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Articles 2701 - 2730 of 3637

Full-Text Articles in Engineering

Development In Crosslinking System For Natural Rubber And Epoxidized Natural Rubber, Nuttida Srirachya Jan 2018

Development In Crosslinking System For Natural Rubber And Epoxidized Natural Rubber, Nuttida Srirachya

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research was divided into two parts. The first part was to investigate the possibility to use maleic anhydride (MA) as a crosslinking agent for epoxidized natural rubber (ENR). The second one was to investigate the possibility to prepare the thermoreversible crosslinking of natural rubber (NR) when using glycerol (Gly) or diethylene glycol (DGly) as a thermoreversible crosslinking agent. For the first part, it was found that both ENR25 and ENR50 can be crosslinked with MA. From FT-IR spectra, the emerge of two peaks at 1735 cm-1 and 1710 cm-1 indicated that the crosslinking was taken place by the ring …


A Numerical Investigation Of Augmented Heat Transfer In Rectangular Ducts With Ribs, Warissara Tangyotkhajorn Jan 2018

A Numerical Investigation Of Augmented Heat Transfer In Rectangular Ducts With Ribs, Warissara Tangyotkhajorn

Chulalongkorn University Theses and Dissertations (Chula ETD)

The application of roughness structure of ribs inside a smooth channel is one effective way of heat transfer augmentation, but the accompanied pressure drop could be high. A novel V-rib design with branches was introduced and numerical simulations on the thermo-fluid impact of heat transfer and pressure drop were investigated. The parameters of investigation include the branching number and the pitch ratio of the V-ribs. It appears that increasing the relative pitch ratio serves to improve the overall performance of a roughened channel. The effect of the branching number is only experienced at low pitch ratio. At high pitch ratio, …


Effect Of Chromium Content On Heat Treatment Behavior And Abrasive Wear Resistance Of Multi-Alloyed White Cast Iron, Jatupon Opapaiboon Jan 2018

Effect Of Chromium Content On Heat Treatment Behavior And Abrasive Wear Resistance Of Multi-Alloyed White Cast Iron, Jatupon Opapaiboon

Chulalongkorn University Theses and Dissertations (Chula ETD)

The effect of Cr content on heat treatment behavior and abrasive wear resistance of multi-alloyed white cast irons with basic composition was investigated. The cast irons with varying Cr content from 3-9% were prepared. The annealed specimens were hardened from 1323K and 1373K austenitizing and then, tempered at 673K to 873K with 50K intervals. The microstructure of each specimen consisted of primary austenite dendrite (γP) and (γ+MC) and (γ+M2C) eutectics in specimens with 3 and 5%Cr. By contrast, (γ+M7C3) eutectic appeared in specimens with 6%Cr and more. The matrix in as-cast state was mostly retained austenite but that in as-hardened …


Preparation And Characterization Of Nickel Based Nanocomposite Coatings With Enhanced Mechanical And Surface Properties, Malay Kumar Das Jan 2018

Preparation And Characterization Of Nickel Based Nanocomposite Coatings With Enhanced Mechanical And Surface Properties, Malay Kumar Das

Chulalongkorn University Theses and Dissertations (Chula ETD)

Ni-W alloy and Ni-W/diamond monolayer and multilayer composite coatings were prepared by electrodeposition from a Ni-W plating bath with diamond particles suspended into the bath. Ni-W/diamond composite coatings were also prepared with varying amounts of Cobalt sulphate additives. The morphology and the composition of the deposits was investigated by means of SEM and EDS, respectively. The effect of operating conditions and additives on the Ni-W coatings were analyzed. The effect of the plating parameters, composite particle size, multilayer deposits and cobalt additives on microstructure and mechanical properties of the Ni-W/diamond composite coatings was investigated. The electrodeposited Ni-W/diamond deposits reported a …


Preparation Of Graphene Nanocomposites For Anticorrosion And Sensors, Nadtinan Promphet Jan 2018

Preparation Of Graphene Nanocomposites For Anticorrosion And Sensors, Nadtinan Promphet

Chulalongkorn University Theses and Dissertations (Chula ETD)

