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Articles 4801 - 4830 of 40908
Full-Text Articles in Engineering
Surface Treatments' Effects On The Capacitor's Dielectric Performance Under Electro-Thermal Stresses, Haider. M. Umran, Feipeng Wang
Surface Treatments' Effects On The Capacitor's Dielectric Performance Under Electro-Thermal Stresses, Haider. M. Umran, Feipeng Wang
Karbala International Journal of Modern Science
Biaxial-oriented polypropylene (BOPP) films are characterized by unfavorable aging behavior because of their poor susceptibility to high temperatures, humidity, and high electric fields. This makes them unqualified to withstand harsh operating conditions, such as in capacitor applications. This study investigates the impact of annealing BOPP samples at 100 °C for five hours after fluorination at different times (15, 30, and 60 minutes) on their electrical and mechanical performance under electro-thermal stresses. Scanning electron microscope (SEM) images confirm that there is an increase in surface roughness and the formation of a dense layer of fluorine-containing groups monotonically with fluorination time. So, …
Electrochemical Syntheses Of Aryl-Substituted Benzothiophenes And Phenanthrenes Using Benzenediazonium Salts As The Aryl Radical Precursors, Li-Yuan Lan, Yang-Ye Jiang, Raymond Daniel Little, Cheng-Chu Zeng
Electrochemical Syntheses Of Aryl-Substituted Benzothiophenes And Phenanthrenes Using Benzenediazonium Salts As The Aryl Radical Precursors, Li-Yuan Lan, Yang-Ye Jiang, Raymond Daniel Little, Cheng-Chu Zeng
Journal of Electrochemistry
Aryl-substituted benzothiophene and phenanthrene are important structural units in medicinal chemistry and materials science. Although extensive effort has been devoted to prepare these compounds and a variety of approaches have been developed to construct the 2-substituted benzothiophene core structure, environmental-friendly and efficient synthetic means are still desired. Based on our previous electrochemical Minisci-type arylation reaction with aryl diazonium salt as the aryl precursor, as well as the work from König’s group, herein, we described the use of paired electrolysis to achieve 2-aryl benzothiophenes and 9-aryl phenanthrenes employing benzenediazonium salts as the aryl radical precursors. Initially, 2-methylthiobenzendiazonium salt 1a and 4-methylbenzene …
Electrochemical Advanced Treatment Of Desulfurization Wastewater From Coal-Fired Power Plants, Ju-Cai Wei, Juan Yi, Xu Wu
Electrochemical Advanced Treatment Of Desulfurization Wastewater From Coal-Fired Power Plants, Ju-Cai Wei, Juan Yi, Xu Wu
Journal of Electrochemistry
Zero-emission of desulfurization wastewater is one of the main demands for coal-fired power plants. As typical high salinity wastewater, it is hard to purify the desulfurization wastewater from coal-fired power plants through traditional physicochemical treatment or biochemical treatment, e.g., COD and Cl–. A high concentration of Cl– ion in desulfurization wastewater restricts wastewater reuse and zero-emission. Electrochemical technology is an attractive method for high salinity wastewater zero-emission, which provides a versatile, efficient, cost-effective, easily automatable, and clean industrial process. For advanced treatment of effluent after triple box process treatment in power plants, this paper reports an electrochemical …
Electrocatalytic Cyclopropanation Of Active Methylene Compounds, Liang-Hua Jie, Hai-Chao Xu
Electrocatalytic Cyclopropanation Of Active Methylene Compounds, Liang-Hua Jie, Hai-Chao Xu
Journal of Electrochemistry
The development of novel strategies to access cyclopropanes has become increasingly important due to the vital role of these three-membered ring structures in synthetic intermediates, natural products, and pharmaceuticals. Herein, we present an electrocatalytic method for the synthesis of cyclopropanes through intermolecular dehydrogenative annulation of active methylene compounds and arylalkenes. This electrochemical process requires no chemical oxidants, allowing for a speedy access to various functionalized cyclopropanes from inexpensive and readily available materials.
