Engineering Commons^™

Rheology Of Asbestos Filled Polystyrene, Richard Henry Young

Theses

A capillary rheometer was used to generate data showing the volumetric flow rate at various pressures for a polystyrene resin and for an asbestos filled polystyrene. Variables evaluated were per cent asbestos and temperature. These data were then used to calculate the maximum shear stress at the capillary wall and the corresponding maximum velocity gradient (shear rate) at the capillary wall. A rheological equation containing three constants was employed to relate the shear stress to the shear rate. In addition, a simple relationship was found between the values of two of the constants and the per cent asbestos. There is …

Thin Layer Ionophoresis Of Sugars, Joseph Gilbert Vrindten

Theses

In 1952, Consden and Stanier published a report on paper ionophoresis of sugars in which they showed experimentally an increase in mobility of sugars with increasing pH in borate buffers. The object of the experiments in this thesis was to determine if this finding was also true of thin layer plates, there being no published literature on similar experiments using thin layer ionophoresis.

Glass plates 20 cm. x 20 cm. were coated with a 300 micron layer of cellulose powder and dried at 105° C. for one hour. They were then stored in an airtight tin box until ready for …

Enthalpy Deviations For The System Methane - Carbon Dioxide, Fred S. Winter

Theses

Enthalpy deviations for the gaseous system, Methane and Carbon Dioxide were developed using the Redlich-Kwong equation of state. Values of enthalpy deviation were obtained at 0.0, 0.0852, 0.19912, 0.3583, 0.6685 and 1.0 weight fraction Methane, at temperatures of 100° F, 280° F and 460° F, at pressures between 200 and 10,000 PSIA.

A computer program in Fortran IV language was developed for solving the Redlich-Kwong equation in terms of the compressibility factor.

The Redlich-Kwong expression for enthalpy deviation, in combination with graphical methods was used to produce the results.

Concepts In Lsi Servo-Control-Electronics, Alfons Alfred Tuszynski

Dissertations

This thesis deals with the engineering aspects of control electronics. It examines modern concepts of servo-control theory in the light of recent developments in the technology of monolithic circuits. Applicational considerations are slanted towards Aerospace standards of reliability and power-consumption economy.

Conclusions drawn from the discussion of fabrication constraints and performance requirements lead to a preference for digital implementations. Yield problems on one hand and aging effects on the other greatly reduce the feasibility rating of analog arrays.

Current practice in servo-control electronics revolves around purely analog implementations, sampled-data systems and Primitive on-off arrangements. The motivation behind the status quo …

Experimental Investigation Of Submerged, Incompressible, Turbulent, Impinging Jets, David Tzeh-Hsian Lee

Theses

Measurements concerning various flow parameters of jets impinging on a smooth lucite plate and a heated metal plate have been carried out. In particular, it is shown that the potential core length of a jet is a function of the Reynolds number and of the jet diameter. It has also been demonstrated that impinging jets behave in many important respects like free jets, except in the immediate vicinity of the target plate.

The flow behavior in the wall jet zone was investigated experimentally, and a satisfactory agreement with the results of the previous investigators was found. The maximum velocity decay …

Financing The Nuclear Fuel Requirements Of Public Utilities, Peter A. Lewis

Theses

A major portion of new electric generating capacity will be nuclear powered. The change to nuclear power will require large outlays of capital not required with conventional fuels to finance nuclear fuel inventories. Nuclear fuel financing requirements are unique because nuclear fuel is not consumed in the same manner as conventional fuels. Financing has not been a problem to date because nuclear fuel can be obtained only through lease from the Atomic Energy Commission. This arrangement will be terminated by June 30, 1973 and from that date on all nuclear fuel must be privately owned. Electric utilities have shown an …

A Rheological Equation Of State For Blood At Low Shear Rates, Anatoly Dritschilo

Theses

In this work a new rheological equation of state is presented and its application to blood is studied. The equation considered is a linear combination of Newtonian and non-Newtonian contributions to the apparent viscosity. The general form of the equation is

 T_ij =-(A + Be^{-1/C|(.5)Δi/j:Δj/i|1/2})Δij

Data from the literature were used to test the equation by generating curves of measured torque (T/L) versus applied shear rate (Ω) that would characterize the behavior of blood at all red cell concentrations and all shear rates in the Gilinson, Dauwalter and Merrill viscometer. The constants for the equation were …

Computer Specification Of Centrifugal Pump And Motor, Paul David O'Lenick

Theses

The purpose of this thesis is to develop a PORTRAIT computer program for selecting a centrifugal pump and motor driver. This is accomplished by means of generalized data which establishes the speed of the Dump and its power requirement. After selection of the pump, the motor is sized and specified. In addition to determining the pump and motor, the program also sizes the discharge and suction lines and the required control valve. The resulting solution yields the pump design data, motor, line and control valve sizes. From this data utility and relative equipment costs can be estimated.

