Engineering Commons^™

Statistical Continuum Theory For Inelastic Behavior Of A Two-Phase Medium, Brent L. Adams, H. Garmestani, S. Lin

Faculty Publications

This work was supported in part (B.L. Adams) by the MRSEC Program of the National Science Foundation under Award no. DMR-9632556. Further support was provided by the Center for Materials Research and Technology (MARTECH at FSU) and Center for Nonlinear and Nonequilibrium Sciences (CENNAS at FAMU). A statistical contiuum mechanics formulation is presented to predict the inelastic behavior of a medium consisting of two isotropic phases. The phase distribution and morphology are represented by a two-point probability function. The isotropic behavior of the single phase medium is represented by a power law relationship between the strain rate and the resolved …

Robotic Tcf And Rigid-Body Calibration Methods, Edward Red, Xuguang Wang

Faculty Publications

For off-line programming to work, systematic methods must be developed to account for non-ideal performance of the parts and devices in the manufacturing cell. Although much of the literature focuses on robot inaccuracy, this paper considers practical methods for the tool control frame (TCF) calibration and rigid-body compensation required to close the inverse kinematics loop for target driven tasks.

Nonlinear Optimal Control Of A Hydraulically Actuated Positioning System, Timothy Mclain, Randal W. Beard

Faculty Publications

In this paper, the nonlinear optimal control problem is formulated for the position control of an electrohydraulic servo system. The optimal control is given by the solution to the Hamilton-Jacobi-Bellman equation, which in this case cannot be solved explicitly. An alternative method, based upon successive Galerkin approximation, is used to obtain an approximate optimal solution. Preliminary simulation results, demonstrating the application of this approach to the position control of a hydraulically actuated device, are presented.

Extracting The Relative Grain Boundary Free Energy And Mobility Functions From The Geometry Of Microstructures, Brent L. Adams, D. Kinderlehrer, W. W. Mullins, Anthony D. Rollett, Shlomo Ta'asan

Faculty Publications

This work was supported primarily by the MRSEC Program of the National Science Foundation under Award Number DMR-9632556. This paper describes a method for extracting, from measurements of a polycrystal, the relative excess free energy and the relative mobility of the grain boundaries as functions of the crystallographic type (five degrees of freedom) and relevant thermodynamic variables. The method requires the simultaneous measurement of both the geometry and the crystallography of a large number of grain boundary intersections; the crystallographic information may be obtained from orientation imaging microscopy (OIM). For simplicity, the intersections will be assumed to be triple junctions …

A Novel Laboratory Course On Advanced Chemical Engineering Experiments, Jochen A. Lauterbach, S. White, X. Lui, G. M. Bodner, W. N. Delgass

Faculty Publications

The chemical engineering curriculum in the United States has trained generations of technical experts who have successfully optimized chemical processes and products once they entered the chemical industry. The U.S. chemical industry, however, has entered a critical stage in which it must be able to create new and differentiated value through technical innovations that arc essential for long-term survival. This innovation process will require new skills that go far beyond the traditional expertise for the optimization of tasks possessed by young chemical engineers. The innovators must be able to identify new opportunities, explore the boundaries of technology, evaluate critical issues, …

Electrode Performance Test On Single Ceramic Fuel Cells Using As Electrolyte Sr‐ And Mg‐Doped Lagao3, Kevin Huang, Man Feng, John B. Goodenough, Christopher Milliken

Faculty Publications

The electrode performance of a single solid oxide fuel cell was evaluated using a 500 μm thick La_0.9Sr_0.1Ga_0.8Mg_0.2O_2.85 (LSGM) as the electrolyte membrane. Comparison of La_0.6Sr_0.4CoO_3-δ (LSCo) and La_0.9Sr_0.1MnO₃ (LSM) as cathodes showed LSCo gave an exchange current density two orders of magnitude higher than that of LSM. Comparison of CeO₂/Ni and LSGM/Ni as anodes showed a degradation of the latter with time, and studies of the anode‐electrolyte interface and the reactivity of NiO and LSGM suggest better anode …

Azimuthal Modulation Of C-Band Scatterometer Over Southern Ocean Sea Ice, David G. Long, David S. Early

Faculty Publications

In a continuing evaluation of the ERS-1 C-band scatterometer as a tool for studying polar sea ice, the authors evaluate the azimuthal modulation characteristics of Antarctic sea ice. ERS-1 AMI scatterometer mode data sets from several study regions dispersed in the Antarctic seasonal sea ice pack are evaluated for azimuthal modulation. When appropriate, the incidence angle dependence is estimated and removed in a study region before determining whether azimuthal modulation is present in the data. Other comparisons are made using the fore and aft beam measurement difference. The results show that over the ice pack, azimuthal modulation is less than …

Local Refinement Of Three-Dimensional Finite Element Meshes, M. L. Staten, Norman L. Jones

Faculty Publications

Mesh refinement is an important tool for editing finite element meshes in order to increase the accuracy of the solution. Refinement is performed in an iterative procedure in which a solution is found, error estimates are calculated, and elements in regions of high error are refined. This process is repeated until the desired accuracy is obtained.

