Engineering Commons^™

Co-Disposal Of Dry Fgd By-Product With Coal Gasification Ash And Inorganic Brines, Jabulani S. Mahlaba, P.C. Pretorius, Subal Maharajh, M.P. Augustyn

Coal Combustion and Gasification Products Journal Archive

There is a growing pressure from the environmental authorities and public bodies to reduce anthropogenic pollution. Stringent environmental legislation is being implemented for industries around the world, even more so for coal consuming industries. Control of gaseous emissions is one of the areas that are receiving considerable attention towards sustainable development. Coal combustion in coal-fired power utilities emits SO~x~ to the atmosphere. Dry flue gas desulphurisation (FGD) is a well known technology often used to mitigate sulphur emissions in coal-fired power utilities. It traditionally uses lime to neutralise SO~x~, and forms a mixture of anhydrite (CaSO~4~), and calcium sulphite (CaSO~3~). …

A Multi-Analytical Approach To Understand The Chemistry Of Fe-Minerals In Feed Coals And Ashes, Marcos L.S. Oliveira, Frans Waanders, Luis F.O. Silva, Andre Jasper, Carlos H. Sampaio, Dursman Mchabe, Rachel S. Hatch, James C. Hower

Coal Combustion and Gasification Products Journal Archive

Seven feed coals used in the Brazilian power generation industry were obtained and subsequently analysed together with fly ash and bottom ash from a major Brazilian power plant. The samples were investigated by means of room temperature FeMo¨ssbauer analyses, X-ray diffraction, Raman spectroscopy, scanning electron microscope and petrographic analysis. In addition, nanometer-sized crystalline phases in coals and ashes were characterised using an energy-dispersive X-ray spectrometer and a high-resolution transmission electron microscope. The major identified Fe-bearing minerals in the coals were found to be actinolite, ankerite, chalcopyrite, chlorite, goethite, illite, ilmenite, magnesioferrite, natrojarosite, pyrite, pyrrhotite, and siderite; whilst in the fly …

The Leachability Of Major Elements At Different Stages Of Weathering In Dry Disposed Coal Fly Ash, S.A. Akinyemi, A. Akinlua, W.M. Gitari, R.O. Akinyeye, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

Large quantities of solid residue are generated by coal-fired power stations in many parts of the World. The disposal and management of the unused fly ash remains a major problem to the environment. The weathered dry disposed ash cores comprise of major element constituents such as Al, Si, Ca, Mg, Fe, Mn, Na+ and K+. The mobility patterns and mineralogical associations of major elements in weathered dry disposed ash dumps aged 1-year-old, 8-year-old and 20-year-old from a coalfired power station in South Africa were investigated using a modified sequential extraction scheme. The extraction sequence was as follows: (1) water soluble, …

Asphaltene As Light Harvesting Material In Dye Sensitized Solar Cell, Rajab Emhemed Abujnah

Open Access Theses & Dissertations

This Dissertation characterizes the first asphaltene DSSC (dye-sensitized solar cell), in which light to electricity conversion efficiency has improved from 0 % to 1.8 %. Four natural organic asphaltene factions, namely, un-fractionated asphaltene, Fr. 1 Asphaltene, Fr.2 asphaltene, Fr.3 and Fr.4 were extracted and tested for various solar cell parameters of TiO2 based dye-sensitized solar cell DSSC. DSSCs were fabricated using the four individual asphaltene dyes. The photovoltaic performance of the cells was examined by determining the various parameters such as open-circuit voltage, short-circuit current, fill factor, and series resistance. The overall energy conversion efficiency was also measured to correlate …

Feasibility Of Wastewater Reuse For Fish Production In Small Communities In A Developing World Setting, Joshua James Girard

USF Tampa Graduate Theses and Dissertations

Eradicating poverty, malnutrition, and the burden of disease have been included as three of the major issues facing the world. The United Nation member countries, having set forth the Millennium Development Goals, have committed themselves to solving these problems. Two major factors which affect solutions to these problems are increasing water stress and implementing improved sanitation. Integration of tilapia aquaculture and reuse of wastewater has been suggested as a solution which addresses both of these factors. The objective of this study is to examine the feasibility, and explore the benefits and drawbacks, to implementing small community wastewater fed (WWF) aquaculture …

Embodied Energy Assessment Of Rainwater Harvesting Systems In Primary School Settings On La Peninsula Valiente, Comarca Ngobe Bugle, Republic Of Panama, Kaitlin Elinor Green