The Santa Clara, 2024-04-26, Santa Clara University
The Santa Clara, 2024-04-26, Santa Clara University
The Santa Clara
No abstract provided.
Measuring Soot In A Novel Configuration For Diffusion Flames Fueled By Ethylene Doped With Iso-Dodecane, Christian Bjork
Measuring Soot In A Novel Configuration For Diffusion Flames Fueled By Ethylene Doped With Iso-Dodecane, Christian Bjork
Honors Scholar Theses
Sustainable Aviation Fuels (SAFs) are seen as the path forward for decarbonizing hard-to-electrify sectors. Using SAFs over traditional fossil fuels abates carbon dioxide emissions but still may present soot emission problems. A milestone in the abatement of soot would be understating its formation mechanisms.
This study aims to quantify soot products resulting from an ethylene flame doped with iso-dodecane, a surrogate SAF component. The burner selected for the investigation is the novel Planar Mixing Layer Flame (PMLF) which allows the tracking of soot formation with the height above the burner (HAB) in a stable diffusion flame. A baseline ethylene-fueled flame …
Response Mechanism Characteristics Of Mining-Induced Fault Activation, Sun Wenbin, Hao Jianbang, Dai Xianzheng, Kong Lingjun
Response Mechanism Characteristics Of Mining-Induced Fault Activation, Sun Wenbin, Hao Jianbang, Dai Xianzheng, Kong Lingjun
Coal Geology & Exploration
In the process of coal mining, mining-induced stress perturbation is a key factor leading to fault activation, which is a primary challenge faced by safe coal mining. Fault activation is prone to induce geological disasters such as rock bursts and floor water inrushes of coal mines. Furthermore, it poses a serious threat to mining safety. Using the Flac3D software for numerical simulations and similar material simulation experiments, this study established a model for faults’ stress-displacement responses under coal mining to analyze the mechanisms behind the evolution of fault structure zones in the process of coal mining. Key findings are …
Laws Of Changes In The Energy Of Gas Hydrate-Bearing Coals Under Different Confining Pressures And Saturations, Zhu Wei, Gao Xia, Zhang Baoyong, Wu Qiang
Laws Of Changes In The Energy Of Gas Hydrate-Bearing Coals Under Different Confining Pressures And Saturations, Zhu Wei, Gao Xia, Zhang Baoyong, Wu Qiang
Coal Geology & Exploration
Gas hydration for the solidification of coal seams susceptible to outbursts is a novel technology used to prevent coal and gas outbursts by reducing gas pressure and enhancing coal strength. However, an unclear understanding of the failure characteristics and the energy dissipation law of gas hydrate-bearing coals under different confining pressures and saturations leads to the lack of a theoretical basis for the prevention of dynamic disasters such as field coal and gas outbursts in deep mines. Based on the deviatoric stress-strain curves obtained using triaxial compression tests, this study calculated and analyzed the laws of changes in energy of …
Preliminarily Exploring The Theories And Technologies For Coalbed Methane Production Using Horizontal Wells: Comparison Of Conditions For Coalbed Methane And Shale Gas Exploitation, Wang Hongyan, Duan Yaoyao, Liu Honglin, Zhao Qun, Chen Shangbin, Lu Haibing, Shi Zhensheng, Sun Qinping, Chen Zhenhong, Zhou Shangwen, Yang Mingwei, Wang Cong
Preliminarily Exploring The Theories And Technologies For Coalbed Methane Production Using Horizontal Wells: Comparison Of Conditions For Coalbed Methane And Shale Gas Exploitation, Wang Hongyan, Duan Yaoyao, Liu Honglin, Zhao Qun, Chen Shangbin, Lu Haibing, Shi Zhensheng, Sun Qinping, Chen Zhenhong, Zhou Shangwen, Yang Mingwei, Wang Cong
Coal Geology & Exploration
Through 30 years of unremitting explorations, coalbed methane (CBM) wells in China have gradually transitioned from vertical to horizontal wells. However, the lack of basic theories on CBM production using horizontal wells is the main challenge to current CBM development. Compared to shales, coal seams exhibit heterogeneity and a minor presence of foliations and brittle minerals, hindering the formation of volumetric fracture networks. Nevertheless, the roofs and floors of coal seams have high sealing capacities and mechanical strength, creating excellent conditions for hydraulic fracturing. Some fractures in coals are filled with calcite, rendering acidification conducive to the improvement of reservoir …
