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Iowa State University

Selected Works

2008

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Articles 31 - 60 of 61

Full-Text Articles in Engineering

The Nonlinear Dynamics Of Tapping Mode Atomic Force Microscopy With Capillary Force Interactions, Nicole N. Hashemi, H. Dankowicz, M.R. Paul Jan 2008

The Nonlinear Dynamics Of Tapping Mode Atomic Force Microscopy With Capillary Force Interactions, Nicole N. Hashemi, H. Dankowicz, M.R. Paul

Nastaran Hashemi

We study the nonlinear dynamics of a tapping mode atomic force microscope with tip-surface interactions that include attractive, repulsive, and capillary force contributions using numerical techniques tailored for hybrid or discontinuous dynamical systems that include forward-time simulation with event handling and numerical pseudo-arclength continuation. We find four branches of periodic solutions that are separated by windows of complex and irregular dynamics. The branches of periodic solutions end where the cantilever comes into grazing contact with event surfaces in state space, corresponding to the onset of capillary interactions and the onset of repulsive forces associated with contact. These windows of irregular …


The Dissipated Power In Atomic Force Microscopy Due To Interactions With A Capillary Fluid Layer, Nicole N. Hashemi, M.R. Paul, H. Dankowicz, W. Jhe Jan 2008

The Dissipated Power In Atomic Force Microscopy Due To Interactions With A Capillary Fluid Layer, Nicole N. Hashemi, M.R. Paul, H. Dankowicz, W. Jhe

Nastaran Hashemi

We study the power dissipated by the tip of an oscillating micron-scale cantilever as it interacts with a sample using a nonlinear model of the tip-surface force interactions that includes attractive, adhesive, repulsive, and capillary contributions. The force interactions of the model are entirely conservative and the dissipated power is due to the hysteretic nature of the interaction with the capillary fluid layer. Using numerical techniques tailored for nonlinear and discontinuous dynamical systems we compute the exact dissipated power over a range of experimentally relevant conditions. This is accomplished by computing precisely the fraction of oscillations that break the fluid …


Melt-Dispersion Mechanism For Fast Reaction Of Aluminum Particles: Extension For Micron Scale Particles And Fluorination, Valery I. Levitas, Michelle L. Pantoya, Kyle W. Watson Jan 2008

Melt-Dispersion Mechanism For Fast Reaction Of Aluminum Particles: Extension For Micron Scale Particles And Fluorination, Valery I. Levitas, Michelle L. Pantoya, Kyle W. Watson

Valery I. Levitas

The theoretically predicted relationship for the relative flame rate versus relative particle size based on the melt dispersion mechanism (MDM), which was previously confirmed for oxidation of 40–120nm diameter aluminum particles, is found to be in agreement with experiments for 1–3μm diameter Al particles and fluorination. The main physical parameters for MDM (pressure in molten particle, cavitation threshold, and nanoclusters’ velocity) have been estimated for micron scale particles. The results suggest parameters that could be controlled during particle synthesis that would enable micron scale Al particles to react and achieve the performance of nanoscale Al particles.


Cognitive State Estimation In Mobile Environments, Michael C. Dorneich, Santosh Mathan, Patricia May Ververs, Stephen D. Whitlow Jan 2008

Cognitive State Estimation In Mobile Environments, Michael C. Dorneich, Santosh Mathan, Patricia May Ververs, Stephen D. Whitlow

Michael C. Dorneich

This chapter presents the unique challenges encountered, difficult trade-offs required, and promising techniques em-ployed when moving cognitive state assessment from the la-boratory to a mobile field environment.


Near-Monodisperse Ni−Cu Bimetallic Nanocrystals Of Variable Composition: Controlled Synthesis And Catalytic Activity For H2 Generation, Yawen Zhang, Wenyu Huang, Susan E. Habas, John N. Kuhn, Michael E. Grass, Yusuke Yamada, Peidong Yang, Gabor A. Somorjai Jan 2008

Near-Monodisperse Ni−Cu Bimetallic Nanocrystals Of Variable Composition: Controlled Synthesis And Catalytic Activity For H2 Generation, Yawen Zhang, Wenyu Huang, Susan E. Habas, John N. Kuhn, Michael E. Grass, Yusuke Yamada, Peidong Yang, Gabor A. Somorjai

Wenyu Huang

Near-monodisperse Ni1−xCux (x = 0.2−0.8) bimetallic nanocrystals were synthesized by a one-pot thermolysis approach in oleylamine/1-octadecene, using metal acetylacetonates as precursors. The nanocrystals form large-area 2D superlattices, and display a catalytic synergistic effect in the hydrolysis of NaBH4 to generate H2 at x = 0.5 in a strongly basic medium. The Ni0.5Cu0.5 nanocrystals show the lowest activation energy, and also exhibit the highest H2 generation rate at 298 K.