Boiling Heat Transfer In The Presence Of Electric Fields, Ronald Francis Lovenguth

Dissertations

The effects of a non-uniform, radial D.C. electric field on the natural convection and nucleate boiling regimes in saturated pool boiling and on the peak heat flux phenomenon were determined for trichlorotrifluoroethane, carbon tetrachloride, dichloromonofluoromethane and chloroform using as a heat transfer surface a 0.02 inch diameter platinum wire.

Bubble departure diameters for the nucleate boiling region were measured by photographic means as a function of the electric field intensity at the heat transfer surface.

The application of an electric field was found to have a significant effect on the natural convection mode of heat transfer and also the peak …

Viscosity-Density Correlation Of Newtonian Liquids, Melvin Leonard Druin

Dissertations

The viscosity of monatomic liquids was modeled by an equation derived from the kinetic theory of gases. Viscosities may be calculated from data on density and molecular weight of the liquid. In adapting this relationship to polyatomic liquids, a single correction factor was developed for each of five series of homologues; n-paraffins, n-1 -alkenes, n-alkylcyclohexanes, n-alkylbenzenes and n-alcohols, to account for the deviations of the calculated viscosities from those reported, extending over a one- to three-hundred degree range. The factor is a function of reduced temperature relative to the normal boiling point, T_rB. A single equation for each …

The Mechanism Of Second Breakdown In Transistors, Eugene David Fabricius

Dissertations

The purpose of this dissertation is to examine the behavior of electrons and holes in a semiconductor or diode under conditions of high current density as a function of temperature, and to relate this behavior to the phenomenon of Second Breakdown. The approach used is that of magnetohydrodynamics, the electrons and holes being treated as a plasma "gas" embedded in the dielectric of the semiconductor.

This approach is unique in the following respects:

1. This is the first attempt to explain second breakdown in terms of magnetohydrodynamics.
2. This is the first time an explanation of pinching in a solid at room …

The Generalized Virial Equation Of State, Ghanshyam R. Patel

Dissertations

A generalized three parameter virial equation of state has been developed and tested for seven pure gases having different molecular characteristics. The equation has also been tested for more than thirteen binary gas mixtures using three different mixture rules. The final equation is as follows:

Z = 1 + B(T)/V + C(T)/V² + D(T)/V³ + E(T)/V⁴ + VF(T)/e^aV + VG(T)/e^bV

The expressions for E(T), F(T), and G(T) along the critical isotherm were derived in terms of critical properties and two constants, a and b which appear in the sixth and seventh terms in the above …

Critical Interaction Constants For Binary Gas Mixtures For Use In The Redlich-Kwong Equation Of State, Warren J. Biss

Theses

In this work, critical interaction constants were used to evaluate the interaction coefficients of the Redlich - Kwong constants for bin-ary gas mixtures. From these constants, the pressure - volume - temperature behavior of the mixtures was calculated using the Redlich - Kwong equation.

The critical interaction constants, T₁₂ and P₁₂ , were evaluated for binary mixtures by solving, simultaneously, two second degree equations relating terminal slopes for critical pressure loci and the mole fractions of the components present. The feasibility of this method was tested by calculating P-V-T data for binary mixtures and comparing this with values …

Premix Molding Compounds : The Effect Of Processing Technique On Profitability And Product Integrity, Albert Robert Kurkowski

Theses

Premix molding compounds, presently manufactured in a double-armed blade kneader mixer, can now be prepared by a new and unique method utilizing a high speed densifier. Compounds processed in a kneader mixer, by virtue of its overlapping, shear mixing motion, are extremely susceptible to glass fiber degradation and. consequent mechanical strength reductions in moldings. Previously, as this was the only equipment, available with the capability to admix highly viscous materials, processors would formulate and design to compensate for the resultant property reductions that are encountered. Also typical of conventional kneader mixer processes is an inherent materials handling problem and mixing …

Effect Of Column Diameter On The Frequency Response Of Water Fluidized Beds, Edward C. Maiuro

Theses

The effect of column diameter on the frequency response of water fluidized beds was investigated.

