Engineering Commons^™

Preparation Of Poly (Bromophenol Blue) Modified Glassy Carbon Electrode And Its Electrocatalytic Activity, Wei Chen, Hong-Bin Luo, Xin-Hua Lin

Journal of Electrochemistry

A film of poly (bromophenol blue) was formed on a glassy carbon electrode by using cyclic voltammetry. A stable film could be obtained with a potential range from -1.0 V to +1.8 V (vs.Ag/AgCl). The experimental results showed that the poly (bromophenol blue) modified glassy carbon electrode could catalyse the oxidation of ascorbic acid. It decreased the oxidation potential by about 270mV but increased the peak current. Meanwhile, this electrode showed a good linear current response for the ascorbic acid range from 2.5 to 250 (g/mL).

Electrochemical Properties Of Polymeric Gel Electrolyte With Gbl/Ec As Plasticizers, Yu-Wen Liu, Yong Zhang, Xiao-Long Li, Qi-Ping Gu, Cui-Fen Zhang, Yu-Dong Huang

Journal of Electrochemistry

Polymeric gel electrolytes (GPE) based on PMMA and PVDF-HFP were prepared using the binary mixtures of γ-butyrolactone (GBL) and ethylene carbonate (EC) as plasticizers. The ionic transport properties and electrochemical stability were studied. The room temperature conductivity reached 1.2 mS·cm^-1, electrochemical stability window exceeded 4.5V. The interfacial stability between GPE and lithium electrode was also investigated. The lithium metal polymer battery (LMPB) prepared with the GPE showed better charge and discharge life cycle when the the lithium metal electrode was treated with 1,4-dioxane.

Research On Phenol Wastewater Treatment By Electrochemical Oxidation, Tian-Cheng Li, Shen-Lin Zhu

Journal of Electrochemistry

Electrochemical oxidation is an effective technology for the phenol wastewater treatment, and the anode properties are important to the electrochemical oxidationefficiency. The over-potentials of oxygen evolution have been measured for thestainless steel, feasible graphite and SnO₂/Ti anode respectively. Moreover, the synthetic phenol wastewater was treated by the electrochemical oxidation with the stainless steel or feasible graphite anodes. The experimental results showed that the order of the over-potential is SnO₂/Ti > graphite > stainless steel; meanwhile, the COD values of purified water were approaching to or less than 100 mg·L^-1, and the phenol concentrations in the purified …

Calcium Zincate Prepared By Ball Mill Method, Sheng-Xian Li, Shuan-Bao Tian, Shao-Shan Zhu

Journal of Electrochemistry

Calcium zincate was prepared by ball milling method and the factors that influence its synthesis were investigated. The composition of the compound was Ca(OH)₂·2Zn(OH)_2^·2H₂O, which was verified by XRD and TG-DTA methods. The results of powder microelectrode and in simulated batteries showed that the material had excellent cyclic performance.

Influence Of Rare Earth Oxide On The Performance Of Secondary Zinc Electrodes, Xian-Ling Meng, Hua-Bin Yang, Jun-Hong Wang, Zuo-Xiang Zhou

Journal of Electrochemistry

Influence of La(OH)₃ or Ce(OH)₃ in secondary zinc electrode was investigated by the cyclic voltammetry, potentiodynamic polarizationand potentiostatic polarization tests and influence of La₂O₃ or CeO₂ in the charge/discharge performance of Zn/Ni battery was studied by galvanostatic charge/discharge experiment. The results showed that the film of rare earth hydroxide prevented the zincate species from transferring toward solution, enhanced hydrogen overpotential and decreased thecorrosion current density (i_corr), and therefore inhibited zinc corrosion. The potentiostatic polarization results at100mV overpotential showed that La(OH)₃ or Ce(OH)₃ oated on the zinc electrode effectively suppressed the …

Fabrication And Studies Of A Novel Ag/Agcl Reference Electrode In High Temperature Molten Chloride Salts, Pei Gao, Xian-Bo Jin, Di-Hua Wang, Xiao-Hong Hu, Zheng Chen

