Engineering Commons^™

State (Hydrodynamics) Identification In The Lower St. Johns River Using The Ensemble Kalman Filter, Hitoshi Tamura

Electronic Theses and Dissertations

This thesis presents a method, Ensemble Kalman Filter (EnKF), applied to a highresolution, shallow water equations model (DG ADCIRC-2DDI) of the Lower St. Johns River with observation data at four gauging stations. EnKF, a sequential data assimilation method for non-linear problems, is developed for tidal flow simulation for estimation of state variables, i.e., water levels and depth-integrated currents for overland unstructured finite element meshes. The shallow water equations model is combined with observation data, which provides the basis of the EnKF applications. In this thesis, EnKF is incorporated into DG ADCIRC-2DDI code to estimate the state variables. Upon its development, …

Influence Of Topographic Elevation Error On Modeled Storm Surge, Matthew Bilskie

Electronic Theses and Dissertations

The following presents a method for determining topographic elevation error for overland unstructured finite element meshes derived from bare earth LiDAR for use in a shallow water equations model. This thesis investigates the development of an optimal interpolation method to produce minimal error for a given element size. In hydrodynamic studies, it is vital to represent the floodplain as accurately as possible since terrain is a critical factor that influences water flow. An essential step in the development of a coastal inundation model is processing and resampling dense bare earth LiDAR to a DEM and ultimately to the mesh nodes; …

An Assessment Of Ecological Processes In The Apalachicola Estuarine System, Florida, Daina Smar

Electronic Theses and Dissertations

The following is a compilation of field data collected in 2011 and 2012 in Apalachicola, FL as part of a five year study assessing the ecological effects of sea level rise in the northern Gulf of Mexico. Many coastal communities, both natural and developed, will soon be working to mitigate the effects of sea level rise, if they are not already doing so. This thesis investigates the natural patterns of the Apalachicola estuarine system through the collection and analysis of in situ water, sediment, and biomass samples. Additionally, results of the field samples are presented and recommendations for additional sampling …

The Potential Of Industrial Waste And Agricultural Feedstock Towards Sustainable Biofuels Production: Techno-Economic And Environmental Impact Perspectives, Felix K. Adom

Dissertations, Master's Theses and Master's Reports - Open

This Ph.D. research is comprised of three major components; (i) Characterization study to analyze the composition of defatted corn syrup (DCS) from a dry corn mill facility (ii) Hydrolysis experiments to optimize the production of fermentable sugars and amino acid platform using DCS and (iii) Sustainability analyses. Analyses of DCS included total solids, ash content, total protein, amino acids, inorganic elements, starch, total carbohydrates, lignin, organic acids, glycerol, and presence of functional groups. Total solids content was 37.4% (± 0.4%) by weight, and the mass balance closure was 101%. Total carbohydrates [27% (± 5%) wt.] comprised of starch (5.6%), soluble …

Integrated Assessment Of Anthropogenic, Climate, And Policy Induced Changes Of Phosphorus Export In The United States Laurentian Great Lakes Watersheds, Meredith Ballard Labeau

Dissertations, Master's Theses and Master's Reports - Open

Anthropogenic activities have increased phosphorus (P) loading in tributaries to the Laurentian Great Lakes resulting in eutrophication in small bays to most notably, Lake Erie. Changes to surface water quality from P loading have resulted in billions of dollars in damage and threaten the health of the world’s largest freshwater resource. To understand the factors affecting P delivery with projected increasing urban lands and biofuels expansion, two spatially explicit models were coupled. The coupled models predict that the majority of the basin will experience a significant increase in urban area P sources while the agriculture intensity and forest sources of …

The Use Of Life-Cycle Analysis To Reduce The Environmental Impact Of Materials In Manufacturing, Megan A. Kreiger

Dissertations, Master's Theses and Master's Reports - Open

This thesis is composed of three life-cycle analysis (LCA) studies of manufacturing to determine cumulative energy demand (CED) and greenhouse gas emissions (GHG). The methods proposed could reduce the environmental impact by reducing the CED in three manufacturing processes.