This dissertation focused on the development of graphene (GO) nanocomposite coating to improve various substrate properties for the sensor application, which is divided into 2 main parts. The first part is the development of GO incorporated into electroless nickel phosphorus (NiP) coating to improve the properties of metal for electrochemical sensor application. Nickel phosphorus - titanium dioxide sol - reduced graphene oxide (NiP-TiO2 sol -RGO) coated surface was successfully prepared by one-pot electroless deposition on the steel substrate. The results show that the homogeneously formation of water-repellent RGO film covering on the coated surface leading to improve the corrosion resistance …


Synthesis Of High Efficiency Amidoxime Polymer Adsorbents For Uranium Extraction From Seawater By Radiation-Induced Polymerization, Wijittra Wongjaikham Jan 2018

Synthesis Of High Efficiency Amidoxime Polymer Adsorbents For Uranium Extraction From Seawater By Radiation-Induced Polymerization, Wijittra Wongjaikham

Chulalongkorn University Theses and Dissertations (Chula ETD)

This study synthesized amidoxime polymer gel for uranium extraction from seawater through a polymerization process with gamma ray or UV-C radiation. The synthesis started with a mixture of acrylonitrile (AN) and methacrylic acid (MAA) monomers together with methylene bisacrylamide as a crosslinker and hydrogen peroxide in the case of UV radiation. The mixture was irradiated with gamma ray at various doses or UV-C for various durations. The resulting polymer gel was ground into fine particles and immersed in a hydroxylamine hydrochloride solution for 90 minutes in order to convert the chemical functional group from the cyano group into the amidoxime …


Green Composites Of Polylactic Acid Filled With Natural Fiber For Biodegradation Application, Chamaiporn Yamoum Jan 2018

Green Composites Of Polylactic Acid Filled With Natural Fiber For Biodegradation Application, Chamaiporn Yamoum

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research focuses on how to use natural fibers available from agricultural residues to produce biodegradable materials such as mulch films. Green composites were prepared from natural fibers (peanut shell and bagasse fiber) and polylactic acid (PLA) together with plasticizers. The presence of plasticizers improved PLA molecular mobility as seen by the reduction of glass transition, cold crystallization, and melting temperatures. The addition of natural fibers into PLA brought down decomposition temperature when compared to PLA. The morphological study of the composites showed poor interfacial adhesion between natural fibers and PLA matrix. Moreover, the loading of plasticizers improved distribution of …


Production Of Biojet Fuel From Palm Fatty Acid Distillate Over Ni/Hzsm-12 Catalyst, Chayanee Hiranyasiri Jan 2018

Production Of Biojet Fuel From Palm Fatty Acid Distillate Over Ni/Hzsm-12 Catalyst, Chayanee Hiranyasiri

Chulalongkorn University Theses and Dissertations (Chula ETD)

Generally, jet fuels are mainly derived from the refining of petroleum feedstock which exhaust greenhouse gases. Therefore, biojet fuel is introduced as an alternative way to solve the problem. Moreover, jet fuel must have a freezing point about -47 °C or below so iso-paraffins which have low freezing point are required. In this study, the hydroprocessing of palm fatty acid distillate (PFAD) over synthesized Ni/HZSM-12 and conventional Ni/HY catalysts which have different morphology and pore size for producing biojet fuel (hydrocarbon in a range of C9-C14) was studied in a continuous flow fixed-bed reactor under conditions of 350-400 °C, 10-30 …


Chance Constrained Optimization For Petrochemical Supply Chain With The Validation Technique, Kan Rungphanich Jan 2018

Chance Constrained Optimization For Petrochemical Supply Chain With The Validation Technique, Kan Rungphanich

Chulalongkorn University Theses and Dissertations (Chula ETD)

Nowadays, the profit is more concern in industry due to high business competition. Therefore, reducing the cost is needed to survive competition. Stochastic optimization had been interesting method to reduce opportunity and over-demand loss in the supply chain under uncertainties. Chance constrained optimization is one of the approaches to stochastic optimization. The uncertainties are included in chance constraint of event under level of confidence. This method is used to design the realistic supply chain giving more stabilities than deterministic optimization. The two case studies have been used to show the effectiveness of chance constrained optimization: the simple supply chain network …


