Engineering Commons^™

General-Purpose Coarse-Grained Toughened Thermoset Model For 44dds/Dgeba/Pes, Michael M. Henry, Stephen Thomas, Mone’T Alberts, Carla E. Estridge, Brittan Farmer, Olivia Mcnair, Eric Jankowski

Materials Science and Engineering Faculty Publications and Presentations

The objective of this work is to predict the morphology and material properties of crosslinking polymers used in aerospace applications. We extend the open-source dybond plugin for HOOMD-Blue to implement a new coarse-grained model of reacting epoxy thermosets and use the 44DDS/DGEBA/PES system as a case study for calibration and validation. We parameterize the coarse-grained model from atomistic solubility data, calibrate reaction dynamics against experiments, and check for size-dependent artifacts. We validate model predictions by comparing glass transition temperatures measurements at arbitrary degree of cure, gel-points, and morphology predictions against experiments. We demonstrate for the first time in molecular simulations …

Anisotropic Cuinse2 Nanocrystals: Synthesis, Optical Properties And Their Effect On Photoelectric Response Of Dye-Sensitized Solar Cell, Ahmed Mysara, M Mohsen Abdelaziz, A N. Emam, A S. Mansour, A A. F. Zikry, M .B Mohamed, Y H. Elbashar

Nanotechnology Research Centre

CuInSe₂ I-III-VI₂ ternary is a semiconductor considered very good efficient solar energy conversion material. An organometallic pyrolysis method is used to prepare monodisperse CuInSe₂ nanoparticles using a mixture of oleylamine, and trioctylphosphine, as capping materials. The particle shape changes to dot, rods or flowers occur via varying the reaction temperatures (160, 200, 220±C) respectively. The obtained particles have been characterized to determine the shape and size of CuInSe₂ nanoparticles using HR-TEM and XRD. The optical and electronic properties of these particles have been investigated and discussed in detail. Then the different shapes of CuInSe …

Basis Set Truncation Further Clarifies Vibrational Coherence Spectra, Daniel B. Turner, Paul C. Arpin

Materials Science and Engineering Faculty Publications and Presentations

Coherent vibrational oscillations in femtosecond transient-absorption spectra have been interpreted since the 1990s using a model based on Gaussian wavepacket dynamics. The oscillations are often studied using probe-wavelength dependent plots of the oscillation amplitude and phase that are known as vibrational coherence spectra. Here we show that restricting the basis of the wavepacket to a small number of eigenstates clarifies several features in vibrational coherence spectra. Improving the understanding of vibrational coherence signatures will help distinguish them from signatures of electronic coherence that arise from measurements of strongly coupled excitonic states in molecular aggregates and light-harvesting proteins.

High-Performance Flexible Bismuth Telluride Thin Film From Solution Processed Colloidal Nanoplates, Madhusudan Kongara, Tony Varghese, Karthik Chinnathambi, Jesse Schimpf, Josh Eixenberger, Paul H. Davis, Yaqiao Wu, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Thermoelectric generators are an environmentally friendly and reliable solid‐state energy conversion technology. Flexible and low‐cost thermoelectric generators are especially suited to power flexible electronics and sensors using body heat or other ambient heat sources. Bismuth telluride (Bi₂Te₃) based thermoelectric materials exhibit their best performance near room temperature making them an ideal candidate to power wearable electronics and sensors using body heat. In this report, Bi₂Te₃ thin films are deposited on a flexible polyimide substrate using low‐cost and scalable manufacturing methods. The synthesized Bi₂Te₃ nanocrystals have a thickness of 35 ± …

Macroeconomic Aspects Of Maintenance Optimization Of Critical Infrastructures, S. A. Timashev, A. V. Bushinskaya

Engineering Management & Systems Engineering Faculty Publications

The main goal of maintenance is prevention, timely detection and elimination of failures and damage. From the point of view of critical infrastructures (CIs), the main purpose of their maintenance is to increase the safety of CIs and / or to ensure life safety. CIs should be optimal in terms of their purpose, cost, as a source of income and profit at all stages of their life cycle, and also acceptable in terms of possible loss of human lives or injuries. The paper considers the assessment of necessary optimal investments in the maintenance (time interval between subsequent maintenance), to increase …