USF Tampa Graduate Theses and Dissertations

The United Nations Millennium Development goals aim to make improvements in access to potable water. In the Bocas del Toro region of Panama, rainwater harvesting systems are making that goal more attainable. Rainwater harvesting, especially in rural, difficult access areas, may be a viable water source improvement that will allow a greater population to access improved water. This study uses the Carnegie Mellon University Economic Input-output Life Cycle Assessment tool to assess the embodied energy of plastic and ferrocement rainwater harvesting systems in rural Panama. Rainwater harvesting systems are assessed as source improvement technologies that increase access to potable water. …

Effects Of Solids Loadings And Particle Size Distribution On Siphon Ceramic Candle Filters, Danielle Renzi

USF Tampa Graduate Theses and Dissertations

In the rural areas of Madagascar only 29% of the population has access to clean water and 10% has access to improved sanitation. It has been estimated that environmental risk factors, such as inadequate access to clean drinking water and proper sanitation, are responsible for 94% of the diarrheal disease burden. This study was focused on testing a point-of-use technology called the Tulip filter, which is a siphon ceramic candle filter impregnated with silver. The purpose is to assess its feasibility for implementation in rural regions of Madagascar through a laboratory study performed at the University of South Florida.

The …

Design Of Small Scale Anaerobic Digesters For Application In Rural Developing Countries, Laurel Erika Rowse

USF Tampa Graduate Theses and Dissertations

The high incidence of upper respiratory diseases, contamination of waterways due to pathogens and nutrients from human and animal wastes, unsustainable deforestation, gender disparities in burden of disease due to unequal exposure to indoor air pollutants, and carbon black emissions from the burning of solid fuels are interrelated problems in many developing countries. Small scale anaerobic digestion provides a means of alleviating these problems by treating livestock waste onsite to produce biogas (methane and carbon dioxide) in rural areas in developing countries. Fuel can then be used for cooking, lighting, and heating. Methane fuel is an alternative to traditional three-stone …

Determining The Global Maximum Biofuel Production Potential Without Conflicting With Food And Feed Consumption, Watcharapol Pumkaew

All Theses

This study tries to resolve the competition between food and biofuel by balancing the allocation between food and feed areas and biofuel areas for the entire world. The maximum energy production is calculated by determining the theoretical amount of energy that can be grown, once food and feed consumption is taken into account, based on the assumption that unprotected grass and woody lands and forest lands can be converted into cultivated lands. The total optimum land area for biofuel energy, 4,926.49 Mha, consists of corn, rapeseed, sugar beet, sugar cane, and grasses. When considering energy conversion efficiency, the maximum energy …

Assessment Of Impacts To Hydroclimatology And River Operations Due To Climate Change Over The Colorado River Basin, William Paul Miller

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation investigated the impacts of climate change to the hydroclimatology and river and reservoir management operations within the Colorado River Basin. Preliminary research indicated observed warming trends throughout the Colorado River Basin and corresponding seasonal trends to the magnitude and timing of runoff in the Colorado River Basin. Subsequent research investigated the changing character of precipitation and corresponding impacts to streamflow over the Colorado River Basin. Analysis of snowpack telemetry (SNOTEL) stations over the American West and Colorado River Basin indicated decreasing trends in annual snowpack, often at least at the 95% confidence interval. A shorter snowpack season was …

Mineralogy And Leaching Characteristics Of Coal Ash From A Major Brazilian Power Plant, Luis F.O. Silva, Colin R. Ward, James C. Hower, Maria Izquierdo, Frans Waanders, Marcos L.S. Oliveira, Zhongsheng Li, Rachel S. Hatch, Xavier Querol

Coal Combustion and Gasification Products Journal Archive

The feed coals, fly ashes and bottom ashes collected from seven different units in a major Brazilian PF power plant have been subjected to comprehensive mineralogical, geochemical, and petrographic studies, to investigate the links between feed coal and ash characteristics. Ashes from two of the units were collected while the coal was being co-fired with oil as part of the boiler start-up procedure, allowing the impact of oil co-firing on ash characteristics also to be evaluated. High proportions of unburnt carbon and high proportions of retained sulphur were found in the fly ashes produced during oil co-firing, probably reflecting less …

Comparison Of Traditional Standard Drainfield With Innovative B&G Treatment Bed For Nutrient Removal From Septic Tank Wastewater, Fahim Hossain

