Engineering Commons^™

Assessment And Prediction Of Surface Water Vulnerability From Non-Point Source Pollution In Midwestern Watersheds, Fadhil K. Jabbar

Doctoral Dissertations

"Non-point source pollution is the leading cause of impairment in surface water in the Midwest. In this research, we seek to predict which watersheds are most vulnerable to point source pollution without field sampling using publically available GIS databases. Watersheds with higher vulnerability ratings can then be targeted for water quality monitoring, and funds used to improve watershed health can be distributed with greater efficacy. To better understand and target watershed vulnerability, we used three different approaches. In the first project, 35 sub-watersheds were sampled in the Lower Grand Watershed, which is a highly agricultural watershed in northern Missouri/southern Iowa. …

Freeform Extrusion Fabrication Of Advanced Ceramics And Ceramic-Based Composites, Wenbin Li

Doctoral Dissertations

"Ceramic On-Demand Extrusion (CODE) is a recently developed freeform extrusion fabrication process for producing dense ceramic components from single and multiple constituents. In this process, aqueous paste of ceramic particles with a very low binder content ( < 1 vol%) is extruded through a moving nozzle to print each layer sequentially. Once one layer is printed, it is surrounded by oil to prevent undesirable water evaporation from the perimeters of the part. The oil level is regulated just below the topmost layer of the part being fabricated. Infrared radiation is then applied to uniformly and partially dry the top layer so that the yield stress of the paste increases to avoid part deformation. By repeating the above steps, the part is printed in a layer-wise fashion, followed by post-processing. Paste extrusion precision of different extrusion mechanisms was compared and analyzed, with an auger extruder determined to be the most suitable paste extruder for the CODE system. A novel fabrication system was developed based on a motion gantry, auger extruders, and peripheral devices. Sample specimens were then produced from 3 mol% yttria stabilized zirconia using this fabrication system, and their properties, including density, flexural strength, Young's modulus, Weibull modulus, fracture toughness, and hardness were measured. The results indicated that superior mechanical properties were achieved by the CODE process among all the additive manufacturing processes. Further development was made on the CODE process to fabricate ceramic components that have external/internal features such as overhangs by using fugitive support material. Finally, ceramic composites with functionally graded materials (FGMs) were fabricated by the CODE process using a dynamic mixing device"--Abstract, page iv.

Modeling And Simulation Of Micro/Nano-Rod Distribution In Micro Channel Flows, Saman Monjezi

Doctoral Dissertations

"The behavior of a typical nanorod particle in microscale flows was theoretically investigated, considering the effect of the wall on the rotational and translation motions of the non-spherical particle. Initially, a systematic method using Brownian dynamics simulation of the rotational motion of nanorod was performed to obtain the average orientation distribution of a nanorod in various range of Peclet number and position from the confining wall. Subsequently, the results of the angle distributions simulation were employed to generate a universal mathematical model for the particle orientation distribution, which our model of concentration distribution of high aspect ratio nanorods in the …

Development Of Lidar Assisted Terrestrial Radar Interferometry For Rock Deformation Monitoring, Ricardo Javier Romero Ramirez

Doctoral Dissertations

"Rock and soil slope movements cost millions of dollars annually. During the past few decades, engineers have relied on traditional methods to detect slope movements. These tools are valuable for small spatial areas but, may not be adequate or cost effective for large spatial areas. Remote sensing methods such as terrestrial laser scanning (TLS) and terrestrial radar interferometry (TRI) provide excellent spatial coverage, and with adequate post-data-processing software, sub-millimetric scale deformation sensitivity can be achieved.

This work will present a comparative experimental study between TLS and TRI. The comparative experimental study will allow us to achieve the two main objectives …

Military Applications Of Geological Engineering, Stephen H. Tupper

Doctoral Dissertations

"This work examines the premise that military engineering and geological engineering are intellectually paired and overlapped in practice to a significant extent. Geological engineering is an established, albeit young, academic discipline that enjoys wide industry and civil demand and is supported by many professional organizations. In contrast, military engineering is an ancient, empirically derived training or "OJT" program with practice-based trade-associations that has narrow government-only utility. The premise is formed by decades-long observation of U. S. Army military engineer officers completing a Master of Science degree in geological engineering as a complement to their practice-based training in military engineering at …

Developing And Evaluating A Partition-Cavity Solar Thermochemical Reactor For Syngas Production Via Computational Fluid Dynamics, Han Zhang

Doctoral Dissertations

"Solar thermochemical processes are attractive since they have the advantages of storing solar energy as chemical fuels. In this dissertation, a partition-cavity solar thermochemical reactor was developed, and the heat and mass transfer of the solar thermochemical processes were numerically analyzed in this directly-irradiated reactor.