Accumulation Characteristics And Exploration Prospects Of Deep Coalbed Methane In The Longtan Formation Of The Nanchuan Block On The Southeastern Margin Of The Sichuan Basin, Guo Tao, Jin Xiaobo, Wu Didi, Xie Fei, Liu Jinxian
Accumulation Characteristics And Exploration Prospects Of Deep Coalbed Methane In The Longtan Formation Of The Nanchuan Block On The Southeastern Margin Of The Sichuan Basin, Guo Tao, Jin Xiaobo, Wu Didi, Xie Fei, Liu Jinxian
Coal Geology & Exploration
Vertical well Y2 in the Nanchuan bloc on the southeastern margin of the Sichuan Basin has yielded daily production of natural flowing gas of 13000 m3, signifying a strategic breakthrough in deep coalbed methane (CBM) exploration on the margin. This study aims to systematically reveal the enrichment and high-yield patterns of CBM in the Nanchuan block. Using data on the regional geology, tests, assays, and production, this study investigated the accumulation characteristic and conducted exploration potential evaluation for deep CBM in the Nanchuan block from the perspective of the quality, pore and fissure characteristics, gas content, and fracability …
Fracture Propagation Mechanism In Directional Perforation And Hydraulic Fracturing Of Coal Seam Horizontal Wells, Pang Tao, Jiang Zaibing, Hui Jiangtao, Jia Bingyi
Fracture Propagation Mechanism In Directional Perforation And Hydraulic Fracturing Of Coal Seam Horizontal Wells, Pang Tao, Jiang Zaibing, Hui Jiangtao, Jia Bingyi
Coal Geology & Exploration
Horizontal well perforation and fracturing in complex coal-bearing strata are key to increasing coal seam permeability and enhancing gas extraction efficiency, with the formation structure and perforation location determining fracture propagation. Considering the characteristics of formation structure and perforation locations, a fracturing geological model is established. Based on the finite element method, a numerical model is constructed to study the effects of perforation location, formation conditions, and the difference between vertical stress and horizontal stress on fracture perforation. Engineering verification is conducted, and construction suggestions are proposed. Key findings are as follows: There are three scenarios for the perforation locations: …
An Intelligent Water Source Discrimination Method For Water Inrushes From Coal Seam Roofs In The Inner Mongolia-Shaanxi Border Region, Wang Hao, Sun Junqing, Zeng Yifan, Shang Hongbo, Wang Tiantian, Qiao Wei
An Intelligent Water Source Discrimination Method For Water Inrushes From Coal Seam Roofs In The Inner Mongolia-Shaanxi Border Region, Wang Hao, Sun Junqing, Zeng Yifan, Shang Hongbo, Wang Tiantian, Qiao Wei
Coal Geology & Exploration
Water hazard on the coal seam proof induced by high-intensity coal mining are increasingly prominent in the Inner Mongolia-Shaanxi border region. The effective, accurate water-source discrimination of the water inrushes is the key to water hazard prevention. This study investigated three typical mines in the Inner Mongolia-Shaanxi border region. To this end, principal component analysis (PCA) was employed to extract principal components from 80 groups of groundwater samples. Then, with inorganic indicators K++Na+, Ca2+, Mg2+, Cl−, SO4 2−, HCO3 − and TDS and organic indicators UV254 …
Experimental Study Of The Thermal Cracking Mechanism Of Limestones During Burning, Zhang Weiqiang, Cao Zhicheng, Zhou Qizhong, Wang Zuoquan, Wu Yun
Experimental Study Of The Thermal Cracking Mechanism Of Limestones During Burning, Zhang Weiqiang, Cao Zhicheng, Zhou Qizhong, Wang Zuoquan, Wu Yun
Coal Geology & Exploration
Spontaneous combustion of coal seams will cause different degrees of structural damage to surrounding rocks at different high temperatures, significantly altering their physical and mechanical properties and engineering geological effects. To delve into the structural evolution patterns of rocks during burning, this study investigated the limestones from the floor of a coal mine in Xuzhou. It conducted thermal cracking experiments under different temperatures, exploring the thermal cracking patterns of rocks on multiple scales. Furthermore, this study revealed the genetic mechanism of thermal cracking by combining numerical simulations and microstructure tests. Key findings are as follows: (1) The thermal cracking temperature …