Studies were made on four columns ranging from four to ten inches in diameter. Water was used to fluidize the beds which consisted of spherical glass beads .0185 inches in diameter. A trace solution of sodium chloride was sinusoidally introduced into the beds. Inlet and outlet concentrations were continuously measured by an electrical conductivity recorder. Separate frequency response tests were conducted on the inlet calmning section in an attempt to obtain the frequency response of this region alone. Results of the tests were expressed as …

A Correlation Of Latent Heats And Densities Of Pure Organic Liquids From Known Vapor Pressure Data, Vincent J. Vasta

Theses

Employing the correlation developed by Kemme (5), which is based on a hole model for a liquid, relating vapor pressures with corresponding liquid densities and the number of carbon atoms in a molecular chain for a homologous series, correlation coefficients were established using multi-linear regression analysis on available literature data. This correlation was newly applied to several straight chain homologous series including the n-acids, formate esters and n-alkyl benzenes.

A second correlation developed by Kemme (5) relating vapor pressure, internal heat of vaporization and the number of carbon atoms for a homologous series was employed to determine correlation coefficients for …

The Optimization Of A Catalytic Methanol Reactor, Peter Wrampe

Theses

The development of a computer program which determines the minimum space time of the methanol synthesis reactants is presented. Also, the optimum temperature profile along the catalytic reactor was predicted for a desired conversion at a given operating pressure, feed composition, and catalyst effectiveness factor.

The equilibrium conversion of methanol was determined at various reaction parameters. Rates of reaction were ascertained and maximized with respect to temperature for various conversions and given reaction parameters. The results, along with those obtained when the design equation was numerically integrated, were compared to published data. Equations were established for various sets of published …

The Plasticization Of 4-Methyl-Pentene-1 (Tpx-Rt-D30) Polymer With Petroleum Jelly, Joseph P. Mccann

Theses

The properties of TPX-RT-D30 (4-methyl-pentene-1 polymer) have been changed by blending petroleum jelly with the polymer. The polymer was blended in a Brabender apparatus with up to 40% by weight petroleum jelly (P.J.) at 270°C, pressed and quenched in water. Samples were die cut for the various tests. The polymer tensile properties (ASTM-638-64T) showed both a break and yield value in all ratios as compared to only a break value for the TPX-RT polymer. Breaking strength ranged from 4000 psi for pure TPX-RT down to 1000 psi at 40% P.J., with a leveling point of 2000 psi at 15% P.J. …

The Effect Of Nitrilotriacetic Acid Upon The Biodegradability Of Linear Alkyl Benzene Sulfonate, John D. Mckenna

Theses

The effects of trisodium nitrilotriacetate (SKTA) and sodium tipolyphosphate (STPP) upon the biological degradation of linear alkyl benzene sulfonate (LAS) ware experimentally investigated by the chemical oxygen demand and methylene blue methods. It was found that when STPP was present with LAS, the degradation of the LAS was better than when alone in solution. It was also found that LAS in solution with SN TA was less degradable than LAS alone. The benzene ring of the MS appeared to degrade after most of the linear portion of the chain had already been degraded.

Realization Of Transfer Impedances Using Distributed Rc Elements In A Common Ground Linvill Configuration, Walter Woronka

Theses

One of several synthesis procedures available for the realization of a transfer admittance is that of Linvill. This synthesis procedure employs an active element, a negative impedance converter (NIC), to shift the poles of passive immittance functions from the negative real axis into the complex plane to realize the desired transfer immittance function.

The Linvill synthesis procedure is extended to networks containing cascaded distributed RC elements and the conditions which must be satisfied to realize a transfer impedance using these distributed elements are defined.

Design Of Linear Control Systems With Distributed Parameter Elements By Parameter Plane Techniques, Murray Weinberg

Dissertations

This dissertation extends the application of parameter plane techniques to a number of areas. Specifically, the parameter plane technique can now be used to determine absolute stability, relative stability, and the location of roots of the closed-loop characteristic equation of systems containing both lumped and distributed parameter elements. The advantages of utilizing this technique are that results can be obtained as two system parameters are varied simultaneously and higher order systems can be treated as easily as low order ones.

Investigation of the mapping of real roots resulted in the derivation of a theorem which relates the number of real …

Noise Spectral Density As A Diagnostic Tool For Reliability Of P-N Junctions, Young Duck Kim

Dissertations

The feasibility of choosing noise-voltage spectral density as a prediction parameter for the degradation of p-n junctions has been examined both theoretically and through a series of life-tests.

