Engineering Commons^™

Study On The Surface States Of Zinc Sulfide Thin Film Doped With Erbium And Their Effect On The Relaxation Luminance, Yujiang Wang, Zhaohong Liu, Zhenxiang Chen

Journal of Electrochemistry

X-ray photoelectron spectrum and characteristics of the capacity, versus thevoltage of the thin film devices are measured to study the surface states of the zinc sulfide thin film.The transient electroluminescence excited by pulses shows the relaxation luminance peaks during anon-exponential decay process of the characteristic transitions activated by Er³⁺ in the ZnS directcurrent thin film electroluminescence (DCTFEL) devices.The surface structures of ZnS:Cu, Cl, Erfilm with the absorption of oxygen, and the effect of the surface states on the relaxation luminance ofthe devices are discussed.

The Oxidation Of Hydrogen Absotbing Alloys And Its Inhibition, Suqin Wang, Baojia Xia, Geping Yin, Pengfei Shi

Journal of Electrochemistry

This paper introduces the method to judge: 1)the possibility of oxidation of themetal hydride electrode in an anode process by cyclic voltammetric curves, 2)the oxidation pattern ofmetal hydride electrode in oxygen atmosphere in various charged states, and 3)the inhibition ofoxidation of hydrogen absorbing alloys by certain surface treatment.

Problems On The Study Of Anodic Films On Pb In Sulfuric Acid Solution (Ⅰ), Wenbin Cai, Houtian Liu, Weifang Zhou

Journal of Electrochemistry

The identification of the phase composition of the anodic film on Pb formed in H₂SO₄ solution in PbO potential region has long been argued, together with the explanation of thecathodic peak at about -0.9V (Hg/HgSO₄) in the linear sweep voltammogram for a Pb-H₂SO₄ system. In this article, a review of our recent investigations was presented on the above problems.

The Influnce Of Conjugated Π Bond In Promoter Molecule On The Direct Electrochemical Reaction Of Cytochrome C, Xiaogang Qu, Tianhong Lu, Shaojun Dong

Journal of Electrochemistry

The promoter effect of thiophene with only one-functional group on the directelectrochemical reaction of cytochrome c was compared with that of tetrahydrothiophene in this report. It was found that thiophene is a good promoter. But tetrahydrothiophene could not facilitate the directelectrochemistry of cytochrome c although this compound is very similar to thiophene in str uctureexcept for conjugated π bond. This demonstrated that the conjugated π bond in thiophene plays animportant role for the acceleration of the direct electrochemistry of cytochrome c.

The Photoelectrochemical Studies Of Passive Films On Rebar Electrodes In Simulated Cement Pore Solution, Wei Chu, Yuanxiang Shi, Baoming Wei, Yong Yang, Xuguang Chen, Zugeng Lin

Journal of Electrochemistry

The electronic properties of the passive film on REBAR electrodes in simulatedcement pore solution (pH=9.0～13.8) have been investigated using in-situ photoelectrochemical methods. The results show that the passive film is composed of mixed oxides of ferrum, and it is an amorphous, n-type semiconductive film. Variations of pH values, ions in the solution and film-formation potentials can affect the composition of the films. There are two main stages in the growthof the film, with two rate functions characterized by linear relation between the film thickness and thelogarithm of time. The addition of inhibitor NaNO₂ changes the composition, structure and growth …

Properties Of Zr-Based Laves Phase Hydrogen Storage Electrode, Xueping Gao, Huabin Yang, Deying Song, Yunshi Zhang, Zuoxiang Zhou, Wei Zhang, Panwen Shen

Journal of Electrochemistry

After treated by HF solution,the surface of Zr(V_0.2Mn_0.2Ni_0.54Mo_0.06)_2.4 alloy was transformed from Zr-rich and Mn-rich layer to Ni-rich layer. In this way, the nickel on thesurface could be believed to be the Raney-type nickel, which could obviously shorten the activation cycles, improve electrocatalytic activity and hydrogen adsorption ability. In this paper, the reaction mechanism on the alloy surface (i.e. the mechanism of nickel-catalysis, hydrogen-adsorption and hydrogen-transference) had been investigated. And the impedance spectra were fitted to an equivalentcircuit using a non-linear, least-squares (NLLS) fitting program.