Methane And Carbon Dioxide Adsorption On Al-Based And Zr-Based Mofs: Effects Of Amino-Functionalization, Orawee Lamoonkit Jan 2018

Methane And Carbon Dioxide Adsorption On Al-Based And Zr-Based Mofs: Effects Of Amino-Functionalization, Orawee Lamoonkit

Chulalongkorn University Theses and Dissertations (Chula ETD)

For natural gas storage, adsorbed natural gas (ANG) technology has attracted great attention. There is a wide range of porous materials for ANG, but the most promising porous adsorbents for natural gas are metal organic frameworks (MOFs). This study examined adsorption of carbon dioxide and methane gases on aluminium (Al) based MOFs and zirconium (Zr) based MOFs including MIL-53(Al), MIL-53(Al)-NH₂, UiO-66, UiO-66-NH₂ 25%, UiO-66-NH₂ 50%, UiO-66-NH₂ 75%, and UiO-66-NH₂. Experiments were carried out in a static system at 33°C and pressures up to 100 psi. Characterization and structural analysis of the adsorbents were investigated by Fourier transform infrared spectroscopy (FTIR), …


Novel Microemulsion Formation By The Hydrophilic- Lipophilic Deviation Concept Using Carboxylate Extended Surfactants For Eor Application, Suchawadee Kumkhuntod Jan 2018

Novel Microemulsion Formation By The Hydrophilic- Lipophilic Deviation Concept Using Carboxylate Extended Surfactants For Eor Application, Suchawadee Kumkhuntod

Chulalongkorn University Theses and Dissertations (Chula ETD)

The Winsor type III (middle phase) microemulsion formation is widely used for enhanced oil recovery (EOR) application. A novel carboxylate surfactant has been an attractive surfactant for the oil recovery due to high chemical stability in harsh reservoir conditions (i.e., high brine concentration and high temperature). This study aims to formulate the middle phase microemulsion in order to obtain the minimum IFT and high solubilization capacity with binary anionic surfactant system using sodium dioctyl sulfosuccinate (AOT) and carboxylate extended surfactants with varying the polyethylene oxide number (EO = 2, 4 and 6) at three mixing molar ratios of 5:5, 7:3 …


Detergency Of Mixed Oily And Particulate Soils By Single And Mixed Surfactant Systems, Thanawan Teerasathittham Jan 2018

Detergency Of Mixed Oily And Particulate Soils By Single And Mixed Surfactant Systems, Thanawan Teerasathittham

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research studies the detergency performance of mixed surfactants of (anionic and nonionic surfactants) for mixed oily and particulate soils on polyester/cotton blend fabric, and compares with a commercial liquid detergent. Palm oil and kaolinite are used as representatives of oily soil and particulate soil, respectively. The anionic surfactants used in this study are methyl ester sulfonate (MES), linear alkyl benzene sulfonate (LAS) and sodium dodecyl sulfate (SDS). The nonionic surfactants are alcohol ethoxylate 7EO (AE7) and alcohol ethoxylate 9EO (AE9). The effect of surfactant concentrations, NaCl concentration, and mixing ratios of the selected surfactant formulations on detergency performance are …


Evaluation Of Environmental Impacts For Non-Metallic Part In Waste Printed Circuit Boards (Pcbs) Using Combined Material Flow Analysis (Mfa) And Life Cycle Assessment (Lca), Warisara Rungsitikul Jan 2018

Evaluation Of Environmental Impacts For Non-Metallic Part In Waste Printed Circuit Boards (Pcbs) Using Combined Material Flow Analysis (Mfa) And Life Cycle Assessment (Lca), Warisara Rungsitikul

Chulalongkorn University Theses and Dissertations (Chula ETD)