Microstructure Evolution And Monomer Partitioning In Reversible Addition - Fragmentation Chain Transfer Microemulsion Polymerization, Jennifer M. O'Donnell, Eric W. Kaler Jan 2008

Microstructure Evolution And Monomer Partitioning In Reversible Addition - Fragmentation Chain Transfer Microemulsion Polymerization, Jennifer M. O'Donnell, Eric W. Kaler

Jennifer M. Heinen

Small-angle neutron scattering (SANS) studies of reversible addition - fragmentation chain transfer (RAFT) microemulsion polymerizations of butyl acrylate and 2-ethylhexyl acrylate with the RAFT agent methyl-2-(O-ethylxanthyl) propionate (MOEP) allow the observed rate retardation to be attributed to slow fragmentation of the macro-RAFT radical. Microemulsion polymerization allows the RAFT mechanism to be investigated in the absence of termination reactions so that the cause of the rate retardation frequently observed in both homogeneous and heterogeneous polymerizations may be isolated. However, the concentration of monomer at the locus of polymerization (Cmon(part)) must be known as a function of conversion before a mechanistic study …


Compensation Effect Of Benzene Hydrogenation On Pt(111) And Pt(100) Analyzed By The Selective Energy Transfer Model, Kaitlin M. Bratlie, Yimin Li, Ragnar Larsson, Gabor A. Somorjai Jan 2008

Compensation Effect Of Benzene Hydrogenation On Pt(111) And Pt(100) Analyzed By The Selective Energy Transfer Model, Kaitlin M. Bratlie, Yimin Li, Ragnar Larsson, Gabor A. Somorjai

Kaitlin M. Bratlie

Kinetic measurements at low temperatures (310-360 K) using gas chromatography (GC) for benzene hydrogenation on Pt(100) and Pt(111) single crystal surfaces have been carried out at Torr pressures. These kinetic measurements demonstrated a linear compensation effect for the production of cyclohexane. A detailed application of the model of selective energy transfer to the experimentally obtained results yields the vibrational frequency of the adsorbate leading to reaction. This frequency is attributed to ring distortion modes. The vibrational frequency of the heat bath, or catalyst, is ascribed to a Pt-H mode. An approximate heat of adsorption of the reacting molecule is also …


Determination Of The Escherichia Coli S-Nitrosoglutathione Response Network Using Integrated Biochemical And Systems Analysis, Laura R. Jarboe, Daniel R. Hyduke, Linh M. Tran, Katherine J.Y. Chou, James C. Liao Jan 2008

Determination Of The Escherichia Coli S-Nitrosoglutathione Response Network Using Integrated Biochemical And Systems Analysis, Laura R. Jarboe, Daniel R. Hyduke, Linh M. Tran, Katherine J.Y. Chou, James C. Liao

Laura R. Jarboe

During infection or denitrification, bacteria encounter reactive nitrogen species. Although the molecular targets of and defensive response against nitric oxide (NO) in Escherichia coli are well studied, the response elements specific to S-nitrosothiols are less clear. Previously, we employed an integrated systems biology approach to unravel the E. coli NO-response network. Here we use a similar approach to confirm that S-nitrosoglutathione (GSNO) primarily impacts the metabolic and regulatory programs of E. coli in minimal medium by reaction with homocysteine and cysteine and subsequent disruption of the methionine biosynthesis pathway. Targeting of homocysteine and cysteine results in altered regulatory activity of …


Melt Dispersion Versus Diffusive Oxidation Mechanism For Aluminum Nanoparticles: Critical Experiments And Controlling Parameters, Valery I. Levitas, Michelle L. Pantoya, Birce Dikici Jan 2008

Melt Dispersion Versus Diffusive Oxidation Mechanism For Aluminum Nanoparticles: Critical Experiments And Controlling Parameters, Valery I. Levitas, Michelle L. Pantoya, Birce Dikici

Valery I. Levitas

Critical experiments were performed on Al and MoO3 thermites. The diameter and alumina shell thickness of the Alnanoparticles were varied, and flame propagation velocities were measured. The results strongly support the melt-dispersion mechanism and contradict the diffusionoxidation mechanism. The parameters that control the oxidation rate and flame velocity are justified and directions for the synthesis of Alnanoparticles (which are opposite to the current directions based on diffusionoxidation) are suggested. An equation for the flame velocity versus Alnanoparticle geometrical parameters, thermomechanical properties, and synthesis parameters is formulated.