The reduction reaction of two-step CeO₂/CeO_2-δ solar redox process was investigated using the coupling of computational fluid dynamics (CFD) and discrete element method (DEM). The reduction rate was studied based on the catalyst textual properties and the reaction condition. The results revealed that the increase of catalyst specific surface area and the …

Multiscale Spatio-Temporal Modeling Of Cell Population In Tissue Architecture And Drug Delivery Nanoparticles, Mohammad Aminul Islam

Doctoral Dissertations

"Multiscale nature of a biological system span at many order of magnitudes in time and space. Molecular interaction at lower scale is connected with the higher scale behavior of tissue or organism. Integrating the dynamics and information at different time and space can give a fundamental physiological understanding of the higher level phenomena. But complex features, functions, interconnectivity between different scales and lack of information on the fundamental physiological property make the model difficult and computationally challenging. The multiscale modeling approach can bridge the gap between different scale by a systemic integration of the complex dynamic behavior.

Here, the focus …

Investigating The Use Of Different Types Of Sealant Materials For Cement Remedial Applications, Murad Mohammedahmed Abdulfarraj

Doctoral Dissertations

"The overall objective is to investigate the ability of several material to mitigate cement failures such as channels, fractures, and micro-annuli in oil and gas wells. The sealant material that can also be used in the wells that are used for geologic storage of carbon dioxide CO₂. Evaluating the sealant material is critical to improve the zonal isolation of the wells, which would lead to safer operations. The approach of this dissertation is to utilize particles gel that has been used successfully in conformance control application, and epoxy resin systems, that have superior seal characteristics compared to conventional …

Characterization Of A Green Electric Solid Propellant For Electric Propulsion, Matthew Scott Glascock

Doctoral Dissertations

"Electric solid propellants are advanced solid chemical rocket propellants that can be controlled (ignited, throttled and extinguished) through the application and removal of an electric current. These propellants are also being considered for use in ablative pulsed plasma thruster and multimode systems. In this work, the behavior and performance of a novel green electric solid propellant operating in an electrothermal ablation-fed pulsed plasma thruster was investigated. Using an inverted pendulum micro-Newton thrust stand, the impulse bit and specific impulse of the device using the electric solid propellant were measured for short-duration and long-duration runs to end-of-life, at energy levels of …

Experimental Study On Enhanced Oil Recovery (Eor) Mechanisms Of Nanogel Combining With Low Salinity Water For Carbonate Reservoirs, Pu Han

Doctoral Dissertations

"Nanomaterials have been widely studied and applied in the oil and gas industry. Among the developed nanomaterials, nano-sized crosslinked polymeric gel particle (nanogel) has shown great potential in recovering residual oil and improving oil recovery. This dissertation carried out their potential EOR mechanisms and the synergetic effect between nanogel and low salinity water. Nanogel used in this study was synthesized through the suspension polymerization process in our lab. The morphology, size distribution, and zeta potential were studied for nanogel dispersed in brine with variable ionic strength. The injectivity of nanogel was elucidated at first to ensure their in-depth penetration ability. …

The Mechanics Of Precision Presplitting, Anthony Joseph Konya

Doctoral Dissertations

"Precision Presplitting is a widely used method of presplit blasting for the mining and construction industries. In recent years considerable effort has gone into the development of empirical equations based on field data to be able to better design the Precision Presplit for various rock types and structural environments. However, the most widely discussed theory about the mechanics of the presplit formation, that of shockwave collisions, does not appear to be applicable for this method of presplitting.