Exploring The Detection Performance Of Different Array Configurations For Multi-Electrode Resistivity Method Tomography Using A 2.5d Finite Element Method, Zhao Rongchun, Lyu Yuzeng, Zhang Zhi, Wei Liuye, Pan Hongxu
Exploring The Detection Performance Of Different Array Configurations For Multi-Electrode Resistivity Method Tomography Using A 2.5d Finite Element Method, Zhao Rongchun, Lyu Yuzeng, Zhang Zhi, Wei Liuye, Pan Hongxu
Coal Geology & Exploration
Multi-electrode resistivity method is equipped with various electrode array configurations. Due to their different electrode arrangements, various electrode array configurations tend to exhibit significantly varying detection effects under different survey environments. Hence, to achieve satisfactory detection effects using high-resolution electrical resistivity tomography, it is necessary to explore the strategy for choosing appropriate array configurations targeting different objects in practical work. Given the high applicability of the method, its forward and inversion calculations remain a critical task. Based on the differential equations to be satisfied by the point source potential in a three-dimensional structure, this study derived the variational problem to …
Three-Dimensional Forward Modeling Using The Transient Electromagnetic Method Under Complex Terrains And The Analysis Of Terrain Effects, Qu Shaobo, Zhu Jiao, Jiang Zhihai, Li Maofei, He Zhilong
Three-Dimensional Forward Modeling Using The Transient Electromagnetic Method Under Complex Terrains And The Analysis Of Terrain Effects, Qu Shaobo, Zhu Jiao, Jiang Zhihai, Li Maofei, He Zhilong
Coal Geology & Exploration
The ground-based transient electromagnetic method (TEM), with unique advantages, has been extensively applied for hydrogeological exploration in coal mines. However, in field exploration, complex terrains tend to cause variations in geometric shapes of transmitting sources and deviations in signals received, reducing exploration accuracy. Hence, by integrating theoretical analysis and numerical simulations with the analysis of actual terrain data, this study systematically investigated the response characteristics of electrical- and magnetic-source TEM fields under complex terrains. Using the vector finite-element electromagnetic forward modeling technique based on second-order backward Euler discretization, this study delved into the laws of influence of peak and valley …
Research On Path Planning Methods For Underground Roadheader Robots, Zhang Xuhui, Zheng Xili, Yang Wenjuan, Li Yuyang, Ma Bing, Dong Zheng, Chen Xin
Research On Path Planning Methods For Underground Roadheader Robots, Zhang Xuhui, Zheng Xili, Yang Wenjuan, Li Yuyang, Ma Bing, Dong Zheng, Chen Xin
Coal Geology & Exploration
In order to solve the problems of difficulty and low efficiency in the movement of robotic roadheaders under conditions of non-full-section roadways in coal mines, the characteristics of unstructured environments in coal mines and the motion characteristics of robotic roadheaders were analyzed, and a path planning method for robotic roadheaders based on deep reinforcement learning was proposed. The tunnel environment was constructed in real time using depth cameras, a virtual model for detecting roadheader-tunnel collisions was established, collision detection was performed in a virtual environment using the hierarchical bounding box method, and an obstacle avoidance strategy under the restrictions of …
Edge Detection Of Low Illumination Image In Cutting Unit Of Shearer, Jia Pengtao, Jin Luwei, Wang Bin, Guo Fengjing, Li Na
Edge Detection Of Low Illumination Image In Cutting Unit Of Shearer, Jia Pengtao, Jin Luwei, Wang Bin, Guo Fengjing, Li Na
Coal Geology & Exploration