Structure Sensitivity Of Carbon−Nitrogen Ring Opening: Impact Of Platinum Particle Size From Below 1 To 5 Nm Upon Pyrrole Hydrogenation Product Selectivity Over Monodisperse Platinum Nanoparticles Loaded Onto Mesoporous Silica, John N. Kuhn, Wenyu Huang, Chia-Kuang Tsung, Yawen Zhang, Gabor A. Somorjai Jan 2008

Structure Sensitivity Of Carbon−Nitrogen Ring Opening: Impact Of Platinum Particle Size From Below 1 To 5 Nm Upon Pyrrole Hydrogenation Product Selectivity Over Monodisperse Platinum Nanoparticles Loaded Onto Mesoporous Silica, John N. Kuhn, Wenyu Huang, Chia-Kuang Tsung, Yawen Zhang, Gabor A. Somorjai

Wenyu Huang

Well-defined platinum nanoparticles between 0.8 and 5.0 nm were prepared using dendrimer and polymer capping agents and supported onto mesoporous SBA-15 silica. Using these model catalysts, pyrrole hydrogenation was demonstrated to be structure sensitive because ring opening occurred more easily over larger particles compared to smaller ones. The phenomenon is caused by surface roughness or electronic effects that change with particle size.


Dendrimer Templated Synthesis Of One Nanometer Rh And Pt Particles Supported On Mesoporous Silica: Catalytic Activity For Ethylene And Pyrrole Hydrogenation, Wenyu Huang, John N. Kuhn, Chia-Kuang Tsung, Yawen Zhang, Susan E. Habas, Peidong Yang, Gabor A. Somorrjai Jan 2008

Dendrimer Templated Synthesis Of One Nanometer Rh And Pt Particles Supported On Mesoporous Silica: Catalytic Activity For Ethylene And Pyrrole Hydrogenation, Wenyu Huang, John N. Kuhn, Chia-Kuang Tsung, Yawen Zhang, Susan E. Habas, Peidong Yang, Gabor A. Somorrjai

Wenyu Huang

Monodisperse rhodium (Rh) and platinum (Pt) nanoparticles as small as ∼1 nm were synthesized within a fourth generation polyaminoamide (PAMAM) dendrimer, a hyperbranched polymer, in aqueous solution and immobilized by depositing onto a high-surface-area SBA-15 mesoporous support. X-ray photoelectron spectroscopy indicated that the as-synthesized Rh and Pt nanoparticles were mostly oxidized. Catalytic activity of the SBA-15 supported Rh and Pt nanoparticles was studied with ethylene hydrogenation at 273 and 293 K in 10 torr of ethylene and 100 torr of H2 after reduction (76 torr of H2 mixed with 690 torr of He) at different temperatures. Catalysts were active without …


Highly Selective Synthesis Of Catalytically Active Monodisperse Rhodium Nanocubes, Yawen Zhang, Michael E. Grass, John N. Kuhn, Feng Tao, Susan E. Habas, Wenyu Huang, Peidong Yang, Gabor A. Somorjai Jan 2008

Highly Selective Synthesis Of Catalytically Active Monodisperse Rhodium Nanocubes, Yawen Zhang, Michael E. Grass, John N. Kuhn, Feng Tao, Susan E. Habas, Wenyu Huang, Peidong Yang, Gabor A. Somorjai

Wenyu Huang

Monodisperse sub-10 nm Rh nanocubes were synthesized with high selectivity (>85%) by a seedless polyol method. The {100} faces of the Rh NCs were effectively stabilized by chemically adsorbed Br− ions from trimethyl(tetradecyl)ammonium bromide (TTAB). This simple one-step polyol route can be readily applied to the preparation of Pt and Pd nanocubes. Moreover, the organic molecules of PVP and TTAB that encapsulated the Rh nanocubes did not prevent catalytic activity for pyrrole hydrogenation and CO oxidation.