Experimental facts show that the noise-voltage spectral density, S_v(w), observed in a p-n junction under the breakdown condition tends to be "white" (which contradicts the 1/f-noise theory), and S_v(w) is inversely proportional to the breakdown current (which contradicts the shot-noise theory). Furthermore, some p-n junctions display one or more multiple peaks of S_v(w) at different current levels which can not be explained by any of the …

Liquid Vapor Equilibrium In Nucleate And Film Boiling, Walter Henry Rothaug

Theses

Liquid vapor equilibrium data were obtained for several solutions and azeotropes under both nucleate and film boiling. The data were invariant between the two boiling regimes indicating that both nucleate and film boiling are equilibrium vaporizations rather than either diffusional or bulk vaporizations. Boiling heat transfer versus temperature data were taken in nucleate and film boiling for the solutions and azeotropes and for several pure liquids. The critical heat flux for methyl alcohol-benzene solutions rose sharply at first and then more moderately with increasing alcohol concentration. The critical heat flux was pratically constant regardless of concentration in ethyl alcohol-benzene solutions. …

Coagulation In Waste Water Treatment, Garret P. Westerhoff

Theses

This paper emphasizes a practical approach to the coagulation of domestic waste water. A portion of the paper is a synopsis of current published literature on the subject. Laboratory studies on the coagulation of raw domestic waste waters were conducted to provide the basis of a practical procedure for the evaluation and design of a coagulation process. Studies included the development of a relationship between the B.O.D. and the soluble and solids portion of two waste tests. The jar test was used for the studies on the coagulation process. The final section of the paper outlines the chemical cost factors …

The Effect Of Internal Combustion Engine Operation Upon The Viscometric Properties Of Polymer Thickened Multi-Viscosity Crankcase Oils, William Charles Philcox

Theses

The effects of engine mileage upon the viscometric properties of seven different brands of multi-viscosity engine oils were examined by subjecting each brand of oil to an average of 1500 miles of service in the crankcases of different passenger cars.

Oil samples were taken every 500 miles after the oil was put in the crankcase. The control oil sample was taken from a can of oil at the time the oil was put in the engine.

The viscosity indices and kinematic viscosities at 100° F and 210° F were calculated for each sample of oil. The percent change in viscosity …

The Effects Of Air-Water Two Phase Flow On The Performance Of A Centrifugal Pump, Karnig Ekizian

Theses

This study investigates the performance of a 1-inch long 4-vane open impeller centrifugal pump under two phase flow conditions. The paddle wheel pump, as branded by its manufacturer the Worthington Corporation, had a specific speed of 3400 (based on gallons per minute, feet of water and revolutions per minute) corresponding to a 7-inch impeller diameter. A 1/8-inch perforated steel pipe carried the compressed air to within four inches of the impeller eye where the air was injected into the water stream (See figures 18 and 20).

The three variable inputs were, water flow rate, pump speed and air flow rate. …

A Study Of The Properties Of The Biconical Antenna, Kurt Frank Hafner Jr.

Theses

Expressions are found for the fields produced by TM and TEM modes along a finitely conducting biconical antenna. Expressions are also found for the TM and TEM fileds along a biconical antenna having a lossy dielectric coating. It is shown that the antenna losses produce an anntenuation of the the fields along the antenna. It is found that because there is a dispersion of the fields along the biconical antenna, the attenuation produced by the losses is, in genaral, not characterized by simple exponential.

A solution is obtained for the fields of the TEM wave along a biconical antenna coated …

Reliability Considerations For Communication Satellites, Frank Polizzi

Theses

A detailed program covering all phases of reliability for a communication satellite was presented. In long mission programs such as this one, reliability is the prime consideration in assuring a successful accomplishment of the stringent goals set forth. Reliability principles and methods were incorporated in delineating each major task in the program. These principles and methods not only aided the reliability personnel in performing their duties better, but also assisted the design group, manufacturing personnel, and the testing and evaluation group in performing their jobs efficiently by being aware and knowledgeable of reliability engineering.

Various reliability disciplines were imposed, as …

Fault Protection With A Digital Computer, George D. Rockefeller

Theses

A fundamental basis has been developed for the use of a time-shared stored-program digital computer to perform many of the electrical power-system protective-relay functions in a substation. Logic operations are given to detect a fault, locate it and initiate the opening of the appropriate circuit breakers, whether the fault is in the station or on lines radiating from the station.

The instantaneous value of the station voltages and currents are sampled at a 0.5 ms rate, converted to digital form and stored for computer main-frame use. Operating times are compatible with the 25 ms breaker trip capability of modern two-cycle …

Heat Transfer Between A Turbulent Round Jet And A Segmented Flat Plate Perpendicular To It, John Edward Chamberlain

Theses

Heat transfer between a room temperature, turbulent round jet and a segmented flat plate perpendicular to it has been investigated.

The heat transfer surface consisted of invar rings insulated from each other with silicone rubber. The source of heat was steam at atmospheric pressure condensing on the back of the heat transfer surface.

Since data were taken over a wide range of vertical distances between the nozzle and the flat surface both the potential cone and the fully developed regions of the jet were observed interacting with the heated plate.

It was determined that two modes of heat transfer occur; …