Engineering Commons^™

Enhancing Stability And Efficiency Of Perovskite Solar Cells With Crosslinkable Silane-Functionalized And Doped Fullerene, Yang Bai, Qingfeng Dong, Yuchuan Shao, Yehao Deng, Qi Wang, Liang Shen, Dong Wang, Wei Wei, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

The instability of hybrid perovskite materials due to water and moisture arises as one major challenge to be addressed before any practical application of the demonstrated high efficiency perovskite solar cells. Here we report a facile strategy that can simultaneously enhance the stability and efficiency of p–i–n planar heterojunction-structure perovskite devices. Crosslinkable silane molecules with hydrophobic functional groups are bonded onto fullerene to make the fullerene layer highly water-resistant. Methylammonium iodide is introduced in the fullerene layer for n-doping via anion-induced electron transfer, resulting in dramatically increased conductivity over 100-fold. With crosslinkable silane-functionalized and doped fullerene electron transport layer, the …

Stabilized Wide Bandgap MapbbrXI3– X Perovskite By Enhanced Grain Size And Improved Crystallinity, Miao Hu, Cheng Bi, Yongbo Yuan, Yang Bai, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Methylammonium lead trihalide perovskite (MAPbX₃, where MA is methylammonium, and X is a halide)-based solar cells have been intensively investigated recently, with the demonstrated certified solar power conversion efficiency (PCE) exceeding 20%. To further boost the PCE to beyond the Schockley–Queisser limit, tandem structured solar cells have been investigated based on integrating MAPbX₃ and low bandgap solar cells. However, the efficiency of the two-terminal integrated perovskite-silicon tandem cells is still low. The best reported efficiency of 13.7% for this type of tandem cells is far smaller than the individual cells yet, partially due to the limited performance …

Ultrahigh Sensitivity Of Methylammonium Lead Tribromide Perovskite Single Crystals To Environmental Gases, Hong-Hua Fang, Sampson Adjokatse, Haotong Wei, Jie Yang, Graeme R. Blake, Jinsong Huang, Jacky Even, Maria Antonietta Loi

Department of Mechanical and Materials Engineering: Faculty Publications

One of the limiting factors to high device performance in photovoltaics is the presence of surface traps. Hence, the understanding and control of carrier recombination at the surface of organic-inorganic hybrid perovskite is critical for the design and optimization of devices with this material as the active layer. We demonstrate that the surface recombination rate (or surface trap state density) inmethylammonium lead tribromide (MAPbBr3) single crystals can be fully and reversibly controlled by the physisorption of oxygen and water molecules, leading to a modulation of the photoluminescence intensity by over two orders of magnitude.We report an unusually low surface recombination …

Temperature-Dependent Helium Ion-Beam Mixing In An Amorphous Sioc/Crystalline Fe Composite, Qing Su, Lloyd Price, Lin Shao, Michael Nastasi

Department of Mechanical and Materials Engineering: Faculty Publications

Temperature dependent He-irradiation-induced ion-beam mixing between amorphous silicon oxycarbide (SiOC) and crystalline Fe was examined with a transmission electron microscope (TEM) and via Rutherford backscattering spectrometry (RBS). The Fe marker layer (7.2 ± 0.8 nm) was placed in between two amorphous SiOC layers (200 nm). The amount of ion-beam mixing after 298, 473, 673, 873, and 1073 K irradiation was investigated. Both TEM and RBS results showed no ion-beam mixing between Fe and SiOC after 473 and 673 K irradiation and a very trivial amount of ion-beam mixing (~2 nm) after 298 K irradiation. At irradiation temperatures higher than 873 …

Pulsed Laser Cutting Of Magnesium-Calcium For Biodegradable Stents, M. P. Sealy, Y. B. Guo, J. F. Liu, C. Li

Department of Mechanical and Materials Engineering: Faculty Publications

There is growing interests in the use of biodegradable magnesium implants for cardiovascular and pulmonary applications such as stents. Magnesium is a metal that has the ability to gradually dissolve and absorb into the human body after implantation. There is very little work discussing the relationship between process parameters and cut quality of magnesium stents by laser cutting. The objective of this research is to determine the effect of laser cutting conditions including peak laser power and cutting speed of a millisecond range pulsed laser on kerf geometry, surface topography, surface roughness, and microstructure. An assessment on the experimental work …

Impact Of Patient Factors On Operative Duration During Laparoscopic Cholecystectomy: Evaluation From The National Surgical Quality Improvement Program Database, Bethany Rose Lowndes, Cornelius A. Thiels, Elizabeth B. Habermann, Juliane Bingener, M. Susan Hallbeck, Denny Yu

Department of Mechanical and Materials Engineering: Faculty Publications

BACKGROUND: Patient factors impact laparoscopic cholecystectomy (LC) difficulty, specifically operative duration. This study quantifies the impact of patient factors on LC duration.

METHODS: The national surgery database (American College of Surgeons National Surgical Quality Improvement Program) was reviewed for all elective LC for biliary colic from 2005 to 2013. Multivariate general linear model and logistic regression were used to evaluate patient factors as predictors of operative duration greater than 60 minutes, adjusted for resident involvement and cholangiography.

RESULTS: A total of 24,099 LC met inclusion criteria. Regression analysis found procedure duration greater than 60 minutes was less likely for patients …

A Comparative Study On Machining Capabilities Of Wet And Dry Nanoscale Electro-Machining, Muhammad P. Jahan, Kamlakar P. Rajurkar, Ajay P. Malshe

Department of Mechanical and Materials Engineering: Faculty Publications

Presently, the nano scale electro-machining (nano-EM) process has been demonstrated in both the liquid and air dielectric mediums, which are known as wet and dry nano-EM respectively. In the current study, two important aspects of the nano-EM have been investigated: the minimum possible feature dimension and mass fabrication capability of nano-EM. Firstly, the investigation has been done on the capability of machining graphene at atomic scale with focus on obtaining smallest possible nano-feature using the wet nano-EM. Secondly, the ability of the nano-EM process for the fabrication of arrays of nano-holes has been investigated using dry nano-EM. It was found …

Integration Of Flow Studies For Robust Selection Of Mechanoresponsive Genes, Nataly Maimari, Ryan M. Pedrigi, Alessandra Russo, Krysia Broda, Rob Krams

Department of Mechanical and Materials Engineering: Faculty Publications

Blood flow is an essential contributor to plaque growth, composition and initiation. It is sensed by endothelial cells, which react to blood flow by expressing >1000 genes. The sheer number of genes implies that one needs genomic techniques to unravel their response in disease. Individual genomic studies have been performed but lack sufficient power to identify subtle changes in gene expression. In this study, we investigated whether a systematic meta-analysis of available microarray studies can improve their consistency.

We identified 17 studies using microarrays, of which 6 were performed in vivo and 11 in vitro. The in vivo studies were …

Floating-Gate Transistor Photodetector With Light Absorbing Layer, Jinsong Huang, Yongbo Yuan

Department of Mechanical and Materials Engineering: Faculty Publications

A field effect transistor photodetector that can operate in room temperature includes a source electrode, a drain electrode, a channel to allow an electric current to flow between the drain and source electrodes, and a gate electrode to receive a bias voltage for controlling the current in the channel. The photodetector includes a light-absorbing material that absorbs light and traps electric charges. The light-absorbing material is configured to generate one or more charges upon absorbing light having a wavelength within a specified range and to hold the one or more charges. The one or more charges held in the light-absorbing …