First, industrial symbiosis is proposed and a LCA is performed on both conventional 1 GW-scaled hydrogenated amorphous silicon (a-Si:H)-based single junction and a-Si:H/microcrystalline-Si:H tandem cell solar PV manufacturing plants and such plants coupled to silane recycling plants. Using a recycling process that results in a silane loss of only 17 versus 85 percent, this results in a CED savings of 81,700 …

Catalytic Effects Of Period Iv Transition Metal In The Oxidation Of Biodiesel, Bradley Clark

Wayne State University Theses

CATALYTIC EFFECTS OF PERIOD IV TRANSITION METALS IN THE OXIDATION OF BIODIESEL

BRADLEY R CLARK

December 2011

Advisors: Dr. Steve Salley, Dr. Simon Ng, Dr. Naiem Henien

Major: Alternative Energy Technology

Degree: Masters of Science

Transition metals have the ability to catalyze free radical autoxidation of unsaturated fatty acid methyl esters (i.e., biodiesel). The catalytic effects of the eight period IV transition metals: V, Cr, Mn, Fe, Co Ni, Cu and Zn in soybean oil and cottonseed oil-based biodiesel are investigated. All metals produced a reduction of the induction period of biodiesel, although there are considerable differences in their catalytic …

Multi-Component Ab2 Metal Hydride Alloys For Nickel Metal Hydride Battery Applications, Jean Nei

Wayne State University Dissertations

Compared to the mish metal-based AB₅ MH alloy commonly used in Ni/MH batteries, the transition metal-based AB₂ MH alloy not only reduces the rare earth dependency, it also has higher specific energy. In order to further improve the performance of AB₂ MH alloy, it's crucial to full understand its multi-phase nature, which includes the main C14/C15 Laves phases and the secondary non-Laves phases.

In order to optimize the gaseous phase and electrochemical advantages of both the C14 and C15 Laves phases, a study was established to recognize the factors that affect the C14/C15 phase abundance. Average electron …

Timing Of Residential Electric Loads To Reduce Air Emissions From Power Generation, Michelle Marinich Rogers

Wayne State University Theses

Over the course of a day, power utilities must respond to changing demand by dispatching or shedding output from different generators. Each generator is associated with a unique profile of air emissions, based on the type of fuel consumed, installed pollution controls, and the generator's efficiency. The aim of this study is to determine whether shifting electric demand to times when cleaner generation sources are available would result in overall emissions reduction.

Dynamic wholesale pricing in the electric power market, specifically the Locational Marginal Price (LMP), provides a means to estimate the marginal generator fuel type. This knowledge was used …

Sustainable Water Management In The University Of Texas At El Paso, Cora Martinez

Open Access Theses & Dissertations

This thesis showed how to improve water and financial savings for UTEP and El Paso by improving water conservation and sustainability of the UTEP campus. The goals of this research were successfully accomplished by focusing in three principal objectives.

1. Analyze historical data of water consumption of the UTEP campus for the past decade.

2. Evaluate water consumption to quantify water consumption by buildings and type of use, as well as provide recommendations for water and cost savings.

3. Synthesize a water management framework within the UTEP Facilities' Geographic Information System (GIS) for long-term monitoring and evaluation

High Pressure Synchrotron X-Ray Diffraction Studies Of Superprotonic Transitions In Phosphate Based Solid Acids, Juan Daniel Hermosillo

Open Access Theses & Dissertations

Certain phosphate based solid acids, such as CsH2PO4 and RbH2PO4, have been shown to exhibit an abrupt, several-order-of-magnitude increase in their proton conductivity when heated above a temperature threshold. This so called superprotonic behavior allows the above-mentioned materials to function as fuel cell electrolytes at temperatures between 150C and 300C, a remarkable application that attracted significant interest especially from the automobile industry. Yet, the microscopic structures and dynamic mechanisms responsible for this behavior are not fully understood. In fact, until very recently, the very nature of the superprotonic behavior has been debate, with some groups attributing the steep proton enhancement …

Water Mass Balances For The Rio Grande/Bravo From Fort Quitman, Texas To Foster Ranch Near Langtry, Texas: An Assessment Of Factors, Ramiro Lujan

