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Full-Text Articles in Engineering

Statistical Continuum Theory For Inelastic Behavior Of A Two-Phase Medium, Brent L. Adams, H. Garmestani, S. Lin Dec 1997

Statistical Continuum Theory For Inelastic Behavior Of A Two-Phase Medium, Brent L. Adams, H. Garmestani, S. Lin

Faculty Publications

This work was supported in part (B.L. Adams) by the MRSEC Program of the National Science Foundation under Award no. DMR-9632556. Further support was provided by the Center for Materials Research and Technology (MARTECH at FSU) and Center for Nonlinear and Nonequilibrium Sciences (CENNAS at FAMU). A statistical contiuum mechanics formulation is presented to predict the inelastic behavior of a medium consisting of two isotropic phases. The phase distribution and morphology are represented by a two-point probability function. The isotropic behavior of the single phase medium is represented by a power law relationship between the strain rate and the resolved …


Robotic Tcf And Rigid-Body Calibration Methods, Edward Red, Xuguang Wang Nov 1997

Robotic Tcf And Rigid-Body Calibration Methods, Edward Red, Xuguang Wang

Faculty Publications

For off-line programming to work, systematic methods must be developed to account for non-ideal performance of the parts and devices in the manufacturing cell. Although much of the literature focuses on robot inaccuracy, this paper considers practical methods for the tool control frame (TCF) calibration and rigid-body compensation required to close the inverse kinematics loop for target driven tasks.


Nonlinear Optimal Control Of A Hydraulically Actuated Positioning System, Timothy Mclain, Randal W. Beard Nov 1997

Nonlinear Optimal Control Of A Hydraulically Actuated Positioning System, Timothy Mclain, Randal W. Beard

Faculty Publications

In this paper, the nonlinear optimal control problem is formulated for the position control of an electrohydraulic servo system. The optimal control is given by the solution to the Hamilton-Jacobi-Bellman equation, which in this case cannot be solved explicitly. An alternative method, based upon successive Galerkin approximation, is used to obtain an approximate optimal solution. Preliminary simulation results, demonstrating the application of this approach to the position control of a hydraulically actuated device, are presented.


Extracting The Relative Grain Boundary Free Energy And Mobility Functions From The Geometry Of Microstructures, Brent L. Adams, D. Kinderlehrer, W. W. Mullins, Anthony D. Rollett, Shlomo Ta'asan Nov 1997

Extracting The Relative Grain Boundary Free Energy And Mobility Functions From The Geometry Of Microstructures, Brent L. Adams, D. Kinderlehrer, W. W. Mullins, Anthony D. Rollett, Shlomo Ta'asan

Faculty Publications

This work was supported primarily by the MRSEC Program of the National Science Foundation under Award Number DMR-9632556. This paper describes a method for extracting, from measurements of a polycrystal, the relative excess free energy and the relative mobility of the grain boundaries as functions of the crystallographic type (five degrees of freedom) and relevant thermodynamic variables. The method requires the simultaneous measurement of both the geometry and the crystallography of a large number of grain boundary intersections; the crystallographic information may be obtained from orientation imaging microscopy (OIM). For simplicity, the intersections will be assumed to be triple junctions …


Electrode Performance Test On Single Ceramic Fuel Cells Using As Electrolyte Sr‐ And Mg‐Doped Lagao3, Kevin Huang, Man Feng, John B. Goodenough, Christopher Milliken Oct 1997

Electrode Performance Test On Single Ceramic Fuel Cells Using As Electrolyte Sr‐ And Mg‐Doped Lagao3, Kevin Huang, Man Feng, John B. Goodenough, Christopher Milliken

Faculty Publications

The electrode performance of a single solid oxide fuel cell was evaluated using a 500 μm thick La0.9Sr0.1Ga0.8Mg0.2O2.85 (LSGM) as the electrolyte membrane. Comparison of La0.6Sr0.4CoO3-δ (LSCo) and La0.9Sr0.1MnO3 (LSM) as cathodes showed LSCo gave an exchange current density two orders of magnitude higher than that of LSM. Comparison of CeO2/Ni and LSGM/Ni as anodes showed a degradation of the latter with time, and studies of the anode‐electrolyte interface and the reactivity of NiO and LSGM suggest better anode …


On-Line Cartesian Trajectory Control Of Mechanisms Along Complex Curves, Edward Red, Zhaoxue Yang May 1997

On-Line Cartesian Trajectory Control Of Mechanisms Along Complex Curves, Edward Red, Zhaoxue Yang

Faculty Publications

New methods have been developed to control a mechanism's realtime Cartesian motion along spatially complex curves such as Non-Uniform Rational B-splines (NURBS). The methods dynamically map the critical trajectory parameters between parameter space, Cartesian space, and joint space. Trajectory models that relate Cartesian tool speeds and accelerations to joint speeds and accelerations have been generalized so that they can be applied to most classes of robots and CNC mechanisms.


