Engineering Commons^™

Promoting Electrocatalytic Activity Of A Composite Sofc Cathode La0.8Sr0.2Mno3+Δ/Ce0.8Gd0.2O2-Δ With Molten Carbonates, Yunhui Gong, Xue Li, Lingling Zhang, Whitney Tharp, Changyong Qin, Kevin Huang

Faculty Publications

The effect of molten carbonates (MCs) on polarization resistance (R_P), a direct measure of oxygen reduction reaction (ORR) activity, of a composite La_0.8Sr_0.2MnO_3+δ/Ce_0.8Gd_0.2O_2-δ (LSM/GDC) solid oxide fuel cell (SOFC) cathode has been systematically investigated in this study over a temperature range of 550–650°C and partial pressure of oxygen (pO₂) span of 10⁻³ ∼ 1 atm. It is shown that the LSM/GDC cathode, either in the pristine or MC-modified states, can be generally modeled by two consecutive parallel circuits consisting of a resistance and a …

In-Situ Study Of E-Beam Al And Hf Metal Deposition On Native Oxide Inp (100), H. Dong, Santosh Kc, A. Azcatl, W. Cabrera, X. Qin, B. Brennan, D. Zhernokletov, K. Cho, R. Wallace

Faculty Publications

The interfacial chemistry of thin Al (∼3 nm) and Hf (∼2 nm) metal films deposited by electron beam (e-beam) evaporation on native oxide InP (100) samples at room temperature and after annealing has been studied by in situ angle resolved X-ray photoelectron spectroscopy and low energy ion scattering spectroscopy. The In-oxides are completely scavenged forming In-In/In-(Al/Hf) bonding after Al and Hf metal deposition. The P-oxide concentration is significantly decreased, and the P-oxide chemical states have been changed to more P-rich oxides upon metal deposition. Indium diffusion through these metals before and after annealing at 250 °C has also been characterized. …

Getting It Right The First Time: Robot Mission Guarantees In The Presence Of Uncertainty, Damian M. Lyons, Ronald C. Arkin, Paramesh Nirmal, Shu Jiang, Tsung-Ming Liu, J. Deeb

Faculty Publications

Certain robot missions need to perform predictably in a physical environment that may only be poorly characterized in advance. We have previously developed an approach to establishing performance guarantees for behaviorbased controllers in a process-algebra framework. We extend that work here to include random variables, and we show how our prior results can be used to generate a Dynamic Bayesian Network for the coupled system of program and environment model. Verification is reduced to a filtering problem for this network. Finally, we present validation results that demonstrate the effectiveness of the verification of a multiple waypoint robot mission using this …

Getting It Right The First Time: Robot Mission Guarantees In The Presence Of Uncertainty, Damian Lyons, Ron Arkin, Paramesh Nirmal, Shu Jiang, Tsung-Ming Liu, Julia Deeb

Faculty Publications

Abstract—Certain robot missions need to perform predictably in a physical environment that may only be poorly characterized in advance. We have previously developed an approach to establishing performance guarantees for behavior-based controllers in a process-algebra framework. We extend that work here to include random variables, and we show how our prior results can be used to generate a Dynamic Bayesian Network for the coupled system of program and environment model. Verification is reduced to a filtering problem for this network. Finally, we present validation results that demonstrate the effectiveness of the verification of a multiple waypoint robot mission using this …

Biologically Enhanced Cathode Design For Improved Capacity And Cycle Life For Lithium-Oxygen Batteries, Dahyun Oh, Jifa Qi, Yi-Chun Lu, Yong Zhang, Yang Shao-Horn, Angela Belcher

Faculty Publications

Lithium-oxygen batteries have a great potential to enhance the gravimetric energy density of fully packaged batteries by two to three times that of lithium ion cells. Recent studies have focused on finding stable electrolytes to address poor cycling capability and improve practical limitations of current lithium-oxygen batteries. In this study, the catalyst electrode, where discharge products are deposited and decomposed, was investigated as it has a critical role in the operation of rechargeable lithium-oxygen batteries. Here we report the electrode design principle to improve specific capacity and cycling performance of lithium-oxygen batteries by utilizing high-efficiency nanocatalysts assembled by M13 virus …

Deployed Communications In An Austere Environment: A Delphi Study, Andrew Soine, James Harker, Alan R. Heminger