Influence Of Reaction With Xef2 On Surface Adhesion Of Al And Al2o3 Surfaces, Tianfu Zhang, Jeong Park, Wenyu Huang, Gabor A. Somoraji Jan 2008

Influence Of Reaction With Xef2 On Surface Adhesion Of Al And Al2o3 Surfaces, Tianfu Zhang, Jeong Park, Wenyu Huang, Gabor A. Somoraji

Wenyu Huang

The change in surfaceadhesion after fluorination of Al and Al2O3surfaces using XeF2 was investigated with atomic force microscopy. The chemical interaction between XeF2 and Al and Al2O3surfaces was studied by in situx-ray photoelectron spectroscopy. Fresh Al and Al2O3surfaces were obtained by etching top silicon layers of Si∕Al and Si∕Al2O3 with XeF2. The surfaceadhesion and chemical composition were measured after the exposure to air or annealing (at 200°C under vacuum). The correlation between the adhesion force increase and presence of AlF3 on the surface was revealed.


Time-Resolved Investigation Of The Acoustic Vibration Of A Single Gold Nanoprism Pair, J. Burgin, P. Langot, N. Del Fatti, F. Vallee, Wenyu Huang, M.A. El-Sayed Jan 2008

Time-Resolved Investigation Of The Acoustic Vibration Of A Single Gold Nanoprism Pair, J. Burgin, P. Langot, N. Del Fatti, F. Vallee, Wenyu Huang, M.A. El-Sayed

Wenyu Huang

The acoustic vibration of single gold nanoprism pairs on a glass substrate has been investigated in the time-domain combining a spatial modulation spectroscopy microscope with a high-sensitivity femtosecond pump−probe setup. Three modes were observed and ascribed to two in-plane and one out-of-plane vibration of the nanoprisms forming the pair, in agreement with a theoretical analysis. The periods of the two former modes with similar nature show weak (about 10%) and well correlated pair to pair fluctuations that can be unambiguously ascribed to variation of the prism geometry. In contrast, strong fluctuations, by almost a factor of 6, of the mode …


(Crcl3)3@2[C4mim][Ome]—Molecular Cluster-Type Chromium(Iii) Chloride Stabilized In A Salt Matrix, Bert Mallick, Harald Kierspel, Anja V. Mudring Jan 2008

(Crcl3)3@2[C4mim][Ome]—Molecular Cluster-Type Chromium(Iii) Chloride Stabilized In A Salt Matrix, Bert Mallick, Harald Kierspel, Anja V. Mudring

Anja V. Mudring

In [C4mim]2[CrCl3]3[OMe]2 molecular (CrCl3)3 units are embedded in a salt matrix of [C4mim][OMe]. This structural subunit can be viewed as a trapped molecular polymorph of CrCl3. Experimental and theoretical investigations indicate that, in contrast to bulk CrCl3, metal−metal bonds are formed at low temperatures.


Finite Element Modeling Of Dynamics Of Martensitic Phase Transitions, Alexander V. Idesman, Joon Yeoun Cho, Valery I. Levitas Jan 2008

Finite Element Modeling Of Dynamics Of Martensitic Phase Transitions, Alexander V. Idesman, Joon Yeoun Cho, Valery I. Levitas

Valery I. Levitas

A finite element approach is suggested for the modeling of the dynamics of multivariant martensitic phase transitions (PTs) in elasticmaterials at the nanoscale in the three dimensional (3D) case. The model consists of a coupled system of the Ginzburg–Landau equations for transformation strain-related order parameters and dynamic elasticity equations. Thermodynamic potential [V. Levitas and D. Preston, Phys. Rev. B66, 134206 (2002)] that captures the main features of macroscopic stress-strain curves is used. The evolution of multivariant microstructure in a 3D specimen for cubic to tetragonal PT in a NiAl alloy is modeled with dynamic and static formulations. The numerical results …


Sub-Two Nanometer Single Crystal Au Nanowires, Ziyang Huo, Chia-Kuang Tsung, Wenyu Huang, Xiaofeng Zhang, Peidong Yang Jan 2008

Sub-Two Nanometer Single Crystal Au Nanowires, Ziyang Huo, Chia-Kuang Tsung, Wenyu Huang, Xiaofeng Zhang, Peidong Yang