Open Access Theses & Dissertations

ABSTRACT

Water availability is declining in many regions of the planet, particularly in arid and semi-arid regions. Water bodies located in these regions, like the Rio Grande/Bravo at the U.S. - Mexico border, are subjected to high water demands. This research project makes an assessment of the spatial and temporal variability of elements intervening in the water mass balance for the section of the Rio Grande/Bravo between Fort Quitman and Langtry, Texas during the time period extending from January 1990 through December 2005. This document mentions the main Rio Grande/Bravo stakeholders from the U.S. and Mexico, and describes issues related …

Evaluation Of A Cash Award Program For Water Conservation, Robert Moss

Open Access Theses & Dissertations

This document is the final report of a water conservation study funded by the U.S. Bureau of Reclamation and The University of Texas at El Paso with cooperation from El Paso Water Utilities. The study period was from September, 1997 through January, 2000.

Investigation Of Gas-Solid Fluidized Bed With Non-Spherical Particles, Mario Alberto Ruvalcaba

Open Access Theses & Dissertations

The number of experimental and numerical studies of multiphase flows has remarkably increased over the last several years. This research has abundant applications in energy, chemical, and conversion processes. Common use of these technologies includes catalytic cracking for petroleum refineries, fluidized bed reactors (type of chemical reactor), interface modification, and has been an important technology breakthrough in coal gasification. The present work will concentrate on the investigation and validation of gas-solid flows utilizing numerical methods. The gas-solid flows study on this research assumes the solid and gas phases as continua with averaged properties.

The fluid flow computation was achieved using …

Measurement And Analysis Of Turbulent Syngas/Air And Methane Oxy-Combustion, Vishwanath Reddy Ardha

Open Access Theses & Dissertations

Development of a next generation gas turbine combustors for power production by using fossil fuels is increasing substantially in order to maintain energy sustainability. National Energy Technology Laboratory has made efforts for developing hydrogen and oxy-fuel based gas turbine combustors which could enhance plant efficiency and ensure low or zero NOx production without sacrificing operational advantages. The current experimental work aims to characterize the turbulent flow-field of premixed syngas/air flames, methane/oxy flames and syngas/oxy flames in a laboratory scaled burner by varying the Reynolds numbers, blockage ratios, firing inputs and blockage ratios in the upstream of the burner. The effects …

Hafnia-Based Nanostructured Thermal Barrier Coatings For Next Generation Gas Turbine Technology, Mohammed Noor-A-Alam

Open Access Theses & Dissertations

Extensive efforts have been directed in the last several decades towards improving thermodynamic efficiency of industrial gas turbines for power generation plants. The central theme of the efforts is to increase the turbine operating temperature and, thus, allowing higher efficiency. Thermal barrier coatings (TBC) constitute an advanced technology to protect the metallic surface from high temperature exposure for long time operation. The TBCs protect the gas turbine components from high temperature and allows further increase in engine operating temperature which subsequently increases the efficiency of the gas turbine power plant. However, the current TBC materials are capable of allowing the …

Microscopic And Spectroscopic Analysis Of Wo3 And Ti-Doped Wo3 Thin Films, Young Taek Yun

Open Access Theses & Dissertations

Tungsten oxide (WO3) has been a subject of high interest for its unique properties, and recently for its importance in different types of industrial applications which ranges from non-emissive displays, optical, microelectronic, catalytic/photocatalytic, humidity, temperature, gas, and biosensor devices. In this study, WO3 and Ti doped thin films were prepared using radio frequency magnetron reactive sputtering at different substrate temperatures ranging from room temperature to 500 ºC in increments of 100 ºC. After forming a hypothesis based on knowledge of established WO3 properties, we attempt in this work to investigate how the doping influences the roughness and the mean grain …

Low Energy Disruption Of Lipid Containing Biomass, Joaquin Rodriguez

Open Access Theses & Dissertations

Lipid containing biomass from microalgae has received recent research interest as a renewable and sustainable feedstock for biofuel production. Algae is known to offer as much as 30 times the energy density than corn based ethanol, the current world standard for biomass based liquid transportation fuels. The development of large scale systems and methods of extracting lipids from microalgae is still in the early stages of development and significant increases in efficiency and reduction in costs are necessary to substantiate algae as a feasible alternative source of fuel. Traditional conversion of algae feedstock into a refineable feedstock for biofuel can …