This research has disproven this theory based on insufficient magnitude of the shockwave from modeling with basic wave mechanics. Other authors have suggested …

Design And Prototyping Of A Real-Time Millimeter Wave Imaging System, Zahra Manzoor

Doctoral Dissertations

"The goal of this work is to design, prototype and test an innovative millimeter wave imaging system that operates in the frequency range of 33-35 GHz and is capable of producing rapid images of various diverse scenes. In particular, the imaging system includes two main sections, one is related to the hardware design of the system, and the other focuses on the development of a novel comprehensive image reconstruction algorithm. The hardware design includes custom transmitter and receiver sub-systems, and a sparse switched array which was optimized for 320 mm x 220 mm aperture plane, and also included an improved …

Study Of Optical Propulsion Concepts And Techniques For Small-Satellites, Jaykob Neil Maser

Doctoral Dissertations

"The first objective of this research is to manufacture and investigate the characteristics and use of asymmetric, metallic, nanostructures for plasmonic force propulsion, a developing method of nano-/picosatellite thrust generation. This project developed a higher-fidelity model of a recently envisioned small spacecraft propulsion system for precision pointing and proximity control. Plasmonic force propulsion harnesses solar light focused onto plasmon reactive sub-wavelength nanostructures to generate polarized oscillations of electrons on the surface of metallic nanostructures which accelerate and expel nanoparticle propellant via strong optical forces. This research also explores how material selection affects the electromagnetic response of the closely positioned asymmetric …

The Effects Of Fatigue And Weathering On The Failure Behavior Of Commercial Soda-Lime-Silicate Glass, Erica Ann Ronchetto

Doctoral Dissertations

"The principle objective of this research is to advance our understanding of the effects of humid conditions on the strength and susceptibility to fatigue of soda-lime silicate (SLS) glass. The two-point bend method was used to evaluate the fatigue characteristics and the degradation of failure strain of fibers drawn from melts of commercial soda-lime silicate glass and exposed to various environmental conditions. Soda lime silicate glasses from two commercial products but with similar nominal compositions were examined. One glass had pristine failure strains about 10% greater than the other, but both had similar fatigue parameters. The fatigue parameter increased from …

Long Period Fiber Grating, Thin Coating Of Graphene And Silver Nanowires, And Corrosion Sensing For Life-Cycle Assessment Of Steel Structures, Chuanrui Guo

Doctoral Dissertations

"This study aims to develop and validate a compact, integrated lab-on-sensor system for simultaneous measurement of strain, temperature and corrosion-induced mass loss in steel structures and concrete reinforcement elements in order to assess their life-cycle performance. The sensing system operates based on the principle of long period fiber gratings (LPFG) that are responsive to both thermal and mechanical deformation, and the change in refractive index of any medium surrounding the optical fiber. To fabricate a LPFG sensor for strain and temperature measurement, a CO₂ laser aided fiber grating system was assembled. To enable mass loss measurement, a low pressure …

Numerical Modeling Study Of A Neutron Depth Profiling (Ndp) System For The Missouri S&T Reactor, Mubarak Mohammed Albarqi

Doctoral Dissertations

”For decades, Neutron Depth Profiling has been used for the non-destructive analysis and quantification of boron in electronic materials and lithium in lithium ion batteries. NDP is one of the few non-destructive analytical techniques capable of measuring the depth profiles of light elements to depths of several microns with nanometer spatial resolution. The technique, however, is applicable only to a handful of light elements with large neutron absorption cross sections. This work discusses the possibility of coupling Particle Induced X-ray Emission spectroscopy with Neutron Depth Profiling to yield additional information about the depth profiles of other elements within a material. …

Building Shared Knowledge For Eor Technologies: Screening Guideline Constructions, Dashboards, And Advanced Data Analysis, Na Zhang

Doctoral Dissertations

"Successful implementation of enhanced oil recovery (EOR) technology requires comprehensive knowledge and experiences based on existing EOR projects. EOR screening guidelines and EOR reservoir analog are served as such knowledge which are considered as the first step for a reservoir engineer to determine the next step techniques to improve the ultimate oil recovery from their assets. The objective of this research work is to provide better assistance for EOR selection by using fundamental statistics methods and machine learning techniques.

