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Full-Text Articles in Engineering

Graphical Display And Data Structure For Virtual Prototyping, David William Manry Apr 1999

Graphical Display And Data Structure For Virtual Prototyping, David William Manry

Doctoral Dissertations

One of the goals of engineering firms is to bring better products to market faster. Although concurrent engineering can aid in this endeavor, it requires that all areas of an organization work simultaneously. Thus, current product data must be accessible to everyone.

Virtual prototyping allows this simultaneous exchange of information. Virtual prototyping not only replaces the physical model in product development with a virtual model, but also it goes further by allowing data associated with each part of the model to be accessed. This data is not limited to just geometric properties but could contain other quantifiable properties, such as …


Magnetic And Mössbauer Spectral Study Of Mixed Valent La₀.₂Sr₀.₈Cu₀.₂Fe₀.₈O2.68 And Related Perovskites, Gary J. Long, Dimitri Hautot, Amitabh Mohan, Ingeborg Kaus, Harlan U. Anderson, Fernande Grandjean Apr 1999

Magnetic And Mössbauer Spectral Study Of Mixed Valent La₀.₂Sr₀.₈Cu₀.₂Fe₀.₈O2.68 And Related Perovskites, Gary J. Long, Dimitri Hautot, Amitabh Mohan, Ingeborg Kaus, Harlan U. Anderson, Fernande Grandjean

Chemistry Faculty Research & Creative Works

The La0.2Sr0.8Cu1-xFexO 3-δ perovskites are important because they are mixed electron and oxygen anion conductors and thus are able to serve as dense oxygen separation membranes. In order to better understand the mechanism for this separation a Mössbauer spectral study has been carried out to determine the ratio of iron(III) to iron(IV) in these mixed valent compounds. The Mössbauer spectra of La0.2Sr0.8Cu0.2Fe0.8O 3-δ obtained between 4.2 and 78 K reveal that its Néel temperature is ~75 K and the two well-resolved magnetic sextets observed …


Stratal Architecture In A Prograding Shoreface Deposit, Eastern Shore, Va: Relationship To Grain Size, Permeability, And Facies Distribution, Andrew C. Miller Apr 1999

Stratal Architecture In A Prograding Shoreface Deposit, Eastern Shore, Va: Relationship To Grain Size, Permeability, And Facies Distribution, Andrew C. Miller

OES Theses and Dissertations

A fundamental concern of the stratigrapher is to develop predictive models of stratigraphic organization. In sedimentology one of the most significant problems that has yet to be resolved is the fact that there is a lack of quantitative information regarding the relationship between geometry of beds, thickness of beds, grain size and sedimentary structures in sandy environments, especially shallow marine deposits. Scientists have also realized the need to correlate quantitative permeability to sedimentary structures and scales of stratigraphic organization. The purpose of the study is to investigate the scales of stratigraphic organization that control the variation of grain size and …


Development And Testing Of An Ac Micro Hollow Cathode Simulator, Thomas E. Caldwell Apr 1999

Development And Testing Of An Ac Micro Hollow Cathode Simulator, Thomas E. Caldwell

Electrical & Computer Engineering Theses & Dissertations

The use of AC source plasma discharge devices in applications such as material processing and film deposition has increased in recent years due to improvements in discharge efficiency made possible by devices such as the micro hollow cathode. Designing hollow cathodes for specific applications requires an understanding of the processes that govern the discharge. Simulation is an inexpensive tool for understanding hollow cathode operation and optimizing the device for specific applications. This thesis describes the development of an AC micro hollow cathode simulator. It details the theoretical models used in the simulation and presents the results of test cases intended …


Information Modeling And Method Engineering: A Psychological Perspective, Keng Siau Apr 1999

Information Modeling And Method Engineering: A Psychological Perspective, Keng Siau

Research Collection School Of Computing and Information Systems

Information modeling is the cornerstone of information systems analysis and design. Information models, the products of information modeling, not only provide the abstractions required to facilitate communication between the analysts and end users, but they also provide a formal basis for developing tools and techniques used in information systems development. The process of designing, constructing, and adapting information modeling methods for information systems development is known as method engineering. Despite the pivotal role of modeling methods in successful information systems development, most modeling methods are designed based on common sense and intuition of the method designers with little or no …


Novel Carbon-Carbon Bond Oxidative Cleavage Of Hexabenzyl-Hexaazaisowurtzitane By N-Buono And (Nh4)2ce(No3)6, Xiao-Pei Guan, Hong Yan, Jian-Guang Sun, Yong-Zhong Yu Mar 1999

Novel Carbon-Carbon Bond Oxidative Cleavage Of Hexabenzyl-Hexaazaisowurtzitane By N-Buono And (Nh4)2ce(No3)6, Xiao-Pei Guan, Hong Yan, Jian-Guang Sun, Yong-Zhong Yu

Publications and Research

Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4′,5′-e]pyrazine dinitrate.