Temporally Multiplexed Ladar Polarimeter, Christian Keyser, Richard Kenneth Martin

AFIT Patents

In a polarimeter, a polarization modulator changes a polarization phase of an output optical pulse with a modulation function that varies in time over the duration of the optical pulse. A static polarization state analyzer, which includes a one or more static polarization component analyzers and detectors, receives the modulated optical pulse after interaction with a target medium and provides time varying intensities of the polarization components of the received pulse. A signal processing module determines a polarization property of the target medium, such as a Mueller matrix, dependent upon time varied intensities over the duration of the received optical …

Fully Inkjet-Printed Multilayered Graphene-Based Flexible Electrodes For Repeatable Electrochemical Response, Twinkle Pandhi, Kiyo Fujimoto, Pete Barnes, Jasmine Cox, Hui Xiong, Paul H. Davis, Harish Subbaraman, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Graphene has proven to be useful in biosensing applications. However, one of the main hurdles with printed graphene-based electrodes is achieving repeatable electrochemical performance from one printed electrode to another. We have developed a consistent fabrication process to control the sheet resistance of inkjet-printed graphene electrodes, thereby accomplishing repeatable electrochemical performance. Herein, we investigated the electrochemical properties of multilayered graphene (MLG) electrodes fully inkjet-printed (IJP) on flexible Kapton substrates. The electrodes were fabricated by inkjet printing three materials – (1) a conductive silver ink for electrical contact, (2) an insulating dielectric ink, and (3) MLG ink as the sensing material. …

Far Infrared Radiation Property Of Elbaite/Alumina Composite Materials, Qi Lu, Bowen Li, Huan Zhang

Michigan Tech Publications

Far infrared materials have been prepared by precipitation method using natural elbaite powder as raw materials, which belongs to tourmaline group. The chemical formula of elbaite is Na(Al, Li)3Al6B3Si6O27(O, OH, F)4. X-ray powder diffraction (XRD) shows that elbaite and alumina in composite material has good crystal form. In addition, XRD results indicate the formation of alumina crystallites show that alumina powder exists as nano-meter particles on the surface of elbaite powder. It can be calculated the particles diameter of Al2O3 is 47.86nm. The maximum infrared radiation rate of tourmaline/alumina composite materials is 0.89 when the ratio of alumina in elbaite …

Comparative Study Of Silk-Based Magnetic Materials: Effect Of Magnetic Particle Types On The Protein Structure And Biomaterial Properties., Ye Xue, Samuel Lofland, Xiao Hu

Faculty Scholarship for the College of Science & Mathematics

This study investigates combining the good biocompatibility and flexibility of silk protein with three types of widely used magnetic nanoparticles to comparatively explore their structures, properties and potential applications in the sustainability and biomaterial fields. The secondary structure of silk protein was quantitatively studied by infrared spectroscopy. It was found that magnetite (Fe3O4) and barium hexaferrite (BaFe12O19) can prohibit β-sheet crystal due to strong coordination bonding between Fe3+ ions and carboxylate ions on silk fibroin chains where cobalt particles showed minimal effect. This was confirmed by thermal analysis, where a high temperature degradation peak was found above 640 °C in …

Mechanochemical Conversion Kinetics Of Red To Black Phosphorus And Scaling Parameters For High Volume Synthesis, Samuel V. Pedersen, Florent Muramutsa, Joshua D. Wood, Chad Husko, David Estrada, Brian J. Jaques

Materials Science and Engineering Faculty Publications and Presentations

Adopting black phosphorus (BP) as a material in electronic and optoelectronic device manufacturing requires the development and understanding of a large-scale synthesis technique. To that end, high-energy planetary ball milling is demonstrated as a scalable synthesis route, and the mechanisms and conversion kinetics of the BP phase transformation are investigated. During the milling process, media collisions rapidly compress amorphous red phosphorus (RP) into crystalline, orthorhombic BP flakes, resulting in a conversion yield of ≈90% for ≈5 g of bulk BP powder. Milling conversion kinetics, monitored via ex situ x-ray diffraction, manifest a sigmoidal behavior best described by the Avrami rate …

