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Articles 1681 - 1710 of 2584

Full-Text Articles in Engineering

Measuring Ligand Exchange On The Surface Of Gold Nanoparticles: A Study Of Competitive Binding Of Ligands Utilizing Fluorescent Resonance Energy Transfer, Daniel D'Unger Aug 2012

Measuring Ligand Exchange On The Surface Of Gold Nanoparticles: A Study Of Competitive Binding Of Ligands Utilizing Fluorescent Resonance Energy Transfer, Daniel D'Unger

All Theses

This study was conducted to track ligand exchange on the surface of metallic nanoparticles in order obtain a better understanding of binding strength of various functional groups. This study develops groundwork for further understanding ligand exchange as nanoparticles transition from engineered to natural systems. A problem exists in knowing the fate of these particles if they are released into natural systems, by accident or with intent. To gain a better understanding of what may occur we look at the binding strength of different ligands. This is done to gain knowledge of the possibility of displacement of ligands occurring in the …

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Biomass And Lipid Production From Heterotrophic And Mixotrophic Fed-Batch Cultivations Of Microalgae Chlorella Protothecoides Using Glycerol, Shwetha Sivakaminathan Aug 2012

Biomass And Lipid Production From Heterotrophic And Mixotrophic Fed-Batch Cultivations Of Microalgae Chlorella Protothecoides Using Glycerol, Shwetha Sivakaminathan

All Theses

Chlorella protothecoides is a microalga that can grow both photo-autotrophically and/or heterotrophically under different culture and environmental conditions. In this study both the heterotrophic growth and mixotrophic growth have been conducted. The heterotrophic experiments were conducted completely in the dark while the mixotrophic experiments had the dark cycles with periodic light exposure. The aim of the study was to independently understand the effect of each mode on biomass and lipid yields.
For the heterotrophic experiments, glycerol was used as an external organic carbon source while yeast extract was used as the nitrogen source. The carbon and nitrogen source were added …

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Functionalized Nanoparticles As Removable Coatings For Reverse Osmosis Membranes, Megan Smith Aug 2012

Functionalized Nanoparticles As Removable Coatings For Reverse Osmosis Membranes, Megan Smith

All Theses

Reverse osmosis (RO) desalination is increasingly used to produce potable water throughout the world. Despite their promising abilities, membrane filtration processes are limited by fouling. Fouling is a broad term for organics, inorganics, colloids and organisms that interact physically, chemically, or biologically with the membrane surface, resulting in reduced flux and shortened membrane lifespan. There is potential to create a snakeskin-like barrier between the membrane and foulants by electrostatically binding a coating material to the membrane that can be released by pH manipulation, removing foulants in the process. The feasibility of using functionalized nanoparticles as removable adsorptive coatings on RO …

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Vibration And Acoustic Performance Of In-Plane Honeycomb Sandwich Panels, Xiao Gong Aug 2012

Vibration And Acoustic Performance Of In-Plane Honeycomb Sandwich Panels, Xiao Gong

All Theses

Sandwich panel structures constructed with cellular honeycomb cores allow for control of acoustic performance due to their ability to optimize effective orthotropic material properties with changes in cell geometry. By modification of topology and geometric parameters of a unit cell, desirable effective properties can be obtained and used to design lightweight structures with reduced vibration and increased sound transmission loss properties. Thus investigating the relation between the geometric configuration of the honeycomb core and vibration and acoustic behavior is important to optimize design of sandwich panels.
In this work, a finite element model is developed in MATLAB to evaluate the …

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Oral Delivery Of Peptide Drugs For Mitigation Of Crohn's Disease, Paul Blichmann Aug 2012

Oral Delivery Of Peptide Drugs For Mitigation Of Crohn's Disease, Paul Blichmann

All Theses

Protein drugs are typically administered intravenously, but this practice has clear disadvantages such as widespread circulation and swift clearance from the body. Orally delivered protein drugs are not yet available but potentially offer improved distribution, retention, and activity by use of protective matrices and cell-specific targeting. Much work has been done on delayed release formulations for the upper intestine, but there has not been overwhelming evidence of protection of peptides from gastric conditions. In many instances the large intestine may be a better release target due to lower proteolytic activity. Afflictions of the colon such as Inflammatory Bowel Disease and …

