Engineering Commons^™

Hydrothermal Preparation And Electrochemical Characterizations Of Vanadate Compound Nav2O5 Crystals, Fang Hu, Xing Ming, Fei Du, Ying-Jin Wei, Gang Chen, Chun-Zhong Wang

Journal of Electrochemistry

The NaV₂O₅ was prepared by a low temperature hydrothermal process. The material crystallized in the layered orthorhombic structure with space group Pmmn. X-ray diffraction confirmed that the material was pure and the scanning electron microscopy showed that the material was composed of needle crystals with 20 μm in length and 200 nm in width. X-ray photoelectron spectroscopy indicated the co-existence of V⁴⁺ and V⁵⁺ in the material,which results in an average V^4.5+ oxidation state of the material. The observed Raman bands were ascribed to different V-O vibrations. The first specific capacity about 120 mAh/g …

Photoelectrochemical Properties Of Tio2 Nanoparticles, Jie Qu, Ying Li, Qi-Wei Jiang, Xue-Ping Gao

Journal of Electrochemistry

The protonated titanate nanoparticles were obtained at room temperature and subsequently calcined at different temperatures(300 ℃,400 ℃,500 ℃,600 ℃ and 700 ℃) in air.The obtained products were characterized by XRD,TEM and UV-Vis.It is found that the grain sizes of TiO₂ nanoparticles calcined at 300 ℃ were about 20 nm,and increased gradually with the temperature rise.Photoelectric performance was measured with I～V curve and electrochemical impedance spectroscopy(EIS).The TiO₂ nanoparticles obtained at 500 ℃ showed the best photoelectrochemical properties with a photovoltaic conversion efficiency of 6.39%,which is much higher than those at other temperatures.In addition,it is also demonstrated that the charge …

Electrooxidation Behaviors Of Tib2 As High Capacity Anodic Material In Neutral Aqueous Electrolytes, Ya-Dong Wang, Xian-Yong Guang, Zhi-Xin Wang, Xin-Ping Ai, Han-Xi Yang

Journal of Electrochemistry

Titanium diborides were investigated as an anodic material for neutral aqueous batteries. It is revealed that this material shows superiorly high electrochemical activities in the neutral electrolytes. The discharge capacities observed for TiB₂ reached 1300 mAh/g at the constant current density of 50 mA/g, exceeding all the metal electrodes reported so far. The electrooxidation of this compound was found to proceed via the electrochemical dissolution of boron to form borofluoride, while titanium remained unchanged at the electrode. These results suggest a possible use of the boride compounds as a new material for constructing neutral aqueous batteries with high electrochemical …

The Electrochemical Performance Of Ncf-Sulfur Cathode, Chun-Rong Zhao, Zhong-Bao Yu, Wei-Kun Wang, Yu-Sheng Yang

Journal of Electrochemistry

The electrochemical performance of NCF-sulfur cathode, with different NCF contents, was investigated by constant current discharge, cyclic voltammetry and AC impedance methods. The morphologies of the cathodes were observed using scanning electron microscopy. The results indicate that the cycle life and rate capability of NCF-sulfur cathode increased. Better performance of sulfur cathode was obtained by 3% and 5% NCF conductive addition. When the current density was 0.4 mA/cm², the 3% NCF-sulfur cathode had an initial capacity of 880 mAh/g and a reversible capacity of 630 mAh/g after 20 cycles.

Preparation And Characterization Of Tin-Nickel Alloy Electromagnetic Shielding Fabric, Ke-Jing Chu, Wei Wang, Bin Sun, Mei-Fang Zhu

Journal of Electrochemistry

A soft electromagnetic shielding fabric was successfully prepared by electroplating tin-nickel alloy on the Cu-plated PET fabric in potassium pyrophosphate system. Results show that the different tin content and different colour can be obtained by changing the ratio of metals in bath. Better corrosion resistance and anti-tarnishing were achieved with the fabric consisting of 68.96% Sn. The tin-nickel alloy surface for the electromagnetic shielding fabric had excellent conductivity, softness, permeability and soft luster, non-sensitized to the human body. Thereby it has broad prospect in EMI field and shielding clothing.