A Relativistic Density-Functional Investigation Of Vibrational Frequencies Of Cn- On Cu And Ag Electrodes, Mengsheng Liao, Xin Lv, Qianer Zhang

Journal of Electrochemistry

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Studies On The Structure Of Licoo2 Synthesized With Tartaric Acid And The Behaviorof Its Rechargeable Lithium Battery, Fuping Zhang

Journal of Electrochemistry

The structure of LiCoO₂ synthesized with tartaric acid and the behavior of itsrechargeable Lithium battery have been studied by XRD, XPS, CV, CT. It has been shown that LiCoO₂ has a space group R3m with hexagonal parameters a=0.2810 nm, c=1.4088 nm. Low-spin state Co³⁺ configuration in LiCoO₂ has been suggested. Also, Li₂O, was identified onits surface. Furthermore, the capacity and the middle working voltage of its Lithium battery are about 120 mA·h·g^-1 and 3.8 V, respectively. The EMF of the cell changes with the Lithium composition of itscathode following E=4.318-0.450 X^2/3 in …

Effect Of Symmetric Alternating Current On Cathode Surface Before Iron Deposition, Xintan Hu

Journal of Electrochemistry

The composition and thickness of active film formed on the surface of cathode made of low carbon steel after treated by symmetric alternating current (SAC) in ferris chloride bathis studied,and the interfacial morphology of the iron deposit and the substrate is also examined. The results show that the active film, which a thickness of 20～25nm can be obtained under SAC densityof about 7 A·dm^-2 ,so that the adherent iron deposit can be achieved on the active film. The effect of SAC on cathode surface is discussed in detail.

Photoelectric Property For Zinc Phthalocyanine Of Doping C60 On Inp Electrode, Mengxiong Zhan, Rongqing Yu, Biaolian Zhen, Dadian Cheng, Lansun Zheng

Journal of Electrochemistry

The curves of spectral and photovoltaic responses to zinc phthalocyanine of doping C₆₀ were determinted. The photovoltaic property for zinc phthalocyanine of doping C₆₀ wereinvestigated on the InP single crystal in the photoelectrochemical cell.The results have shown that: 1)The photovoltaic effect and the in tensities of the spectral response and of the photovoltaic responsefor ZnPc of doping C₆₀ were greater than those of ZnPc; 2)had better redox couple in the cells.

Studies On The Bright Zinc-Nickel Alloy Palting In Alkaline Baths, Jiale Cai, Shaomin Zhou

Journal of Electrochemistry

The electrochemical properties of the Zn-Ni plating baths and the structure andperformance of the obtained deposits were investigated. The results show that the nickel content of theobtained deposits is incereased with decreasing of Zn²⁺/Ni²⁺ ratio in the baths and with increasing of cathodic current density; The cathode current efficiency is increased with increasing of Zn[Ⅱ] content in the bath and with decreasing of cathodic current density. The ZN-11 additive used is thereaction product of heterocyclic compound and polyamines with epichlorohydrin, it has a higheradsorptivity on Hg-electrode at potential between -0.16～-1.68 V (vs. Hg/HgO, 1 mol·L^-1 KOH). …

Broadband Dynamic, Holographically Self-Recorded, And Static Hexagonal Scattering Patterns In Photorefractive Knbo3:Fe, Nickolai Kukhtarev, Tatiana V. Kukhtareva, John Caulfield, Partha P. Banerjee, Hsueh-Ling Yu, Lambertus Hesselink

Electrical and Computer Engineering Faculty Publications

We have observed and explained three types of hexagon pattern formation in photo refractive crystal KNb03:Fe. These are:

• Dynamic (laser induced)
• Semipermanent (holographically stored)
• Permanent (induced by a static domain grid) over a wide wavelength range

Preprocessing Of Microcirculatory Images., Mohamed S. Mansour

Electronic Theses and Dissertations

This thesis project consists of the development of a computerized image processing system to preprocess microvascular images of the mouse Latisimus Dorsi Muscle (LDM). This research has been conducted in association with the Division of Plastic and Reconstructive Surgery at the University of Louisville. The input to the system is a set of 35 or more overlapping microscopic fields or sub_images containing segments of the LDM microcirculation, the output is an adjacent single montage encompassing the entire LDM microvasculature. The developed system presents practical solutions to the problems of image registration, overlap resolution, and image segmentation, in addition, the results …