Faculty Publications

The information and communications technology (ICT) field is undergoing a period of tremendous change. The exponential growth rate of ICT capability in recent decades, which has had an undeniable effect on every aspect of our society, will likely have ramifications for military operations in austere environments. 1 The Air Force’s 689th Combat Communications Wing commissioned a study to forecast the future of mobile ICT in such environments. Researchers at the Air Force Institute of Technology chose to employ the Delphi technique as the methodology for executing this task. The following scenario, based on the results of that study, demonstrates how …

Enhanced Reversibility And Durability Of A Solid Oxide Fe–Air Redox Battery By Carbothermic Reaction Derived Energy Storage Materials, Xuan Zhao, Xue Li, Yunhui Gong, Kevin Huang

Faculty Publications

The recently developed solid oxide metal–air redox battery is a new technology capable of high-rate chemistry. Here we report that the performance, reversibility and stability of a solid oxide iron–air redox battery can be significantly improved by nanostructuring energy storage materials from a carbothermic reaction.

Mammalian Cells Preferentially Internalize Hydrogel Nanodiscs Over Nanorods And Use Shape-Specific Uptake Mechanisms, Rachit Agarwal, Vikramjit Singh, Patrick Jurney, Li Shi, S. Sreenivasan, Krishnendu Roy

Faculty Publications

Size, surface charge, and material compositions are known to influence cell uptake of nanoparticles. However, the effect of particle geometry, i.e., the interplay between nanoscale shape and size, is less understood. Here we show that when shape is decoupled from volume, charge, and material composition, under typical in vitro conditions, mammalian epithelial and immune cells preferentially internalize disc-shaped, negatively charged hydrophilic nanoparticles of high aspect ratios compared with nanorods and lower aspect-ratio nanodiscs. Endothelial cells also prefer nanodiscs, however those of intermediate aspect ratio. Interestingly, unlike nanospheres, larger-sized hydrogel nanodiscs and nanorods are internalized more efficiently than their smallest counterparts. …

Modeling The Relaxation Time Of Dna Confined In A Nanochannel, Douglas R. Tree, Yanwei Wang, Kevin D. Dorfman

Faculty Publications

Using a mapping between a Rouse dumbbell model and fine-grained Monte Carlo simulations, we have computed the relaxation time of λ-DNA in a high ionic strength buffer confined in a nanochannel. The relaxation time thus obtained agrees quantitatively with experimental data [Reisner et al., Phys. Rev. Lett. 94, 196101 (2005)] using only a single O(1) fitting parameter to account for the uncertainty in model parameters. In addition to validating our mapping, this agreement supports our previous estimates of the friction coefficient of DNA confined in a nanochannel [Tree et al., Phys. Rev. Lett. 108, 228105 …

A Clamped Dual-Ridged Waveguide Measurement System For The Broadband, Nondestructive Characterization Of Sheet Materials, Milo W. Hyde Iv, Michael J. Havrilla

Faculty Publications

A novel two-port probe which uses dual-ridged waveguides for the nondestructive, broadband characterization of sheet materials is presented. The new probe is shown to possess approximately 2 to 3 times the bandwidth of traditional coaxial and rectangular/circular waveguide probe systems while maintaining the structural robustness characteristic of rectangular/circular waveguide probe systems. The theoretical development of the probe is presented, namely, by applying Love’s equivalence theorem and enforcing the continuity of transverse fields at the dual-ridged waveguide apertures, a system of coupled magnetic field integral equations is derived. The system of coupled magnetic field integral equations is solved using the method …

In Situ Study Of The Role Of Substrate Temperature During Atomic Layer Deposition Of Hfo2 On Inp, H. Dong, Santosh Kc, X. Qin, B. Brennan, S. Mcdonnell, D. Zhernokletov, C. Hinkle, J. Kim, K. Cho, R. Wallace

Faculty Publications

The dependence of the “self cleaning” effect of the substrate oxides on substrate temperature during atomic layer deposition (ALD) of HfO2 on various chemically treated and native oxide InP (100) substrates is investigated using in situ X-ray photoelectron spectroscopy. The removal of In-oxide is found to be more efficient at higher ALD temperatures. The P oxidation states on native oxide and acid etched samples are seen to change, with the total P-oxide concentration remaining constant, after 10 cycles of ALD HfO2 at different temperatures. An (NH4)2 S treatment is seen to effectively remove native oxides and passivate the InP surfaces …

A New Solid Oxide Molybdenum–Air Redox Battery, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang

