Engineering Commons^™

Biocrude Production From Lignin In Hydrothermal Medium: Effect Of Rapid Heating And Short Residence Time, Kyoko Hirayama

Civil & Environmental Engineering Theses & Dissertations

This study aims to address knowledge gaps in the production of valuable products from waste streams generated during lignocellulosic biofuel production. The primary objective is to develop a process that converts lignin, a byproduct of bioethanol refineries, into a sustainable biolubricant.

The first chapter examines recent advancements in synthesizing biolubricants and investigates their scalability. It explores innovative materials, catalysts, chemical modification approaches, and additives that have emerged in the field. A particular hurdle is the oxidative stability of biolubricants derived from plant oils, which are prone to autooxidation due to their C=C bonds. To overcome this, the study aims to …

Synthesis And Characterization Of Cobalt(Iii) Complexes And A Vanadium(Iv) Complex With Flavonoids As Ligands, Ethan Schroeder

Chemistry & Biochemistry Theses & Dissertations

For many years now, transition metal complexes have been used as favorable additional chemotherapeutic approaches to medicine that were previously unexplored in the literature. One well-known chemotherapeutic drug, cisplatin, has been applied, but is limited in use due to its toxicity to the cells and its undesirable side effects to humans. Newly developed cobalt-based complexes with ligands known as flavonoids are being used to fight cancer. Flavonoids, compounds mainly found in fruits and vegetables, are shown to have antioxidative and anticancer properties. Use of flavonoids as ligands in transition metal complexes, e.g., those with a Ru(II) metal center, have been …

Ber Analysis Of Bpsk Modulation Scheme For Multiple Combining Schemes Over Flat Fading Channel, Zuhaib Nishtar, Jamil Afzal

Neutrosophic Systems with Applications

Focus of the study was to provide error-free communication in mobile communication with higher data rates, spectral efficiency, and energy efficient. Basically, work was done to investigate the performance of the Binary Phase Shift Keying (BPSK) modulation technique for multiple combining schemes and the behavior of signal in wireless communication where multipath propagation and uncertainty in the system. We use the Multiple-input Multiple-output (MIMO) and antenna diversity to get many copies of the same signal; some of them were faded, but some had sufficient information. Then the next step was to combine or select the best signal to achieve the …

Generalized Double Statistical Convergence Sequences On Ideals In Neutrosophic Normed Spaces, Jeyaraman M., Iswariya S., Pandiselvi R.

Neutrosophic Systems with Applications

In this present research, having view in the Neutrosophic norm (u, v, w), which we presented I2-lacunary statistical convergence and I2-lacunary convergence strongly, looked into interactions between them, and made a few findings regarding the respective categories. At least went further to look at how both of such case approaches relate to I2-statistical convergence within the relevant Neutrosophic normed space.

Towards Sustainable Water Management: Soil Analysis, Modeling, And Sensor Implementation On A Micro-Basin Chile's Los Lagos Region, Tammy N. Huynh

Civil Engineering ETDs

The Los Lagos region of Chile is experiencing ecological and socioeconomic challenges because of climate change. Despite efforts by the agricultural sector to understand and manage water resources, the lack of basic water quantification data affects their ability to effectively plan and implement water management strategies. This research aims to address this critical issue through three key objectives. First, characterize soil properties related to texture and structure in a micro-basin of the Los Lagos region. Secondly, it aims to investigate the hydrologic budget of the micro-basin with an emphasis on soil moisture using the Soil Moisture Routing model (SMR). Lastly, …

Combining Semi-Continuous And Discrete Water Quality Data To Characterize Solute Transport, Biogeochemical Processes, And Wildfire Disturbances In Fluvial Systems, Justin Rae Nichols

Civil Engineering ETDs

In the past decade, high-frequency water quality sondes have become more abundant in watersheds across North America and Europe and are gaining a foothold in Asia and South America. In this dissertation, three relevant topics associated with high-frequency data are investigated, i.e., the impact of winter’s precipitation on surface water quality and stream metabolism, the longitudinal propagation of wildfire disturbances through a fluvial network, and the use of machine learning with high-frequency data to estimate fluvial nutrient processing. First, we found that significant snow precipitation can cause surface water anoxia and declines in stream metabolism. Second, our data illustrate that …