Activated Carbon Produced From Agricultural Residues, Daniel W. Armstrong, V. J. Flanigan, William Joseph James, Jui-Lung Li, Kimber L. Rundlett Mar 1999

Activated Carbon Produced From Agricultural Residues, Daniel W. Armstrong, V. J. Flanigan, William Joseph James, Jui-Lung Li, Kimber L. Rundlett

Chemistry Faculty Research & Creative Works

A process for producing activated carbon from agricultural residues by heating the residues to a temperature in the range of about 250° C. to about 550° C. to volatilize organic compounds in the residues and to carbonize the residues and further heating to activate the carbonized residues. Activated carbon produced from agricultural residues.


Santa Clara Magazine, Volume 40 Number 4, March 1999, Santa Clara University Mar 1999

Santa Clara Magazine, Volume 40 Number 4, March 1999, Santa Clara University

Santa Clara Magazine

8 - ENGAGING HEARTS AND MINDS By President Paul L. Locatelli, S.J. '60. Does an SCU education help students become more humane, more able to engage with life? Do students work to transform the world? Does a Santa Clara education fire both their hearts and minds?

12 - TREASURE ISLANDS By Sam Scott '96. The Women Broncos soccer team soars to the 1998 NCAA Finals. With a roster packed with talent, players and coach hold high hopes for 1999·

16 - SOCKING IT TO THEM By Connie Hinckley. Six SCU faculty emeriti apply intellectual curiosity and passion to their retirement …


Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 15, Number 3, March 1999, College Of Engineering And Computer Science, Wright State University Mar 1999

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 15, Number 3, March 1999, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

A ten page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.


Space Charge Structure Of A Glow Discharge In The Presence Of A Longitudinal Inhomogeneity, Frank A. Tersigni Mar 1999

Space Charge Structure Of A Glow Discharge In The Presence Of A Longitudinal Inhomogeneity, Frank A. Tersigni

Theses and Dissertations

A survey of space charge structures arising due to inhomogeneities in glow discharges was conducted. Space charge structures associated with tube geometries, the cathode sheath, striations, and shockwaves were examined. Space charge effects on the Electron Energy Distribution Function (EEDF) were explored for a geometric inhomogeneity using an approximate nonlocal solution to the one dimensional Boltzmann equation after Godyak. The approximate solution partially captured qualitative aspects of space charge effects on the EEDF. Simplification of collisional effects and adaptation of an approximate electric field restricted quantitative comparisons with experimental data. It is recommended that any future analysis of space charge …


Target Pose Estimation From Radar Data Using Adaptive Networks, Andrew W. Learn Mar 1999

Target Pose Estimation From Radar Data Using Adaptive Networks, Andrew W. Learn

Theses and Dissertations

his research investigates and extends recent work by J.C. Principe at the University of Florida in target pose estimation using adaptive networks. First, Principe's technique is successfully extended to estimate both azimuth and elevation using SAR images. A network trained and tested using MSTAR data yields mean errors of less than six degrees in azimuth and five degrees in elevation. Second, the technique is applied to high-range resolution radar (HRR) signatures. Ground target (azimuth only) testing yields mean errors of less than 11 degrees for most classes. Air target testing for networks trained and tested on the same aircraft class …


Incorporating Scene Mosaics As Visual Indexes Into Uav Video Imagery Databases, Timothy I. Page Mar 1999

Incorporating Scene Mosaics As Visual Indexes Into Uav Video Imagery Databases, Timothy I. Page

Theses and Dissertations

The rise of large digital video archives has strengthened the need for more efficient ways of indexing video files an accessing the information contained in them. Reconnaissance platforms, such as the Predator UAV, are contributing thousands of hours of video footage that require analysis, storage, and retrieval. A process is proposed for converting a video stream into a series of mosaic and selected still images that provide complete coverage of the original video. The video mosaic images can be utilized as visual indexes into a video database. In addition, mosaic images contain information from an entire sequence of video frames …


