Engineering Commons^™

Abiotic, Biotic, And Bio-Enhanced Reduction Of Hexavalent Chromium, Chloroform And Co-Contaminants Using Nano-Scale Zero Valent Iron In Highly Contaminated Groundwater, Eduardo Robleto Martinez

UNLV Theses, Dissertations, Professional Papers, and Capstones

Investigations of groundwater in a former industrial perchlorate manufacturing site have shown high contamination with perchlorate, chlorate, nitrate, hexavalent chromium (Cr (VI)), and chloroform (CF) with levels greater than 3,000, 30,000, 300, 100, and 4 mg/L, respectively. Remediation efforts using biological reduction to desired contaminant levels at this site has been challenging due to high contaminant concentrations, and high total dissolved solids (TDS). Furthermore, removal of Cr(VI) and CF in the presence of nitrate, chlorate, and perchlorate has not been examined at the contaminated site. Nano-scale Zero-Valent-Iron (NZVI) has been effective at reducing groundwater contamination both with and without bacterial …

An Evaluation Of Bank Storage At Lake Mead Reservoir In The Southwest United States, Jon Woodrow Wilson

UNLV Theses, Dissertations, Professional Papers, and Capstones

A water balance model is employed at Lake Mead to monitor and verify changing hydrology that affects total volume at the reservoir. Bank storage, which is defined as the volume of water captured in permeable lithologic layers subject to changes induced by contact and proximity to an open waterbody, is one component that is updated regularly and is based upon data and methods that were developed in the 1960’s from observations made within the first 30 years of the reservoir's maturation. Since this period, the reservoir has undergone further development and a current understanding of additional hydrologic affects to bank …

A Framework For Vector-Weighted Deep Neural Networks, Carter Chiu

UNLV Theses, Dissertations, Professional Papers, and Capstones

The vast majority of advances in deep neural network research operate on the basis of a real-valued weight space. Recent work in alternative spaces have challenged and complemented this idea; for instance, the use of complex- or binary-valued weights have yielded promising and fascinating results. We propose a framework for a novel weight space consisting of vector values which we christen VectorNet. We first develop the theoretical foundations of our proposed approach, including formalizing the requisite theory for forward and backpropagating values in a vector-weighted layer. We also introduce the concept of expansion and aggregation functions for conversion between real …

Chemical And Electronic Surface Structure Of Chalcopyrite-Based Thin Films For Solar Water Splitting, James C. Carter

UNLV Theses, Dissertations, Professional Papers, and Capstones

In recent years, various thin film solar devices have reached markedly high efficiencies on both the laboratory and large area scale. To further evaluate their potential, and help drive device optimization of efficient solar devices, a detailed understanding of the chemical and electronic structure of the surfaces and interfaces is required. It is these interfaces that play a pivotal role in dictating aspects of device performance. Chalcopyrite-based materials, such as Cu(In,Ga)S2 (CIGS) are regarded as one of the most promising absorber materials for use in highly efficient solar devices. In the context of photoelectrochemical (PEC) hydrogen generation, the tunability of …

Utility Of Bench Scale Sand Tank Experiments At Assessing Permeable Reactive Barrier Design, Brandon Meier

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this work was to evaluate the utility of bench scale sand tank experiments at assessing permeable reactive barrier (PRB) design. Our criteria for meeting this goal was that differences between PRB designs could be identified solely by measuring concentration in outflow from the sand tank models. For our PRB designs (funnel-and-gate, staggered wells, and parallel bars), numerical simulations clearly showed that PRB design had a quantifiable effect on outflow concentration, provided that the solute reacted with the PRB materials. Conversely, use of a conservative (non-reactive) solute did not allow us to discern between PRB design alternatives. Employing …

Pressure Driven Electronic Band Gap Engineering In Tin(Iv)-O,N Compounds, Daniel Thomas Sneed

UNLV Theses, Dissertations, Professional Papers, and Capstones

The intrinsic link between long-range order, coordination geometry, and the electronic properties of a system must be understood in order to tailor function-specific materials. Although material properties are typically tailored using chemical dopants, such methods can cause irreversible changes to the structure, limiting the range of functionality. The application of high pressure may provide an alternative “clean” method to tune the electronic properties of semiconducting materials by tailoring their defect density and structure.