Printed circuit boards (PCBs) have become common components in most electric and electronic equipment. Because of their wide ranges of application, waste PCBs is becoming one of the most rapidly growing wastes. Recycling of waste PCBs is an important subject not only for the protection of the environment but also for the recovery of valuable metals. This study aimed to evaluate the waste PCBs management strategies using the combination of material flow analysis (MFA, STAN v.2.6.801) and life cycle assessment (LCA, SimaPro v.8.3.0.0) methods. The waste management scenario was considered for three different options; disposal of the waste PCBs (Option …


Removal Of Mixed Vocs Of Benzene, Toluene, And Xylene By Using Catalytic Corona Discharge System, Issaree Tantiprapa Jan 2018

Removal Of Mixed Vocs Of Benzene, Toluene, And Xylene By Using Catalytic Corona Discharge System, Issaree Tantiprapa

Chulalongkorn University Theses and Dissertations (Chula ETD)

Silver (Ag) and Manganese (Mn) catalysts were loaded on TiO₂ and Al₂O₃ supports on quartz wool that were tested for the oxidation of mixed Volatile Organic Compounds (VOCs) of benzene, toluene, and xylene in nonthermal plasma corona discharge. The total feed concentration of VOCs was fixed at 100 ppm. The catalyst located between the pin and plate electrodes with a constant gap distance of 15 mm and the pin and plate plasma reactor had an inside diameter of 9 mm. The outlet stream was analyzed by gas chromatography equipped with TCD and FID detectors. The operating parameters including applied voltage, …


Adsorption Of Methane And Carbon Dioxide On Activated Carbon And Metal Organic Frameworks, Chutima Sudsuansi Jan 2018

Adsorption Of Methane And Carbon Dioxide On Activated Carbon And Metal Organic Frameworks, Chutima Sudsuansi

Chulalongkorn University Theses and Dissertations (Chula ETD)

Natural gas has gain popularity for transportation among other fuels since it is the cleanest burning fossil fuel. However, the important challenge for utilizing natural gas is its comparatively low volumetric energy storage density. Consequently, a suitable natural gas storage is needed. Adsorbed natural gas (ANG) is an interesting alternative because it could be expected to reduce the cost and potential damage from compressed natural gas (CNG) and liquefied natural gas (LNG) technology. Comparative adsorption of methane and carbon dioxide on activated carbon ZIF-8, UiO-66, and MIL-53 (Al) was investigated at 35 °C and up to 100 psi. The addition …


Identification Of Crude Oils And Fuel Oils After Weathering Using Biomarkers, Pyrogenic Index And Asphaltenes Contents, Hathairat Thongkorn Jan 2018

Identification Of Crude Oils And Fuel Oils After Weathering Using Biomarkers, Pyrogenic Index And Asphaltenes Contents, Hathairat Thongkorn

Chulalongkorn University Theses and Dissertations (Chula ETD)

Oil spills have become a global problem. This is one of the serious problems in marine environment. The spills are generally from reservoir zipping, accident or unauthorized drainage. Typically, the spilled oils are fuel oils or crude oils which are difficult to differentiate. After oil spill incident, oils are undergone weathering processes such as evaporation, dissolution, and biodegradation etc., which are main factor of depleting hydrocarbon. This work focuses on the distribution of hydrocarbon and diagnostic ratio of polycyclic aromatic hydrocarbons such as pristane, phytane, phenanthrene, pyrene, chrysene and biomarker in hopane group after weathering processes. Moreover, measuring of Al, …


Heat Exchanger Network Retrofit Under Fouling Effect, Jaturaporn Yanyongsak Jan 2018

Heat Exchanger Network Retrofit Under Fouling Effect, Jaturaporn Yanyongsak

Chulalongkorn University Theses and Dissertations (Chula ETD)

The energy conservation by heat exchanger network (HEN) is important in process design according to an increase of energy costs and global environmental concerns. To minimize the energy consumption with positive net present value (NPV), the retrofitted HEN plays an important role in process energy systems. The HEN retrofit model is based on stage-wise superstructure by Yee and Grossmann (1990). In addition, fouling deposition on the surface area of heat exchangers causes extra energy consumption, production loss and maintenance costs. The new proposed model is retrofitting HEN with fouling effects. This method achieves HEN with the optimal trade-offs between energy …