Journal of Electrochemistry

A new method for the easy fabrication of a stable and long life silver/silver chloride reference electrode in molten chloride salts is described in this paper. The method is based on the fact that simply placing the silica glass in molten NaCl or its vapour in the presence of oxygen resulted in satisfactory conductivity for sodium ion and possibly calcium ion in the material.The performance of such made electrode has been investigated in a few typical chloride systems at temperatures ranging from 400 to 900℃. Due to the wholly sealed construction, the reference electrode is stable, temperature-reversible, contamination free to …

The Electrophoretic Deposition Of Nano Hydroxyapatite Coating On Titanium Surface, Fei Chen, Chang-Jian Lin, Zhou-Cheng Wang

Journal of Electrochemistry

A hydroxyapatite coating with nano-structure on the roughened titanium surface was prepared by electrophoretic deposition process. To decrease sintering temperature the HAp nanoparticles synthesizedby a wet chemical method was used. It is observed that the coating is uniform without cracks. After sintering the nano-strueture of HAp coating remains unchanged. The surface treatment of Ti is applied to form a distribution of small pits and TiO₂ thin layer that improve the adhesion of coatingto Ti substrate. It is shown that the bonding strength of coating is as high as 18±2.5MPa. The hardness and Young's modulus are 40.6 and 0.42 GPa, …

The Fabrication And Electrochemical Studies On Carbon Nanotube Array Electrodes, Quan-Yong Gao, Jing Zhang, Yong Yang

Journal of Electrochemistry

An improved technique for fabrication of carbon nanotube array electrodes has been proposed in this work. Firstly, carbon nanotubes (CNs) array electrodes were prepared by combsination of Chemical Vapor Decomposition (CVD) method and sputtering techniques in anodized aluminum oxide (AAO) membrane. The CNs/AAO was immersed into HF solution to remove the barrier layer. Controlling the immersing time, the CNs array electrodes with different length contacted with electrolyte can be prepared. The morphology of CNs array electrodes was observed by SEM. The electrochemical properties of CNs array electrodes were investigated by cyclic voltammetry and electrochemical impedance spectroscopy. Cyclic voltammetric curves of …

Impact Of The Synthesis Process On Structure Properties For Afci Fuel Candidates, Thomas Hartmann, Kenneth Czerwinski

Fuels Campaign (TRP)

Transmutation work at Los Alamos National Laboratory is currently focused on mono-nitride ceramic fuel forms, and consists of closely coordinated “hot” actinide and “cold” inert and surrogate fuels work. Matrix and surrogate materials work involves three major components: (1) fuel matrix synthesis and fabrication, (2) fuel performance, and (3) fuel materials modeling. The synthesis and fabrication component supports basic material studies, as well as actinide fuel fabrication work through fuel fabrication process development. Fuel performance studies are examining the tolerance of nitride-type fuel to heavy irradiation damage. The fuel materials simulation work involves both atomistic and continuum scale modeling employing …

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 21, Number 5, February 2005, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

A six page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.

Specification Of A Common Framework For Characterizing Alignment, Paolo Bouquet, Marc Ehrig, Jerome Euzenat, Enrico Franconi, Pascal Hitzler, Markus Krotzsch, Luciano Serafini, Giorgos Stamu, York Sure, Sergio Tessaris

Computer Science and Engineering Faculty Publications

Definition of a common framework for characterizing alignment of heterogeneous information. This report describes various approaches towards this goal and shows the relations between them. It also provides a description of the alignment sructure and process.

The Value Of Mobile Applications: A Utility Company Study, Fiona Fui-Hoon Nah, Keng Siau, Hong Sheng

Research Collection School Of Computing and Information Systems

The value proposition of mobile applications i.e. the net value of the benefits and costs associated with the adoption and adaptation of mobile applications is discussed. A means-ends network that depicts the fundamental relationships among the objectives such as efficiency, effectiveness, customer satisfaction, security, cost, and employee acceptance, was developed. The network is useful to researchers as it highlights the issues, concerns, and values of mobile applications. The network help the managers and practitioners to achieve their companies' objectives of implementing mobile and wireless applications.