Wenyu Huang

Ultrathin single crystal Au nanowires with diameter of ∼1.6 nm and length of few micrometers were synthesized with high yield by simply mixing HAuCl4 and oleylamine at room temperature. High resolution transmission electron microscopy studies revealed that all of these nanowires are single crystalline and grew along the [111] direction. The valency evolution of the gold species during the synthesis was studied by X-ray photoelectron spectroscopy, which showed a clear Au3+ → Au+ → Au stepwise reduction at different reaction stages. Small angle X-ray scattering and small-angle X-ray diffraction suggest mesostructure formation upon HAuCl4 and oleylamine mixing. The slow in …


A Systematic Tool For Deriving Crew Console Layouts, Olu Olofinboba, Robert Demers, Michael C. Dorneich, Chris Hamblin, John Wise Jan 2008

A Systematic Tool For Deriving Crew Console Layouts, Olu Olofinboba, Robert Demers, Michael C. Dorneich, Chris Hamblin, John Wise

Michael C. Dorneich

This paper describes the use of the Function Allocation Matrix Tool (FAMT) for designing spacecraft cockpit layouts. NASA's Constellation Program intends to return humans to the moon by 2020, followed by exploration to Mars and beyond. The Orion Crew Exploration Vehicle (CEV) will serve as primary vehicle for transporting the crew. Orion will be equipped with a modern 'glass cockpit' that will allow the operators to command and control all of the vehicle's systems via graphics-based displays not unlike those now common in modern flight decks. The design of Orion's displays and controls places an increased emphasis on human-computer interaction …


A Reactive Oxide Overlayer On Rhodium Nanoparticles During Co Oxidation And Its Size Dependence Studied By In Situ Ambient-Pressure X-Ray Photoelectron Spectroscopy, Michael E. Grass, Hendrik Bluhm, Yawen Zhang, Derek Butcher, Jeong Y. Park, Yimin Li, Kaitlin M. Bratlie, Tianfu Zhang, Gabor A. Somorjai Jan 2008

A Reactive Oxide Overlayer On Rhodium Nanoparticles During Co Oxidation And Its Size Dependence Studied By In Situ Ambient-Pressure X-Ray Photoelectron Spectroscopy, Michael E. Grass, Hendrik Bluhm, Yawen Zhang, Derek Butcher, Jeong Y. Park, Yimin Li, Kaitlin M. Bratlie, Tianfu Zhang, Gabor A. Somorjai

Kaitlin M. Bratlie

The smaller, the better: In situ synchrotron ambient pressure X-ray photoelectron spectroscopy allows examination of the oxidation state of the surface of the rhodium nanoparticles (NPs) during CO oxidation in an O2 atmosphere. 2 nm NPs oxidize to a larger extent than 7 nm NPs during reaction at 150-200°C, which correlates with a fivefold increase in turnover frequency for the smaller nanoparticles.


Seven-Coordinate Ruthenium Atoms Sequestered In Praseodymium Clusters In The Chloride {Rupr3}Cl3, Nina Hermann, Anja V. Mudring, Gerd Meyer Jan 2008

Seven-Coordinate Ruthenium Atoms Sequestered In Praseodymium Clusters In The Chloride {Rupr3}Cl3, Nina Hermann, Anja V. Mudring, Gerd Meyer

Anja V. Mudring

The first example for an endohedral transition-metal atom (Ru) sequestered in a seven-coordinate surrounding of rare-earth metal atoms (Pr) has been found for {RuPr3}Cl3. The monocapped trigonal prisms of Pr atoms share two rectangular faces, forming a zigzag chain with Ru−Ru distances of 308 pm. Intracluster bonding is dominated by Ru−Pr bonding with very little Ru−Ru bonding.


Estimation Of Second Order Phase Transition Temperature Of The Orthorhombic Phase Of Gd5(Sixge1−X)4 Using Arrott Plots, Ravi L. Hadimani, Y. Melikhov, J. E. Snyder, David C. Jiles Jan 2008

Estimation Of Second Order Phase Transition Temperature Of The Orthorhombic Phase Of Gd5(Sixge1−X)4 Using Arrott Plots, Ravi L. Hadimani, Y. Melikhov, J. E. Snyder, David C. Jiles