Framing Energy And Minerals For Future Pathways, Michelle Michot Foss, Michael S. Moats, Kwame Awuah-Offei

Materials Science and Engineering Faculty Research & Creative Works

We present a challenge for Group of Twenty (G20) discussions that entails (1) greater awareness of the role of non-fuel minerals in the global economy overall, but specifically in the energy sector; and (2) the introduction and acceleration of alternative energy sources and technologies. We focus on chemical battery energy storage, given its prominence in all views and outlooks of energy futures, especially for mobility. We present recommendations for G20 discussions and actions on battery materials, and the crucial underlying supply chains for mineral commodities.

Resource-Saving Technologies For The Production Of Elastic Leather Materials: Collective Monograph, Olena Korotych, Anatolii Danylkovych, Serhii Bilinskyi, Serhii Bondarenko, Slava Branovitska, Vasyl Chervinskyi, Nataliia Khliebnikova, Alona Kudzieva, Viktor Lishchuk, Nataliia Lysenko, Olena Mokrousova, Nataliia Omelchenko, Vera Palamar, Yuliia Potakh, Oksana Romanyuk, Olga Sanginova, Oleksandr Zhyhotsky

Chemistry Publications and Other Works

This monograph contains a collection of recent research papers focusing on advancing existing technologies and developing new technologies to improve the environmentally friendliness and save resources during the production of elastic leather materials. The papers are organized based on the type of technological process used to preserve raw hides. A lot of attention is devoted to mathematical planning, simulations, and multicriteria optimization of the technological processes using newly developed chemical reagents. The monograph contains a complex study of physicochemical properties and characteristics of the resulting leather materials. The developed technologies were tested by the private joint-stock company Chinbar (Kyiv, Ukraine) …

On The Recovery And Fatigue Life Extension Of Stainless Steel 316 Metals By Means Of Recovery Heat Treatment, Ali Haghshenas, M. M. Khonsari

Faculty Publications

In this paper, we propose a methodology for enhancing the fatigue life of SS316 by performing intermittent recovery heat-treatment (RHT) in the Argon environment at different temperatures. To this end, fully-reversed fatigue bending tests are conducted on the heat-treated SS316 specimens. Damping values are obtained using the impact excitation technique to assess the damage remaining in the material after each RHT and the corresponding fatigue life. Damping is also used to distinguish the three stages of the fatigue phenomenon and the onset of crack initiation. The results show that by performing intermittent RHTs, the density of dislocation is decreased substantially …

Microstructural Influence On Mechanical Properties Of A Lightweight Ultrahigh Strength Fe-18mn-10al-0.9c-5ni (Wt%) Steel, Michael Piston, Laura Bartlett, Krista R. Limmer, Daniel M. Field

Materials Science and Engineering Faculty Research & Creative Works

This study evaluates the role of thermomechanical processing and heat treatment on the microstructure and mechanical properties of a hot rolled, annealed, and aged Fe-18Mn-10Al-0.9C-5Ni (wt%) steel. The steel exhibited rapid age hardening kinetics when aged in the temperature range of 500-600 ⁰C for up to 50 h, which has been shown in other work to be the result of B2 ordering in the ferrite and K-carbide precipitation within the austenite matrix. The ultimate tensile strength increased from 1120 MPa in the annealed condition to 1230 MPa after 2 h of aging at 570 ⁰C. Charpy V-notch toughness was evaluated …

Manual For Thin Asphalt Overlays, Lerose Lane, R. Gary Hicks, Dingxin Cheng, Erik Updyke

Mineta Transportation Institute

This manual presents best practices on project selection, mix design, and construction to ensure a superior product when constructing thin asphalt overlays. Experience shows these treatments provide excellent performance when placed on pavements in fair to good condition using proper construction techniques. Though sometime referred to by other names, thin asphalt overlays have been widely used for pavement preservation throughout the world for over 50 years.