In this paper, a fractional differentiation-based edge detection algorithm named Lif is proposed to address the edge detection problems of missing edge and fuzzy details in the cutting unit of shearers working in low-light underground environments. First, the initial fractional mask operator was built using a larger detection template according to the Grünwald-Letnikov definition of the fractional derivative. Then, the weight coefficients at various positions of the mask operator were determined according to the theory of Pascal’s triangle, and the mask operator was extended to four different directions. Finally, the mask operator was convolved with the image, and the local …
Table Of Contents, The Editors
Exploring Dynamic Parameters And Tooth Structure Of Self-Propelled Borehole Repairing Drill Bits, Liu Yong, Li Yang, Wei Jianping, Yuan Yongwang, Dai Shuo, Li Linyu
Exploring Dynamic Parameters And Tooth Structure Of Self-Propelled Borehole Repairing Drill Bits, Liu Yong, Li Yang, Wei Jianping, Yuan Yongwang, Dai Shuo, Li Linyu
Coal Geology & Exploration
Self-propelled borehole repairing drill bits provide an effective technique for repairing long boreholes that have failed. In order to further improve the borehole repair speed and gas drainage efficiency, based on the theory of jet recoil, the relationship between the jet recoil force and nozzle parameters was analyzed, and a theoretical model was established for rotational mechanics of self-propelled borehole repairing drill bits. Subsequently, the coal-breaking processes of drill bits with different tooth structures were simulated using LS-DYNA, the failure modes in coal mass broken by cutting teeth and the rules of variation in the volume of coal broken by …
Prediction Of Mine Water Inflow Along Mining Faces Using The Ssa-Cg-Attention Multifactor Model, Ding Yingying, Yin Shangxian, Lian Huiqing, Liu Wei, Li Qixing, Qi Rongrong, Bu Changsen, Xia Xiangxue, Li Shuqian
Prediction Of Mine Water Inflow Along Mining Faces Using The Ssa-Cg-Attention Multifactor Model, Ding Yingying, Yin Shangxian, Lian Huiqing, Liu Wei, Li Qixing, Qi Rongrong, Bu Changsen, Xia Xiangxue, Li Shuqian
Coal Geology & Exploration
Predicting mine water inflow plays an important role in ensuring mine safety, optimizing resource allocation, and improving work efficiency. This study aims to improve the accuracy and stability of the predicted mine water inflow. Given their strong correlations with water inflow, borehole water level and microseismic energy were chosen as multifactor characteristic variables. Using these variables, this study developed the SSA-CG-Attention multifactor prediction model for mine water inflow along mining faces. The new model extracted effective nonlinear local features of data utilizing a new network structure, which was formed by integrating a convolutional neural network (CNN) based on the time …
Intelligent Identification Method For Overburden Three Zones Of A Goaf, Li Jianwen, Zhao Wen, Wu Zhenkun, Xu Xiaobing, Wang Qingtao, Duan Longchen
Intelligent Identification Method For Overburden Three Zones Of A Goaf, Li Jianwen, Zhao Wen, Wu Zhenkun, Xu Xiaobing, Wang Qingtao, Duan Longchen
Coal Geology & Exploration
In this paper, an intelligent identification method was proposed to ascertain overlying strata failure types and fracture development in the overlying strata of a goaf, and identify three zones (sagging zone, fractured zone and caving zone) quickly and accurately. This method is expected to be a basis in later development of goaf treatment plans. A coal mine goaf in Shandong Province was introduced for case study, where the Bayesian Online Changepoint Detection (BOCD) algorithm was employed to analyze the changes and response characteristics of the drilling fluid loss and drilling rate over the drilling process at the boundaries of three …
Mechanism And Application Of Cross-Interface Fracturing For Permeability Enhancement Through The Roof Blasting Of Tectonic Coal Seams, Gao Kui, Wang Youwei, Qiao Guodong, Tian Yu, Fu Shigui
Mechanism And Application Of Cross-Interface Fracturing For Permeability Enhancement Through The Roof Blasting Of Tectonic Coal Seams, Gao Kui, Wang Youwei, Qiao Guodong, Tian Yu, Fu Shigui
Coal Geology & Exploration