We have explored a number of optoelectronic relevant materials with promising characteristics, specifically Sn-(O,N) compounds which have been predicted to undergo pressure-mediated opening of their optical band …

Carbon Management And Volatile Fatty Acid Production In Primary Clarifiers At A Wastewater Treatment Plant, Brittany Nicole Radke

UNLV Theses, Dissertations, Professional Papers, and Capstones

An increasing number of treatment plants are required to remove nutrients from domestic wastewater to lessen the impact of nutrient loading to water bodies. Enhanced Biological Phosphorus Removal (EBPR) is one of the processes commonly used to remove phosphorus from domestic wastewater. The presence of an adequate quantity of volatile fatty acids (VFA) in the wastewater influent to EBPR is important for process efficiency and stability. The objective of this research was to investigate the production of VFAs through fermentation of sludge in primary clarifiers as it related to improving nutrient removal, primarily targeting phosphorus.

The research tested, in full-scale, …

Application Of Data-Driven And Process-Based Modeling Approaches For Water Quality Simulation In Lakes And Freshwater Reservoirs, Ali Saber Sichani

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lakes and freshwater reservoirs often serve as the primary drinking and irrigation water sources for surrounding communities. They provide recreational and tourism opportunities, thereby promoting the prosperity of neighboring communities. Reliable estimates of water quality in lakes and reservoirs can improve management practices to protect water resources.

Seasonal water temperature and solar shortwave radiation variations, and their subsequent interactions with water column aquatic life, combined with seasonal variations of mixing intensity throughout the water column, result in variations of water quality constituents with depth during the annual cycle. The complexity of these variations entails the use of advanced water quality …

Classification Of Vegetation In Aerial Imagery Via Neural Network, Gevand Balayan

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis focuses on the task of trying to find a Neural Network that is best suited for identifying vegetation from aerial imagery. The goal is to find a way to quickly classify items in an image as highly likely to be vegetation(trees, grass, bushes and shrubs) and then interpolate that data and use it to mark sections of an image as vegetation. This has practical applications as well. The main motivation of this work came from the effort that our town takes in conserving water. By creating an AI that can easily recognize plants, we can better monitor the …

Numerical Analysis And Fluid Flow Modeling Of Incompressible Navier-Stokes Equations, Tahj Hill

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Navier-Stokes equations (NSE) are an essential set of partial differential equations for governing the motion of fluids. In this paper, we will study the NSE for an incompressible flow, one which density ρ = ρ0 is constant.

First, we will present the derivation of the NSE and discuss solutions and boundary conditions for the equations. We will then discuss the Reynolds number, a dimensionless number that is important in the observations of fluid flow patterns. We will study the NSE at various Reynolds numbers, and use the Reynolds number to write the NSE in a nondimensional form.

We will …

Analysis Of Bitcoin Cryptocurrency And Its Mining Techniques, Suman Ghimire

UNLV Theses, Dissertations, Professional Papers, and Capstones

Bitcoin is a peer-to-peer digital, decentralized cryptocurrency created by an individual under pseudonym Satoshi Nakamoto. In fact, it is the first digital, decentralized currency. Several developers and organizations have explored the importance of digital cryptocurrency and the concept of the blockchain. Bitcoin is assumed to be one of the secure and comfortable payment methods that can be used in the upcoming days. The backbone of Bitcoin mining is the concept of the blockchain, which is assumed to beone of the ingenious invention of this century. The blockchain is the collection of blocks that are linked together in such a way …

A Monolithic Arbitrary Lagrangian-Eulerian Finite Element Method For An Unsteady Stokes/Parabolic Interface Problem, Ian Kesler

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this thesis, a non-conservative arbitrary Lagrangian-Eulerian (ALE) method is developed

and analyzed for a type of linearized Fluid-Structure Interaction (FSI) problem in a

time dependent domain with a moving interface - an unsteady Stokes/parabolic interface

problem with jump coefficients. The corresponding mixed finite element approximation is

analyzed for both semi- and full discretization based upon the so-called non-conservative

ALE scheme. The stability and optimal convergence properties in the energy norm are

obtained for both schemes.