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Neutronic Evaluation Of Zro2-Mgo Inert Fuels, E. Fridman, S. Kolesnikov, E. Shwageraus, A. Galperin

Fuels Campaign (TRP)

This report presents the results of the Task 3, defined in working program as: evaluation of burnable poison designs. Adopting the basic design of a standard PWR and Pu loadings required for 18-month cycle (results of Task 2), this part of the program is aimed to estimate performance of each BP design and BP material to address challenges of Fertile-Free Fuel (FFF) Concept. Finally, an optimal BP design will be developed and an overall feasibility of FFF concept will be determined. Basically, the main challenge encountered in neutronic design for a FFF core is to develop reactivity control system which …

Reinforcement Learning-Based Output Feedback Control Of Nonlinear Systems With Input Constraints, Pingan He, Jagannathan Sarangapani

Electrical and Computer Engineering Faculty Research & Creative Works

A novel neural network (NN) -based output feedback controller with magnitude constraints is designed to deliver a desired tracking performance for a class of multi-input-multi-output (MIMO) discrete-time strict feedback nonlinear systems. Reinforcement learning in discrete time is proposed for the output feedback controller, which uses three NN: 1) a NN observer to estimate the system states with the input-output data; 2) a critic NN to approximate certain strategic utility function; and 3) an action NN to minimize both the strategic utility function and the unknown dynamics estimation errors. The magnitude constraints are manifested as saturation nonlinearities in the output feedback …

Smartacking: Improving Tcp Performance From The Receiving End, Daniel K. Blandford, Sally A. Goldman, Sergey Gorinsky, Yan Zhou, Daniel R. Dooly

All Computer Science and Engineering Research

We present smartacking, a technique that improves performance of Transmission Control Protocol (TCP) via adaptive generation of acknowledgments (ACKs) at the receiver. When the bottleneck link is underutilized, the receiver transmits an ACK for each delivered data segment and thereby allows the connection to acquire the available capacity promptly. When the bottleneck link is at its capacity, the smartacking receiver sends ACKs with a lower frequency reducing the control traffic overhead and slowing down the congestion window growth to utilize the network capacity more effectively. To promote quick deployment of the technique, our primary implementation of smartacking modifies only the …

Advantageous Goes Ir Results For Ash Mapping At High Latitudes: Cleveland Eruptions 2001, Yingxin Gu, William I. Rose, David J. Schneider, Gregg J. S. Bluth, M. I. Watson

Department of Geological and Mining Engineering and Sciences Publications

The February 2001 eruption of Cleveland Volcano, Alaska allowed for comparisons of volcanic ash detection using two-band thermal infrared (10–12 μm) remote sensing from MODIS, AVHRR, and GOES 10. Results show that high latitude GOES volcanic cloud sensing the range of about 50 to 65°N is significantly enhanced. For the Cleveland volcanic clouds the MODIS and AVHRR data have zenith angles 6–65 degrees and the GOES has zenith angles that are around 70 degrees. The enhancements are explained by distortion in the satellite view of the cloud's lateral extent because the satellite zenith angles result in a “side-looking” aspect and …

Computer-Simulation-Assisted Lean Manufacturing Training, Luoding Wang

Theses and Dissertations

This thesis assesses the potential of using computer simulation to aid existing lean manufacturing training methods such as lecture and live simulation. An investigation of this possibility was carried out in conjunction with UMEP's Lean 101 class. In the study, two experimental computer simulation models demonstrating the push and pull production scenarios were constructed using ProModel software. Simulation models were equipped with a Visual Basic interface to aid trainees to manipulate the model via ActiveX. Constructed computer simulation was compared with live simulation to answer these research questions: 1. Was computer simulation able to teach additional lean concepts not covered …

Design Concepts And Process Analysis For Transmuter Fuel Manufacturing: Quarterly Progress Report #1, Jamil M. Renno, Georg F. Mauer

Fuels Campaign (TRP)

A Hot Cell robotic assembly: Pick and place dynamic simulation, including feedback control with Matlab, was developed for dispersion fuel manufacture.