Chemical Stability Study Of Bace0.9Nd0.1O3−Α High Temperature Proton-Conducting Ceramic, Fanglin Chen, O. Toft Sorensen, Guangyao Meng, Dingkum Peng Jan 1997

Chemical Stability Study Of Bace0.9Nd0.1O3−Α High Temperature Proton-Conducting Ceramic, Fanglin Chen, O. Toft Sorensen, Guangyao Meng, Dingkum Peng

Faculty Publications

BaCe0.9Nd0.1O3−a (BCN) ceramic is known to be an excellent high-temperature proton conductor and is a candidate electrolyte for use in solid oxide fuel cells, hydrogen or steam sensors and steam electrolysers. In this work, the chemical stability of BCN was investigated systematically by combining XRD and DTA–TG techniques to study its processing compatibility and its feasibility in potential applications. It was found that above 1200 °C, BCN reacted with alumina or zirconia, leading to the loss of barium and an excess of cerium. In cold water, both sintered BCN disks and powder samples had very …


Preparation Of Nd-Doped Baceo3 Proton-Conducting Ceramics By Homogeneous Oxalate Coprecipitation, Fanglin Chen, Ping Wang, O. Toft Sorensen, Guangyao Meng, Dingkum Peng Jan 1997

Preparation Of Nd-Doped Baceo3 Proton-Conducting Ceramics By Homogeneous Oxalate Coprecipitation, Fanglin Chen, Ping Wang, O. Toft Sorensen, Guangyao Meng, Dingkum Peng

Faculty Publications

Nd-doped BaCeO3 have been obtained from homogeneous coprecipitated oxalates when calcined at temperatures T≥1000 °C. Ball-milling of the calcined powders well disperses the agglomerates and consequently has a beneficial effect in the densification process. The calcination temperature has a major influence on the sintering process and powders calcined at 1100 °C possess good sinterabilities. The pressure applied to press the green pellets has no apparent influence on the sintered density at sintering temperatures of T≥1400 °C. By controlling the processing variables it was possible to obtain near fully dense Nd-doped BaCeO3 ceramics with homogeneous microstructure at a sintering …


Molecular-Level Modeling Of The Viscoelasticity Of Crosslinked Polymers: Effect Of Time And Temperature, P. P. Simon, Harry J. Ploehn Jan 1997

Molecular-Level Modeling Of The Viscoelasticity Of Crosslinked Polymers: Effect Of Time And Temperature, P. P. Simon, Harry J. Ploehn

Faculty Publications

We present a new molecular-level picture of chain dynamics for describing the viscoelasticity of crosslinked polymers. The associated mathematical model consists of a time-dependent momentum balance on a representative polymer segment in the crosslinked network, plus phenomenological expressions for forces acting on the segments. These include a cohesive force that accounts for intermolecular attraction, an entropic force describing the thermodynamics governing chain conformations, and a frictional force that captures the temperature dependence of relative chain motion. We treat the case of oscillatory uniaxial deformation. Solution of the model equations in the frequency domain yields the dynamic moduli as functions of …


Extracting The Grain Boundary Character/Free Energy Relationship From The Microstructure: Pure <100> And <111> Tilt Boundaries, Brent L. Adams, S. Costiner, D. Kinderlehrer, W. W. Mullins, Shlomo Ta'asan Jan 1997

Extracting The Grain Boundary Character/Free Energy Relationship From The Microstructure: Pure <100> And <111> Tilt Boundaries, Brent L. Adams, S. Costiner, D. Kinderlehrer, W. W. Mullins, Shlomo Ta'asan

Faculty Publications

This work was supported primarily by the MRSEC Program of the National Science Foundation under Award Number DMR-9632556. Analysis is described to extract the excess free energy of grain boundaries from the mesotexture of well-equilibrated polycrystalline samples. The approach is based upon the force and torque balances at triple junctions described in the classical work of Herring. The main advantage of the approach is that the free energy function is obtained over the full fundamental zone of grain boundary types. For the purposes of exposition, the method is described for specified two-parameter hypersurfaces in the fundamental zone for cubic polycrystals …