David C. Jiles

Gd5(SixGe1−x)4 for 0.41⩽x⩽0.5 is orthorhombic and ferromagnetic at lower temperature, monoclinic and paramagnetic at higher temperature, and shows a first order magnetic-structural phase transition between the two. Magnetic moment versus magnetic field (MH) isotherms were measured just above the first order transitiontemperature for Gd5Si1.95Ge2.05 and Gd5Si2Ge2 samples and the field-induced coupled phase transition from paramagnetic/monoclinic to ferromagnetic/orthorhombic phase was observed. Using the method developed by Arrott [Phys. Rev.108, 1394 (1957)], the ferromagnetic portions of the MH isotherms were used to project the second order magnetic phase transitiontemperature of the orthorhombic phase, a region where the transition does not occur due …


Absolute Phase-Assisted Three-Dimensional Data Registration For A Dual-Camera Structured Light System, Song Zhang, Shing-Tung Yau Jan 2008

Absolute Phase-Assisted Three-Dimensional Data Registration For A Dual-Camera Structured Light System, Song Zhang, Shing-Tung Yau

Song Zhang

For a three-dimensional shape measurement system with a single projector and multiple cameras, registering patches from different cameras is crucial. Registration usually involves a complicated and time-consuming procedure. We propose a new method that can robustly match different patches via absolute phase without significantly increasing its cost. For y and z coordinates, the transformations from one camera to the other are approximated as third-order polynomial functions of the absolute phase. The x coordinates involve only translations and scalings. These functions are calibrated and only need to be determined once. Experiments demonstrated that the alignment error is within RMS 0.7 mm …


Physical And Chemical Properties Of Corn Distillers Wet Grains, Kurt A. Rosentrater, R. Michael Lehman Jan 2008

Physical And Chemical Properties Of Corn Distillers Wet Grains, Kurt A. Rosentrater, R. Michael Lehman

Kurt A. Rosentrater

The production of corn-based ethanol in the United States is dramatically increasing, and consequently, so is the quantity of generated coproducts, all of which are currently fed to livestock. Distillers Wet Grain (DWG) is one of these coproduct feeds. Many studies have investigated the nutritional properties of DWG and the response of livestock (primarily beef and dairy) to inclusion of these ingredients in their diets. To date, physical properties have been largely ignored, but they are needed for the design of storage facilities and equipment. The objective of this research was to quantify physical and chemical property values for typical …


Concentration Of Key Elements In North American Meat & Bone Meal, Rafael A. Garcia, Kurt A. Rosentrater Jan 2008

Concentration Of Key Elements In North American Meat & Bone Meal, Rafael A. Garcia, Kurt A. Rosentrater

Kurt A. Rosentrater

Meat & bone meal (MBM) and related rendered protein commodities have potential for use in applications other than animal feed, including use as a fuel or a phosphorus fertilizer. In order to develop these applications, data on the elemental composition are required; the currently available elemental composition data have important limitations. To generate more appropriate and reliable data, MBM samples were collected from 17 North American rendering plants, carefully prepared and analyzed for 20 elements. Preliminary studies showed that the sample preparation process artificially increased levels of sulfur and nickel in a manner that was correctable. Concentrations of many elements …


Determining Machining Parameters Of Corn Byproduct Filled Plastics, Kurt A. Rosentrater, Andrew W. Otieno, Pratyusha Melampati Jan 2008

Determining Machining Parameters Of Corn Byproduct Filled Plastics, Kurt A. Rosentrater, Andrew W. Otieno, Pratyusha Melampati

Kurt A. Rosentrater

In a collaborative project between the USDA and Northern Illinois University, the use of corn ethanol processing byproducts (i.e., DDGS) as bio-filler materials in the compression molding of phenolic plastics has been studied. This paper reports on the results of a machinability study in the milling of various grades of this material. Three types of samples were studied: 100% (0% DDGS), 75% (25% DDGS), and 50% (50% DDGS) phenolic samples. The milling operation was carried out with a fixed depth of cut of 2.0 mm using a 12.5 mm diameter two-fluted end-mill. The cutting speed was varied between 120 and …


No Differences In Decomposition Rates Observed Between Bacillus Thuringiensis And Non-Bacillus Thuringiensis Corn Residue Incubated In The Field, R. Michael Lehman, Shannon L. Osborne, Kurt A. Rosentrater Jan 2008

No Differences In Decomposition Rates Observed Between Bacillus Thuringiensis And Non-Bacillus Thuringiensis Corn Residue Incubated In The Field, R. Michael Lehman, Shannon L. Osborne, Kurt A. Rosentrater