Electrosynthesis Of 2,2-Dimethylolpropionic Acid, Hong-Yan Sun, Zhen-Hai Liang

Journal of Electrochemistry

The Ti/SnO₂+Sb₂O₄/PbO₂ electrode was prepared.The structure phase and valent state were characterized by means of XRD and XPS.The 2,2-dimethylolpropionic acid was synthesized on the Ti/SnO₂+Sb₂O₄/PbO₂ anode by direct electro-oxidation of 2,2-dimethylolpropionaldehyde.The product and crude material were analyzed by HPLC,the effects of the concentration of 2,2-dimethylolpropionaldehyde,pH,potential and reaction temperature were studied.The results showed that the optimum conditions were anode potential 1.8 V,pH=1,reaction temperature 15 ℃ and 2,2-dimethylolpropionaldehyde concentration 0.10mol/L.Under the optimum conditions,the selectivity of 36%,the current efficiency of 28% and the conversion of 58% were reached.The reported …

The Electrochemical Behavior And Determination Of Carbendazim On Iron Montmorillonite Modified Electrode, Xiao-Li Jiang, Rong Li, Xiao-Ying He, Jiang Li, Ying Li

Journal of Electrochemistry

The FeCl₃ modified clay electrode was made.The electrochemical behavior of carbendazim(BCM) on the modified electrode was studied by cyclic voltammetry.The impacts of pH,scan rate and dosages of modifier were discussed and the important kinetic parameters of the electrochemical process were determined.The results indicated that the process was controlled by diffusion.The effective area of FeMM-CMC/GCE(A)=0.027 cm²,the transfer electron numbers(n)=2 and the diffusion coefficient(D)=5.115×10^-6cm²/s.Under the optimized conditions,a good linearity was found between the first order derivative of peak current and concentration of BCM in the range of 2.00×10^-5～8.00×10^-4mol/L,with i′p=-8.045×10^-7-0.0237c,correlation …

Voltage Delay On Li/Socl2 And Bcx Cells During Discharge, Shu-Tao Liu, Yi-Ping Wu, Hong-Hua Ge, Guo-Ding Zhou

Journal of Electrochemistry

The impedance change of both lithium and carbon electrodes during the process of discharge was studied by AC impedance spectroscopy.It shows that the impedance of lithium electrode at initial stage was reduced by 80%～90% and kept nearly unchanged after wards;the carbon electrode impedance initially did not change much but quickly increased just before the end of discharge.The improvement of voltage delay might be related with the higher open-circuit voltage of BCX cell.It is suggested that the voltage delay problem may be solved by the application of supercapacitor.

Synthesis,Characteristics And Electrochemical Performance Of Nano-Sized Snco/Graphite Composites As Anode For Lithium Ion Batteries, Jin-Shu Cai, Ling Huang, Fu-Sheng Ke, Shi-Gang Sun

Journal of Electrochemistry

The nano-structural Sn-Co/graphite composites were prepared by chemical reduction of the alloy electroless deposition solution in graphite suspensions, and the composites were annealed at 500 ℃. The phase structure and surface morphology of the composites were measured by XRD, SEM and Raman. The results indicate that there were high dispersions and high loadings of Sn-Co nanoparticles on graphite by thermal treatment. Electrochemical lithium storage performance was studied preliminarily on the obtained samples. The graphite modified with the Sn-Co nanoparticles possessed a higher electrochemical reversible capacity than that of graphite during the charge and discharge process. The appetency between the Sn-Co …

High Utilization Aupt Nanoparticles Supported On Mwcnts For Methanol Electro-Oxidation In Alkaline Medium, Xun Guo, Dao-Jun Guo, Xin-Ping Qiu, Li-Quan Chen, Wen-Tao Zhu