Methane Hydrate Formation And Dissociation : Roles Of Promoters, Kimhak Neak Jan 2018

Methane Hydrate Formation And Dissociation : Roles Of Promoters, Kimhak Neak

Chulalongkorn University Theses and Dissertations (Chula ETD)

Roles of promoters become necessary in methane hydrate formation for the attempt of gas storage application, but some additives might cause unwanted results in gas recovery. The effects of amino acids (l-leucine and l-valine) and surfactants, sodium dodecyl sulfate (SDS), and methyl ester sulfonate (MES) was investigated at 8 MPa and 2 to 4 °C. L-leucine system enhanced hydrate formation because of its surface activity and surface adsorption at interfaces. A noticeable methane uptake yield was also observed in the l-valine solution. Its influences might be from the nature of l-valine that has non-polar, aliphatic hydrophobic side chain resulting in …


Optimization Of Single Refrigerant Conocophillips Lng Cascade Process, Naken Saetang Jan 2018

Optimization Of Single Refrigerant Conocophillips Lng Cascade Process, Naken Saetang

Chulalongkorn University Theses and Dissertations (Chula ETD)

An LNG cascade process operates under high pressure and extremely low temperature to liquefy natural gas, requiring very high work input to the compressors. This thesis performed the optimization of the single refrigerant ConocoPhillips LNG process by a global optimization technique based on the domain and image partitioning methodology (Faria and Bagajewicz, 2012) to minimize work input to the system. The procedure consists of an NLP upper bound and MILP lower bound models. The lower bound model was formulated by discretizing and linear relaxation of the upper bound non-linear equations by assigning new integer variables and a set of linear …


Energy And Exergy Analysis For Cryogenic Process Design/Retrofit, Nattawat Threerachannarong Jan 2018

Energy And Exergy Analysis For Cryogenic Process Design/Retrofit, Nattawat Threerachannarong

Chulalongkorn University Theses and Dissertations (Chula ETD)

Energy and Exergy analysis are one of alternative techniques to analyze chemical processes in term of energy quality parameters such as enthalpy, entropy and exergetic temperature. The exergetic temperature can conduct Exergy Composite Curves diagram (ECCs) (Marmolejo-Correa, 2012) which represents exergy targets: exergy requirement, exergy rejection and exergy destruction etc. In addition, these targets can be used for improving processes. The strength points of these analysis are to design the new process and to improve the utility performance. Therefore, these analysis methods have been applied to low-temperature process that requires a large amount of energy consumption. In this work, there …


Removal Of Mixed Vocs Of Benzene, Toluene And Xylene By A Multistage Corona Discharge System, Nitikorn Ditthawat Jan 2018

Removal Of Mixed Vocs Of Benzene, Toluene And Xylene By A Multistage Corona Discharge System, Nitikorn Ditthawat

Chulalongkorn University Theses and Dissertations (Chula ETD)

The oxidation of mixed volatile organic compounds (VOCs) of benzene, tol-uene and xylene in non-thermal plasma corona discharge was investigated. An initial total VOCs concentration of 100 ppm and feed flow rate of 50.0 ml/min were firstly fixed to investigate the effects of an applied voltage and input frequency on VOCs conversion, power consumption and CO₂ and CO selectivities. For a single stage plasma system, under the optimum applied voltage of 8 kV and input frequency of 500 Hz, the system gave the high CO₂ selectivity with the low CO selectivity and the lowest power consumption. At the optimum operationable …


Life Cycle Assessment Of End Of Life Strategies For Waste From Petroleum Production, Nuntawat Urairat Jan 2018

Life Cycle Assessment Of End Of Life Strategies For Waste From Petroleum Production, Nuntawat Urairat

Chulalongkorn University Theses and Dissertations (Chula ETD)