Modeling Annual Water Balance In The Seasonal Budyko Framework, Negin Alimohammadi

Electronic Theses and Dissertations

In this thesis, the role of soil water storage change on the annual water balance is evaluated based on observations at a large number of watersheds located in a spectrum of climate regions, and an annual water balance model is developed at the seasonal scale based on Budyko hypthesis. The annual water storage change is quantified based on water balance closure given the available data of precipitation, runoff, and evaporation estimated from remote sensing data and meteorology reanalysis. The responses of annual runoff, evaporation, and storage change to the interannual variability of precipitation and potential evaporation are then analyzed. Both …

Field And Laboratory Comparison Of The Hydraulic Performance Of Two Ceramic Pot Water Filters, Duncan Peabody

USF Tampa Graduate Theses and Dissertations

Currently 884 million people worldwide are living without access to an improved source of drinking water (WHO/UNICEF, 2011). Piped-water on premises is the ultimate goal of World Health Organization (WHO) due to the ability to treat all of the water and distribute it safely in pressurized pipes. However, Household Water Treatment and Safe Storage (HWTS) is an option for improving the quality of drinking water where that infrastructure is not yet developed, especially where there is a risk of recontamination between point of collection and point of use (Clasen, 2006).

This study analyzed one such HWTS, the ceramic pot water …

Aggregation Of Sediment And Bacteria With Mucilage From The Opuntia Ficus-Indica Cactus, Audrey Lynn Buttice

USF Tampa Graduate Theses and Dissertations

Flocculants are commonly used in industrial settings where solid-liquid separations are desired including industrial and municipal wastewater management and potable water production facilities. Conventional flocculants include inorganic metal salts and synthetic organic polymers. The cost, availability, and harmful effects of the non-biodegradable nature of these flocculants have led to the widespread study of natural flocculants. Current natural flocculants being studied include polysaccharides cultivated from microbial extracellular matrix products and plant based materials. In this study, the mucilage of Opuntia ficus-indica cactus was evaluated as a natural flocculant for sediments and bacteria. The O. ficus-indica cactus is also known as the …

Crack Analysis In Silicon Solar Cells, Maria Ines Echeverria Molina

USF Tampa Graduate Theses and Dissertations

Solar cell business has been very critical and challenging since more efficient and low costs materials are required to decrease the costs and to increase the production yield for the amount of electrical energy converted from the Sun's energy. The silicon-based solar cell has proven to be the most efficient and cost-effective photovoltaic industrial device. However, the production cost of the solar cell increases due to the presence of cracks (internal as well as external) in the silicon wafer. The cracks of the wafer are monitored while fabricating the solar cell but the present monitoring techniques are not sufficient when …

Precipitation Of Phosphate Minerals From Effluent Of Anaerobically Digested Swine Manure, Alex Y. Lin

USF Tampa Graduate Theses and Dissertations

Swine production represents approximately 40% of the world's meat production, and its wastes contain high concentrations of organic carbon, nitrogen (N), and phosphorus (P). Anaerobic digestion is an increasingly popular technology for treating animal wastes while simultaneously generating energy. Its propagation and ability to solubilize organic N and P make adding a struvite recovery process attractive. Recovering struvite (MgNH4PO4) from anaerobically digested swine waste can address global P shortages, meet P discharge guidelines, and produce slow-release fertilizer, which can be sold for revenue.

Anaerobic digesters were operated with at organic loading rates of 3.4-3.9 g volatile solids per liter per …

Design Of Colloidal Composite Catalysts For Co2 Photoreduction And For Co Oxidation, Bijith D. Mankidy

USF Tampa Graduate Theses and Dissertations

In this doctoral dissertation, novel colloidal routes were used to synthesize nanomaterials with unique features. We have studied the impact of nanoparticle size of catalyst, role of high surface area of a photocatalyst, and the effect of varying elemental composition of co-catalytic nanoparticles in combination with core-shell plasmonic nanoparticles. We have demonstrated how physical and chemical characteristics of nanomaterials with these unique features play a role in catalytic reactions, specifically the oxidation of CO and the photoreduction of CO2. The first objective of this doctoral dissertation involved the preparation of CoO nanoparticles with discrete nanoparticles sizes (1-14 nm) using a …