Electronic Theses and Dissertations

Nowadays people are more alert about conservation of water and water scarcity. The amount of usable water is decreasing due to unavailability of pure water for day to day use. Both surface and groundwater is contaminated by untreated wastewater discharged from improper onsite wastewater treatment system, nutrient laden agricultural runoff and increasing use of fertilizer in fields. This elevated nutrient level is increasing the maintenance and operation cost of water treatment plant. So it is an important task to remove those nutrients from wastewater and other water bodies by applying environmental friendly process. In the USA, about 25% homes are …

Water Resources, Health, And The Sustainability Of Interventions To Achieve Water And Sanitation Targets Of The Millennium Development Goals In A Changing World, Lauren M. Fry

Dissertations, Master's Theses and Master's Reports - Open

This dissertation addresses sustainability of rapid provision of safe water and sanitation required to meet the Millennium Development Goals. Review of health-related literature and global statistics demonstrates engineers' role in achieving the MDGs. This review is followed by analyses relating to social, environmental, and health aspects of meeting MDG targets.

Analysis of national indicators showed that inadequate investment, poor or nonexistent policies and governance are challenges to global sanitation coverage in addition to lack of financial resources and gender disparity. Although water availability was not found to be a challenge globally, geospatial analysis demonstrated that water availability is a potentially …

The Very Basics Of Sustainability - An Alternative Viewpoint (Slides With Audio) (Large File! To Speed Up Download, Right-Click On "Download" Link To Save To Own Pc.), Jim Mcgovern

Other resources

This presentation sets out the very basics of ‘sustainability’, although a definition of sustainability is not attempted. Some of the very basics are the context in which the Earth and humankind exist in space and time, the Earth’s climate, the Earth’s population and humankind’s options and choices. The author advocates keeping an open mind on all available options, including the use of oil, gas, coal, tar sands, carbon capture and sequestration, nuclear power etc., as well as the technologies that are more widely considered ‘green’. The author also argues that, in addressing the challenges that humankind faces, globally concerted effort …

Simultaneous Nitrification And Denitrification Of Wastewater Using A Silicone Membrane Aerated Bioreactor, Kirk Hjelte Waltz

Master's Theses

The purpose of this thesis is to investigate the use of a single reactor to biologically treat wastewater by simultaneously oxidizing ammonia, and reducing nitrate and nitrite. The Environmental Protection Agency (EPA) places strict discharge restrictions on these compounds due to their inherent toxicity to humans, wildlife, and ecosystems. The use of a simultaneous system can assist the conventional wastewater treatment technology that requires separate systems, by creating a system that needs less time and smaller size to reach effluent requirements. To conduct this research, a bench-scale membrane aerated biofilm reactor was built using silicone tubing for aeration. Batch and …

Using Oceanic-Atmospheric Oscillations For Long Lead Time Streamflow Forecasting, Ajay Kalra, Sajjad Ahmad

Civil and Environmental Engineering and Construction Faculty Research

We present a data-driven model, Support Vector Machine (SVM), for long lead time streamflow forecasting using oceanic-atmospheric oscillations. The SVM is based on statistical learning theory that uses a hypothesis space of linear functions based on Kernel approach and has been used to predict a quantity forward in time on the basis of training from past data. The strength of SVM lies in minimizing the empirical classification error and maximizing the geometric margin by solving inverse problem. The SVM model is applied to three gages, i.e., Cisco, Green River, and Lees Ferry in the Upper Colorado River Basin in the …

Nutrient And Pathogen Removal In A Subsurface Upflow Wetland System Using Green Sorption Media, Zhemin Xuan

Electronic Theses and Dissertations

Due to environmental health and nutrient impact concerns, the conventional on-site sewage collection, treatment, and disposal systems are no longer able to meet the nutrient reduction requirements for wastewater effluent and may represent a large fraction of pollutant loads. The loads include not only nitrogen (N) and phosphorus (P), but also pathogens such as fecal coliform and E. coli which indicate the presence of other disease-causing bacteria flowing into aquatic system that adversely affect public health. A subsurface upflow wetland, which is an effective small-scale wastewater treatment system with low energy and maintenance requirements and operational costs, fits the current …

Development Of Measurement And Modeling Techniques To Quantify Atmospheric Deposition Of Persistent, Bioaccumulative And Toxic Chemicals In The Great Lakes, Mark D. Rowe

Dissertations, Master's Theses and Master's Reports - Open

Measurement and modeling techniques were developed to improve over-water gaseous air-water exchange measurements for persistent bioaccumulative and toxic chemicals (PBTs). Analytical methods were applied to atmospheric measurements of hexachlorobenzene (HCB), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs). Additionally, the sampling and analytical methods are well suited to study semivolatile organic compounds (SOCs) in air with applications related to secondary organic aerosol formation, urban, and indoor air quality.