Mechanisms To Reduce Cyber Threats And Risks, Saad Alsuwaileh

Journal of Police and Legal Sciences

Addressing the mechanisms of reducing cyber threats and risks Research Because cyberspace is an important arena for various international interactions, especially in recent times in light of the increase in cyber-attacks between some countries, which affects their national security. In this context, many countries are trying to make an effort to develop their capabilities to be used in any cyber-attack, or to take adequate preventive measures to protect them from any possible cyberattacks, especially in light of the impact of these attacks on vital places and institutions such as banks and ministries or on important facilities such as water and …

Study Of Radiation Effects In Gan-Based Devices, Han Gao

Electrical Engineering Theses and Dissertations

Radiation tolerance of wide-bandgap Gallium Nitride (GaN) high-electron-mobility transistors (HEMT) has been studied, including X-ray-induced TID effects, heavy-ion-induced single event effects, and neutron-induced single event effects. Threshold voltage shift is observed in X-ray irradiation experiments, which recovers over time, indicating no permanent damage formed inside the device. Heavy-ion radiation effects in GaN HEMTs have been studied as a function of bias voltage, ion LET, radiation flux, and total fluence. A statistically significant amount of heavy-ion-induced gate dielectric degradation was observed, which consisted of hard breakdown and soft breakdown. Specific critical injection level experiments were designed and carried out to explore …

Empowering 5g Mmwave: Leveraging Kml Placemarks For Enhanced Rf Design And Deployment Efficiency, Gustavo A. Fernandez

School of Mathematical & Statistical Sciences Faculty Publications

This publication explores the significance of Keyhole Markup Language (KML) in telecommunications, particularly in the context of 5G mmWave RF design and planning. With the advent of 5G mmWave technology, the demand for seamless and efficient network deployments has never been greater. The deployment of small cells and repeaters for 5G mmWave necessitates utmost precision in location accuracy and rapid information exchange during site surveys and evaluations. The challenges of mmWave frequencies, including their limited range and susceptibility to attenuation, intensify the complexity and criticality of this process. Network operators must ensure that the chosen location is devoid of obstacles …

Nickel Recovery From Low-Grade Laterites: Study Of Thermal Pre-Treatments To Improve The Efficiency Of The Hydrometallurgical Process, Johana Borda, Robinson Torres

Journal of Sustainable Mining

The processing of lower-grade laterites to obtain nickel has increased due to the gradual depletion of higher-grade sulphide ore reserves. However, the extraction from laterites has been limited because conventional technologies imply a considerable expense of energy or reagents. In this document, the effect of thermal pre-treatments on a laterite sample is demonstrated to improve nickel leaching under moderate conditions. The influence of agents such as coke, coal and NaCl in the heat treatment was also studied. With the results it is presumed that part of the nickel occluded in the goethite migrates to the iron oxides surface during the …

European Feedback On Post-Mining Seismicity, Isabelle Contrucci, Dalija Namjesnik, Peter Niemz, Paloma Primo, Andrzej Kotyrba, Grzegorz Mutke, Petr Konicek, Pascal Dominique, Tobias Rudolph, Stefan Möllerherm, Jannes Kinscher, Emmanuelle Klein, Simone Cesca

Journal of Sustainable Mining

Following the Paris Agreement adopted in 2015, Europe has committed to reducing its greenhouse gas emissions. In this context, the abandonment of coal as an energy source, both in terms of consumption and production, will lead to the closure of many mines in the years to come.

Mine closure guidelines to manage residual mining risks already exist in European countries. However, they do not include post-mining seismic risk management due to a lack of sufficient studies and knowledge on this subject. After mining closure, the flooding of the mining works leads to hydromechanical loading of the underground and, in the …

Missing Value Imputation For Single Omics And Multi-Omics Data, Meng Song

Dissertations

The integration analyses of multi-omics data have the advantages of extending our understanding of biological system across multiple omics layers, unraveling the functional mechanism of complex disease development, and refining the discovery of novel drug targets. However, multi-omics studies often face challenges such as data heterogeneity, missing values problem, interpretability, and imbalance classes. Among these challenges, the missing values problem is a critical issue for large cohort studies as not all samples will get a complete measurement for all the omics layers. To address the problem of missing values in multi-omics data, I focused on the imputation of completely missing …

Neutrosophic Gsα* - Open And Closed Maps In Neutrosophic Topological Spaces, P. Anbarasi Rodrigo, S. Maheswari

Neutrosophic Systems with Applications

The main aim of this paper is to introduce a new concept of Neu-mapping namely Neugsa*-open maps and Neugsa* -closed maps in Neu-topological spaces. Additionally, we relate the properties and characterizations of these mappings with the other mappings in Neu-topological spaces.