Limited infrastructure funding at the local, state, and federal levels has resulted in greater emphasis on the use of pavement preservation techniques to extend pavement life and reduce maintenance costs. Thin asphalt overlays are …

A Review Of Inkjet Printed Graphene And Carbon Nanotubes Based Gas Sensors, Twinkle Pandhi, Ashita Chandnani, Harish Subbaraman, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Graphene and carbon nanotube (CNT)-based gas/vapor sensors have gained much traction for numerous applications over the last decade due to their excellent sensing performance at ambient conditions. Inkjet printing various forms of graphene (reduced graphene oxide or modified graphene) and CNT (single-wall nanotubes (SWNTs) or multiwall nanotubes (MWNTs)) nanomaterials allows fabrication onto flexible substrates which enable gas sensing applications in flexible electronics. This review focuses on their recent developments and provides an overview of the state-of-the-art in inkjet printing of graphene and CNT based sensors targeting gases, such as NO₂, Cl₂, CO₂, NH_{3 …}

Impact Of Arsenic Species On Self-Assembly Of Triangular And Hexagonal Tensile-Strained Gaas(111)A Quantum Dots, Christopher F. Schuck, Kevin D. Vallejo, Trent Garrett, Qing Yuan, Ying Wang, Baolai Liang, Paul J. Simmonds

Materials Science and Engineering Faculty Publications and Presentations

We use dimeric arsenic (As₂) or tetrameric arsenic (As₄) during molecular beam epitaxy to manipulate the structural and optical properties of GaAs(111)A tensile-strained quantum dots (TSQDs). Choice of arsenic species affects nucleation and growth behavior during TSQD self-assembly. Previously, epitaxial GaAs(111)A TSQDs have been grown with As₄, producing TSQDs with a triangular base, and 'A-step' edges perpendicular to the three 1̅1̅2 directions. We demonstrate that using As₂ at low substrate temperature also results in triangular GaAs(111)A TSQDs, but with 'B-step' edges perpendicular to the three 112̅ directions. We can therefore invert the crystallographic …

Partially Reprapable Automated Open Source Bag Valve Mask-Based Ventilator, Aliaksei Petsiuk, Nagendra G. Tanikella, Samantha Dertinger, Adam Pringle, Shane Oberloier, Joshua M. Pearce

Michigan Tech Publications

This study describes the development of a simple and easy-to-build portable automated bag valve mask (BVM) compression system, which, during acute shortages and supply chain disruptions can serve as a temporary emergency ventilator. The resuscitation system is based on the Arduino controller with a real-time operating system installed on a largely RepRap 3-D printable parametric component-based structure. The cost of the materials for the system is under $170, which makes it affordable for replication by makers around the world. The device provides a controlled breathing mode with tidal volumes from 100 to 800 mL, breathing rates from 5 to 40 …

Open Source High-Temperature Reprap For 3-D Printing Heat-Sterilizable Ppe And Other Applications, Noah G. Skrzypczak, Nagendra G. Tanikella, Joshua M. Pearce

Michigan Tech Publications

Thermal sterilization is generally avoided for 3-D printed components because of the relatively low deformation temperatures for common thermoplastics used for material extrusion-based additive manufacturing. 3-D printing materials required for high-temperature heat sterilizable components for COVID-19 and other applications demands 3-D printers with heated beds, hot ends that can reach higher temperatures than polytetrafluoroethylene (PTFE) hot ends and heated chambers to avoid part warping and delamination. There are several high temperature printers on the market, but their high costs make them inaccessible for full home-based distributed manufacturing required during pandemic lockdowns. To allow for all these requirements to be met …

Economic Savings For Scientific Free And Open Source Technology: A Review, Joshua M. Pearce

Michigan Tech Publications

Both the free and open source software (FOSS) as well as the distributed digital manufacturing of free and open source hardware (FOSH) has shown particular promise among scientists for developing custom scientific tools. Early research found substantial economic savings for these technologies, but as the open source design paradigm has grown by orders of magnitude it is possible that the savings observed in the early work was isolated to special cases. Today there are examples of open source technology for science in the vast majority of disciplines and several resources dedicated specifically to publishing them. Do the tremendous economic savings …