A novel gas-phase cleanup method is described for use with thermal desorption methods for analysis of atmospheric SOCs using multicapillary denuders. The cleanup selectively removed hydrogen-bonding chemicals from samples, including much of …

Sustainable Development Extension Plan (Sudex): Community Mobilization Through Proactive Participation And Synergistic Alliance To Alliviate Poverty And Achieve Sustainable Self Sufficiency, Stephen Forbes

Open Access Theses & Dissertations

This Dissertation describes a sustainable development extension plan (Sudex Plan) to help communities in developing countries achieve Goal 1 of the United Nation's Millennium Development Goals (MDG). Goal 1 focuses on reducing poverty and hunger by 50% by the year 2015, but all the MDG are interrelated and one can not be achieved without considering the others, and to attain any is an empty accomplishment without ways to ensure that they can be sustained and continuously improved with the means to pass on the information, knowledge and lessons learned from community to community, generation to generation. The Sudex Plan is …

Bioflocculation For Control Of Wastewater Pond Microalgae, Daniel Thomas Frost

Master's Theses

Investigates several hypotheses regarding the use of bioflocculation as a harvesting method for wastewater pond microalgae. Research performed on pilot-scale high rate ponds (HRPs) on the California Central Coast.

Rank-Data Distribution Method (R-D Method) For Daily Time-Series Bayesian Networks And Total Maximum Daily Load Estimation, Joon-Hee Lee

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Daily time series-based models are required to estimate the higher frequency fluctuations of nutrient loads and concentrations. Some mechanistic mathematical models can provide daily time series outputs of nutrient concentrations but it is difficult to incorporate non-numerical data, such as management scenarios, to mechanistic mathematical models. Bayesian networks (BNs) were designed to accept and process inputs of varied types of both numerical and non-numerical inputs.

A Rank-Data distribution method (R-D method) was developed to provide large time series of daily predicted flows and Total Phosphorus (TP) loads to BNs driving daily time series estimates of T-P concentrations into Hyrum and …

2008 Fall Engr333 Project Assignment, Matthew K. Heun

ENGR 333

The Fall 2008 semester ENGR333 project assessed the feasibility of a Green Revolving Fund for Calvin College. I asked the students “What would it take to implement a Calvin Energy Efficiency Fund (CEEF)?”

The project emerged from the work of the previous year’s students who uncovered the concept of green revolving funds.

Immediately after the Fall 2008 semester, I went on sabbatical to South Africa for all of 2009. While I was away, the Calvin administration established the Calvin Energy Recovery Fund (CERF). Over the next decade, CERF saved hundreds of thousands of dollars in energy costs and was …

Massive Spatiotemporal Watershed Hydrological Storm Event Response Model (Mhserm) With Time-Lapsed Nexrad Radar Feed, Changqing Song

Civil & Environmental Engineering Theses & Dissertations

Correctly and efficiently estimating hydrological responses corresponding to a specific storm event at the streams in a watershed is the main goal of any sound water resource management strategy. Methods for calculating a stream flow hydrograph at the selected streams typically require a great deal of spatial and temporal watershed data such as geomorphological data, soil survey, landcover, precipitation data, and stream network information to name a few. However, extracting and preprocessing such data for estimation and analysis is a hugely time-consuming task, especially for a watershed with hundreds of streams and lakes and complicated landcover and soil characteristics. To …

Nyumba Ya Mungu Reservoir System Simulation By Using Hec-Ressim Model, Deogratias Mulungu

Tanzania Journal of Engineering and Technology (TJET)

This research paper focused on estimating effective water and optimization of the NyM reservoir for storage conservation and hydropower generation. Several models were used in the study: the Rainfall-Runoff model, GFFS was used to fill in missing data, and the HEC-ResSim Model and the NWBM for reservoir system simulation and water balance respectively. The effective inflows to the NyM reservoir were determined using HEC-ResSim model and the NWBM used to check the total water loss in the system. For the reservoir system simulation, the HEC-ResSim model was used to estimate water loss through irrigation abstractions in Kikuletwa and Ruvu reaches …