Equation Of State Of H2o Ice Using Melt-Recrystallization, Zachary Michael Grande

UNLV Theses, Dissertations, Professional Papers, and Capstones

The recent surge in exoplanet discoveries due to advancements in astrophysical technology and analysis has brought the reliability of early equation of state measurements into question as they are the limiting factor when modeling composition of these planets. H2O content is among the most important for the search of habitable planets as well as in understanding planetary dynamics and atmosphere formation. Over the last three decades the equation of state of H2O has been investigated with various techniques but, has suffered from anisotropic strain and poor powder statistics resulting in a large discrepancy in equation of state fits. At pressures …

Assessing Simulated Transmissivity In Numerical Flow Models Of Complex Hydrogeology, Afan Tarar

UNLV Theses, Dissertations, Professional Papers, and Capstones

Accurately extracting a meaningful transmissivity, a target value within one order of magnitude of field estimates, in numerical models poses a significant challenge when modeling complex groundwater systems. Aquifer transmissivity is directly proportional to the aquifer thickness and the estimated aquifer hydraulic conductivity. In complex geologic conditions (especially in fractured systems) with multiple heterogeneous and anisotropic hydrogeologic units, transmissivity can vary over several orders of magnitude.

To extract a meaningful value of transmissivity from a numerical model, a simple five-layer MODFLOW model was constructed. Each layer in the model was assigned a fixed hydraulic conductivity and thickness. The model simulates …

Utilization Of Remote Sensing Data For Estimation Of The Groundwater Storage Variation, Gaurang Mistry

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater is the most extracted raw material, with an average withdrawal rate of 982 km3 per year, where 70 percent of the total groundwater withdrawn is used for agriculture globally (Margat & van der Gun, 2013). With climate change and increased water demands in recent years, monitoring the changes in the groundwater storage is of the utmost importance. This thesis presents an analysis that determines the rates, trends, and directions where groundwater storage is going in Pakistan. It also correlates fluctuations in groundwater storage with variations in precipitation and agricultural productivity in the country. The overall objectives of this thesis …

Multi-Resolution Spatio-Temporal Change Analyses Of Hydro-Climatological Variables In Association With Large-Scale Oceanic-Atmospheric Climate Signals, Kazi Ali Tamaddun

UNLV Theses, Dissertations, Professional Papers, and Capstones

The primary objective of the work presented in this dissertation was to evaluate the change patterns, i.e., a gradual change known as the trend, and an abrupt change known as the shift, of multiple hydro-climatological variables, namely, streamflow, snow water equivalent (SWE), temperature, precipitation, and potential evapotranspiration (PET), in association with the large-scale oceanic-atmospheric climate signals. Moreover, both observed datasets and modeled simulations were used to evaluate such change patterns to assess the efficacy of the modeled datasets in emulating the observed trends and shifts under the influence of uncertainties and inconsistencies. A secondary objective of this study was to …

The Affective Perceptual Model: Enhancing Communication Quality For Persons With Pimd, Jadin Tredup

UNLV Theses, Dissertations, Professional Papers, and Capstones

Methods for prolonged compassionate care for persons with Profound Intellectual and Multiple Disabilities (PIMD) require a rotating cast of import people in the subjects life in order to facilitate interaction with the external environment. As subjects continue to age, dependency on these people increases with complexity of communications while the quality of communication decreases. It is theorized that a machine learning (ML) system could replicate the attuning process and replace these people to promote independence. This thesis extends this idea to develop a conceptual and formal model and system prototype.

The main contributions of this thesis are: (1) proposal of …

Optimization Of Useful Hard X-Ray Photochemistry, David Lewis Goldberger

UNLV Theses, Dissertations, Professional Papers, and Capstones

X-ray induced damage is generally considered a nuisance, but in the field of Useful Hard X-ray Photochemistry we harness the highly ionizing and penetrating properties of hard X-rays (> 7 keV) to initiate novel photochemical decomposition and synthesis at ambient and extreme conditions. Preliminary experiments suggest that the energy of irradiating photons and the sample pressure play roles in determining the nature of X-ray induced damage. Here, we present the X-ray energy dependence of damage induced in strontium oxalate, strontium nitrate, and barium nitrate, as well as the pressure dependence of X-ray induced damage of strontium oxalate. Our results indicate …

Design, Layout, And Testing Of Sige Apds Fabricated In A Bicmos Process, Dane Laurence Gentry