Journal of Electrochemistry

We synthesized gold-platinum electrocatalysts supported on multi-walled carbon nanotubes(MWCNTs) with high utilization by a simple one-step method.A high Pt loading series of bimetallic AuPt/MWCNTs catalysts were prepared by the improved ethylene glycol reduction method,and then were compared in terms of the electrocatalytic activity for methanol electro-oxidation using cyclic voltammetry(CV) and chronoamperometry in alkaline solutions.The structure of AuPt/MWCNTs was characterized by the transmission electron microscopy(TEM),X-ray diffraction(XRD) and energy-dispersive X-ray spectroscopy(EDS).The results showed that the AuPt/MWCNTs catalysts had high Pt utilization,uniform AuPt nanoparticles size and good electrocatalytic activity for methanol electro-oxidation.The effect of Au/Pt mass ratio on electrocatalytic activity was also investigated.The …

Adaptive Control Of Woofer-Tweeter Adaptive Optics, Jimmie J. Perez

Theses and Dissertations

Adaptive optics applies advanced sensing and control to improve the ability of optical systems to collect images through a turbulent atmosphere. The results of this research effort demonstrate that the combination of two recent approaches improves the performance of adaptive optics in directed energy and laser communication scenarios. The first approach is adaptive control, which offers improved performance over fixed-gain controllers in the presence of rapidly changing turbulence. The second approach incorporated into the study is a dual-mirror system. The two mirrors are a high-bandwidth, low-actuator-stroke (tweeter) mirror and a low-bandwidth, large actuator-stroke (woofer) mirror. The woofer-tweeter combination allows for …

Automated Virtual Machine Introspection For Host-Based Intrusion Detection, Brett A. Pagel

Theses and Dissertations

This thesis examines techniques to automate configuration of an intrusion detection system utilizing hardware-assisted virtualization. These techniques are used to detect the version of a running guest operating system, automatically configure version-specific operating system information needed by the introspection library, and to locate and monitor important operating system data structures. This research simplifies introspection library configuration and is a step toward operating system independent introspection. An operating system detection algorithm and Windows virtual machine system service dispatch table monitor are implemented using the Xen hypervisor and a modified version of the XenAccess library. All detection and monitoring is implemented from …

Simulation Scoring Systems, Raynald Bedard

Publications

Simulation scoring systems including software, methods of use, and related methods that provide for simulating and scoring of aircraft flight and other missions, particularly where such simulating is purely electronic and particularly where such scoring is objective and particularly where such scoring has a plurality of gradations, as to distinguish a plurality of skill levels.

An Fpga-Based System For Tracking Digital Information Transmitted Via Peer-To-Peer Protocols, Karl R. Schrader

Theses and Dissertations

This thesis addresses the problem of identifying and tracking digital information that is shared using peer-to-peer file transfer and Voice over IP (VoIP) protocols. The goal of the research is to develop a system for detecting and tracking the illicit dissemination of sensitive government information using file sharing applications within a target network, and tracking terrorist cells or criminal organizations that are covertly communicating using VoIP applications. A digital forensic tool is developed using an FPGA-based embedded software application. The tool is designed to process file transfers using the BitTorrent peer-to-peer protocol and VoIP phone calls made using the Session …

Programmer Friendly Refactoring Tools, Emerson Murphy-Hill

Dissertations and Theses

Tools that perform semi-automated refactoring are currently under-utilized by programmers. If more programmers adopted refactoring tools, software projects could make enormous productivity gains. However, as more advanced refactoring tools are designed, a great chasm widens between how the tools must be used and how programmers want to use them. This dissertation begins to bridge this chasm by exposing usability guidelines to direct the design of the next generation of programmer-friendly refactoring tools, so that refactoring tools fit the way programmers behave, not vice-versa.