Transient Wave Mixing And Recording Kinetics In Photorefractive Barium Titanate: A Nonlinear Coupled Mode Approach, Partha P. Banerjee, John M. Jarem

Electrical and Computer Engineering Faculty Publications

By using rigorous coupled-wave diffraction theory along with a time-dependent nonlinear formulation, we analyze two- and multiplewave coupling and the grating kinetics in BaTi03 with different boundary interfaces. Efffects of electrostatic and optical anisotropy have been included in the analysis. Significant mode conversion to higher orders is observed only when the boundary interfaces are highly mismatched.

A Two-Dimensional Model For Watershed Runoff And Pollutant Transport, Laura Jean Howard

Civil & Environmental Engineering Theses & Dissertations

A two-dimensional mathematical model is developed for the quantitative and qualitative analysis of watershed runoff for a given rainfall event. The runoff is routed through a receiving channel. The model is designed for use on a personal computer. Full documentation is included in the Appendix. The model is capable of accommodating downstream boundary conditions, temporally varied effective rainfall conditions, and spatially varied watershed conditions. Output takes the form of flow depths, discharges, and concentrations. The model was tested for quantity and quality using existing experimental data, and the results are presented herein.

Guest Editorial: Special Section On Photorefractive Nonlinear Optics, Partha P. Banerjee

Electrical and Computer Engineering Faculty Publications

Hand in hand with experimental work in photorefractives, there is a lot of activity in modeling photorefractive materials and experimental observations in the open literature. This special section contains a paper by Banerjee and Jarem, who use a rigorous coupled wave theory to analyze two- and multiple-wave mixing photorefractive barium titanate, modeled through the Kukhtarev equations.

Single-Layer-Coated Surfaces With Linearized Reflectance Versus Angle Of Incidence: Application To Passive And Active Silicon Rotation Sensors, R. M.A. Azzam, M. M. K. Howlader, T. Y. Georgiou

Electrical Engineering Faculty Publications

A transparent or absorbing substrate can be coated with a transparent thin film to produce a linear reflectanceversus- angle-of-incidence response over a certain range of angles. Linearization at and near normal incidence is a special case that leads to a maximally flat response for p-polarized, s-polarized, or unpolarized light. For midrange and high-range linearization with moderate and high slopes, respectively, the best results are obtained when the incident light is s polarized. Application to a Si substrate that is coated with a SiO₂ film leads to novel passive and active reflection rotation sensors. Experimental results and an error analysis …

Comparison Of Time-Domain Reflectometry Performance Factors For Several Dielectric Geometries: Theory And Experiments, S. V. Maheshwarla, R. Venkatasubramanian, Robert F. Boehm

Electrical & Computer Engineering Faculty Research

We propose three nontraditional dielectric geometries and present an experimental and theoretical analysis and comparison of time domain reflectometry (TDR) performances for them. The traditional geometry (the probes inserted in material of essentially infinite extent) is compared to three nontraditional geometries where the probes are affixed outside of a core sample, inside of a bore, or flat on the surface of a semi-infinite solid. Our derivation relates the velocity of electromagnetic wave propagation to the complex permittivities and permeabilities of the media and the geometry for the three nontraditional configurations. Experimental results for air, styrofoam, dry sand, wet sand of …

37th Rocky Mountain Conference On Analytical Chemistry

Rocky Mountain Conference on Magnetic Resonance

Final program, abstracts, and information about the 37th annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-sponsored by the Colorado Section of the American Chemical Society and the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, July 23-27, 1995.

Santa Clara Magazine, Volume 37 Number 3, Summer 1995, Santa Clara University

Santa Clara Magazine

6 - GARBAGE IN: GOODS OUT Lee Hornberger ' 69, associate professor of mechanical engineering, has only one word to say to you: plastics. By Maureen Mclnaney '85

10 - SCU 101 More than a hundred (count 'em) things every student shou ld do before graduating from Santa Clara.