Deep Learning For Multi-Structured Javanese Gamelan Note Generator, Arik Kurniawati, Eko Mulyanto Yuniarno, Yoyon Kusnendar Suprapto

Knowledge Engineering and Data Science

Javanese gamelan, a traditional Indonesian musical style, has several song structures called gendhing. Gendhing (songs) are written in conventional notation and require gamelan musicians to recognize patterns in the structure of each song. Usually, previous research on gendhing focuses on artistic and ethnomusicological perspectives, but this study is to explore the correlation between gendhing as traditional music in Indonesia and deep learning technology that replaces the task of gamelan composers. This research proposes CNN-LSTM to generate notation of ricikan struktural instruments as an accompaniment to Javanese gamelan music compositions based on balungan notation, rhythm, song structure, and gatra …

Neutrosophic Gsα* - Open And Closed Maps In Neutrosophic Topological Spaces, P. Anbarasi Rodrigo, S. Maheswari

Neutrosophic Systems with Applications

The main aim of this paper is to introduce a new concept of Neu-mapping namely Neugsa*-open maps and Neugsa* -closed maps in Neu-topological spaces. Additionally, we relate the properties and characterizations of these mappings with the other mappings in Neu-topological spaces.

Integrating External Sensors With Crazyflie Drones, Xiaowen Wang, Dheryta Jaisinghani, Andrew Berns

Summer Undergraduate Research Program (SURP) Symposium

• Drones are widely used: Mini drones such as Crazyflie 2.1 are used in a variety of fields.
• Grove Sound Sensor function: Grove Sound Sensor can capture sound, providing more application possibilities for drones.
• The potential of Crazyflie 2.1: Although Crazyflie 2.1 has the potential to be an integrated sensor platform, prior to this project, it was uncertain whether sensors could be connected on it.
• Project motivation: Our project aims to explore whether Crazyflie 2.1 can be connected to the Grove Sound Sensor and collect and process data from the sensor.
• Impact of the project: If successful, this project will open …

Molybdenum Disulfide (Mos₂) As A Nanocellulose Substrate, Mariana Torres, Dylan Seiffert, Elise Hong-Miller, T. E. Kidd

Summer Undergraduate Research Program (SURP) Symposium

Cellulose is a substance abundant in nature, found in fruits and vegetables, plant cell walls (National Center for Biotechnology Information, 2023), and wood (Sjostrom, 1993). The abundance of cellulose is attributable to its linear chemical structure, as it is composed of long strands of glucose molecules linked together by hydrogen atoms, which enable the substance to withstand significant pressure without breaking (Rongpipi et al., 2019). This property—known as high tensile strength—is joined by its non-toxicity and sustainability, given cellulose may be degraded and renewed naturally (Kaur, 2021). These various properties indicate versatility, and its resultant current and desired uses—such as …

Flow Through Processing Of Nanocellulose For Space Exploration Applications, Dylan Seiffert, T. E. Kidd

Summer Undergraduate Research Program (SURP) Symposium

Nanocellulose is synthesized from cellulose, which is the most abundant organic molecule found in nature. Nanocellulose solids are biodegradable and have a strength-to-weight ratio eight times that of steel¹. The production of nanocellulose solids is challenging due to the large volume loss that occurs during the curing process as well as the time and cost associated with ultrasonic processing. The loss of volume during curing often results in cracking and deformation of the cured solid. The issues caused by the large volume loss can be mitigated using additives that do not compromise the strength, shape, or machineability of …

Impacts And Applications Of Vegetable Glycerin On Nanocellulose, Elise Hong-Miller, Dylan Seiffert, T. E. Kidd