Is Parallel Programming Hard, And If So, Why?, Paul E. Mckenney, Maged M. Michael, Manish Gupta, Philip William Howard, Josh Triplett, Jonathan Walpole

Computer Science Faculty Publications and Presentations

Of the 200+ parallel-programming languages and environments created in the 1990s, almost all are now defunct. Given that parallel systems are now well within the budget of the typical hobbyist or graduate student, it is not unreasonable to expect a new cohort in excess of several thousand parallel languages and environments to appear in the 2010s. If this expected new cohort is to have more practical impact than did its 1990s counterpart, a robust and widely applicable framework will be required that encompasses exactly what, if anything, is hard about parallel programming. This paper revisits the fundamental precepts of concurrent …

Learning Image‐Text Associations, Tao Jiang, Ah-Hwee Tan

Research Collection School Of Computing and Information Systems

Web information fusion can be defined as the problem of collating and tracking information related to specific topics on the World Wide Web. Whereas most existing work on Web information fusion has focused on text-based multidocument summarization, this paper concerns the topic of image and text association, a cornerstone of cross-media Web information fusion. Specifically, we present two learning methods for discovering the underlying associations between images and texts based on small training data sets. The first method based on vague transformation measures the information similarity between the visual features and the textual features through a set of predefined domain-specific …

Tilted Parallel Dielectric Slab As A Multilevel Attenuator For Incident P- Or S-Polarized Light, R. M.A. Azzam

Electrical Engineering Faculty Publications

Under the condition of first-order blooming, a parallel dielectric slab, which is inserted in the path of an obliquely incident p- or s-polarized light beam, introduces multiple discrete attenuation levels given by 1/3, 4/27, 4/243,...... in reflection and 4/9, 4/81, 4/729,...... in transmission. These attenuation levels are independent of the slab refractive index, incident p or s linear polarization, or the presence of identical transparent surface coatings at the front and back sides of the slab. Therefore, the tilted slab provides multidecade reflectance and attenuation reference values that can be used in calibrating spectrophotometers and filters, and also …

Nanometrology Device Standards For Scanning Probe Mmicroscopes And Processes For Their Fabrication And Use, Peter Moeck

Physics Faculty Publications and Presentations

Nanometrology device standards and methods for fabricating and using such devices in conjunction With scanning probe microscopes are described. The fabrication methods comprise: (1) epitaxial growth that produces nanometer sized islands of knoWn morphology, structural, morphological and chemical stability in typical nanometrology environments, and large height-to-width nano-island aspect ratios, and (2) marking suitable crystallographic directions on the device for alignment With a scanning direction.

Power Scaling Of Large Mode Area Thulium Fiber Lasers In Various Spectral And Temporal Regimes, Timothy Mccomb

Electronic Theses and Dissertations

High power thulium fiber lasers are interesting for a myriad of applications due to their potential for high average output power, excellent beam quality, compactness, portability, high operating efficiency and broad, eye-safe spectral range from 1.8-2.1 microns. Currently, the majority of thulium laser research effort is being invested into scaling average output powers; however, such output powers are being scaled with no degree of control on laser system output spectrum or temporal behavior. Thulium fiber laser technology is not useful for many of its most important applications without implementation of techniques enabling tunable, narrow spectral widths with appropriate pulse durations …

Creating Lakes From Open Pit Mines: Processes And Considerations, Emphasis On Northern Environments, Christopher H. Gammons, Les N. Harris, James M. Castro, Peter A. Cott, Bruce W. Hanna

Geological Engineering

Creating Lakes from Open Pit Mines: Processes and Considerations, Emphasis on Northern Environments. This document summarizes the literature of mining pit lakes (through 2007), with a particular focus on issues that are likely to be of special relevance to the creation and management of pit lakes in northern climates. Pit lakes are simply waterbodies formed by filling the open pit left upon the completion of mining operations with water. Like natural lakes, mining pit lakes display a huge diversity in each of these subject areas. However, pit lakes are young and therefore are typically in a non-equilibrium state with respect …

Santa Clara Magazine, Volume 51 Number 3, Winter 2009, Santa Clara University

Santa Clara Magazine

18 - EVERYTHING IS ILLUMINATED By Christine Cole. For the first time since the invention of the printing press, artists have put quill pen to paper to hand-write-in calligraphy-the Bible in its entirety. The result is a wonder to behold. And available to readers and gazers at Santa Clara.