Much research has been done on mesh refinement. Research has been focused on two-dimensional meshes and three-dimensional tetrahedral meshes ([1] Ning et al. (1993) Finite Elements in Analysis and Design, 13, 299–318; [2] Rivara, M. (1991) …

Singular And Plural Non-Deterministic Parameters, Sigurd Meldal, M. A. Walicki

Faculty Publications

The article defines algebraic semantics of singular (call-time-choice) and plural (run-time-choice) nondeterministic parameter passing and presents a specification language in which operations with both kinds of parameters can be defined simultaneously. Sound and complete calculi for both semantics are introduced. We study the relations between the two semantics and point out that axioms for operations with plural arguments may be considered as axiom schemata for operations with singular arguments.

A Unified Green's Function Analysis Of Complicated Dfb Lasers, Jim D. Freeze, Michael A. Jensen, Richard H. Selfridge

Faculty Publications

An efficient full-wave analysis technique for one-dimensional optical domains, known as the recursive Green's function method (RGFM), is presented for evaluation of distributed feedback (DFB) laser cavities with arbitrary material profiles. The method first constructs the Green's function of an inhomogeneous domain and subsequently uses Green's theorem to determine the laser optical field, lasing wavelength, and threshold gain. The technique is applied to investigate the performance of three DFB laser structures: a chirped-grating configuration, a modulated stripe width design, and a reduced duty cycle complex-coupled device. These structures are evaluated in terms of their single-mode lasing behavior and the uniformity …

Effect Of Temperature On Wetting Angle, Guna S. Selvaduray, R. Brindos

Faculty Publications

No abstract provided.

Predicting The Viscosity Of Alkanes Using Nonequilibrium Molecular Dynamics: Evaluation Of Intermolecular Potential Models, Richard L. Rowley, William Allen

Faculty Publications

Nonequilibrium molecular dynamics (NEMD) viscosity simulations of branched and linear alkanes at liquid densities were performed using both united-atom (UA) and all-atom (AA) intermolecular potential models in order to study the relative efficacy of the models in predicting fluid viscosity. Both models were used in conjunction with fixed bond lengths and bond angles, but different torsional potentials were investigated. The commonly used Ryckaert—Bellemans intermolecular potential model, which accurately predicts viscosities for short straight-chain alkanes, produced values for branched and long-chain alkanes that were significantly below experimental values. Likewise, a more complex UA model that uses transferrable site potentials and is …

An Ontology Tool For Distributed Information Environments, Kuhanandha Mahalingam, Michael N. Huhns

Faculty Publications

This paper describes how ontologies can be used for query formulation and semantic reconciliation in large distributed information environments. It presents a tool, written in Java, that can be used to create and browse ontologies, and construct ontology-based queries. The tool incorporates several abstraction mechanisms that enable users to manage large ontologies, which are typical of large information environments. The tool is being applied to an information system for healthcare administrators, which spans hospitals, clinics, and governmental health departments.

Secondary Dark Rings Of Internal Conical Refraction, Karl F. Warnick, David V. Arnold

Faculty Publications

This paper treats the phenomenon of internal conical refraction, in which a narrow beam propagating along an optical axis of a biaxial anisotropic medium spreads into a hollow cone. An expression is obtained for the intensity distribution produced by conical refraction that predicts additional fringes concentric to the well known Poggendorf dark ring for certain propagation distances and beam widths.

On-Line Cartesian Trajectory Control Of Mechanisms Along Complex Curves, Edward Red, Zhaoxue Yang

Faculty Publications

New methods have been developed to control a mechanism's realtime Cartesian motion along spatially complex curves such as Non-Uniform Rational B-splines (NURBS). The methods dynamically map the critical trajectory parameters between parameter space, Cartesian space, and joint space. Trajectory models that relate Cartesian tool speeds and accelerations to joint speeds and accelerations have been generalized so that they can be applied to most classes of robots and CNC mechanisms.