Deep coal mining is challenging due to deteriorating geological conditions. After undergoing multiphase tectonic movements, primary coals have evolved into soft tectonic coal seams with low permeability and high gas content, complicating drilling in coal seams. In this case, the blasting-induced fractures are not well-developed and are prone to be re-compacted. So far, no fundamental breakthrough has been achieved in the key technology of fracturing for permeability enhancement technology through the roof blasting of tectonic coal seams. Given this, this study established test models for similar simulation tests and numerical analysis on the roof blasting of coal seams. By monitoring …
Machine Learning-Based Gps Jamming And Spoofing Detection, Alberto Squatrito
Machine Learning-Based Gps Jamming And Spoofing Detection, Alberto Squatrito
Doctoral Dissertations and Master's Theses
The increasing reliance on Global Positioning System (GPS) technology across various sectors has exposed vulnerabilities to malicious attacks, particularly GPS jamming and spoofing. This thesis presents an analysis into detection and mitigation strategies for enhancing the resilience of GPS receivers against jamming and spoofing attacks. The research entails the development of a simulated GPS signal and a receiver model to accurately decode and extract information from simulated GPS signals. The study implements the generation of jammed and spoofed signals to emulate potential threats faced by GPS receivers in practical settings. The core innovation lies in the integration of machine learning …
Research On Tar-Rich Coals: Progress And Prospects, Wang Shuangming, Bao Yuan, Hao Yonghui, Wang Shengquan, Shi Qingmin, Li Dan, Hu Yiliang
Research On Tar-Rich Coals: Progress And Prospects, Wang Shuangming, Bao Yuan, Hao Yonghui, Wang Shengquan, Shi Qingmin, Li Dan, Hu Yiliang
Coal Geology & Exploration
Tar-rich coals are a coal-based oil and gas resource that integrates the properties of coal, oil, and gas. Given China's energy endowment of abundant coal resources but limited oil and gas reserves, exploiting tar-rich coals plays a significant role in alleviating China's tight supply of oil and gas resources and achieving green development and low-carbon utilization of coals. Using tar-rich coals as the keyword, we searched the CNKI and Web of Science databases for academic articles and patents published from 1985 to the end of 2023. Based on the search results, we statistically analyzed the process and main aspects of …
Sulphate Contamination In An Abandoned Coal Mine In Light Of Mining Effects, Qi Yueming, Zhou Pei, Zhou Lai, Jiang Dan, Yang Yuqing, Liu Yanzhuo
Sulphate Contamination In An Abandoned Coal Mine In Light Of Mining Effects, Qi Yueming, Zhou Pei, Zhou Lai, Jiang Dan, Yang Yuqing, Liu Yanzhuo
Coal Geology & Exploration
Abandoned high-sulfur coal mines will become deeply buried acid-producing contamination sites, posing hazards to adjacent aquifers and surrounding environments. Furthermore, mining effects and the complex spatial distribution of abandoned mines complicate the assessment of the contamination processes and degrees in adjacent aquifers. Focusing on a certain abandoned coal mine, this study examined the migration characteristics of SO4 2− pollution in acid mine drainage using numerical simulations by taking sulfate (SO4 2−) as the characteristic contaminant and considering the effects of the fractures formed by the mining of multiple coal seams on the aquifer structure. Furthermore, it analyzed …
Exploring The Pore Structure Of Reconstructed Soils And Its Effects On Water And Salt Transport Based On Ct Scanning, Li Huakun, Zheng Liugen, Chen Yongchun, Li Bing, Tao Pengfei, Li Hao
Exploring The Pore Structure Of Reconstructed Soils And Its Effects On Water And Salt Transport Based On Ct Scanning, Li Huakun, Zheng Liugen, Chen Yongchun, Li Bing, Tao Pengfei, Li Hao
Coal Geology & Exploration
Coal gangue serves as a critical material for landfilling and reclamation in the subsidence areas of coal mines. However, due to its rough textures and poor water-holding capacity, soils reconstructed using coal gangue exhibit somewhat different pore structures and water-salt transport from undisturbed soils. To explore the changes in the pore structure of the reconstructed soils and their effects on water and salt transport, this study analyzed the differences in the pore structures between four samples from undisturbed soils, the overburden, mud-gangue mixtures, and gangue using CT scanning and image analysis. Furthermore, an indoor experimental device was designed to simulate …