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Microstructural And Mechanical Characterization Of Soy-Based Polyethylene Fibers, Ozgun Ozdemir Aug 2012

Microstructural And Mechanical Characterization Of Soy-Based Polyethylene Fibers, Ozgun Ozdemir

All Theses

Bio-composite fibers have attracted increasing attention from environmentally-conscious consumers because of their low cost and biodegradability. Soy protein isolates and other purified forms have been proposed as bio-based substitutes for pure synthetic polymers for use in textiles. However, fibers from pure soy proteins do not possess adequate properties for use as textile fibers. Therefore, this research aimed to investigate composite fibers consisting of soy and polyethylene for their microstructure and mechanical properties. Changes in properties with increasing filler content and long-term properties of fibers were systematically examined.
First, the microstructure of the fibers was investigated by optical analysis. Six different …

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Relating Burst Pressure To Seal Peel Strength In Pouches, William Bernal Aug 2012

Relating Burst Pressure To Seal Peel Strength In Pouches, William Bernal

All Theses

This work was aimed at studying the relationship between burst pressure and seal peel strength. Past researchers developed a force balance equation based on the analysis of a force diagram to relate burst pressure to seal strength. The theoretical formula S=P(D/2) (S=Seal Strength, P=Burst Pressure, D=Restraining Plate Gap) has been studied by past researchers with contrasting results.
The theoretical formula was tested by varying dwell time to produce seals of varying strength. Pouches were burst tested at each of these dwell times to obtain burst pressures, burst peeling times, and burst locations. Corresponding peel tests were performed with crosshead speeds …

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Deformation And Adhesion Of Thin Metallic Films On Flexible Substrates, Julia Reid Aug 2012

Deformation And Adhesion Of Thin Metallic Films On Flexible Substrates, Julia Reid

All Theses

Flexible electronics are conductive circuits, components and lines integrated onto elastic substrates. These systems often consist of metallic thin films deposited onto thin sheets of glass, metals stainless steel or polymeric materials such as polyethylene or polystyrene. These systems are currently being studied for a wide variety of aeronautic and astronautical applications including: electronic skins, solar sails, and antennae structures. For applications include only moderately elevated temperatures (near 200 ¡C) and low strains (insert range), engineers have proposed incorporation metallic lines onto polymeric substrates. Like traditional microelectronic systems with films on hard substrates, the reliability is controlled by the film-substrate …

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The Formulation Of A Bone Targeted Drug Delivery System Of Poly(Glycolic Acid)-Poly(Ethylene Glycol) Coated Hydroxyapatite Nanoparticles For The Delivery Of Statins, Erika Jelen Aug 2012

The Formulation Of A Bone Targeted Drug Delivery System Of Poly(Glycolic Acid)-Poly(Ethylene Glycol) Coated Hydroxyapatite Nanoparticles For The Delivery Of Statins, Erika Jelen

All Theses

Bone is a form of mineralized connective tissue that provides strength and rigidity to the skeleton. The two primary components within bone tissue are an organic extracellular matrix, containing type I collagen, and an inorganic mineral component composed mainly of calcium phosphate hydroxyapatite crystals. Over time the microarchitecture of bone can break down due to a variety of different factors, mainly the onset of osteoporosis in post-menopausal women, Paget's disease, and the experience of a loss of gravity during space flight. Currently there are about ten million people in the United States alone suffering from osteoporosis.
The prevention of further …

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Design Of Advanced Fouling-Resistant And Self-Cleaning Membranes For Treatment Of Oily And Impaired Waters, Daniel Wandera Aug 2012

Design Of Advanced Fouling-Resistant And Self-Cleaning Membranes For Treatment Of Oily And Impaired Waters, Daniel Wandera

All Dissertations

The overall goal of my Doctor of Philosophy (PhD) research was to design and develop advanced anti-fouling and self-cleaning membranes for treating impaired waters. Initial work focused on the development of membranes to treat produced water, which is oily wastewater that is co-produced during oil and gas exploration. Economical, environmentally sustainable treatment of the large volumes of produced water is a grand challenge for oil and gas companies. While membranes offer many advantages over more conventional treatment methods, membrane-based treatment processes for oily waters often fail due to membrane fouling. Therefore, the primary objective of my doctoral research was to …