Analysis Of The Applicability Of Video Segmentation To Unmanned Aerial Vehicle Surveillance Video, Bradley L. Pyburn Mar 1999

Analysis Of The Applicability Of Video Segmentation To Unmanned Aerial Vehicle Surveillance Video, Bradley L. Pyburn

Theses and Dissertations

The focus of this research is to determine if applying edge detection segmentation (proposed by Ramin Zabih, Justin Miller, and Kevin Mai) to Unmanned Aerial Vehicle (UAV) video footage can provide meaningful segments for database storage and retrieval. The edge detection segmentation algorithm is applied to fifty-four UAV video sequences containing visual effects such as abrupt camera changes, camera zooms, motion (rapid and gradual), and cloud cover while varying the frame rate from 5 fps to 30 fps. An analysis of the results is performed to compare actual versus expected outcomes, similar sequences, and scenes with motion, along with explaining …


Graphical User Interface And Microprocessor Control Enhancement Of A Pseudorandom Code Generator, John M. Kos Mar 1999

Graphical User Interface And Microprocessor Control Enhancement Of A Pseudorandom Code Generator, John M. Kos

Theses and Dissertations

Modern digital communication techniques often require the generation of pseudorandom numbers or sequences. The ability to quickly and easily produce various codes such as maximal length codes, Gold codes, Jet Propulsion Laboratory ranging codes, syncopated codes, and non-linear codes in a laboratory environment is essential. This thesis addresses the issue of providing automated computer control to previously built, manually controlled hardware incorporating the Stanford Telecom STEL-1032 Pseudo-Random Number (PRN) Coder. By incorporating a microcontroller into existing hardware, the STEL-1032 can now be conveniently controlled from a MATLAB Graphical User Interface (GUI). The user can quickly create, save, and recall various …


A New Sequential Goodness Of Fit Test For The Three-Parameter Gamma Distribution With Known Shape Based On Skewness And Kurtosis, Chil Ho Park Mar 1999

A New Sequential Goodness Of Fit Test For The Three-Parameter Gamma Distribution With Known Shape Based On Skewness And Kurtosis, Chil Ho Park

Theses and Dissertations

This research presents a new sequential goodness of fit test for the three-parameter gamma distribution with a known shape. The test is accomplished by employing two new tests, sample skewness and sample kurtosis, sequentially as test statistics. Unlike the typical goodness of fit test, using parameter estimation methods such as maximum likelihood estimation and minimum distance estimation, this test using the two test statistics above does not involve a substantial degree of computational complexity. Large Monte Carlo simulation has been used to determine critical values and overall significance levels for all combinations of the two tests, and to conduct extensive …


Electrical Characterization Of Ion-Implanted 4h-Silicon Carbide, Christian P. Morath Mar 1999

Electrical Characterization Of Ion-Implanted 4h-Silicon Carbide, Christian P. Morath

Theses and Dissertations

Electrical characterization has been performed on ion-implanted p-type 4H-SiC to assess the activation efficiency and implantation-related damage recrystallization with the intention of developing an implantation/annealing scheme. Low doped (Na - Nd = 5x10(exp 15)/cu cm) epitaxial p-type layers grown by MOCVD were implanted with Al or B at doses ranging from 1x10(exp 13) to 1x10(exp 14)/sq cm at room temperature or 500 deg. C. The electrical technique of Temperature Dependent Hall Effect (TDHE) indicated that Al and B act as shallow acceptors 4H-SiC with ionization energies of ^252 and ^285 meV, respectively. The highest activation efficiency for Al and B …


Trade-Off Analysis Of Communications Capabilities Of Inter-Satellite Links, Andrew J. Feltman Mar 1999

Trade-Off Analysis Of Communications Capabilities Of Inter-Satellite Links, Andrew J. Feltman

Theses and Dissertations

This thesis designs, develops, and uses software Graphical User Interfaces (GUIs) to analyze the communications capabilities of Radio Frequency (RF) Inter-Satellite Links (ISLs). The GUIs are geared towards analyzing the proposed ISLs of the Discoverer II program, but are general enough to permit analysis of any free-space RF ISLs. Discoverer II is a demonstration program of low-earth orbiting satellites and is primarily focused on satellite-based sensor technology. This thesis shows RF ISLs can meet the program requirement to broadcast the sensor data back to CONUS in near-real-time. The GUIs operate in real-time and explore trade-offs in the communications capability by …