UNLV Theses, Dissertations, Professional Papers, and Capstones

This Thesis is concerned with the design, layout, and testing of avalanche photodiodes (APDs). APDs are a type of photodetector and, thus, convert light signals into electrical signals (current or voltage). APDs can be fabricated using silicon (Si). In this Thesis, however, three integrated circuit (IC) chips containing various silicon-germanium (SiGe) APDs with different sizes, structures, and geometries were designed, laid out, and fabricated using the Austriamicrosystems (AMS) 0.35μm SiGe BiCMOS (S35) process. This was done in order to compare SiGe APDs to Si only APDs and investigate the hypothesis that SiGe APDs are capable of detecting longer wavelengths than …

Design And Preliminary Evaluation Of A Supercritical Carbon Dioxide Brayton Cycle For Solar Dish Concentrator Clean Energy Production, Danielle Nobles-Lookingbill

UNLV Theses, Dissertations, Professional Papers, and Capstones

As we move toward energy independence and more ambitious clean energy goals, solar energy research must push the efficiency limits of traditional energy generation systems. Increases in efficiency can be achieved by increasing the hot temperature of the power cycle. Recent research demonstrates the potential for increased efficiency and a vastly smaller component size when supercritical carbon dioxide Brayton power cycles are used. Concentrated solar and nuclear heat sources are capable of achieving the high working fluid temperatures needed for significant efficiency gains. This NSF EPSCoR funded, experimental research system is designed to exploit the uniquely immense solar irradiance of …

Mitigating Accumulation Of Aeolian Dust Particles On Solar Power Generator Panels Without Water, Sanjana Das

UNLV Theses, Dissertations, Professional Papers, and Capstones

Accumulation of dust on solar panels poses a serious problem as it can significantly reduce light absorption and electrical energy output. Several factors affect the dust accumulation such as location, dust properties, wind velocity, system orientation, ambient temperature, humidity, and panel surface properties. Experimental and theoretical studies show that short circuit current and maximum power output of photovoltaic panels reduce approximately linearly with dust concentration. Incidentally, the locations with higher solar energy concentrations are also arid or semi-arid regions with higher dust concentrations. In order to avoid loss in power output, most PV installations perform periodic panel cleaning with water. …

Conformal Mapping Improvement Of The Boundary Element Method Solution For Underground Water Flow In A Domain With A Very Singular Boundary, Megan Romero

UNLV Theses, Dissertations, Professional Papers, and Capstones

Numerical solutions using a Boundary Element Method (BEM) for a confined flow in a very singular finite domain are developed. Typically, in scientific journal publications, authors avoid domains with many and more malignant singularities due to the extremely big and difficult to estimate errors in the numerical calculations. Using exact Conformal Mapping solutions for simplified domains with the same singularity as in the original domain, this problem can be solved numerically with improvements introduced by Conformal Mapping solutions. Firstly, to experiment with improving the BEM solution by Conformal Mapping, a domain inside a rectangle is considered. The exact solution inside …

Static And Dynamic Quantitative Microbial Risk Assessment Of Potable Reuse Paradigms, Erfaneh Amoueyan

UNLV Theses, Dissertations, Professional Papers, and Capstones

In recent years, potable reuse applications have become more common due to population growth and increased water demand, especially in communities with limited or variable water resources. However, there are concerns about potential exposure to pathogens and chemical compounds in treated wastewater. Therefore, advanced wastewater treatment processes are of paramount importance in any potable reuse system. The overall aim of this study was to develop and implement static and dynamic QMRAs to compare public health risk in various potable reuse scenarios. Cryptosporidium, norovirus, adenovirus, and Salmonella were chosen as the target pathogens. The research evaluated the performance of full advanced …

Bi-Directional Testing For Change Point Detection In Poisson Processes, Moinak Bhaduri

UNLV Theses, Dissertations, Professional Papers, and Capstones

Point processes often serve as a natural language to chronicle an event's temporal evolution, and significant changes in the flow, synonymous with non-stationarity, are usually triggered by assignable and frequently preventable causes, often heralding devastating ramifications. Examples include amplified restlessness of a volcano, increased frequencies of airplane crashes, hurricanes, mining mishaps, among others. Guessing these time points of changes, therefore, merits utmost care. Switching the way time traditionally propagates, we posit a new genre of bidirectional tests which, despite a frugal construct, prove to be exceedingly efficient in culling out non-stationarity under a wide spectrum of environments. A journey surveying …