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Thermo-Mechanical Modeling Of The Electrically-Assisted Manufacturing (Eam) Technique During Open Die Forging, Wesley Salandro Aug 2012

Thermo-Mechanical Modeling Of The Electrically-Assisted Manufacturing (Eam) Technique During Open Die Forging, Wesley Salandro

All Dissertations

This thesis contains all of the steps which allow the Electrically-Assisted Manufacturing (EAM) technique to be experimentally explored and analytically modeled for an electrically-assisted forging operation. Chapter 1 includes the problem statement, proposed solution, and literature reviews on EAM. Chapter 2 describes a thorough background on the EAM technique, highlights prior EAM research, and explains the research approach taken for this thesis. The coupled thermo-mechanical modeling strategy, along with the introduction of the Electroplastic Effect Coefficient (EEC) is provided in Chapter 3. Chapter 4 explains the two different approaches to determine the EEC profiles when modeling a particular metal. The …

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Investigating The Role Of Mechanosensitive Ion Channels In Urothelial Cell Pressure Mechanotransduction, Shawn Olsen Aug 2012

Investigating The Role Of Mechanosensitive Ion Channels In Urothelial Cell Pressure Mechanotransduction, Shawn Olsen

All Dissertations

Overactive bladder (OAB) is a bladder disorder that is characterized by bladder storage symptoms of urgency with or without urge incontinence, frequency, nocturia, and, as of 2003, affected approximately 16.5% of adults in the United States with an annual treatment cost of over $65 billion. While therapies are available to mitigate the symptoms of OAB, there are no treatments for the cause of OAB, due to the lack of understanding of the etiology of the disorder. Recent research has provided evidence that the bladder urothelium is not just a passive barrier, but is also sensitive to various chemical and mechanical …

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Engineering Single-Molecule, Nanoscale, And Microscale Bio-Functional Materials Via Click Chemistry, Michael Daniele Aug 2012

Engineering Single-Molecule, Nanoscale, And Microscale Bio-Functional Materials Via Click Chemistry, Michael Daniele

All Dissertations

To expand the design envelope and supplement the materials library available to biomaterials scientists, the copper(I)-catalyzed azide-alkyne cycloaddition (CuCAAC) was explored as a route to design, synthesize and characterize bio-functional small-molecules, nanoparticles, and microfibers. In each engineered system, the use of click chemistry provided facile, bio-orthogonal control for materials synthesis; moreover, the results provided a methodology and more complete, fundamental understanding of the use of click chemistry as a tool for the synergy of biotechnology, polymer and materials science. Fluorophores with well-defined photophysical characteristics (ranging from UV to NIR fluorescence) were used as building blocks for small-molecule, fluorescent biosensors. Fluorophores …

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Prediction Of The Wear & Evolution Of Cutting Tools In A Carbide / Ti-6al-4v Machining Tribosystem By Volumetric Tool Wear Characterization & Modeling, Mathew Kuttolamadom Aug 2012

Prediction Of The Wear & Evolution Of Cutting Tools In A Carbide / Ti-6al-4v Machining Tribosystem By Volumetric Tool Wear Characterization & Modeling, Mathew Kuttolamadom

All Dissertations

The objective of this research work is to create a comprehensive microstructural wear mechanism-based predictive model of tool wear in the tungsten carbide / Ti-6Al-4V machining tribosystem, and to develop a new topology characterization method for worn cutting tools in order to validate the model predictions. This is accomplished by blending first principle wear mechanism models using a weighting scheme derived from scanning electron microscopy (SEM) imaging and energy dispersive x-ray spectroscopy (EDS) analysis of tools worn under different operational conditions. In addition, the topology of worn tools is characterized through scanning by white light interferometry (WLI), and then application …

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Prognostic And Health-Management Oriented Fuel Cell Modeling And On-Line Supervisory System Development, Xian Zhang Aug 2012

Prognostic And Health-Management Oriented Fuel Cell Modeling And On-Line Supervisory System Development, Xian Zhang