In this dissertation, a total of 977 worldwide EOR projects with the most uniformed, high-quality, and comprehensive information were collected from …

Development Of Stage-I Tempered High Strength Cast Steel For Ground Engaging Tools, Viraj Ashok Athavale

Doctoral Dissertations

"Ground Engaging Tools (GET) are the expendable replacement parts used in heavy machinery used with mining or construction equipment. GET’s protect the expensive machine components from the wear and tear found common in high-impact or high-abrasion environments. The goal of this project is to develop advanced next-generation alloy choices that outperforms the existing GET materials. A method of predicting tempered hardness of mixed microstructures was formulated. Using this model, two alloy series viz. Cr-Ni-Mo and Mn-Si-Mo-V were proposed and experimented with the goal of obtaining a high strength and impact resistant cast steel. Cast iterations of Cr-Ni-Mo alloy series were …

Techno-Economic Optimization And Environmental Life Cycle Assessment Of Microgrids Using Genetic Algorithm And Artificial Neural Networks, Prashant Nagapurkar

Doctoral Dissertations

"This dissertation focuses primarily on techno-economic optimization and environmental life cycle assessment (LCA) of sustainable energy generation technologies. This work is divided into five papers. The first paper discusses the techno-economic optimization and environmental life cycle assessment of microgrids located in the USA using genetic algorithm. In this paper, a methodology was developed that assessed the techno-economic and environmental performance of a small scale microgrid located in US cities of Tucson, Lubbock and Dickinson. Providing uninterrupted power the microgrid was composed of seven components -- solar photovoltaics, wind-turbines, lead acid batteries, biodiesel generators, fuel cells, electrolyzers and H₂ tanks. …

Oxide Inclusion Evolution And Factors That Influence Their Size And Morphology, Obinna M. Adaba

Doctoral Dissertations

"The evolution of oxide inclusion size distribution and the shape of the distribution during steelmaking and casting and the process variables that influence the inclusion characteristics at different stages were investigated and documented. A statistical method for transforming the 2D size distribution to their actual 3D distributions and the application of a kinetic model to determine nucleation and growth mechanisms were tested. Finally, laboratory experiments were performed to study the effects of preexisting inclusions, steel active oxygen content, and supersaturation on the size and morphology of Al₂O₃ inclusions.

The inclusion size, composition, and morphology following steel deoxidation …

Deep Understanding Of Degradation In Lithium Ion Batteries Through Experimental And First-Principles Study, Yufang He

Doctoral Dissertations

"The growing interests in Lithium-ion Batteries (LIBs) have significantly accelerated the development of active materials. However, the key challenge is that electrode materials suffer from degradation, which include transition metal dissolution, solid electrolyte interphase (SEI) layer formation, and mechanical fracture. To address these issues, applying an ultrathin coating onto active materials via Atomic Layer Deposition (ALD) is an efficient way. Although numerious works have been done for active material performance improvement via ALD technology, the fundamental enhancement mechanisms of ALD coating on battery performance improvement are not yet known. Therefore, this dissertation consists of four papers, which focused on the …

Three-Dimensional Nanotube Arrays For Solar Energy Harvesting And Production Of Solar Fuels, Wipula P. R. Liyanage

Doctoral Dissertations

"Over the past decade extensive research has been carried out on photovoltaic semiconductors to provide a solution towards a renewable energy future. Fabricating high-efficiency photovoltaic devices largely rely on nanostructuring the photoabsorber layers due to the ability of improving photoabsorption, photocurrent generation and transport in nanometer scale. Vertically aligned, highly uniform nanorods and nanowire arrays for solar energy conversion have been explored as potential candidates for solar energy conversion and solar-fuel generation owing to their enhanced photoconversion efficiencies.

However, controlled fabrication of nanorod and especially nanotube arrays with uniform size and shape and a pre-determined distribution density is still a …

Volumetric Error Compensation For Industrial Robots And Machine Tools, Le Ma

Doctoral Dissertations

“A more efficient and increasingly popular volumetric error compensation method for machine tools is to compute compensation tables in axis space with tool tip volumetric measurements. However, machine tools have high-order geometric errors and some workspace is not reachable by measurement devices, the compensation method suffers a curve-fitting challenge, overfitting measurements in measured space and losing accuracy around and out of the measured space. Paper I presents a novel method that aims to uniformly interpolate and extrapolate the compensation tables throughout the entire workspace. By using a uniform constraint to bound the tool tip error slopes, an optimal model with …

Atomistic Simulations Of Deformation In Metallic Nanolayered Composites, Sixie Huang

Doctoral Dissertations

"The mechanical behavior of Metallic Nanolayered Composites (MNCs) is governed by their underlying microstructure. In this dissertation, the roles of the interlayer spacing (grain size, d) and the intralayer biphase spacing (layer thickness, h) on mechanical response of Cu/Nb MNCs are examined by Molecular Dynamics (MD) simulations. The study of the strength of MNCs show that small changes in both d and h play a profound role in the relative plastic contributions from grain boundary sliding and dislocation glide. The interplay of d and h leads to a very broad transition region from grain boundary sliding dominated flow, where the …