Parametric Nasopharyngeal Swab For Sampling Covid-19 And Other Respiratory Viruses: Open Source Design, Sla 3-D Printing And Uv Curing System, Nicole Gallup, Adam M. Pringle, Shane Oberloier, Nagendra G. Tanikella, Joshua M. Pearce

Michigan Tech Publications

Access to nasopharyngeal swabs for sampling remain a bottleneck in some regions for COVID-19 testing. This study develops a distributed manufacturing solution using only an open source manufacturing tool chain consisting of two types of open source 3-D printing and batch UV curing, and provides a parametric fully free design of a nasopharyngeal swab. The swab was designed using parametric OpenSCAD in two components (a head with engineered break point and various handles), which has several advantages: i) minimizing print time on relatively slow SLA printers, ii) enabling the use of smaller print volume open source SLA printers, iii) reducing …

Open Source Arc Analyzer: Multi-Sensor Monitoring Of Wire Arc Additive Manufacturing, Adam M. Pringle, Shane Oberloier, Aliaksei Petsiuk, Paul G. Sanders, Joshua M. Pearce

Michigan Tech Publications

Low-cost high-resolution metal 3-D printing remains elusive for the scientific community. Low-cost gas metal arc wire (GMAW)-based 3-D printing enables wire arc additive manufacturing (WAAM) for near net shape applications, but has limited resolution due to the complexities of the arcing process. To begin to monitor and thus control these complexities, the initial designs of the open source GMAW 3-D printer have evolved to include current and voltage monitoring. Building on this prior work, in this study, the design, fabrication and use of the open source arc analyzer is described. The arc analyzer is a multi-sensor monitoring system for quantifying …

Mechanical Properties Of Direct Waste Printing Of Polylactic Acid With Universal Pellets Extruder: Comparison To Fused Filament Fabrication On Open-Source Desktop Three-Dimensional Printers, Arthur Alexandre, Fabio A. Cruz Sanchez, Hakim Boudaoud, Mauricio Camargo, Joshua M. Pearce

Michigan Tech Publications

Fused filament fabrication (FFF) is the most common and widespread additive manufacturing (AM) technique, but it requires the formation of filament. Fused granular fabrication (FGF), where plastic granules are directly three-dimensional (3D) printed, has become a promising technique for the AM technology. FGF could be a key driver to promote further greening of distributed recycling thanks to the reduced melt solidification steps and elimination of the filament extruder system. However, only large-scale FGF systems have been tested for technical and economic viability of recycling plastic materials. The objective of this work is to evaluate the performance of the FFF and …

Additively Manufactured Parametric Universal Clip-System: An Open Source Approach For Aiding Personal Exposure Easurement In The Breathing Zone, Kirsi Kukko, Jan Sher Akmal, Anneli Kangas, Mika Salmi, Roy Björkstrand, Anna-Kaisa Viitanen, Jouni Partanen, Joshua M. Pearce

Michigan Tech Publications

Design for additive manufacturing is adopted to help solve problems inherent to attaching active personal sampler systems to workers for monitoring their breathing zone. A novel and parametric 3D printable clip system was designed with an open source Computer-aided design (CAD) system and was additively manufactured. The concept was first tested with a simple clip design, and when it was found to be functional, the ability of the innovative and open source design to be extended to other applications was demonstrated by designing another tooling system. The clip system was tested for mechanical stress test to establish a minimum lifetime …

Assessment Of Material State For Predicting The Durability Of Composites, Vamsee Vadlamudi, Muthu Ram Prabhu Elenchezhian, Partha Pratim Das, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)

The long term behavior of composites have been extensively studied for the last four decades. Given the heterogeneity of these materials, the damage accumulation mechanisms lead to superior fatigue performance of composites compared to metals. However, due to the ‘sudden death’ behavior controlled by defect coupling, the precursor to fracture plane development of these materials, the challenge remains on how to assess the real-time material state and predict when it becomes critical? In the recent past, broadband dielectric spectroscopy (BbDS) has been used successfully to assess the material state and predict the material state change (triggered by defect coupling) for …