Thermal Performance Investigation Of Thermoelectric Cooling System With Various Hot-Side Cooling Methods, Bowo Y. Prasetyo, Parisya P. Rosulindo, Fujen Wang
Thermal Performance Investigation Of Thermoelectric Cooling System With Various Hot-Side Cooling Methods, Bowo Y. Prasetyo, Parisya P. Rosulindo, Fujen Wang
Makara Journal of Technology
Thermoelectric devices have been widely used in various applications, including cooling and power generation. The potential application of thermoelectric cooling systems has been studied. However, these systems still face challenges in achieving optimal performance compared with other cooling systems. Several factors, including the hot-side cooling method, influence the performance of thermoelectric systems. This study aimed to investigate the effects of different hot-side cooling methods on the thermoelectric performance and thermal behavior of thermoelectric cooling systems. The testing methods involved the combination of the thermoelectric module with five hot-side heat exchangers, including a square heatsink, a round heatsink, a two-pipe heat …
Towards A Practical Method For Monitoring Kinetic Processes In Polymers With Low-Frequency Raman Spectroscopy, Robert Vito Chimenti
Towards A Practical Method For Monitoring Kinetic Processes In Polymers With Low-Frequency Raman Spectroscopy, Robert Vito Chimenti
Theses and Dissertations
Unlike liquids and crystalline solids, glassy materials exist in a constant state of structural nonequilibrium. Therefore, a comprehensive understanding of material kinetics is critical for understanding the structure-property-processing relationships of polymeric materials. Amorphous materials universally display low-frequency Raman features related to the phonon density of states resulting in a broad disorder band for Raman shifts below 100 cm-1, which is related to the conformational entropy and the modulus. This disorder band is dominated by the Boson peak, a feature due to phonon scattering because of disorder and can be related to the transverse sound velocity of the material, and a …
A 2-D Numerical Model For Evaluating Daylight Penetration In Short Tunnels For Enhanced Driver Safety, Joachim James
A 2-D Numerical Model For Evaluating Daylight Penetration In Short Tunnels For Enhanced Driver Safety, Joachim James
Master's Theses
It is commonly assumed that daylight will adequately penetrate short tunnels, leading to the misconception that artificial lighting is unnecessary during the daytime. Past studies revealed higher frequency of crashes in short tunnels and despite that there is lack of national guidelines warranting artificial lighting for short tunnels. Inadequately lit tunnels pose safety risks, while excessive lighting can be costly. Hence, it becomes crucial to investigate the extent of daylight penetration in short tunnels and identify disappearance zones within these tunnels. This research can help determine the necessity of artificial lighting, and which specific areas of the tunnel require lighting. …
Mathematical Modeling For Dental Decay Prevention In Children And Adolescents, Mahdiyeh Soltaninejad
Mathematical Modeling For Dental Decay Prevention In Children And Adolescents, Mahdiyeh Soltaninejad
Dissertations
The high prevalence of dental caries among children and adolescents, especially those from lower socio-economic backgrounds, is a significant nationwide health concern. Early prevention, such as dental sealants and fluoride varnish (FV), is essential, but access to this care remains limited and disparate. In this research, a national dataset is utilized to assess sealants' reach and effectiveness in preventing tooth decay, particularly focusing on 2nd molars that emerge during early adolescence, a current gap in the knowledge base. FV is recommended to be delivered during medical well-child visits to children who are not seeing a dentist. Challenges and facilitators in …