Relationships Between Pacific And Atlantic Ocean Sea Surface Temperatures And U.S. Streamflow Variability, Glenn A. Tootle, Thomas C. Piechota

Civil and Environmental Engineering and Construction Faculty Research

An evaluation of Pacific and Atlantic Ocean sea surface temperatures (SSTs) and continental U.S. streamflow was performed to identify coupled regions of SST and continental U.S. streamflow variability. Both SSTs and streamflow displayed temporal variability when applying the singular value decomposition (SVD) statistical method. Initially, an extended temporal evaluation was performed using the entire period of record (i.e., all years from 1951 to 2002). This was followed by an interdecadal-temporal evaluation for the Pacific (Atlantic) Ocean based on the phase of the Pacific Decadal Oscillation (PDO) (Atlantic Multidecadal Oscillation (AMO)). Finally, an extended temporal evaluation was performed using detrended SST …

Evaluation Of Prefermentation As A Unit Process Upon Biological Nutrient Removal Including Biokinetic And Wastewater Parameters, Terrence Mccue

Electronic Theses and Dissertations

The objective of this dissertation was to provide a controlled comparison of identical continuous flow BNR processes both with and without prefermentation in order to provide a stronger, more quantitative, technical basis for design engineers to evaluate the potential benefits of prefermentation to EBPR in treating domestic wastewater. In addition, the even less understood effect of prefermentation on denitrification kinetics and anoxic phosphorus (P) uptake was studied and quantified. Other aspects of BNR performance, which might change due to use of prefermentation, will also be addressed, including anaerobic stabilization. Potential benefits to BNR processes derived from prefermentation are compared and …

Stormwater Irrigation Of Saint Augustine Grass: Nitrogen Balance And Evapotranspiration, Ewoud Hulstein

Electronic Theses and Dissertations

A change in surface condition of a watershed, which is usually caused by development, can have measured effects on the naturally occurring hydrologic cycle and nitrogen cycle. This could result in environmental problems, such as reduced springflow and eutrophication. In an effort to address these issues, a combination of best management practices (BMPs) can be adhered to. The practice of using excess stormwater as a source for irrigation is proposed as a BMP for the minimization of impacts by development to the hydrologic and nitrogen cycles. To study the proposed BMP, a field experiment was installed in an outdoor location …

Guiding Growth: A Survey Of Tax Incentives, New England Environmental Finance Center, Muskie School Of Public Service

Legislation

Current development patterns and increased tax pressures in local municipalities combine to harm both Maine’s natural resources and its quality of life. Previous initiatives such as the implementation of zoning laws did not fully result in the desired outcomes. Zoning laws were often too flexible and often did not resist market and political pressures to change zoning regulations to allow development with possible economic growth. A sound taxation system or fee structure may be the solution to slow down development in natural areas and direct it towards areas appropriate for growth.

To protect Maine’s natural resources more successfully from future …

Selected Chemoautotrophic Processes In Wastewater Treatment: Low Temperature Nitrification Inhibition By An Azo Dye And Biofiltration For Odor Control Of Hydrogen Sulfide, Ronald W. Martin Jr.

Dissertations, Master's Theses and Master's Reports - Open

Biochemical processes by chemoautotrophs such as nitrifiers and sulfide and iron oxidizers are used extensively in wastewater treatment. The research described in this dissertation involved the study of two selected biological processes utilized in wastewater treatment mediated by chemoautotrophic bacteria: nitrification (biological removal of ammonia and nitrogen) and hydrogen sulfide (H2S) removal from odorous air using biofiltration.

A municipal wastewater treatment plant (WWTP) receiving industrial dyeing discharge containing the azo dye, acid black 1 (AB1) failed to meet discharge limits, especially during the winter. Dyeing discharge mixed with domestic sewage was fed to sequencing batch reactors at 22oC and 7oC. …

Development And Application Of A Computer Simulation Tool For Ecological Risk Assessments, Haiyi Lu

Theses

In an effort to improve tools in ecological risk assessment (ERA), an ERA software tool was developed and applied. Based on a preliminary evaluation of existing ecorisk models, the relative deficiencies were identified and included the need for a user-friendly interface, an interactive database management system (DBMS), and a comprehensive evaluation of exposure pathways. In this research, Visual Basic (VB) 6.0 and Microsoft SQL server were selected for developing the Windows-based interface and local DBMS, respectively. For the exposure estimate, Yuma and Aberdeen Proving Grounds were identified as baseline ecosystems. Terrestrial and aquatic plant and animal receptor selection was based …