Underwater Acoustic Communications And Adaptive Signal Processing, Mohammadhossein Behgam

Doctoral Dissertations

"This dissertation proposes three new algorithms for underwater acoustic wireless communications. One is a new tail-biting circular MAP decoder for full tail-biting convolution (FTBC) codes for very short data blocks intended for Internet of Underwater Things (IoUT). The proposed algorithm was evaluated by ocean experiments and computer simulations on both Physical (PHY) and Media access control (MAC) layers. The ocean experimental results show that without channel equalization, the full tail-biting convolution (FTBC) codes with short packet lengths not only can perform similarly to zero-tailing convolution (ZTC) codes in terms of bit error rate (BER) in the PHY layer. Computer simulation …

Build Strategy Investigation Of Ti-6al-4v Produced Via A Hybrid Additive Manufacturing Process, Lei Yan

Doctoral Dissertations

“Till now, laser metal deposition (LMD) has been developed with the capability of near-net shape high-performance metal parts fabrication, especially complicated titanium alloys, nickel alloys, and aluminum alloys. However, LMD processed parts usually do not meet end-use requirements without post treatments. In-process part quality inspection and inner features machining are impossible within a single LMD process. Hybrid additive manufacturing (HAM), which integrates additive and subtractive manufacturing in one process, has been proposed to increase the feasibility of complex parts fabrication. This dissertation aims to improve the applications of Ti-6Al-4V parts fabricated via a HAM technique. The first research topic is …

Feasibility And Assessment Of Using Recycled Rubber For Infrastructure Applications, Ahmed A. Gheni

Doctoral Dissertations

“The United States needs to mine billions of tons of raw natural aggregate each year. At the same time, millions of scrap tires are stockpiled every year. Therefore, replacing natural aggregate with recycled crumb rubber aggregate will be beneficial to the construction industry and environment. This research aimed to investigate the feasibility of using recycled rubber in new construction applications. Based on size, recycled rubber was selected to match its natural counterpart. Different ratios of recycled crumb rubber were used as a fine aggregate replacement in concrete masonry units (CMUs) where the rubberized units showed a lower unit weight, higher …

Design, Fabrication, And Characterization Of Functionally Graded Materials, Sreekar Karnati

Doctoral Dissertations

“The aim of this research was to investigate the feasibility of fabricating custom designed, graded materials using Laser Metal Deposition (LMD) that will cater for functionality and unconventional repair. The ultimate goal of the project is to establish the versatility of LMD for fabricating advanced materials and tackling problems that have been conventionally difficult or in cases infeasible. In order to accomplish these goals, this research involved investigations into, the feasibility of using elemental powders as modular feedstocks, the feasibility of fabricating tailored gradients with these custom compositions, and finally leveraging the advantages of grading materials using LMD to successfully …

On Developing A Graphitic White Iron For Metal-To-Metal Wear Systems, Jie Wan

Doctoral Dissertations

"This research addressed heat dissipation issues related to the adhesive wear observed in metal-to-metal wear systems, by developing a graphitic white iron to increase thermal diffusivity of the wear components. One of the premium materials commonly used in current metal-to-metal wear systems is Fe15Mo18Cr and field returned parts were characterized as part of this study. Failure analysis showed that white layers were formed on the wearing surface due to frictional heating and surface deformation. These white layers were extremely brittle and could be fractured easily during use, which in turn led to micro-galling defects that caused parts leakage. Increasing thermal …

Improving Base Metal Electrowinning, Charles Ebenezer Abbey

Doctoral Dissertations

"In zinc electrowinning, Mn oxidizes to form MnO₂ on Pb-Ag anodes, cell walls and pipes. MnO₂ reduces anode corrosion but also leads to short circuits and maintenance issues. MnO₂ is thought to interact with chloride ions and produce oxidized chlorine species. The interactions between Mn and Cl are not well understood. Bench scale experiments were conducted to investigate the effects of the manganese to chloride ratio on anode corrosion rate and electrolyte chemistry using rolled Pb-Ag anodes. Increasing the average Mn/Cl^- ratio from ~7:1 to ~11:1 reduced the anode corrosion rate. Anode scales produced with Mn/Cl …