Fundamental Tradeoffs In Estimation Of Finite-State Hidden Markov Models, Justin Le

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hidden Markov models (HMMs) constitute a broad and flexible class of statistical models that are widely used in studying processes that evolve over time and are only observable through the collection of noisy data. Two problems are essential to the use of HMMs: state estimation and parameter estimation. In state estimation, an algorithm estimates the sequence of states of the process that most likely generated a certain sequence of observations in the data. In parameter estimation, an algorithm computes the probability distributions that govern the time-evolution of states and the sampling of data. Although algorithms for the two problems are …

A Novel Approach To Analyzing Strain Heterogeneity In Polycrystalline Quartz Specimens Deformed At High Pressure And Temperature, Nolan Ambrose Regis

UNLV Theses, Dissertations, Professional Papers, and Capstones

Rheological studies of rocks and minerals allow researchers to study the grain-scale deformation mechanisms that govern large-scale geologic processes from mountain building to mantle mixing. Deforming rock samples with high pressure and temperature apparatuses similar to the Griggs piston cylinder apparatus allows us to simulate deformation at depth. However, many apparatuses are limited to “cook-and-look” analysis and require modeling techniques to determine the evolution of deformation patterns found in experimental samples. A previous study used two-dimensional finite element models to analyze the development of stress and strain patterns in polycrystalline rocks. The study suggested rhythmic patterns in deformed rocks develop …

Design On High Performance Nanoscale Cmos Circuits With Low Temperature Sensitivity, Ming Zhu

UNLV Theses, Dissertations, Professional Papers, and Capstones

With the rapid development of integrated circuit (IC) design and manufacturing technology, the transistor size now can be shrunk into only couple of nanometers whereas billions of transistors can be squeezed into a square millimeter, providing unprecedented computation power. However, accompanied with continuous device miniaturization and increased integration density is the explosive growth of on-chip power dissipation and a wide range of temperature fluctuation, which can heavily and negatively affect the delay performance of the circuit, or in the worst case, the circuit may malfunction and the system can be unreliable. Therefore, improved performance resilience against temperature variations has become …

Design & Delivery Of Automated Winston-Lutz Test For Isocentric & Off-Axis Delivery Stability Utilizing Truebeam Developer Mode & Electronic Portal Imaging Device, Mahmoud Mohammad Yaqoub

UNLV Theses, Dissertations, Professional Papers, and Capstones

The uncertainties in treatment delivery cannot be ignored in radiation therapy. Thus, the quality assurance QA tests are very important task of the medical physicist in clinical practice. Assuring the coincidence between the mechanical isocenter of the Linear Accelerator (LINAC) and its radiation beams isocenter is one of the most important qualities need to be tested, and the Winston Lust (WL) test is the

most popular technique to perform this task, especially for the treatment modalities which need high precision in beam delivery such as the stereotactic radiosurgery/stereotactic body radiotherapy (SRS/SBRT). The linear accelerator-based SRS/SBRT is a well-established method in …

Surface And Interface Characterization Of Solution-Processed Metal Oxides And Pedot:Pss Using Photoelectron Spectroscopy, Lynette M. Kogler

UNLV Theses, Dissertations, Professional Papers, and Capstones

Solution-processed materials are appealing for use in printable electronics as a means to lower production costs, but precise control of the process is crucial for achieving the desired properties in the final materials and their interfaces. Electronic interface properties depend on both the involved materials and their fabrication processes, impacting the development and commercialization of these materials. Analyzing the chemical and electronic structure of these materials, particularly at the surfaces and interfaces, is important not only for insuring that the materials have the desired properties, but also for understanding the effects of the fabrication process and how to modify properties …

Investigation Of Setting Time And Compressive Strength Of Ready-Mixed Concrete Blended With Returned Fresh Concrete, Negasi Niguse Gebremichael

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Center for Sustainable Transportation Infrastructure (CSTI), in its 2012 study, estimated that out of all the concrete leaving the plant, between 2% and 7% of concrete returns to the plant unused as a returned fresh concrete (RFC). Disposal of both the truck wash water and RFC is a growing concern for the industry. Most industry personnel contacted during the investigation, agree that reusing is superior to recycling of this substantial RFC economically and environmentally. This study will determine if the reuse of RFC in subsequent batches compromises the quality of newly blended concrete.

The effect of RFC on fresh …