16 - CHIAPAS: ROOTS OF A REBELLION Members of the SCU community bear witness to an indigenous struggle. By Trina Kleist '80 Photographs by Charles Barry

22 - PRESENTING PARADISE A modern translation with commentary helps readers scale the heights of Dante's heaven. By James Torrens, S.J.

24 - HAVE BALL, …

Ohmic Contact To Ion Implanted Gallium Arsenide Antimonide For Application To Indium Aluminum Arsenide-Gallium Arsenide Antimonide Heterostructure Insulated-Gate Field Effect Transistors, Kenneth G. Merkel Ii

Theses and Dissertations

The p-channel In_0.52Al_0.48As-GaAs_1-xSb_x heterostructure insulated-gate field effect transistor (p-HIGFET) is a candidate for complementary integrated circuits due to superior cutoff characteristics and low gate leakage current. Advancement of the In_0.52Al_0.48As-GaAs_1-xSb_x p-HIGFET requires improved source-drain design. Five main tasks were accomplished to achieve this goal. First, thermal limits of the In_0.52Al_0.48As-GaAs_0.51Sb_0.49 HIGFET were investigated. Second, the temperature dependence of band gap and impurity energies were determined for beryllium doped In_0.52Al_0.48. Third, high acceptor concentrations were obtained …

Studies Of Mixing Processes In Gases And Effects On Combustion And Stability, Frank Paul Kozusko Jr.

Mathematics & Statistics Theses & Dissertations

Three physical models of laminar mixing of initially separated gases are studied. Two models study the effects of the mixing dynamics on the chemical reactions between the gases. The third model studies the structure and stability of a laminar mixing layer in a binary gas. The three models are:

1. Two ideal and incompressible gases representing fuel and oxidizer are initially at rest and separated across an infinite linear interface in a two dimensional system. Combustion, expected as the gases mix, will lead to a rapid rise in temperature in a localized area, i.e. ignition. The mixing of the gases …

Fault Tolerance In Critical Real-Time Systems, Balaji Tirukarneswaran

Electrical & Computer Engineering Theses & Dissertations

Critical real-time applications require work to be completed before a predefined deadline, else the consequences may be catastrophic. The anticipation of faults in such systems necessitates the need for fault tolerance. Fault tolerance can be achieved in many different ways. A real-time system designer may impose restrictions on any of the system performance measures such as the latency, throughput and number of processors, depending on the type of application. In this work, several different fault tolerant strategies for any given DFG (Data Flow Graph) are discussed. DFG models are developed using the strategies and the resulting worst case performances a.re …

Comparison Of System Identification Techniques For The Dexterous Orbital Servicing System (Doss), Allan Terrence Morris

Electrical & Computer Engineering Theses & Dissertations

The major contribution of system identification is the development of analytical models of a system. Many identification techniques can adequately describe the input and output map. One of the challenges of these techniques is to correctly infer from the measured data the characteristics of the individual, contributing components producing a more accurate system model.

In this thesis linear, dynamic, multivariable state-space models for three joints of the Dexterous Orbital Servicing System (DOSS) are identified. DOSS is a representative space station manipulator at the NASA Langley Research Center. The dynamic models of the manipulator will first be estimated by applying nonparametric …

Managing Reclamation Facilities For Ecosystem Benefits, Lawrence J. Macdonnell

Sustainable Use of the West's Water (Summer Conference, June 12-14)

26 pages.

Contains references.

Searching For Sustainable Use Of Montana’S Water: A Series Of Vignettes, Matthew Mckinney

Sustainable Use of the West's Water (Summer Conference, June 12-14)

24 pages.

Contains references.

Water Rights And The Commonwealth, Eric T. Freyfogle

Sustainable Use of the West's Water (Summer Conference, June 12-14)

20 pages.

Regional Water Planning In New Mexico: An Opportunity For Citizen Involvement In State Government, Lucy Moore

Sustainable Use of the West's Water (Summer Conference, June 12-14)

12 pages.

Contains references.

The Oregon Watershed Health Program: Local Empowerment To Restore Watersheds, Mary Lou Soscia

Sustainable Use of the West's Water (Summer Conference, June 12-14)

9 pages.

Washington State Initiatives For Sustainable Water Use, Kenneth O. Slattery

Sustainable Use of the West's Water (Summer Conference, June 12-14)

8 pages.