Electrochemical Surface Characterization Of Titanium Alloy(Ti-6al-4v), Jian-Zhong Chen, Qing-Liang Gao, Zhong-Yi Wang, Wen-Jing Xue Feb 1999

Electrochemical Surface Characterization Of Titanium Alloy(Ti-6al-4v), Jian-Zhong Chen, Qing-Liang Gao, Zhong-Yi Wang, Wen-Jing Xue

Journal of Electrochemistry

With its low density and high strength ratio, titanium alloy(Ti6Al4V) has become one of the most important materials both in the fields of aerospace and biomedical assays. Recently, titanium alloy was used as the implantation materials in human body because of its biocompatibility. The elecrochemical impedance techniques were then used to investigate the corrosion behavior of this material in hydrochloride and sulfuric acid solutions. A comparison between impedance spectra and anodic polarization over the correlated range of applied voltage confirms that AC impedance data can be used as a powerful tool for surface characterization of titanium …


Electrodeposition Of Neodymium-Iron Group Alloy Films In (P-Ch3C6H4So3)3Nd System, Peng Liu, Ye-Xiang Tong, Qi-Qin Yang, Yan-Sheng Yang Feb 1999

Electrodeposition Of Neodymium-Iron Group Alloy Films In (P-Ch3C6H4So3)3Nd System, Peng Liu, Ye-Xiang Tong, Qi-Qin Yang, Yan-Sheng Yang

Journal of Electrochemistry

Neodymium p-toluenesulfonate was prepared and applied to the electrodepositon of neodymium-iron group alloy films. This salt has high solubility in DMF and can be dehydrated easily. Cyclic voltammograms of Pt electrode in (p-CH3C6H4SO3) 3Nd + MCl2(M=Fe,Co,Ni) + DMF indicated that the neodymiun-iron group alloys can be elcetrodeposited from this medium, the Nd-Fe, Nd-Co and Nd-Ni films were obtained by electrolysis at constant potential. The Nd-Fe, Nd-Co and Nd-Ni films are amorphous in which the rare earth contents are in the range of 15 at%~60 at% as analyzed by XRD and …


Study Of Localized Corrosion Of Metals By Using The Electrochemical Techniques With Spatial Resolution, Chang-Jian Lin, Xiang-Dong Zhuo, Zu-De Feng, Rong-Gui Du, Zhao-Wu Tian Feb 1999

Study Of Localized Corrosion Of Metals By Using The Electrochemical Techniques With Spatial Resolution, Chang-Jian Lin, Xiang-Dong Zhuo, Zu-De Feng, Rong-Gui Du, Zhao-Wu Tian

Journal of Electrochemistry

The electrochemical inhomogeneities at interface of metal/solution play an important and often controlling role in localized corrosion of metals. The traditional electrochemical techniques involving potential, current density or ac impedance measurements over bulk specimens can only provide average and general information of the interface. Thus, the development of in situ imaging techniques is essential for further characterizing electrochemical inhomogeneities at the metal/solution interface of localized corrosion system. The electrochemical techniques with spatial resolution,including scanning single micro electrode, scanning double micro electrodse and scanning micro chemical probes are reviewed. The effects of electrochemical inhomogeneities on the corrosion behavior, and the mechanism …


Effect Of Stress On Electrochemical Behaviour Of Various Thermal History Zones And Different Phase Structures On The Weldment For Low Alloy Steel, Yin-Shun Wu, De-Yu Liu, Bei Cao, Feng-Li Wang, Zhi Fang, Lin Zhang, Zheng-Rong Zhang, Hai Yang Feb 1999

Effect Of Stress On Electrochemical Behaviour Of Various Thermal History Zones And Different Phase Structures On The Weldment For Low Alloy Steel, Yin-Shun Wu, De-Yu Liu, Bei Cao, Feng-Li Wang, Zhi Fang, Lin Zhang, Zheng-Rong Zhang, Hai Yang

Journal of Electrochemistry

The electrochemical behaviour of various thermal history zones on the weldment for steel 16Mn and also of the ferrite, pearlite in various zones was measured by use of a self-developed measuring technique for investigating the electrochemicl behaviour of single and mixed phase structures in metal materials. Especially the effect of stress on this electrochemical behaviour was investigated. The results showed that by comparison with non-stress condition, the free corrosion potential of the various thermal history zones and of the ferrite, pearlite under stress condition was shifted in negative direction, correspondingly their free corrosion current density was increased, the free corrosion …