Teaching Electromagnetic Field Theory Using Differential Forms, Karl F. Warnick, Richard H. Selfridge, David V. Arnold

Faculty Publications

The calculus of differential forms has significant advantages over traditional methods as a tool for teaching electromagnetic (EM) field theory. First, films clarify the relationship between field intensity and flux density, by providing distinct mathematical and graphical representations for the two types of fields. Second, Ampere's and Faraday's laws obtain graphical representations that are as intuitive as the representation of Gauss's law. Third, the vector Stokes theorem and the divergence theorem become special cases of a single relationship that is easier for the student to remember, apply, and visualize than their vector formulations. Fourth, computational simplifications result from the use …

Analytical Models For Vehicle/Gap Distribution On Automated Highway Systems, Jacob Tsao, Randolph W. Hall, Indrajit Chatterjee

Faculty Publications

Highway congestion has in recent years become a pervasive problem for urban and suburban areas alike. The concept of Automated Highway Systems is based on the belief that integration of sensing, communication, and control technologies into vehicles and highways can lead to a large improvement in capacity and safety without requiring a significant amount of additional highway right-of-way. A fundamental determinant of Automated Highway Systems capacity is the vehicle-following rule, the rule that governs the behavior of vehicles traveling along a common lane (e.g., the spacing between any two longitudinally adjacent vehicles). Vehicle following affects the longitudinal capacity (achievable flow …

Concatenated Multilevel Coded Modulation Schemes For Digital Satellite Broadcasting, Robert H. Morelos-Zaragoza, Hideki Imai

Faculty Publications

The error performance of bandwith-efficient concatenated multilevel coded modulation (MCM) schemes for digital satellite broadcasting is analyzed. Nonstandard partitioning, multistage decoding, and outer Reed-Solomon (RS) codes are employed to provided unequal error protection capabilities.

Internet-Based Agents: Applications And Infrastructure, Munindar P. Singh, Michael N. Huhns

Faculty Publications

Software agents are mitigating the complexity of modern information systems—technically by providing a locus for managing information subsets, and psychologically by providing an abstraction for human interaction with them.

The Effects Of Organic Compounds On Inhibition Of Hydrogen Permeation Through A Mild Steel Membrane, H. A. Duarte, D. M. See, Branko N. Popov, Ralph E. White

Faculty Publications

The effectiveness of 5-(4-pyridyl)-2,7-nonadiene, and 1 phenyl-2-propyn-ol (PP) on inhibition of the hydrogen evolution reaction on a 1010 steel membrane and on the degree of hydrogen ingress into the membrane was determined. Hydrogen evolution rates and permeation currents were monitored as a function of time at different applied potentials. In the presence of 0.5 g/liter PP in the electrolyte, the hydrogen discharge and permeation current density were inhibited by 98 and 95%, respectively.

Molecular-Level Modeling Of The Viscoelasticity Of Crosslinked Polymers: Effect Of Time And Temperature, Philip P. Simon, Harry J. Ploehn

Faculty Publications

We present a new molecular-level picture of chain dynamics for describing the viscoelasticity of crosslinked polymers. The associated mathematical model consists of a time-dependent momentum balance on a representative polymer segment in the crosslinked network, plus phenomenological expressions for forces acting on the segments. These include a cohesive force that accounts for intermolecular attraction, an entropic force describing the thermodynamics governing chain conformations, and a frictional force that captures the temperature dependence of relative chain motion. We treat the case of oscillatory uniaxial deformation. Solution of the model equations in the frequency domain yields the dynamic moduli as functions of …

Mathematical Modeling Of Proton‐Exchange‐Membrane Fuel‐Cell Stacks, Dhanwa Thirumalai, Ralph E. White

Faculty Publications

No abstract provided.

The Effects Of Organic Compounds On Inhibition Of Hydrogen Permeation Through A Mild Steel Membrane, H. A. Duarte, D. M. See, Branko Popov, Ralph E. White

Faculty Publications

No abstract provided.

Tradeoffs In The Design Of A Spaceborne Scanning Pencil Beam Scatterometer: Application To Seawinds, David G. Long, Chialin T. Wu, Michael W. Spencer

Faculty Publications

SeaWinds is a spaceborne wind scatterometer to be flown on the second Japanese Advanced Earth Observing Satellite (ADEOS-II) in 1999. An important international element of NASA's Earth Observing System (EOS), SeaWinds is an advanced follow-on to the NASA scatterometer (NSCAT) on the first ADEOS platform. Unlike previous operational spaceborne scatterometer systems. SeaWinds employs a scanning "pencil-beam" antenna rather than a "fan-beam" antenna, making the instrument more compact and yielding greater ocean coverage. The goals of this paper are twofold. First, the overall SeaWinds functional design and backscatter measurement approach are described, and the relative advantages of the pencil-beam technique are …