24 - HOLD THE LINE By David McKay Wilson. At Harlem's Frederick Douglass Academy, basketball coach Pat Mangan '84 has built a legendary program by making sure his players have their priorities straight. Family first. School second. Then hoops.

28 - LESSONS IN DIPLOMACY. By Sam Scott '96. How Bob LaMonte …

Ipas: International Paper Airplanes In Space, Getaway Special Team 2009

Reports and Proposals

No abstract provided.

Preserving Assets In At-Risk Municipalities: Financial Strategies For Climate Change Adaptation, New England Environmental Finance Center

Climate Change

A large share of America's population, businesses and economic activity now occurs in coastal areas. At the same time, during this century many coastal communities are likely to be severely impacted by sea level rise and increased storm surge and tidal flooding.

“What to do” about this vulnerability is the subject of this brief. It is intended to help municipalities identify courses of action and steps they might take toward increasing their resilience, especially regarding financial resources that will need to be allocated toward the various strategies identified.

Thermocapillary Effects In Driven Dewetting And Self-Assembly Of Pulsed Laser-Irradiated Metallic Films, Agegnehu Atena, Mikhail Khenner

Mathematics Faculty Publications

In this paper the lubrication-type dynamical model is developed of a molten, pulsed laser-irradiated metallic film. The heat transfer problem that incorporates the absorbed heat from a single beam or interfering beams is solved analytically. Using this temperature field, we derive the 3D long-wave evolution PDE for the film height. To get insights into dynamics of dewetting, we study the 2D version of the evolution equation by means of a linear stability analysis and by numerical simulations. The stabilizing and destabilizing effects of various system parameters, such as the peak laser beam intensity, the film optical thickness, the Biot and …

Demonstrating Sustainable Farm Management Systems. Final Report For Rcg05-Ord13, Tara Slaven, Francis Bright, Jodie Hawley, Joe Sherrard

Natural resources research reports

The Ord River Irrigation Area (ORIA) has a 'flow through' irrigation system. That is, irrigation water is diverted from Lake Kununurra and any waste water from the irrigation system and farms flows directly back into the river downstream. This means that any sediment, nutrient or chemicals in tailwater from farms flows straight into the river.

The Ord Land and Water Management Plan 2000 specifies goals to improve surface water quality. The goals are to reduce the load of chemical and nutrient contamination and sediment in tailwater by 40 per cent.

The aim of this project was to develop and demonstrate …

Thermocapillary Effects In Driven Dewetting And Self-Assembly Of Pulsed Laser-Irradiated Metallic Films, Agegnehu Atena, Mikhail Khenner

Mathematics Faculty Publications

In this paper the lubrication-type dynamical model is developed of a molten, pulsed laser-irradiated metallic film. The heat transfer problem that incorporates the absorbed heat from a single beam or interfering beams is solved analytically. Using this temperature field, we derive the 3D long-wave evolution PDE for the film height. To get insights into dynamics of dewetting, we study the 2D version of the evolution equation by means of a linear stability analysis and by numerical simulations. The stabilizing and destabilizing effects of various system parameters, such as the peak laser beam intensity, the film optical thickness, the Biot and …

Systems Chemistry And Parrondo’S Paradox: Computational Models Of Thermal Cycling, Daniel C. Osipovitch, Carl Barratt, Pauline M. Schwartz

Chemistry and Chemical Engineering Faculty Publications

A mathematical concept known as Parrondo’s paradox motivated the development of several novel computational models of chemical systems in which thermal cycling was explored. In these kinetics systems we compared the rates of formation of product under cycling temperature and steady-sate conditions. We found that a greater concentration of product was predicted under oscillating temperature conditions. Our computational models of thermal cycling suggest new applications in chemical and chemical engineering systems.

Funboe Factsheet, Getaway Special Team 2009

Reports and Proposals

No abstract provided.

Sides: Space Italian Dressing Experimental Setup, Getaway Special Team 2009

Reports and Proposals

No abstract provided.