Study On Steel Corrosion In Simulated Biofilm Environment In Seawater, Qing-Fei Wang, Jing Sui, Run-Xi Su, De-Ying Kong, Shi-Zhe Song Feb 1999

Study On Steel Corrosion In Simulated Biofilm Environment In Seawater, Qing-Fei Wang, Jing Sui, Run-Xi Su, De-Ying Kong, Shi-Zhe Song

Journal of Electrochemistry

Biofilm is one of the main factors that influence metal corrosion in seawater environment. According to the structure and property of biofilm, a natural biopolymeric gel, calcium alginate(an extracellular biopolymer containing carboxylate functional groups) can deposite on metal surfaces to form films. Corrosion behavior of alloyed steel E2, 10CrMoAl and 18-8 stainless steel were studied in simulated biofilm environment by various electrochemical methods ,including measurements of the corrosion potential, polarization curves,galvanic current and electrochemical impedance. The results show that such an approach is informative to reveal “how” and “to what extent” biofilm can influence the metal corrosion process.


Studies Of Electrochemical Characteristics Of Pasted Nickel Hydroxide Electrode With Surface Deposited Cobalt, Xian-You Wang, Yun-Shi Zhang, Jie Yan, Zheng Zhu, Hua-Tang Yuan, De-Ying Song Feb 1999

Studies Of Electrochemical Characteristics Of Pasted Nickel Hydroxide Electrode With Surface Deposited Cobalt, Xian-You Wang, Yun-Shi Zhang, Jie Yan, Zheng Zhu, Hua-Tang Yuan, De-Ying Song

Journal of Electrochemistry

The surface of the spherical nickel hydroxide particles used as an active material in pasted nickel electrodes is surface-deposited with cobalt. This paper investigated the effects of the amount of cobalt deposit on the characteristics of nickel hydroxide electrode. The performances of the electrode, such as discharge capacity, utilization of active material and reversibility of Ni(OH)2/NiOOH redox reaction, were studied by comparing the charging/discharging curves and cyclic voltammograms. The mechanism of action of cobalt deposits has been described in terms of the electrochemical impedance spectroscopy of nickel hydroxide electrode.


Electrohydrodimerization Of Fumarodinitrile On Liquid Gallium Electrode, He Wei, Huang Ying, Sheng-Tao Zhang Feb 1999

Electrohydrodimerization Of Fumarodinitrile On Liquid Gallium Electrode, He Wei, Huang Ying, Sheng-Tao Zhang

Journal of Electrochemistry

Electrohydrodimerization (EHD) of fumarodinitrile on liquid gallium electrode can take place not only in hydrotropic solution of tetraethylammonium p-toluenesulphonate (TEA-PTS), but also in aqueous solution containing low concentration of strong surfactants, such as TritonX-100. In solution without organic surfactant, FDN yields a single two-electron reduction wave corresponding to the formation of a saturated monomer called as butanedinitrile. If some TEA-PTS or TritonX-100 is added into the solution, the original two-electron wave is splitted into two continuous single-electron reduction wave and corresponding EHD of fumarodinitrile is obtained.


Study On The Mechanism Of Ni/Zro2 Composite Electrodeposition, Qun-Jia Peng, Dao-Bin Mu, Ju-Sheng Ma, Xiang-Yun Tang Feb 1999

Study On The Mechanism Of Ni/Zro2 Composite Electrodeposition, Qun-Jia Peng, Dao-Bin Mu, Ju-Sheng Ma, Xiang-Yun Tang

Journal of Electrochemistry

The effects of cathodic current density and amount of particle dispersion in solution on the codeposition of Ni/ZrO2 composite in Watts bath were studied, and the machanism of the composite electrodeposition was investigated. The study shows that the composite electrodeposition is controlled by the transfer of particles to the cathode when the dispersion amount is small, causing the decrease of the codeposition with the increase of current density. With large amount dispersion, the composite electrodeposition is first controlled by the strong adsorption of particles on the cathode at low current density, resulting in the increase of the codeposition with …


Kinetic Study Of Electrooxidation Of Benzene, Xin-Sheng Zhang, Ping Ding, Ying-Chun Dai, Wei-Kang Yuan Feb 1999

Kinetic Study Of Electrooxidation Of Benzene, Xin-Sheng Zhang, Ping Ding, Ying-Chun Dai, Wei-Kang Yuan

Journal of Electrochemistry

A reaction kinetic study for electrochemical oxidation of benzene was performed on a PbO2 rotating disk electrode in 1 mol/L H2SO4 aqueous solution. The reaction orders, the activation energies and transfer coefficient were measured, and the kinetic expression was obtained.