Radar Backscatter Measurement Accuracy For A Spaceborne Pencil-Beam Wind Scatterometer With Transmit Modulation, David G. Long, Michael W. Spencer

Faculty Publications

Scatterometers are remote sensing radars designed to measure near-surface winds over the ocean. The difficulties of accommodating traditional fan-beam scatterometers on spacecraft has lead to the development of a scanning pencil-beam instrument known as SeaWinds. SeaWinds will be part of the Japanese Advanced Earth Observing Satellite II (ADEOS-II) to be launched in 1999. To analyze the performance of the SeaWinds design, a new expression for the measurement accuracy of a pencil-beam system is required. In this paper the authors derive a general expression for the backscatter measurement accuracy for a pencil-beam scatterometer which includes the effects of transmit signal modulation …

Extracting The Grain Boundary Character/Free Energy Relationship From The Microstructure: Pure <100> And <111> Tilt Boundaries, Brent L. Adams, S. Costiner, D. Kinderlehrer, W. W. Mullins, Shlomo Ta'asan

Faculty Publications

This work was supported primarily by the MRSEC Program of the National Science Foundation under Award Number DMR-9632556. Analysis is described to extract the excess free energy of grain boundaries from the mesotexture of well-equilibrated polycrystalline samples. The approach is based upon the force and torque balances at triple junctions described in the classical work of Herring. The main advantage of the approach is that the free energy function is obtained over the full fundamental zone of grain boundary types. For the purposes of exposition, the method is described for specified two-parameter hypersurfaces in the fundamental zone for cubic polycrystals …

Soot In Coal Combustion Systems, Thomas H. Fletcher, Jinliang Ma, Jim Rigby, Alexander L. Brown, Brent W. Webb

Faculty Publications

Soot is generated from coal when volatile matter, tar in particular, undergoes secondary reactions at high temperatures. A description of soot in coal flames allows better calculations of radiative transfer and temperatures in near-burner regions, which in turn allows more accurate predictions of NO_x formation in coal-fired furnaces. Experiments are reviewed that examine the formation, agglomeration and properties of coal-derived soot, including pyrolysis experiments and combustion experiments. This review includes the types of experiments performed, the soot yields obtained, the size of the soot particles and agglomerates, the optical properties of soot, the relationship between coal-derived soot and soot …

Release Of Inorganic Material During Coal Devolatilization, Larry L. Baxter, Reginald E. Mitchell, Thomas H. Fletcher

Faculty Publications

Experimental results presented in this paper indicate that coal devolatilization products convectively remove a fraction of the nonvolatile components of inorganic material atomically dispersed in the coal matrix. Results from three facilities burning six different coals illustrate this mechanism of ash transformation and release from coal particles. Titanium is chosen to illustrate this type of mass release from coal particles on the basis of its low volatility and mode of occurrence in the coal. During moderate rates of devolatilization (10⁴ K/s heating rate), no significant loss of titanium is noted. At more rapid rates of heating/devolatilization (10⁵ K/s) …

Chemical Stability Study Of Bace0.9Nd0.1O3−Α High Temperature Proton-Conducting Ceramic, Fanglin Chen, O. Toft Sorensen, Guangyao Meng, Dingkum Peng

Faculty Publications

BaCe_0.9Nd_0.1O_3−a (BCN) ceramic is known to be an excellent high-temperature proton conductor and is a candidate electrolyte for use in solid oxide fuel cells, hydrogen or steam sensors and steam electrolysers. In this work, the chemical stability of BCN was investigated systematically by combining XRD and DTA–TG techniques to study its processing compatibility and its feasibility in potential applications. It was found that above 1200 °C, BCN reacted with alumina or zirconia, leading to the loss of barium and an excess of cerium. In cold water, both sintered BCN disks and powder samples had very …

Preparation Of Nd-Doped Baceo3 Proton-Conducting Ceramics By Homogeneous Oxalate Coprecipitation, Fanglin Chen, Ping Wang, O. Toft Sorensen, Guangyao Meng, Dingkum Peng

Faculty Publications

Nd-doped BaCeO₃ have been obtained from homogeneous coprecipitated oxalates when calcined at temperatures T≥1000 °C. Ball-milling of the calcined powders well disperses the agglomerates and consequently has a beneficial effect in the densification process. The calcination temperature has a major influence on the sintering process and powders calcined at 1100 °C possess good sinterabilities. The pressure applied to press the green pellets has no apparent influence on the sintered density at sintering temperatures of T≥1400 °C. By controlling the processing variables it was possible to obtain near fully dense Nd-doped BaCeO₃ ceramics with homogeneous microstructure at a sintering …