Summer Undergraduate Research Program (SURP) Symposium

Nanocellulose is created by breaking down cellulose, the most common organic molecule found in nature. Nanocellulose has attractive properties, such as a very high strength-to-weight ratio, for many different applications. A major challenge is that nanocellulose has a very high shrinkage % (~90%) when it is dried, as well as a strong probability to crack. Different additives can be added in varying amounts to either mitigate or intensify these aspects, as well as affect its drying conditions. This investigation is helping the National Aeronautics and Space Administration (NASA) and the U.S. Army to find a use for this highly renewable …

Ultramicroelectrode Experiments: Principles, Fabrications And Voltmmetric Behaviors, Zhen Ma, Jia-Yang Lin, Wen-Jing Nan, Lian-Huan Han, Dong-Ping Zhan

Journal of Electrochemistry

Due to the small size at least in one dimension (< 25 μm), ultramicroelectrode (UME) has small electric-double-layer capacitance, low IR drop, rapid mass transfer rate, fast response, high signal/noise ratio and high spatiotenporal resolution. UME is qualified not only to study the kinetics of fast electrode processes, but also to act as the probe of scanning electrochemical microscopies to obtain the localized chemical or electrochemical reactivity of the substrates. Thus, UMEs play a significant role in various research domains of electrochemistry, and have become an important electrochemical experimental method. Herein, we will introduce the basic principles, a simple fabrication method and voltammetric experimental protocols of UME, providing a guide to carry out the UME experiments.

Band Alignments Of Metal/Oxides-Water Interfaces Using Ab Initio Molecular Dynamics, Yong-Bin Zhuang, Jun Cheng

Journal of Electrochemistry

Band alignments of electrode-water interfaces are of crucial importance for understanding electrochemical interfaces. In the scenario of electrocatalysis, applied potentials are equivalent to the Fermi levels of metals in the electrochemical cells; in the scenario of photo(electro)catalysis, semiconducting oxides under illumination have chemical reactivities toward redox reactions if the redox potentials of the reactions straddle the conduction band minimums (CBMs) or valence band maximums (VBMs) of the oxides. Computational band alignments allow us to obtain the Fermi level of metals, as well as the CBM and VBM of semiconducting oxides with respect to reference electrodes. In this tutorial, we describe …

Recent Progress Of Bifunctional Electrocatalysts For Oxygen Electrodes In Unitized Regenerative Fuel Cells, Tian-Long Zheng, Ming-Yu Ou, Song Xu, Xin-Biao Mao, Shi-Yi Wang, Qing-Gang He

Journal of Electrochemistry

Unitized regenerative fuel cells (URFCs), which oxidize hydrogen to water to generate electrical power under thefuel cells (FCs) mode and electrolyze water to hydrogen under the water electrolysis (WE) mode for recycling, areknown as clean and sustainable energy conversion devices. In contrast to the hydrogen oxidation reaction (HOR) andhydrogen evolution reaction (HER) on the hydrogen electrode side, the sluggish kinetics of oxygen reduction reaction(ORR) and oxygen evolution reaction (OER) on the oxygen electrode side requires highly efficient bifunctional oxygencatalysts. Conventional precious metal oxygen catalysts combine Pt and IrO₂ with excellent ORR and OER activities toachieve bifunctional electrocatalysis performance, but …

Electrochemical Scanning Tunneling Microscopy: Taking The Initial Stage Of Cu Electrodeposition On Au(111) As An Example, Zhuo Tan, Kai-Xuan Li, Bing-Wei Mao, Jia-Wei Yan

Journal of Electrochemistry

Electrochemical scanning tunneling microscopy (ECSTM) plays an important role in the field of electrochemistry, which can obtain potential-dependent structural information of electrode surface with high spatial resolution and observe some reaction processes in electrolyte solutions, and provide a powerful way to understand the interfacial structure and electrode processes from the perspective of high spatial resolution. In this article, the study of electrodeposition of Cu on Au (111) by ECSTM is taken as an example to introduce the experimental methods required for ECSTM and share our experience with other electrochemical groups. Firstly, the working principle of STM is introduced so that …

An Investigative Study On Quick Switching System Using Fuzzy And Neutrosophic Poisson Distribution, Uma G, Nandhitha S