Environmental Investigation Of Bio-Modification Of Steel Slag Through Microbially Induced Carbonate Precipitation, Junke Zhang, Peidong Su, Yadong Li, Lin Li

Civil and Architectural Engineering Faculty Research

Steel slag (SS) is one of byproduct of steel manufacture industry. The environmental concerns of SS may limit their re-use in different applications. The goal of this study was to investigate the leaching behavior of metals from SS before and after treated by microbially induced carbonate precipitation (MICP). Toxicity characteristic leaching procedure, synthetic precipitation leaching procedure and water leaching tests were performed to evaluate the leaching behavior of major elements (Fe, Mg and Ca) and trace elements (Ba, Cu and Mn) in three scenarios. The concentrations of leaching metals increased with the content of SS. After it reached the peak …

Decentralized Renewable Hybrid Mini-Grids For Rural Communities: Culmination Of The Irep Framework And Scale Up To Urban Communities, Blessing Ugwoke, Adedoyin Adeleke, Stefano P. Corgnati, Joshua M. Pearce, Pierluigi Leone

Michigan Tech Publications

The Integrated Rural Energy Planning (IREP) framework offers a unified road map for locating, planning and operating decentralized renewable hybrid off-grid energy systems for localized (rural) applications in low-income countries. This paper presents the culmination of the IREP framework and aims to illustrate the final step of the IREP framework for two communities in Nigeria. It is focused on two aspects. Firstly, the techno-economic modeling (investment and operation optimization) of a hybrid mini-grid system using HOMER Pro, a techno-economic evaluation tool; and evaluating the benefits of demand side management (DSM) based on energy efficiency on the overall system economics using …

Peritectic Behavior Detection In The Fe-C-Mn-Al-Si Steel System Using Fiber Optic Temperature Mapping, Muhammad Roman, Damilola Balogun, Rex E. Gerald Ii, Laura Bartlett, Jie Huang, Ronald J. O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Peritectic reactions can cause surface defects and breakouts in continuous casting and the peritectic region is often avoided by adjusting the chemical composition of the steel to cast outside of the peritectic sensitivity range. However, the combined effects of C, Mn, Al, and Si on the boundaries that map peritectic region are still disputed for many advanced high strength steel grades. An apparatus for performing controlled solidification experiments is being developed to characterize the effects of chemical composition on the uniformity of shell growth during solidification using a copper chill mold with an embedded fiber-optic temperature sensor that enables high …

Interactions Between Dry Vibratable Tundish Linings And Steel Melts, Tyler M. Richards, Ronald J. O'Malley, Jeffrey D. Smith, Todd P. Sander

Materials Science and Engineering Faculty Research & Creative Works

Interactions between two tundish working linings and molten steel were investigated using industrial samples and laboratory testing. Periclase-based dry vibe linings from two production facilities were sampled and examined after casting: one containing 30 wt.% olivine and one without olivine. Cathodoluminescence imaging, secondary electron microscopy, energydispersive spectroscopy and x-ray diffraction analysis were performed to characterize the interactions. An experiment was developed to replicate the conditions found in a production tundish on the laboratory scale. Results comparing interactions observed in laboratory lining tests and commercial lining samples for the two lining materials are presented and discussed.

New Experimental Apparatus To Investigate Hot Tearing Behavior In Steel, Yanru Lu, Laura Bartlett, Ronald J. O'Malley, Semen Naumovich Lekakh, Mario F. Buchely

Materials Science and Engineering Faculty Research & Creative Works

Hot tearing is a complex thermomechanical phenomenon occurring in the semi-solid region. Strain in this region can induce cracking and localized alloying element segregation. An apparatus for investigating hot tearing was developed utilizing a servo-motor controlled cylinder to apply a pre-determined amount of strain to the solidifying shell. A special mold was developed using filling and solidification modeling to ensure that dendrite growth was perpendicular to applied strain. A computer-automated system was utilized to control the strain and strain rate and measure the force and displacement. Solidification experiments utilizing AISI 1020 steel validated the apparatus capabilities and optimized testing parameters.