Faculty Publications

A new type of rechargeable molybdenum–air battery based on the technologies of reversible solid oxide fuel cells and chemical looping is reported in this study. The reversible solid oxide fuel cell serves as the electrical unit to realize the charging and discharging cycles while a pair of Mo/MoO2 redox couple integrated with the reversible solid oxide fuel cell stores electrical energy via an H2–H2O oxygen shuttle. The specific charge of the new battery reaches 1117 A h per kg-Mo at 550°C, which is 45% higher than the non-rechargeable Mo–air battery. The corresponding discharge specific energy is 974 W h per …

Microfluidic Valves Made From Polymerized Polyethylene Glycol Diacrylate, Gregory P. Nordin

Faculty Publications

Pneumatically actuated, non-elastomeric membrane valves fabricated from polymerized polyethylene glycol diacrylate (poly-PEGDA) have been characterized for temporal response, valve closure, and long-term durability. A ∼100 ms valve opening time and a ∼20 ms closure time offer valve operation as fast as 8 Hz with potential for further improvement. Comparison of circular and rectangular valve geometries indicates that the surface area for membrane interaction in the valve region is important for valve performance. After initial fabrication, the fluid pressure required to open a closed circular valve is ∼50 kPa higher than the control pressure holding the valve closed. However, after ∼1000 …

Is Dna A Good Model Polymer?, Douglas R. Tree, Abhiram Muralidhar, Patrick S. Doyle, Kevin D. Dorfman

Faculty Publications

The details surrounding the crossover from wormlike-specific to universal polymeric behavior has been the subject of debate and confusion even for the simple case of a dilute, unconfined wormlike chain. We have directly computed the polymer size, form factor, free energy, and Kirkwood diffusivity for unconfined wormlike chains as a function of molecular weight, focusing on persistence lengths and effective widths that represent single-stranded and double-stranded DNA in a high ionic strength buffer. To do so, we use a chain-growth Monte Carlo algorithm, the pruned-enriched Rosenbluth method (PERM), which allows us to estimate equilibrium and near-equilibrium dynamic properties of wormlike …

Advances In The Redcat Software Package, Chris Schmidt, Stephanie J. Irausquin, Homayoun Valafar

Faculty Publications

Background

Residual Dipolar Couplings (RDCs) have emerged in the past two decades as an informative source of experimental restraints for the study of structure and dynamics of biological macromolecules and complexes. The REDCAT software package was previously introduced for the analysis of molecular structures using RDC data. Here we report additional features that have been included in this software package in order to expand the scope of its analyses. We first discuss the features that enhance REDCATs user-friendly nature, such as the integration of a number of analyses into one single operation and enabling convenient examination of a structural ensemble …

Performance Guarantees For C-Wmd Robot Missions, Shu Jiang, Ronald C. Arkin, Damian M. Lyons, Tsung-Ming Liu, Dagon Harrington

Faculty Publications

Robotics has been considered as one of the five key technology areas for defense against attacks with weapons of mass destruction (WMD). However, due to the mass impact nature of WMD, failures of counter-WMD (C-WMD) missions can have catastrophic consequences.To ensure robot's success in carrying out C-WMD missions, we have developed a novel verification framework in providing performance guarantees for behavior-based and probabilistic robot algorithms in complex real-world environments. This paper describes the system architecture and discusses how the verification framework can be used to provide pre-mission performance guarantees for robots in executing C-WMD missions.

Characterization Of The 5 Ghz Elevator Shaft Channel, Ruoyu Sun, David W. Matolak

Faculty Publications

In this paper we provide channel characterization results for the elevator shaft channel in the 5-GHz band, based upon measurements conducted in four buildings. This channel is of interest for several applications, including WiFi and public safety. Although several authors have provided elevator shaft channel characteristics for lower-frequency bands (255-MHz, 900-MHz, 1.9-GHz), to our knowledge this is the first work that addresses the 5-GHz band. Moreover, prior work has not thoroughly addressed channel characteristics when the elevator car is in motion, whereas here we provide measurement and modeling results for this dynamic condition. Our measurements were of power delay profiles, …

Enhanced Reducibility And Conductivity Of Na/K-Doped Srti0.8Nb0.2O3, Guoliang Xiao, Sirikanda Nuansaeng, Lei Zhang, Suwit Suthirakun, Andreas Heyden, Hans-Conrad Zur Loye, Fanglin Chen

Faculty Publications

Donor and acceptor co-doped SrTiO₃ materials have shown interesting features in their conductivity and reducibility. In this work, 10 mol% Na⁺ or K⁺ as acceptor dopants have been introduced into the A-site of donor-doped strontium titanate, SrTi_0.8Nb_0.2O₃, and the doping impact on their properties has been studied. By doping with Na or K, the sinterability of SrTi_0.8Nb_0.2O₃ in reducing atmospheres has been improved. Na_0.1Sr_0.9Ti_0.8Nb_0.2O₃ and K_0.1Sr_0.9Ti_0.8Nb_0.2O₃ show metallic …