Kurt A. Rosentrater

Recent speculation of slower residue decomposition for Bacillus thuringiensis (Bt) corn (Zea mays L.) hybrids compared with non-Bt corn hybrids has prompted investigative study. We evaluated the residue decomposition rates of Bt and non-Bt corn hybrids over a period of 22 mo under field conditions using the litter bag technique. The four corn hybrids used were (i) DKC60–16 (Bt+, Cry1Ab protein active against the leptidopteran European corn borer, event MON810), (ii) DKC60–12 (Bt+, Cry3Bb1 protein active against the coleopteran corn rootworm, event MON863), (iii) DKC60–14 (stacked Bt++, Cry1Ab and Cry3Bb1 proteins) and, (iv) DKC60–15 (Bt−, base genetics). The biochemical and …


Sorption Isotherm Characteristics Of Distillers Dried Grains With Solubles (Ddgs), Vykundeshwari Ganesan, Kasiviswanathan Muthukumarappan, Kurt A. Rosentrater Jan 2008

Sorption Isotherm Characteristics Of Distillers Dried Grains With Solubles (Ddgs), Vykundeshwari Ganesan, Kasiviswanathan Muthukumarappan, Kurt A. Rosentrater

Kurt A. Rosentrater

Distillers dried grains with solubles (DDGS) is widely recognized as a highly nutritious animal feed ingredient. With the exponential growth of the fuel ethanol industry in the past several years, significant quantities of distillers grains are now being produced. To effectively utilize these feeds in the domestic market, these coproduct streams have to be transported greater distances and must be stored in various structures until final use. Unfortunately, DDGS flow is often problematic as it frequently becomes restricted by caking and bridging during storage and transport. This issue may arise from a number of factors, including storage moisture, temperature, relative …


Properties Of Distillers Grains Composites: A Preliminary Investigation, Vanessa Cheesbrough, Kurt A. Rosentrater, Jerry Visser Jan 2008

Properties Of Distillers Grains Composites: A Preliminary Investigation, Vanessa Cheesbrough, Kurt A. Rosentrater, Jerry Visser

Kurt A. Rosentrater

Interest in renewable biofuel sources has intensified in recent years, leading to greatly increased production of ethanol and its primary coproduct, Distillers Dried Grain with Solubles (DDGS). Consequently, the development of new outlets for DDGS has become crucial to maintaining the economic viability of the industry. In light of these developments, this preliminary study aimed to determine the suitability of DDGS for use as a biofiller in low-cost composites that could be produced by rapid prototyping applications. The effects of DDGS content, particle size, curing temperature, and compression on resulting properties, such as flexural strength, modulus of elasticity, water activity, …


Potential Bleaching Techniques For Corn Distillers Grains, Jessica A. Saunders, Kurt A. Rosentrater, P. G. Krishnan Jan 2008

Potential Bleaching Techniques For Corn Distillers Grains, Jessica A. Saunders, Kurt A. Rosentrater, P. G. Krishnan

Kurt A. Rosentrater

The ethanol industry is booming and extensive research is now being pursued to develop alternative uses for Distillers Dried Grains (DDG) and Distillers Dried Grains with Solubles (DDGS), coproducts of the ethanol production process. Currently, DDG and DDGS are used exclusively as livestock feed. The low starch, high protein and high fiber coproducts appear to be ideally suited for diets treating medical conditions such as diabetes and Celiac’s disease by virtue of their chemical composition. Processing methods need to be investigated to create flours that can be used effectively. Modifying aspects such as color, odor and baking functionality may eventually …


Effect Of Flow Agent Addition On The Physical Properties Of Ddgs With Varying Moisture Content And Soluble Levels, Kurt A. Rosentrater, Kasiviswanathan Muthukumarappan, Vykundeshwari Ganesan Jan 2008

Effect Of Flow Agent Addition On The Physical Properties Of Ddgs With Varying Moisture Content And Soluble Levels, Kurt A. Rosentrater, Kasiviswanathan Muthukumarappan, Vykundeshwari Ganesan

Kurt A. Rosentrater

Distillers Dried Grains with Solubles (DDGS) is widely recognized as a highly nutritious animal feed ingredient. With the exponential growth of the fuel ethanol industry in the past several years, significant quantities of distillers grains are now being produced. To effectively utilize these feeds in the domestic market, these coproduct streams have to be transported greater distances, and must be stored in various structures until final use. Unfortunately, DDGS flow is often problematic, as it frequently becomes restricted by caking and bridging during storage and transport. This issue may arise from a number of factors, including storage moisture, temperature, relative …