Assessment Of Methods To Manipulate Thermal Emission And Evaluate The Quality Of Thermal Radiation For Direct Energy Conversion, Samantha Wijewardane

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Control of spectral thermal emission from surfaces may be desirable in some energy related applications, such as nano-scale antenna energy conversion and thermophotovoltaic conversion. There are a number of methods, from commercially available paints to advanced surface gratings that can be used to modify the thermal emission from a surface. To find out the proper emission controlling technique for a given energy conversion method all the surface emission controlling methods are comprehensively reviewed regarding the emission control capabilities and the range of possible applications. Radiation with high degree of coherence can be emitted using advanced surface emission controlling techniques. …

Sustainable Riparian Restoration - The Utilization Of Sewage Effluent To Construct Wetlands Along The Rio Grande: A String Of Pearls Approach To Replenishment, Michael Earl Landis

Open Access Theses & Dissertations

The Rio Grande, from Elephant Butte Dam to El Paso, has been transformed from a free-flowing wild river into a highly engineered irrigation system. The Rio Grande Project, authorized by Congress in 1905, mandated the Bureau of Reclamation to store and deliver water exclusively to farmers. The river, maintained by the International Boundary and Water Commission, has been straightened and channelized between levees. The laws and policies governing the use of the waters of the Rio Grande are prohibitive to ecological restoration. Prior Appropriation doctrine allows for the exclusive use of these waters.

One sustainable tactic for replenishing the denuded …

Development Of The Control And Ignition Systems On A High Pressure Gas Turbine Combustor, Carlos Alejandro Valdez

Open Access Theses & Dissertations

The ignition and control systems of a laboratory scale high-pressure gas turbine combustor were developed in the present work. This work provides a detailed description of the design, development and testing of the remote control system developed for a High Pressure Gas Turbine Combustor (HPTC).

The combustor has the capability to operate at pressures up to 1.5 MPa and temperatures up to 2400 K. It is also designed for a maximum air and fuel flow rates of 81.93 g/s and 35.77 g/s respectively. The fuel used will be CH4 for the early experiments but it is designed to operate using …

Sustainable Design Of Complex Industrial And Energy Systems Under Uncertainty, Zheng Liu

Wayne State University Dissertations

Depletion of natural resources, environmental pressure, economic globalization, etc., demand seriously industrial organizations to ensure that their manufacturing be sustainable. On the other hand, the efforts of pursing sustainability also give raise to potential opportunities for improvements and collaborations among various types of industries.

Owing to inherent complexity and uncertainty, however, sustainability problems of industrial and energy systems are always very difficult to deal with, which has made industrial practice mostly experience based. For existing research efforts on the study of industrial sustainability, although systems approaches have been applied in dealing with the challenge of system complexity, most of them …

Linear And Non-Linear Deformations Of A Wind Turbine Blade Considering Warping And All Aeroelastic Load Couplings, Fouad Mohammad Mohammad

Wayne State University Dissertations

The structural dynamics behavior of the blade of a horizontal axis wind turbine that reacts to the different components of the aerodynamic loading were studied by many researchers using different approaches and assumptions. In the present research, the author considered all the extensional, torsional and flexural loadings acting on the blade with their couplings, variable airfoil cross sections with warping effects, shear deflection, rotary inertia and with or without blade's pretwist for both the linear small deformation case and the nonlinear large deformation case. To the best knowledge of the author the simultaneous inclusion of all these factors has not …

Biofuels Production From Hydrotreating Of Vegetable Oil Using Supported Noble Metals, And Transition Metal Carbide And Nitride, Huali Wang

Wayne State University Dissertations

The focus of this research is to prepare non-sulfided hydrotreating catalysts, supported noble metal and transition metal carbide/ nitride, and evaluate their hydrocracking activities and selectivities by using soybean oil as the feedstock. For comparison study, catalytic cracking of soybean oil over a commercialized ZSM-5 was investigated. However, steady state could not be reached because significant amounts of tar and coke were generated during the reaction though a high yield (21%) of jet fuel was obtained from the process. Compared to the catalytic cracking process, less tar and coke were formed during the hydrocracking process and stable continuous flow reaction …