Which One Is Better? Comparing Options To Describe Frequency Dependent Losses, Eric Bogatin, Don Degroot, Paul G. Huray, Yuriy Shlepnev

Faculty Publications

In any channel operating at 2 Gbps and above, conductor and dielectric losses can dominate channel performance. These effects must be included in any accurate system simulation. The problem isn't that simulators don't do this; there are several choices in interconnect loss mathematical expressions and it's difficult to decide how to transform fab information into simulator input. There are different combinations of parameterized mathematical expressions for dielectric and conductor loss which are in popular use in the industry. Each works to some extent. This paper takes each mathematical expression, explains its origin, evaluates its predicted insertion loss magnitude and phase …

On The Primitives Of Causality: From The Semantics Of Agonist And Antagonist To Models Of Accident Causation And System Safety, Loïc Brevault, Francesca Favaro, Joseph Saleh

Faculty Publications

Controversial discussions on causality have been present in ancient philosophy since the days of Aristotle. Despite the use of this concept in numerous subjects, there is no consensus on the definition of causality and its possible mathematization. Many authors have analyzed the relation between causes and effects; the predominant school of thought reduces causation to a physical relation (either deterministic or probabilistic) between two events. The distinction between causes and consequences is not always clear and meaningful as different “layers of understanding” may be applied to the notion of causality. From this point of view the cause-effect implication relation can …

Ground State Of The Singly Ionized Oxygen Vacancy In Rutile Tio2, A. T. Brant, Nancy C. Giles, Shan Yang (杨山), M. A. R. Sarker, S. Watauchi, M. Nagao, I. Tanaka, D. A. Tryk, A. Manivannan, Larry E. Halliburton

Faculty Publications

Results from electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) experiments are used to establish the model for the ground state of the singly ionized oxygen vacancy in the interior of bulk rutile TiO₂ crystals. Hyperfine from ⁴⁷Ti and ⁴⁹Ti nuclei show that the unpaired electron in this S = 1/2 defect is localized on one titanium ion adjacent to the oxygen vacancy (i.e., the spin is not shared by two titanium ions). These defects are formed at low temperature (∼35 K) in as-grown oxidized crystals when sub-band-gap 442 nm laser light converts doubly ionized nonparamagnetic …

A Multi-Physics Model For Solid Oxide Iron-Air Redox Flow Battery: Simulation Of Discharge Behavior At High Current Density, Meng Guo, Xuan Zhao, Ralph E. White, Kevin Huang

Faculty Publications

A rigorous physics-based mathematical model for a solid oxide iron-air redox flow battery system is presented in this paper. The modeled flow battery system combines a Fe-FeO redox couple as the energy storage unit and a regenerative solid oxide fuel cell as the electrical functioning unit in a 2D axial symmetric geometry. This model was developed from fundamental theories of reaction engineering in which basic transport phenomena and chemical/electrochemical kinetics are included. The model shows good agreement with the experimental data. Simulation results for the chemical, electrochemical and transport behavior of the battery are discussed.

Protein Structure Validation And Identification From Unassigned Residual Dipolar Coupling Data Using 2d-Pdpa, Arjang Fahim, Rishi Mukhopadhyay, Ryan Yandle, James H. Prestegard, Homayoun Valafar

Faculty Publications

More than 90% of protein structures submitted to the PDB each year are homologous to some previously characterized protein structure. The extensive resources that are required for structural characterization of proteins can be justified for the 10% of the novel structures, but not for the remaining 90%. This report presents the 2D-PDPA method, which utilizes unassigned residual dipolar coupling in order to address the economics of structure determination of routine proteins by reducing the data acquisition and processing time. 2D-PDPA has been demonstrated to successfully identify the correct structure of an array of proteins that range from 46 to 445 …

A Forward-Secure Certificate-Based Signature Scheme, Jiguo Li, Huiyun Teng, Xinyu Huang, Yichen Zhang, Jianying Zhou

Faculty Publications

Cryptographic computations are often carried out on insecure devices for which the threat of key exposure raises a serious concern. In an effort to address the key exposure problem, the notion of forward security was first presented by Günther in 1990. In a forward-secure scheme, secret keys are updated at regular periods of time; exposure of the secret key corresponding to a given time period does not enable an adversary to ‘break’ the scheme for any prior time period. In this paper, we first introduce forward security into certificate-based cryptography and define the security model of forward-secure certificate-based signatures (CBSs). …