All Dissertations

Of the fuel cells being studied, the proton exchange membrane fuel cell (PEMFC) is viewed as the most promising for transportation. Yet until today, the commercialization of the PEMFC has not been widespread in spite of its large expectation. Poor long term performances or durability, and high production and maintenance costs are the main reasons. For the final commercialization of fuel cells in the transportation field, durability issues must be addressed, while costs should be further brought down. At the same time, health-monitoring and prognosis techniques are of great significance in terms of scheduling condition-based maintenance (CBM) to minimize repair …

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Laboratory Characterization And Theoretical Analysis Of Contaminant Mass Transfer, Xiaoling Liu Aug 2012

Laboratory Characterization And Theoretical Analysis Of Contaminant Mass Transfer, Xiaoling Liu

All Dissertations

Chlorinated volatile organic compounds (CVOCs) in fractured, low permeability material can be a long-term source of groundwater contaminants and they are among the most difficult remediation challenges. Thermal methods are a possible remediation option, where heat is used to boil water and the volatile compounds are stripped out by partitioning into the resulting water vapor. Theoretical analysis indicates that only a small fraction of pore water removal may lead to a significant geometric reduction in the dissolved concentration [(Udell(, 1998]. Previous modeling studies [(Falta and Murdoch(, 2011; (Pruess(, 1983] suggest that a lower permeability limit exists for effective mass transfer …

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On Simulation And Modeling Of Turbulent Non-Premixed Reacting Shear Flames At Low And High Pressure, Justin Foster Aug 2012

On Simulation And Modeling Of Turbulent Non-Premixed Reacting Shear Flames At Low And High Pressure, Justin Foster

All Dissertations

A database of simulations of fundamental turbulent H2/O2 and H2/Air shear layer flames has been developed using the direct numerical simulation technique in which all length and time scales of a flow are fully resolved without resort to turbulence modeling. The formulation includes the fully-compressible form of the governing equations, a pressure dependent detailed chemical kinetics scheme (9 species, 19 steps), a cubic real gas equation of state, realistic property models, and generalized heat and mass diffusion models. Simulations were conducted for a temporally developing shear layer geometry and cover a wide range of initial pressures (1 atm < P < 125 atm) and flame Reynolds numbers (850 < Re < 4500). These supercomputing simulations are the largest yet performed for high pressure conditions to the author's knowledge. Computational requirements for the largest simulations included mesh sizes of ~3/4 billion grid points and ~2.2 million CPU-hrs conducted on nearly 4,000 CPU cores on Clemson's Palmetto cluster.

The database …

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Propagation Of Uncertainty In Light-Frame Wood Buildings, Seyed Masood Hassanzadehshirazi Aug 2012

Propagation Of Uncertainty In Light-Frame Wood Buildings, Seyed Masood Hassanzadehshirazi

All Dissertations

Light-frame wood construction is the most common form of construction for residential and low-rise commercial buildings (e.g. hotels and motels) in North America. In these buildings, shearwalls are the primary systems resisting lateral loads induced by earthquakes and winds. Past earthquake events have revealed that the structural performance of nominally identical light-frame wood buildings varied significantly. Although much research has been conducted investigating the uncertainty in the performance of wood shearwalls and buildings under earthquake loading, the focus of many of these studies was on the uncertainty due to the earthquake motions, referred as earthquake-to-earthquake uncertainty, the influences of variability …

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Model Of A Mechanical Clock Escapement, John Wagner, David Moline, Eugene Vold Jul 2012

Model Of A Mechanical Clock Escapement, John Wagner, David Moline, Eugene Vold

Publications

The mechanical tower clock originated in Europe during the 14th century to sound hourly bells and later display hands on a dial. An important innovation was the escapement mechanism, which converts stored energy into oscillatory motion for fixed time intervals through the pendulum swing. Previous work has modeled the escapement mechanism in terms of inelastic and elastic collisions. We derive and experimentally verify a theoretical model in terms of impulsive differential equations for the Graham escapement mechanism in a Seth Thomas tower clock. The model offers insight into the clock’s mechanical behavior and the functionality of the deadbeat escapement mechanism.