The deployment of remote manufacturing of transmuter fuel is a necessity for the transmutation applications. In the reporting period, a virtual hot cell for the manufacturing of dispersion fuel was designed using MSC.visualNastran^©, ProEngineer^© and MATLAB^©. Atypical events were successfully simulated. Relevant physical quantities arising during such events were monitored as well.

Creep Of Granular Ice With And Without Dispersed Particles, Min Song, David M. Cole, Ian Baker

Dartmouth Scholarship

The effects of silt-sized particles (average diameter of 50 m m) on the compressive creep of polycrystalline ice have been studied at stress levels from 0.1 to 1.45MPa and temperatures of –12 8 C and –10 8 C. Dislocation densities during creep have been estimated using a dislocation-based model of anelasticity. The results indicate that at low concentrations (up to 4wt.% % ), particles increase the minimum creep rate. Power-law behavior with an exponent of 3 was observed for both particle-free ice and ice with 1 wt.% % particles when the stress was >0.3 MPa. In contrast, linear behavior was …

Effect Of Silicon Content On The Corrosion Resistance And Radiation-Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems: Quarterly Progress Report (August 2004 – October 2004), Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this collaborative research project involving the University of Nevada Las Vegas (UNLV), Los Alamos National Laboratory (LANL) and Idaho State University (ISU) is to evaluate the effect of silicon (Si) content on the corrosion behavior and radiation-induced embrittlement of martensitic stainless steels having chemical compositions similar to that of the modified 9Cr-1Mo steel. Recent studies at LANL involving Alloy EP-823 of different Si content have demonstrated that increased Si content in this alloy may enhance the corrosion resistance in molten lead-bismutheutectic (LBE). Since very little data exists in the open literature on the beneficial effect of Si …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements: Quarterly Progress Report (September 01 – November 30, 2004), Ajit K. Roy

Transmutation Sciences Materials (TRP)

Accomplishments:

● A technical paper titled “Residual Stress Characterization in Structural Materials by Destructive and Nondestructive Techniques” has been accepted for publication in the Journal of Materials Engineering and Performance, ASM International, Ohio.

● The PAS method has been applied to develop calibration curves for line shape parameters (S and T) using unstressed and stressed (different magnitude) tensile specimens of martensitic stainless steels. These curves will enable the determination of residual stresses in plastically-deformed materials once the magnitude of S or T parameter is determined by the PAS technique.

● The tensile and welded specimens have been irradiated by low …

Robust Control Techniques For State Tracking In The Presence Of Variable Time Delays, Jarrett Goodell, Marc Compere, Miguel Simon, Wilford Smith, Ronnie Wright, Mark Brudnak

Publications

In this paper, a distributed driver-in-the-Ioop and hardware-in-the-Ioop simulator is described with a driver on a motion simulator at the U.S. Army TARDEC Ground Vehicle Simulation Laboratory (GVSL). Realistic power system response is achieved by linking the driver in the GVSL with a full-sized hybrid electric power system located 2,450 miles away at the TARDEC Power and Energy Systems Integration Laboratory (P&E SIL), which is developed and maintained by Science Applications International Corporation (SAIC). The goal is to close the loop between the GVSL and P&E SIL over the Internet to provide a realistic driving experience in addition to realistic …

A Multi-Server Markovian Queueing Model With Primary And Secondary Services, Valentina Klimenok, Srinivas R. Chakravarthy, Alexander Dudin