Cyclic Durability Of A Solid Oxide Fe-Air Redox Battery Operated At 650°C, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang

Faculty Publications

The recently developed rechargeable solid oxide metal-air redox battery has shown a great potential for applications in mid- to large-scale stationary energy storage. Cyclic durability is one of the most important requirements for stationary energy storage. In this study, we report the cyclic durability of a solid oxide Fe-air redox battery operated at 650°C. The battery was continuously cycled 100 times under a current density of 50 mA/cm² with rather flat performance, producing an average specific energy of 760 Wh/kg-Fe at a round-trip efficiency of 55.5%. The post-test examination indicated that the performance losses could arise from the fuel-electrode …

Cyclic Durability Of A Solid Oxide Fe-Air Redox Battery Operated At 650°C, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang

Faculty Publications

The recently developed rechargeable solid oxide metal-air redox battery has shown a great potential for applications in mid- to large-scale stationary energy storage. Cyclic durability is one of the most important requirements for stationary energy storage. In this study, we report the cyclic durability of a solid oxide Fe-air redox battery operated at 650◦C. The battery was continuously cycled 100 times under a current density of 50 mA/cm2 with rather flat performance, producing an average specific energy of 760 Wh/kg-Fe at a round-trip efficiency of 55.5%. The post-test examination indicated that the performance losses could arise from the fuel-electrode of …

Indium Diffusion Through High-K Dielectrics In High-K/Inp Stacks, H. Dong, W. Cabrera, R. Galatage, Santosh Kc, B. Brennan, X. Qin, S. Mcdonnell, D. Zhernokletov, C. Hinkle, K. Cho, Y. Chabal, R. Wallace

Faculty Publications

Evidence of indium diffusion through high-k dielectric (Al2O3 and HfO2) films grown on InP (100) by atomic layer deposition is observed by angle resolved X-ray photoelectron spectroscopy and low energy ion scattering spectroscopy. The analysis establishes that In-out diffusion occurs and results in the formation of a POx rich interface.High mobility III-V channel materials are contenders to replace Si in semiconductor devices like metal oxide semiconductor filed effect transistors (MOSFETs) for the sub 22 nm technology node.1 Extensive research is being carried out to determine the validity of these III-V materials for use as the channel, in a variety of …

Non-Redundant Sensor Fault Detection Using An Improved Dynamic Model, Brandon Cannon, Robert C. Leishman, Timothy W. Mclain, Joseph Jackson, Jovan Boskovic

Faculty Publications

This paper proposes a method of detecting faults in non-redundant sensors. Such a method is advantageous for small unmanned aerial vehicles (UAVs), which are prevented from carrying redundant sensors due to size, weight, and power constraints. The method we propose uses a multiplicative extended Kalman lter (MEKF) for estimation and employs hypothesis testing to detect faults. This method has been shown to detect bias, drift, and increased noise in a non-redundant sensor real-time on board an autonomous rotorcraft.

Robust Motion Estimation With Rgb-D Cameras, Robert C. Leishman, Daniel Koch, Timothy W. Mclain

Faculty Publications

Estimating vehicle motion using vision sensors in real time has been greatly explored in the past few years due to speed improvements and advances in computer hardware. Six degree of freedom motion estimation using vision information is desirable due to a vision sensors low cost, low power requirements and light weight and for the quality of the solutions that can be obtained using few assumptions about the environment. However, cameras have the downside of not providing good estimates when visual features are sparse or not available. Also, there are problems with changes in lighting and when light is low or …

Searching For Stable SiNCN Clusters: Combination Of Stochastic Potential Surface Search And Pseudopotential Plane-Wave Car-Parinello Simulated Annealing Simulations, Xiaofeng F. Duan, Lingyu Huang, Larry W. Burggraf

Faculty Publications

To find low energy Si_nC_n structures out of hundreds to thousands of isomers we have developed a general method to search for stable isomeric structures that combines Stochastic Potential Surface Search and Pseudopotential Plane-Wave Density Functional Theory Car-Parinello Molecular Dynamics simulated annealing (PSPW-CPMD-SA). We enhanced the Sunders stochastic search method to generate random cluster structures used as seed structures for PSPW-CPMD-SA simulations. This method ensures that each SA simulation samples a different potential surface region to find the regional minimum structure. By iterations of this automated, parallel process on a high performance computer we located hundreds to …