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Deviations In Standard Aggregate Gradation And Its Affects On The Properties Of Portland Cement Concrete, Marcus Balitsaris Jun 2012

Deviations In Standard Aggregate Gradation And Its Affects On The Properties Of Portland Cement Concrete, Marcus Balitsaris

All Theses

Aggregate gradation is the particle size distribution of both the stone and sand present in the concrete matrix. It is an aggregate property that has been heavily researched for over a century but the effects of which on concrete properties is still somewhat misunderstood. Past research has revealed that aggregate gradation dictates the proportion of aggregate to cement paste in concrete, and can play a major variable that determines the overall durability of the construction material. Increasingly, aggregate in South Carolina are failing to meet the standard aggregate gradation for portland cement concrete, however, the effects of such failed aggregate …

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Resource Allocation Framework: Validation Of Numerical Models Of Complex Engineering Systems Against Physical Experiments, Joshua Hegenderfer Jun 2012

Resource Allocation Framework: Validation Of Numerical Models Of Complex Engineering Systems Against Physical Experiments, Joshua Hegenderfer

All Dissertations

An increasing reliance on complex numerical simulations for high consequence decision making is the motivation for experiment-based validation and uncertainty quantification to assess, and when needed, to improve the predictive capabilities of numerical models. Uncertainties and biases in model predictions can be reduced by taking two distinct actions: (i) increasing the number of experiments in the model calibration process, and/or (ii) improving the physics sophistication of the numerical model. Therefore, decision makers must select between further code development and experimentation while allocating the finite amount of available resources. This dissertation presents a novel framework to assist in this selection between …

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Mobile Devices Within Manufacturing Environments: A Bmw Applicability Study, Beshoy Morkos, Torsten Rilka, Joachim Taiber, Joshua D. Summers, Laine Mears, Georges Fadel May 2012

Mobile Devices Within Manufacturing Environments: A Bmw Applicability Study, Beshoy Morkos, Torsten Rilka, Joachim Taiber, Joshua D. Summers, Laine Mears, Georges Fadel

All CEDAR Publications

With the growing need of mobile devices within manufacturing industries, new domains for their use in automotive OEMs have emerged. Advent technology has enabled the development of devices such as ultra-mobile personal computers that provide the function of a computer in a compact, mobile configuration and augmented reality (wearable mobile devices) in a production environment where hands free operation is essential. The use of mobile devices allows for more effective communication and data sharing/recording. This paper details BMW’s preliminary investigation and applicability study of implementing mobile devices within their manufacturing environment to view potential benefits that could be achieved. Manufacturing …

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Assembly Time Modeling Through Connective Complexity Metrics, James L. Mathieson, Bradley A. Wallace, Joshua D. Summers May 2012

Assembly Time Modeling Through Connective Complexity Metrics, James L. Mathieson, Bradley A. Wallace, Joshua D. Summers

All CEDAR Publications

This paper presents an approach for the development of surrogate models predicting the assembly time of a system based on complexity metrics of the physical system architecture when detailed geometric information is unavailable. A convention for modelling physical architecture is presented, followed by a sample of 10 analysed systems used for training and three systems used for validation. These systems are evaluated on complexity metrics developed from graph theoretic measures. An example model is developed based on a series of regressions of trends observed within the sample data. This is validated against the systems that are not used to develop …

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Evaluation Of An Enrichment Culture That Reductively Dechlorinates Γ-Hexachlorocyclohexane, Christina Anderson May 2012

Evaluation Of An Enrichment Culture That Reductively Dechlorinates Γ-Hexachlorocyclohexane, Christina Anderson

All Theses

In a previous study using microcosms from a site contaminated with γ- hexachlorocyclohexane (γ-HCH), rapid anaerobic biodegradation of γ-HCH to benzene and chlorobenzene was observed. Enrichment cultures were developed and subsequently transferred to an anaerobic sulfate-free HEPES buffered medium without loss of γ-HCH dechlorination, thus suggesting γ-HCH undergoes anaerobic biodegradation via chlororespiration. The overall objective of this thesis was to further characterize the enrichment culture.
To do so, one specific objective was to determine the effect of vancomycin on γ-HCH in an enrichment culture grown in a sulfate-free HEPES buffered medium using hydrogen as the electron donor. This objective would …

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A Tool For Selection Of Design For Manufacturing And Assembly Rules During Product Design Stage While Considering End Of Life Conditions, Vikrant Rayate May 2012