Industrial & Manufacturing Engineering Presentations And Conference Materials

We study a multi-server queueing model in which the arrivals occur according to a Markovian arrival process. An arriving customer either (a) is lost due to all main servers being busy; or (b) enters into service with one of the main servers and leaves the system (as a satisfied primary customer); (c) enters into a service with one of the main servers, gets service in self-service mode, and is impatient to get a final service with one of the main servers, may leave the system (as a dissatisfied secondary customer); or (d) enters into service with one of the main …

Quantifying Savings From Improved Boiler Operation, Kevin Carpenter, J. Kelly Kissock

Mechanical and Aerospace Engineering Faculty Publications

On/off operation and excess combustion air reduce boiler energy efficiency. This paper presents methods to quantify energy savings from switching to modulation control mode and reducing excess air in natural gas fired boilers.

The methods include calculation of combustion temperature, calculation of the relationship between internal convection coefficient and gas flow rate, and calculation of overall heat transfer assuming a parallel-flow heat exchanger model. The method for estimating savings from changing from on/off to modulation control accounts for purge and drift losses through the boiler and the improved heat transfer within the boiler due to the reduced combustion gas flow …

The Effects Of Humidity On The Dielectric Response In Ferroelectric Polymer Films Made By Langmuir-Blodgett Deposition, Kristin L. Kraemer, Alexander V. Sorokin, Christina M. Othon, Stephen Ducharme, Vladimir M. Fridkin

Stephen Ducharme Publications

No abstract provided.

Non-Verbal Communication With Autistic Children Using Digital Libraries, Gondy A. Leroy, John Huang '05, Serena Chuang '05, Marjorie H. Charlop

CGU Faculty Publications and Research

Autism spectrum disorder (ASD) has become one of the most prevalent mental disorders over the last few years and its prevalence is still growing. The disorder is characterized by a wide variety of symptoms such as lack of social behavior, extreme withdrawal, and problems communicating. Because of the diversity in symptoms and the wide variety in severity for those, each autistic child has different needs and requires individualized therapy. This leads to long waiting lists for therapy.

Dlpconvert: Converting Owl Dlp Statements To Logic Programs, Boris Motik, Denny Vrandecic, Pascal Hitzler, York Sure, Rudi Studer

Computer Science and Engineering Faculty Publications

In the past few years, the W3C has been establishing standards for the fundamental building blocks of the Semantic Web. With RDF a common data model has been provided. A major step was the introduction of the ontology definition languages RDFS—offering very basic semantics—and the Web Ontology Language OWL As these standards are still very new, only a limited support of tools for inferencing and querying exists. Still, the availability of such tools will be crucial for the development of the Semantic Web.

Literature Survey Of Wind Turbine Aeroelastic Stability, Scott M. Larwood

All Faculty Reports - School of Engineering and Computer Science

A literature survey of wind turbine aeroelastic stability is presented. The subject received early interest as the emergent wind industry looked to lessons from the helicopter industry. There has not been a utility-scale turbine with flutter problems, but there is a concern over the behavior of larger, more flexible turbines. Blades of innovative design with bend-twist coupling and tip sweep are also a concern. Much of the aerodynamic modeling was formulated in the 1930s by Theodorsen. Modern authors have developed finite element structural models for eigenvalue solutions to the stability models. Calculations for a 1.5 MW turbine blade with bend-twist …

Test 1856: Mccormick Mtx 120 Diesel, Nebraska Tractor Test Lab

Nebraska Tractor Tests

No abstract provided.

Santa Clara Magazine, Volume 47 Number 3, Winter 2005, Santa Clara University

Santa Clara Magazine

8 - AFTER AMERICA by Deepa Arora. Thomas J. Reese, S.J., the former editor of the Jesuit weekly magazine, America, is spending a sabbatical year at SCU. He sat down for an exclusive interview with SCM to reflect on what he has witnessed, what inspires him, and the future of the Church.

16 - A HALF-CENTURY OF ART AND HISTORY AT SCU by Victoria Hendel De La O. "Through its exhibitions and collections, the museum allows students and faculty to expand the walls of the classroom," says Rebecca M. Schapp, director of the de Saisset Museum, which is celebrating its …