theses and Dissertations

The conventional method used in attribute control charts is the Shewhart three sigma limits. The implicit assumption of the Normal distribution in this approach is not appropriate for skewed distributions such as Poisson, Geometric and Negative Binomial. Normal approximations perform poorly in the tail area of the these distributions. In this research, a type of attribute control chart is introduced to monitor the processes that provide count data. The economic objective of this chart is to minimize the cost of its errors which is determined by the designer. This objective is a linear function of type I and II errors. …

Characterization Of Isotropic Surface Texture In The Boundary Lubrication Regime And The Frictional Response, Edwin H. Bird

Mechanical Engineering Undergraduate Honors Theses

In the dynamic nature of today’s engineering components the use of nanolubricants and the control of micron and sub-micron surface texture features can greatly aid in reducing frictional losses and thus reduce energy consumption. The primary purpose of this paper is to define texture and analyze the effects of an isotropic surface texture and lubrication on the frictional response of contacting surfaces in boundary lubrication. This experiment was carried out using a steel ball-on-disk tribometer set-up where the steel disk had a sandblasted surface texture using 40-60 grit glass beads to produce an average roughness, Sa, of 2.120 μm uniformly …

The Effect Of Diffusion On The Evaporation Rate Of Liquid Hydrocarbons Using Nanosediments In Lakes On Titan, Tyler M. Scogin

Mechanical Engineering Undergraduate Honors Theses

Titan, Saturn's largest moon, has a "hydrological" cycle with hydrocarbons including methane and ethane in its atmosphere, and may be analogous to a frozen prebiotic Earth. Tholins created in Titan's atmosphere fall to the surface and interact with these liquid hydrocarbons. As a surrogate for tholins, nanophase silica was used as the nanosediment that interacts with the chosen liquids used to be analogous to those found on Titan. The effect on the evaporation rate of these liquids with and without the added silica was explored through 10 experiments.

Experimental And Simulation Studies Of The Permeation Of Water Through Polydimethylsiloxane (Pdms), Dilawer Singh

Mechanical Engineering Undergraduate Honors Theses

Experimental and computational techniques were used to test the permeation of water through polydimethylsiloxane (PDMS). The experimental portion consisted of creating a permeation cell in such a way that water’s only path to escape was through a PDMS membrane. Weight measurements were recorded and turned into a permeation coefficient of water through different types of PDMS. The membranes were then stretched to a certain amount to study the effect on water permeation. The computational part used Large-scale Atomic / Molecular Massively Parallel Simulator (LAMMPS) to study the diffusion coefficient of water through PDMS. The initial step was to translate coarse-grain …

Ultrathin Ptfe Coating For Hypodermic Needles Enabled By Mussel-Inspired Pda Adhesive Layer, Spencer A. Foust

Mechanical Engineering Undergraduate Honors Theses

Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, commonly known by its brand name Teflon®, which has many desirable properties such as a low coefficient of friction, high temperature resistance, anti-microbial properties, hydrophobicity, biocompatibility, and chemical resistance. One of the major challenges caused by the non-stick property of PTFE is its poor adhesion to substrates: PTFE coatings can be easily detached from surfaces under frictional forces and shear. The molecule polydopamine (PDA) was discovered as the key protein for adhesion between polytetrafluoroethylene and substrates of many materials, including steel, and thus has been used as a unique approach for coatings. …

Tht And Capillary Electrophoresis To Monitor The Effects Of Solutions Conditions On Amylin Aggregation, Michael May

Graduate Theses and Dissertations

Amylin (hIAPP) aggregates have been found in 90% of patients with type II diabetes at autopsy, and are suspected to play a role in the death of islet &beta-cells¹. However, this aggregation process is not well understood. Here, we explore methods that utilize capillary electrophoresis (CE) as a means to better understand amylin's aggregation process.

We examined the effects of solutions conditions: agitation, pH, salt, and temperature on amylin aggregation using Thioflavin T, dot blots, and capillary electrophoresis. Thiofalvin T was used to predict the lag time to &beta-sheet formation. Our results indicated all variables with the exception …

An Innovative Approach Towards Applying Chaum Mixing To Sms, Matthew Patrick Rothmeyer

Graduate Theses and Dissertations

Currently there are few user-friendly applications for anonymous communication across multiple platforms, leaving data that is often both personal and private vulnerable to malicious activity. Mobile devices such as smartphones are prime candidates for such an application as they are pervasive and have standardized communication protocols. Through the application of mixing techniques, these devices can provide anonymity for groups of individuals numbering 30 to 40 members. In this work, a Chaum mix inspired, smartphone based network that uses the Short Message Service (SMS) is described first in theory and then in implementation. This system leverages both techniques used by current …

Fabrication And Characterization Of Amorphous/Nanocrystalline Thin Film Composite, Benjamin Seth Newton

Graduate Theses and Dissertations

Combining the absorption abilities of amorphous silicon and the electron transport capabilities of crystalline silicon would be a great advantage to not only solar cells but other semiconductor devices. In this work composite films were created using molecular beam epitaxy and electron beam deposition interchangeably as a method to create metallic precursors. Aluminum induced crystallization techniques were used to convert an amorphous silicon film with a capping layer of aluminum nanodots into a film composed of a mixture of amorphous silicon and nanocrystalline silicon. This layer was grown into the amorphous layer by cannibalizing a portion of the amorphous silicon …

Examination Of Nitrogen To Phosphorus Ratio In Nutrient Removal From Wastewater Through Chlorella Vulgaris, Courtney L. Hill