Pitting Corrosion Of Ni-Based Alloy In Thiosulfate-Ion Containing Chloride Solutions, Yung-Fa Lee, Ting-Yu Wang, Wen-Ta Tsai Feb 1999

Pitting Corrosion Of Ni-Based Alloy In Thiosulfate-Ion Containing Chloride Solutions, Yung-Fa Lee, Ting-Yu Wang, Wen-Ta Tsai

Journal of Electrochemistry

The effect of thiosulfate ion on the pitting corrosion behavior of Ni-Based Alloy 690 in chloride solution was investigated. In plain sodium thiosulfate solution, Alloy 690 was immune to pitting corrosion. However, the addition of low concentration of sodium thiosulfate can enhance the initiation of pitting corrosion of Alloy 690. Nevertheless, inhibition of pitting corrosion was observed at high concentration of addition.


Oxidation Mechanism Of Hypophosphite, Dong-Bai Sun, Ying Jin, Hong-Ying Yu, De-Jun Yang Feb 1999

Oxidation Mechanism Of Hypophosphite, Dong-Bai Sun, Ying Jin, Hong-Ying Yu, De-Jun Yang

Journal of Electrochemistry

There exist two oxidation current peaks on the anodic polarization curve between -0.7 V and 0 V (SCE) in Na-hypophosphite solution. Peak Ⅰ (-0.55 V, SCE) , which represents the oxidation process from H2PO2- to H2PO3-, has been studied previously. Peak Ⅱ, which is located at the potential about -0.4 V (SCE), is investigated emphatically in this paper. The results show that, peak Ⅰ and Ⅱ are corresponding to two successive steps in oxidation process of H2PO2-, i.e. peak Ⅱ corresponds to the oxidation process of …


Synthesis And Application Of Polymeric Corrosion Inhibitor For Reinforced Concrete, Wei-Wei Lin, Sheng-Xian Wang, Jian-Qing Zhang, Jun Yuan, Zhen-Guo Ji Feb 1999

Synthesis And Application Of Polymeric Corrosion Inhibitor For Reinforced Concrete, Wei-Wei Lin, Sheng-Xian Wang, Jian-Qing Zhang, Jun Yuan, Zhen-Guo Ji

Journal of Electrochemistry

A new polymer E-T was synthesized and used as a corrosion inhibitor for reinforced concrete. The inhibitive behavior and mechanism were studied with linear polarization, Tafel polarization, EIS and XPS method in simulated pore solution system with concrete samples. The result showed that the polymer was a mixing type inhibitor. A 1% dosage was sufficient to imhibit the corrosion of steel in simulated pore solution system. The salt endurance was enhanced from 0.02 mol/L to 0.10 mol/L. The result also showed the good synergetic effect of NaNO2, especially in low NaNO2 concentration. The EIS showed that E-T …


Structural And Electrochemical Studies On Todorokite/Vernadite As Cathodes For Rechargeable Lithium Ion Batteries, Wei Chu, De-Yao Liu, Jin-Kua You, Yong Yang, Zu-Geng Lin Feb 1999

Structural And Electrochemical Studies On Todorokite/Vernadite As Cathodes For Rechargeable Lithium Ion Batteries, Wei Chu, De-Yao Liu, Jin-Kua You, Yong Yang, Zu-Geng Lin

Journal of Electrochemistry

XRD, TEM, ICP, low scan-rate CV and charge/discharge tests were carried out for the studies on the structural and electrochemical behavior of a prepared 3 V manganese oxide cathode for rechargeable lithium ion batteries.XRD analysis revealed that the cathode sample is mainly composed of tunneled Todorokite and layered Vernadite. TEM investigation confirmed that the morphology of the sample is a laminated construction with approximate 10nm layer space. The reversibility of Li+ removal/intercalation and structural stability of this sample framework to lithium insertion are good in CV and charge/discharge tests. The discharge capacities were found to be about 129mAh/g obtained …