The waste treatment and disposal of oil refining industry sector are one of the significant aspects of environmental concerns. Because they are not only generated in substantial amounts, but also contained with various hazardous substances such as waste oils, spent catalysts, and mercury-contaminated materials. This study aimed to develop and evaluate the waste management strategies, from waste generator (WG) to waste processors (WP), using the material flow analysis (MFA, STAN v.2.6.601) and life cycle assessment (LCA, SimaPro v.8.3.0.0) as an assessment tool. The functional unit is the amount of waste generated from six refineries in the year 2015. The waste …


Kinetics Study For Fischer-Tropsch Synthesis Over Cobalt Catalyst By Kinetic Monte-Carlo Simulation, Nuttawut Pugingna Jan 2018

Kinetics Study For Fischer-Tropsch Synthesis Over Cobalt Catalyst By Kinetic Monte-Carlo Simulation, Nuttawut Pugingna

Chulalongkorn University Theses and Dissertations (Chula ETD)

Kinetic Monte-Carlo simulation was utilized to study the kinetic behaviors of C₁ and C₂ formation in the Fischer-Tropsch synthesis over the cobalt surface by varying reaction conditions. Two reaction models: the carbide mechanism and the CO insertion mechanism were applied to this simulation. The production rates and fractional coverages of each adsorbed species could be calculated under the steady state. Moreover, the combination between carbide and CO insertion mechanism was also studied to suggest the possibility of each reaction mechanism, and compared the results with the reported experimental results under the same conditions. It was ob-served that the C–C bond …


Effecst Of Water On The Methane Hydrate Formation And Dissociation With Hollow Silica And Activated Carbon, Sarocha Rungrussamee Jan 2018

Effecst Of Water On The Methane Hydrate Formation And Dissociation With Hollow Silica And Activated Carbon, Sarocha Rungrussamee

Chulalongkorn University Theses and Dissertations (Chula ETD)

The porous materials, hollow silica (HSC) and activated carbon (AC), were selected to investigate their effects with water on methane hydrate formation and dissociation. The methane hydrate formation with the porous materials was conducted at 8 MPa and 277 K. The dissociation of hydrates was achieved by thermal stimulation with 294 K temperature driving force. The result showed that the hydrate formation of the system with 1:14 HSC to water ratio, the system with excess water, provided the highest methane consumed and water conversion to hydrates. That is because the HSC has low density allowing it to float on water …


Heat Exchanger Network Design/Retrofit With Partitioning Technique For Linearization Of Specific Heat Capacity-Temperature Relation, Siwat Valeekiatkul Jan 2018

Heat Exchanger Network Design/Retrofit With Partitioning Technique For Linearization Of Specific Heat Capacity-Temperature Relation, Siwat Valeekiatkul

Chulalongkorn University Theses and Dissertations (Chula ETD)

Heat Exchanger Network (HEN) design has been studied for 40 years starting from heuristic technique; pinch analysis and design method to mathematical programming. The stage-wise superstructure by mathematical programming from Yee and Grossmann (1990) was one of the famous models suitable for industrial HEN design under assumption of constant average specific heat capacity (Cp) which generally should be fitted by empirical form of cubic equation. Zhu and Asante (1999) and Ayotte-Sauvé et al. (2017) used piece-wise linearization called stream segment model, to approximate Cp. Their Cp approximation techniques used high number of piece-wises to calculate Cp accurately. This paper presents …


Use Of Binary Surfactant Formulations In Low Ift Foam And Surfactant Flood, Sorrawit Tantipalakul Jan 2018

Use Of Binary Surfactant Formulations In Low Ift Foam And Surfactant Flood, Sorrawit Tantipalakul

Chulalongkorn University Theses and Dissertations (Chula ETD)

Viscous fingering and early breakthrough are the main problems observed during the water flooding. These problems could be overcome by using foam flooding by coinjection of surfactant solution and nitrogen gas as a mobility control in a porous media to help improve the sweep efficiency. To gain the maximum benefits of foam flooding, ultra-low interfacial tension foam was studied to obtain a foaming system with high sweep efficiency and at the same time high oil solubilization to help mobilize the oil phase from reservoir rock. In this work, mixed surfactant systems between sodium dioctylsulfosuccinate (AOT) and internal olefin sulfonate (IOS) …