Neutrosophic Systems with Applications

Stephens and Larson (1967) stated the sampling system as an allotted grouping of two or three sampling plans and the rules for switching between the plans for sentencing the lots of manufactured products. Quick Switching System (QSS) by Romboski (1969) is a sampling system with reference to the Single Sampling Plan (SSP) involves normal and tightened plans by adopting a switching rule. QSS provides quality protection and a reduction in the cost of inspection. The idea of fuzzy logic is adopted in the system to handle situations of fraction non-confirmation, uncertainty, or vagueness present in the parameters. The sampling plans …

62nd Annual Rocky Mountain Conference On Magnetic Resonance

Rocky Mountain Conference on Magnetic Resonance

Final program, abstracts, and information about the 62nd annual meeting of the Rocky Mountain Conference on Magnetic Resonance, co-endorsed by the Colorado Section of the American Chemical Society and the Society for Applied Spectroscopy. Held in Sonesta Denver Downtown, Denver, Colorado, July 23-27, 2023.

An Investigative Study On Quick Switching System Using Fuzzy And Neutrosophic Poisson Distribution, Uma G, Nandhitha S

Neutrosophic Systems with Applications

Stephens and Larson (1967) stated the sampling system as an allotted grouping of two or three sampling plans and the rules for switching between the plans for sentencing the lots of manufactured products. Quick Switching System (QSS) by Romboski (1969) is a sampling system with reference to the Single Sampling Plan (SSP) involves normal and tightened plans by adopting a switching rule. QSS provides quality protection and a reduction in the cost of inspection. The idea of fuzzy logic is adopted in the system to handle situations of fraction non-confirmation, uncertainty, or vagueness present in the parameters. The sampling plans …

Exfoliation And Spray Deposition Of Graphene Nanoplatelets In Ethyl Acetate And Acetone: Implications For Additive Manufacturing Of Low-Cost Electrodes And Heat Sinks, Muhammed Ramazan Oduncu, Zhifan Ke, Bingyuan Zhao, Zhongxia Shang, Robin Simpson, Haiyan Wang, Alexander Wei

Department of Chemistry Faculty Publications

Nonaqueous dispersions of graphene nanoplatelets (GrNPs) can be used to prepare thin films and coatings free of surfactants, but typically involve polar organic solvents with high boiling points and low exposure limits. Here, we describe the mechanochemical exfoliation and dispersion of GrNPs in volatile aprotic solvents such as ethyl acetate (EtOAc) and acetone, which rank favorably in green solvent selection guides. GrNPs in powder form were exfoliated with a solvent on a horizontal ball mill for 48 h and then sonicated at moderate power to produce suspensions in excess of 300 μg/mL with minimum loss of dispersion stability over 7 …

Table Of Contents, The Editors

Coal Geology & Exploration

No abstract provided.

Propagation Of Hydraulic Fractures In Thin Interbedded Tight Sandstones, Yang Fan, Mei Wenbo, Li Liang, Sun Zening, An Qi, Yang Qi, Lu Meiquan, Yang Ruiyue

Coal Geology & Exploration

Thin interbedded tight sandstone reservoirs are characterized by strong vertical heterogeneity due to the superimposed pattern of the deposited sandstones and mudstones. As a result, hydraulic fractures are difficult to propagate vertically to effectively connect the reservoirs. Given this, ascertaining the vertical propagation patterns of hydraulic fractures in thin interbeds is of great significance for the development of thin interbedded tight sandstones. With the thin interbedded tight sandstone reservoirs of the lower Shihezi Formation in the Linxing block, Ordos Basin as a case study, this study built the fracture propagation model of these sandstones. Accordingly, it analyzed the effects of …

Iron Occurrence In Coal Measures And Its Release Mechanism During Water-Rock Interactions: Taking A Mine In The Eastern Grassland As An Example, Wang Tiantian

Coal Geology & Exploration

The mine water with iron out of limit corrodes the water distribution pipeline and the industrial equipment, thereby damaging the liver of human body, and further threatening the human health. The enrichment or dilution of iron in mine water is determined by the iron content and its occurrence in coal measures, as well as its release mechanism during water-coal and water-rock interactions. Herein, 18 groups of coal and rock samples were collected from a mine in the eastern grassland, and had the iron content, occurrence and carrier in the coal measure analyzed with an inductively coupled plasma mass spectrometry (ICP-MS), …