Civil Engineering Undergraduate Honors Theses

A need for phosphorus removal is becoming increasingly evident as some wastewater treatment plants struggle to meet wastewater effluent nutrient requirements. High nutrient levels in wastewater effluents have also caused ongoing tension between the state of Oklahoma and Arkansas regarding the pollution of the Illinois River. This research seeks to establish the relationship between nitrogen to phosphorus ratio in wastewater and the level of nutrient reduction using Chlorella vulgaris. Seed cultures of Chlorella vulgaris were added into solutions with various ratios of nitrate to phosphate representative of treated domestic wastewater and the removal of nitrogen and phosphorus were measured in …

Shear Capacity Of Prestressed Lightweight Self-Consolidating Concrete, Micah Alan Wyssmann

Civil Engineering Undergraduate Honors Theses

In prestressed members, self-consolidating concrete (SCC) has in some cases exhibited lower shear capacity than conventional concrete, which has been attributed to decreased aggregate interlock. However, little data is currently available to assess whether use of lightweight aggregate in prestressed SCC beams has further impact on aggregate interlock and shear strength. This study measured the shear capacity of six prestressed beams made from three different concrete mixtures: lightweight self-consolidating concrete (LWSCC) with expanded shale aggregate, LWSCC with expanded clay aggregate, and control normal weight SCC with limestone aggregate. Predicted shear capacities were determined based on current ACI Building Code and …

Robust Network Interdiction With Invisible Interdiction Assets, Nail Orkun Baycik

Graduate Theses and Dissertations

We study a version of the shortest path network interdiction problem in which the follower seeks to find the shortest path on a given network and the leader seeks to maximize the follower's shortest path length by interdicting arcs. We consider placement of interdictions that are not visible to the follower; however, we seek to locate interdictions in a manner that is robust against the possibility that some interdiction locations become known to the follower. We formulate the problem as a bi-level program, and use the simulated annealing heuristic to identify high quality solutions. We apply our approach to investigate …

Comparing Virus Ultrafiltration Of Bacteriophages With Filtration Of Minute Virus Of Mice, Kent Smith

Graduate Theses and Dissertations

Industrial production of protein therapeutics demand rigorous testing and clearance of viruses. The U.S. Food and Drug Administration dictate the purity of pharmaceuticals with regards to viral contamination. As this testing is time consuming and expensive using mammalian cells and viruses, bacteriophages may provide a faster and cheaper alternative for membrane filtration processes. We used ultrafiltration membranes to filter protein solutions with viruses. Two bacteriophages were tested against membranes with two different pore sizes. These membranes were then tested by inverting the membrane's orientation. Flux measurements and log virus removal data were taken. Flux and log virus removal were seen …

Fabrication Of Single Nanowire Device Using Electron Beam Lithography, Thach Pham

Graduate Theses and Dissertations

One dimensional nanostructure materials such as nanowires have drawn many interests among the scientific community for a wide range of applications such as field-effect transistors [1], [2], inverters[3], light-emitting diode [1], lasers [4], nanosensors [5], [6], and photodetectors [7]... Comparing with the characterization of nanowire arrays, characterizing a single nanowire will definitely provide a better understanding on new nanowire properties due to simplified behaviors of devices. Although promising theories could be drawn from those results, fabrication of test structure for single nanowire measurements cannot be easily processed using standard microfabrication techniques. Therefore, electron beam lithography integrated with photolithography technique has …

Broadband Nanostructured Antireflection Coating For Enhancing Inas/Gaas Quantum Dots Solar Cells Performance, Jony C. Sarker

Graduate Theses and Dissertations

The broadband suppression in reflection is one of the primary focuses in high efficiency solar cell research. In this thesis, a moth-eye inspired nanostructure antireflection coating is fabricated on InAs/GaAs quantum dots solar cell in order to enhance the power conversion efficiency. The abrupt refractive index transition between air and GaAs surface is replaced by a tapering zinc oxide nanoneedle on planar tantalum pentoxide coating. The antireflection structure provides gradual reduction of refractive index away from the solar cell top surface.

The nanostructured antireflection coating is fabricated by utilizing chemical bath deposition of tapered zinc oxide nanoneedles on planar tantalum …

Infrared Energy Harvesting For Optoplasmonics From Nanostructured Metamaterials, Gregory Thomas Forcherio

Graduate Theses and Dissertations

Metamaterials exhibit unique optical resonance characteristics which permit precise engineering of energy pathways within a device. The ability of plasmonic nanostructures to guide electromagnetism offers a platform to reduce global dependence on fossil fuels by harvesting waste heat, which comprises 60% of generated energy around the world. Plasmonic metamaterials were hypothesized to support an exchange of energy between resonance modes, enabling generation of higher energy photons from waste infrared energy. Infrared irradiation of a metamaterial at the Fano coupling lattice resonance was anticipated to re-emit as higher energy visible light at the plasmon resonance. Photonic signals from harvested thermal energy …

High Temperature Ltcc Based Sic Double-Sided Cooling Power Electronic Module, Hao Zhang

Graduate Theses and Dissertations

This objective of this dissertation research is to investigate a module packaging technology for high temperature double-sided cooling power electronic module application. A high-temperature wire-bondless low-temperature co-fired ceramic (LTCC) based double-sided cooling power electronic module was designed, simulated and fabricated. In this module, the conventional copper base plate is removed to reduce the thermal resistance between the device junctions to the heat sink and to improve the reliability of the module by eliminating the large area solder joint between the power substrate and the copper base plate. A low-temperature co-fired ceramic (LTCC) substrate with cavities and vias is used as …