Conversion Of N-Pentane To Aromatics: Effect Of Surface Modification By Chemical Liquid Deposition And Promoter Over Nano Scale Ga/Hzsm-5, Sukkatad Sintapanin Jan 2018

Conversion Of N-Pentane To Aromatics: Effect Of Surface Modification By Chemical Liquid Deposition And Promoter Over Nano Scale Ga/Hzsm-5, Sukkatad Sintapanin

Chulalongkorn University Theses and Dissertations (Chula ETD)

This work studied the effects of chemical liquid deposition, i.e., TEOS concentration and multicycle silylation on Ga/HZSM-5 on their catalytic performance in aromatization of n-pentane. The parent nano scale HZSM-5 zeolite catalysts were incorporated with Ga by impregnation method followed by silylation via chemical liquid deposition (CLD) using tetraethyl orthosilicate (TEOS) by varying concentrations and number of cycles. Moreover, the small amount of Pt, Zn, La and P was introduced by co-impregnation method to study the effect of promoter. The physical and chemical properties of catalysts were characterized by N2 physisorption, XRD, NH3-TPD, IPA-TPD, TPO, TPR, SEM and 27Al MAS …


Development Of Lcsoft As A Tool For Life Cycle Assessment Of Environmental Impacts : Incorporating Additional Lcia Methodologies And Environmental Footprint, Tanathip Rattanatum Jan 2018

Development Of Lcsoft As A Tool For Life Cycle Assessment Of Environmental Impacts : Incorporating Additional Lcia Methodologies And Environmental Footprint, Tanathip Rattanatum

Chulalongkorn University Theses and Dissertations (Chula ETD)

Life Cycle Assessment (LCA) is a technique to calculate, assess, and analyze environmental impacts through the entire life cycle of products. LCSoft has been continuously developed as LCA software which has ability to integrate with other software e.g. process simulation software and economic analysis software. In addition, LCSoft has several functions which can analyse various environmental effects such as sensitivity analysis, alternative comparison, and eco efficiency analysis. In this thesis, several features were added into LCSoft to cover a wider application range from users and more industrial technologies. This thesis consists of four main parts. First, adding more essential equipment …


Furfurylamine-Based Polybenzoxazine Adsorbent For Co2 Capture: Effect Of Carbonization Temperature And Activation Methods, Thanabhumi Vongtiang Jan 2018

Furfurylamine-Based Polybenzoxazine Adsorbent For Co2 Capture: Effect Of Carbonization Temperature And Activation Methods, Thanabhumi Vongtiang

Chulalongkorn University Theses and Dissertations (Chula ETD)

Carbon sorbents are of interest for post-combustion CO₂ capture. Polymers are one of the potential precursors to develop carbon adsorbent with suitable surface functionalities. In this research, furfurylamine-based polybezoxazine was used to produce the carbon adsorbent because of its superior properties such as high char yield, high thermal stability, and low water adsorption. To obtain the carbon adsorbent, benzoxazine monomer was prepared by using furfurylamine, paraformaldehyde, and phenol. Polymerization by a sol-gel technique using xylene as a solvent was employed. The obtained polymer was carbonized at various temperatures: 600, 700, and 800 °C. Physical and chemical activation were then conducted …


Development Of Group-Contribution Models For Use In Surfactant Selection - Case Studies Of Single And Mixed Surfactant Applications, Woramet Chanachichalermwong Jan 2018

Development Of Group-Contribution Models For Use In Surfactant Selection - Case Studies Of Single And Mixed Surfactant Applications, Woramet Chanachichalermwong

Chulalongkorn University Theses and Dissertations (Chula ETD)

Microemulsion is the surfactant/oil/water system that is applied to many applications such as enhanced oil recovery, cleaning agents, environmental remediation and drug delivery system. To select the suitable surfactant to form an efficient microemulsion system for each specific condition and application, a systematic selection method is needed to reduce time and valuable resources that may be required in the design of an interest product. This work developed a systematic method to select suitable surfactants for a specific application based on several properties including but not limited to types of emulsion, emulsion stability, solubility and toxicology. Since not all models are …