A Tool For Selection Of Design For Manufacturing And Assembly Rules During Product Design Stage While Considering End Of Life Conditions, Vikrant Rayate

All Theses

The research presents a tool for selecting appropriate Design for Manufacturing and Design for Assembly rules during product design while considering Design for Disassembly rules and end-of-life recovery conditions. This tool exposes the relations between the various types of design rules and end-of-life recovery parameters. Four different relationship types are developed in this research: recovery conditions and recovery options relationship, Design for Disassembly rules and recovery options relationship, Design for Disassembly rules and recovery conditions relationship, Design for Disassembly rules, and Design for Manufacturing and Design for Assembly rules relationship. The purpose of this tool is to build these relations …

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Piercing The Cloud And Marking The Onion: Removing The Anonymity Of The Tor Network, James Ashworth May 2012

Piercing The Cloud And Marking The Onion: Removing The Anonymity Of The Tor Network, James Ashworth

All Theses

In this work, we extend previous work done on removing anonymity from The Onion Routing network (Tor). We explore previous techniques for removing Tor's anonymity developed on a private Tor network, and attempt to reproduce these results on the global public network.
We find that the previous work done on the private network is unable to be carried over to the public network. This is mainly due to the level of jitter on the public network overwhelming our earlier method for compromising Tor's anonymity. We develop a new method for compromising Tor's anonymity by using a clustering algorithm to analyze …

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Surface Characterization Of Nephila Clavipes Dragline Silk, Benoit Faugas May 2012

Surface Characterization Of Nephila Clavipes Dragline Silk, Benoit Faugas

All Theses

To design synthetic fibers for extreme applications, many research groups are trying to identify how the structure of natural fibers (such as spider silk) leads to desirable properties such as high tensile strength.
Spider silk is a biological fiber having mechanical properties that exceed those of the best man made fibers in terms of high tensile strength and large extensibility, this combination providing the silk with a large work of rupture. While the bulk structure, composition and properties have been intensively studied elsewhere, this study focuses on elucidating the Nephila clavipes spider dragline silk surface structure and composition, as well …

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A New Metaheuristic Algorithm Motivated By The Rooting Phenomena In Plants, Behzad Nemati May 2012

A New Metaheuristic Algorithm Motivated By The Rooting Phenomena In Plants, Behzad Nemati

All Theses

In this thesis, we present a new metaheuristic algorithm for analyzing challenging optimization problems. Initial testing reveals the potential for the algorithm, which is based on the rooting phenomena found in plants in nature, to quickly produce effective solutions to challenging combinatorial optimization problems in the class NP. We present computational results describing the proposed metaheuristic's efficacy for an important class of scheduling problems and discuss areas of future work and application.

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Finite Element Modeling And Design Of Honeycomb Sandwich Panels For Acoustic Performance, David Griese May 2012

Finite Element Modeling And Design Of Honeycomb Sandwich Panels For Acoustic Performance, David Griese

All Theses

Honeycomb cellular metamaterial structures offer many distinct advantages over homogenous materials because their effective material properties depend on both their constituent material properties and their geometric cell configuration. From this, a wide range of targeted effective material properties can be achieved thus supporting forward design by tailoring the honeycomb cellular materials and properties for specific applications. One area that has not been fully explored is the set of acoustic properties of honeycomb materials and how these can offer increased design flexibility when targeting acoustic performance. Understanding these relations, the designer can effectively tune designs to perform better in specific acoustic …

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Application Of Microbial Fuel Cells In A Forested Wetland, Jianing Dai May 2012

Application Of Microbial Fuel Cells In A Forested Wetland, Jianing Dai

All Theses

ABSTRACT
Electricity can be generated from forest residues, especially the organic matter from litter fall, in freshwater forested wetland environments with a microbial fuel cell (MFC) system. Electricity generation efficiency was examined for cypress, tupelo, and pine litter extracts, using dual-chamber reactors. The maximum power density generated with cypress extracts was on the level of 320 mW/m2, higher than tupelo (230 mW/m2), and pine (210 mW/m2). The efficacy of cypress extracts was also higher than tupelo and
pine, demonstrating that organic matter from cypress litter is a preferred substrate for electricity generation with MFCs. Meanwhile, low aromaticity of the substrate …

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